Search Documents

By M. G. Rylatt, G. M. Popplewell

"Production from Canada's first diamond mine is planned for the last quarter of 1998. The climatic conditions and the variation in kimberlite types to be treated have lead to the development of a compact and flexible processing plant.High kimberlite moisture contents and winter temperatures below -40°C have dictated a process flowsheet with limited in-circuit storage to reduce materials handling difficulties. The latest developments in High Pressure Grinding Roll technology will be used to liberate the valuable diamond, reduce diamond breakage, and increase fines production to reduce the amount of material for down stream processing in the Heavy Medium Separation section.A varying heavy mineral concentrate yield has lead to the development of a final Recovery section that will incorporate Attrition Milling and Wet High Intensity Magnetic Separation for concentrate reduction. The latest developments in diamond X-ray sorting will be used to produce a final diamond concentrate for mechanical sizing, weighing and packing.Fine tailings thickening will utilise Deep Bed Compression type thickeners. This relatively new technology can produce;i) high underflow densities at low flocculant dosage rates, andii) clear overflowswith a smaller thickening area than conventional high-rate thickeners."

Jan 1, 1998

The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016

By Jaana Romppanen, Satu Jyrkönen, Tiina Ranki, Peter Björklund, Markku Lahtinen, Kaj Eklund, Päivi Suikkanen

Outotec is continuously developing our existing process equipment and new equipment solutions to enhance the Flash Smelting process. Thanks to the long operating history of the Outotec Flash Smelting process feedback from the numerous operating references are available and is utilized. The general goals for development work are to improve equipment performance, thus realizing savings in Smelter plant operation costs by increasing the process efficiency and online availability. Digitalization also opens new possibilities for the feeding equipment and furnace operation monitoring. These solutions will improve the safety and performance of the smelter, and provide process and equipment related information which has not been available earlier. INTRODUCTION The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. The Flash Smelting technology, is now owned and developed by Outotec Oyj and the first plant, is now owned by Boliden Harjavalta Oy. The two companies have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a hot theme/topic during the first days of Flash Smelting, it has nevertheless been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. Along with the process technology development, also development of the equipment has taken place over time. Outotec is continuously working on developing our equipment to better suit the changing need of our customers in the continuously changing operational environment. Orebodies are getting more challenging with lower ore grades and more impurities. Achieving high recoveries for all valuable elements becomes more difficult with high slag quantities and with the need to tackle the high impurity concentrations. There is a need for higher capacities in greenfield and brownfield smelters. The role of the Loss-in-Weight Feeder, the Air Slide and Concentrate Burner is to ensure even feed into the reaction shaft of the Flash Smelting Furnace, and to enable controlling the process well, thereby enabling the best performance for the customers smelter. The design of the Flash Smelting Furnace aims for high availability, long campaign and safe operation.

Jan 1, 2019

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013

By D. Saramak, Z. Naziemiec

"Chalcedonite is an unique rock due to the relatively small area of its occurrence. It also possesses multi-raw-material features therefore it should be given a special protection aiming at its complete and optimal utilization. It is the natural sedimentary rock and the only mine in Poland, located in Inowlodz, where the opencast mining from “Teofilow” deposit is carried out.Chalcedonite mainly consists of cryptocrystalline and microcrystalline chalcedony together with small amounts of autogenous and detrital quartz. The chalcedony itself is a fairy common mineral and many forms of its occurrence is known, some of them are semi-precious minerals. Among the most popular ones following can be found: agate, bloodstone, onyx, carnelian, chrysoprase. Many countries own chalcedony deposits: Australia, Brazil, India, Canada, Namibia Russia, South Africa. However chalcedony in its pure form does not occur in the mentioned chalcedonite rock. The pores, which take usually from 5% to 25% of volume and have sizes smaller than 0.5 mm, are the characteristic feature of all chalcedonite forms. The paper presents some crucial problems of its processing together with most significant directions of its applications. New method of chalcedonite enrichment based on densimetric separation (patented in Poland) is presented. Results of investigation show that the obtained products can increase quality of concrete and filter grits."

Jan 1, 2016

By J. C. Kurnia

Methane is recognized as one of the prime causes of underground mine disasters around the globe. A cost-effective mine ventilation system and methane control is required to ensure a safe and productive environment in an underground mine whilst keeping energy usage and operating cost at minimum. Typically methane enters a mine environment or tunnel from localized distributed sources at high initial concentration. Hence, an understanding of its dispersion from discrete sources is important to design a methane management system via effective ventilation. This study employs computational fluid dynamics to model methane dispersion in an underground tunnel which has a number of discrete sources of methane and effective ways to dilute and or disperse it. Air flow distribution within the tunnel as well as methane dispersion is simulated by solving the governing transport equations subject to appropriate boundary conditions. First, the effectiveness of ventilation duct placement is examined. Several possibilities are explored and investigated. It is found that the common configuration utilized in underground mine performs best as compared to other configurations in maintaining the concentration of methane below permissible levels. Next, a novel intermittent airflow ventilation system is proposed and evaluated via simulation with the goal of reducing the energy cost whilst maintaining methane level in the mining face below the allowable level. Parametric studies are conducted to investigate effects of various factors influencing the effectiveness and performance of this novel intermittent ventilation system. This study will provide some new ideas for designing an efficient and effective underground mine ventilation system by lowering the net average amount of air that needs to be circulated in the tunnel for a safe operation. KEYWORDS

Aug 1, 2013

By S. Sillitoe

In mining, as in other business and engineering enterprises, efficient operation depends upon how well and how quickly the lines of communication can function. Mines have used the telephone on and between levels for many years, but in the hoisting shaft maintenance of physical wire connections for communication with the moving cage or skip has been found, for all practical purposes, impossible. A most natural solution was, therefore, the code-bell or buzzer signal system between fixed levels, and this has been standard practice throughout the mining world for many years. However, this system has serious limitations which make it impossible to signal a cage between levels in the shaft, and it requires crude, hazardous or costly methods for signalling during daily shaft inspection. Radio signalling overcomes these difficulties, because the communication medium is never broken and the cage-tender or shaft inspector can safely signal to, and receive signals from, the hoistman at any time from any position in the shaft, whether stationary or in motion. In addition to both audible and visual code signalling, two-way telephone communication and slack cable alarm are facilities made possible in recent commercially developed equipment.

Jan 1, 1949

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015

By Masaharu Moteki

At present, the Unmanned Construction System (UCS) is adapted on initial operation against the disaster. For instance, it has been used in Unzen. When the scale of the disaster is big, or the danger to a person is big, the UCS is expected as a quick and safe construction technology. The Remote Controlled UCS is introduced into construction site to repair earth-fill embankment or to remove rock, as urgent measures after the disaster outbreak. For improvement of the operability, shortening of the skill time, reduction of the fatigue, examination of the most suitable system (placement of a monitor and the joy stick) of the remote system is a main theme in the Public Works Research Institute (PWRI). In the report of this year, when the operator controls construction machine directly or he controls it using remote system (he can check the situation of site only via monitor), the degree of achievement, construction efficiency and construction precision were inspected. The remote system which is based on the system used at Unzen was developed at PWRI.

Aug 1, 2013

By T. Crivits, I. Bellemans, K. Verbeken

In the metallurgical industry, furnace cooling is often employed to enhance furnace lifetime. Hence, the pyrometallurgical phase comes in close contact with a non-air coolant. The proximity of the pyrometallurgical phases to the coolants may lead to dangerous situations. In case of a breach of the cooling circuit, the contact between a hot and a cold liquid may cause a vapour explosion. The outcome of this vapour explosion includes a pressure wave which could result in damage to the furnace, bodily injuries or even casualties. To prevent such dramatic events, the origin of vapour explosions is currently being studied in more detail. For this purpose, OpenFOAM was used to perform Computational Fluid Dynamics (CFD) simulations. In a first step, simulations were run to get a better idea of the influence of the compressibility on the simulations. The obtained results help in getting a better insight on the need of computational power, and possible numerical errors using compressible or incompressible solvers in future simulations. In a second step, systems without vapour explosions were simulated and compared to experimental results with mercury and aluminum. INTRODUCTION Humanity started using metals for tools around the Chalcolitic (~7400 cal BC), when copper was melted in small furnaces (Radivojevic, Rehren, Farid, Pernicka, & Camurcouglu, 2017). Nowadays, metallurgy has grown into a major industry and it has become impossible to imagine society without metals. In the pyrometallurgical industry, coolants (low temperature liquids, for example water) and pyrometallurgical phases (high temperature liquids, such as slags, mattes and alloys) are typically present in close proximity of each other. The interaction between these two phases can have catastrophic consequences (Tveit et al., 2008; Ferguson & Zsamboky, 2017). A vapour explosion may occur as the consequence of the rapid evaporation and expansion of the coolant. Whereas the volume of a gas increases linearly with the temperature (approximately a factor four by heating from 100°C to 1300°C), a simple calculation of the ratio of the two specific volumes shows that evaporation causes the volume of water to increase by a factor of 1700 at 100°C and ambient pressure (Table 1 and equation (1)), a number that was also found in literature (George, Nexhip, George-Kennedy, Foster, & Walton, 2006). The volume change occurs so fast that it resembles an explosion, hence the name vapour explosion. Such an explosion at industrial scale can cause economical losses, bodily injuries or even fatalities.

Jan 1, 2019

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

By K. Woo

"With ever-increasing global demand for mineral resources, mining companies are considering developing deeper, more complex and lower grade ore bodies. Recent years have seen the transition from surface to underground mass mining operations to access deeper resources, with mass mining methods such as block and panel caving being favoured due to the tonnages and economics achievable when dealing with lower grade ore. However, the rock engineering interactions involved with such plans are complex and challenging given the significant disturbance caused to the surface environment. If not properly accounted for, the unexpected propagation of a cave breaking through to surface or the differential surface displacements otherwise produced may threaten the safety and integrity of overlying mine and civil infrastructure.This paper reports the findings of a comprehensive research programme focussed on investigating and integrating new developments in remote sensing characterization and monitoring technologies with state-of-the-art numerical modelling to better manage the challenges and geo-risk associated with the transitioning from open pit to underground mass mining. Procedures were developed to integrate discrete fracture networks (DFN) into finite-element/discrete-element analyses to simulate the influence of rock mass fabric on cave propagation and the evolution of caving-induced surface subsidence and step-path failure of large open pit slopes through the progressive failure of rock bridges. The results clearly showed that caving-induced surface deformations tend to be discontinuous and asymmetric due to large movements around the cave controlled by geologic structures, rock mass heterogeneity and topographic effects. Although parallel investigations of empirical design charts used to predict caving-induced deformations were found to be moderately sufficient for assessing the extent of macro deformations directly above the undercut (i.e. caving collapse features), numerical modelling was found to provide the only means to confidently estimate the lateral extent of smaller strain subsidence.These results were further supported by the use of high-resolution synthetic aperture radar (SAR) data to monitor the ground deformations associated with block caving production, and to use these to calibrate and constrain a series of predictive 3-D numerical models focussed on Rio Tinto's Palabora mine in South Africa. The InSAR data was obtained from Canada’s recently launched RADARSAT-2. The close fit achieved between the predictive 3-D numerical model and InSAR monitoring data demonstrates the significant value of InSAR calibrated 3-D numerical models applied to subsidence prediction.Collectively, the results from this research programme have helped to further the characterization, assessment and understanding of mass mining-induced subsidence, and its evolution, by addressing existing limitations in the use of empirical and numerical design methods. The limitations and uncertainty arising from mine site data were detailed, specifically the representation of mine geology, rock mass properties, in-situ stresses and cave propagation, together with means to constrain these inputs and calibrate sophisticated 3-D numerical models through back analysis and integration with high resolution monitoring data."

Jan 1, 2015

By John F. Vynne

This paper will discuss several of the systems and processes that have been developed over the past few years, and are now being utilized by major mining companies on draglines in North America, Australia and South Africa. These technologies include production monitors and reporting systems, GPS navigation systems, structural integrity monitoring systems, structural analysis studies to increase the dragline RSLs, and inspection and response strategies. The use of these technologies provides significant increases in dragline production, and reduces maintenance costs and downtime. The question that needs to be asked is what value is there in monitoring? Increasing dragline productivity is dependent upon to two items with the overall goal being to maximize the number of bank cubic meters moved and to uncover more coal: 1) maximizing payload and 2) maximizing the number of cycles. If you do not measure and try to optimize the parameters that impact payload and number of cycles, there is very little chance that you can improve overall dragline productivity. These parameters are: Maximizing payload is dependent upon the following: ? Geology ? Blasting ? Monitor weighing accuracy ? Engage location ? Disengage Location ? Rigging ? Suspended load ? Bucket characteristics ? Operator skills ? Minimizing rehandle Maximizing the number of cycles depends upon maximizing digging time, and minimizing cycle and delay/down times by: ? Minimizing Operational Delays ? Minimizing Mechanical Delays ? Minimizing Idle time ? Minimizing Walking time ? Minimizing Fill Time ? Minimizing Swing Angle ? Maximizing Swing & Return Rates ? Minimizing Spot Time A third reason to monitor, conduct structural analysis studies, and have inspection strategies is to prevent catastrophic failures such as shown in the following photographs (figures 1 & 2).

May 1, 2008

By Bill Dupley

We believe that the inability of employees to effectively manage information has reached an epidemic problem throughout the corporate world. ? All the available knowledge in the world is accelerating at a phenomenal rate. ? The whole world's codified knowledge base (all historical information in library books and electronic files) doubled every 30 years in the early 20th century. ? By the 1970s, the world's knowledge base doubled every seven years. ? Information researchers predict that by the year 2010, all the world's codified knowledge will double every 11 hours.

May 1, 2003

By Doug Ashbury

Diamond Miners? Challenges ? Remote ? 300 kilometres from Yellowknife ? Sub-Arctic conditions ? permafrost, climate ? No power ? No all-weather roads ? Ore bodies difficult to find ? Caribou, fish of special concern ? Communities with low education, little experience, but high expectations ? Major investment required ? Diavik C$1.3 billion

Apr 1, 2005

By Mei-Yan Yang, Ltd. Yunnan Yuntong Zinc Co., Yong-Xiang Li, Xing-Zheng Dai, Hong-Liang Wang, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"The removal of iron asgoethite from the high iron bearing solutions generated in zinc hydrometallurgy using a strong airflow device was investigated. The influence of oxygen flow, copper ion concentration, temperature and reaction time on iron precipitation as goethite was studied. The optimum conditions were: oxygen flow 0.2-0.35m3/h, copper ion concentration 0.25-0.5g/L, temperature 80-90oC, zinc oxide powder neutralizing agent and a reaction time of5to 7hours. Under the optimal conditions, the Fe2+concentration was reduced to 0.025g/L after iron precipitation, and the goethite residue contained 38.7wt.%Fe. The SEM and XRD analyses showed that the iron was present as well formed FeOOH crystals in the iron residue, and the amount of iron sulphate was very low. Production practice shows that, when the average iron concentration in the feed solution was 11.61g/L and 4.08g/L after precipitation, the weight of iron removed was 1,439kg/day. When the average iron concentration in the feed solution was 14.51g/L and 2.73g/L after precipitation, the weight of iron removed was 2,454kg/day. This represents a ~70 percent increase in iron removal.INTRODUCTIONThe objective of iron removal is to produce a small volume of iron residue, and our industrial goethite process meets this requirement. The high Fe(II) solution in our reactor isoxidized/hydrolyzed to precipitate goethite and the precipitate is sent to a pyro metallurgical furnace for final residue treatment. Some literature discusses (DengYong-guiet al., 2008;Meiguang-guiet al., 2001;Zhongzhu-qianet al., 1980) research on iron hydrolysis; one of the reported rate limiting parameters was the low availability of the oxidant when using air and another was the inhomogeneous air distribution. There are two iron hydrolysis-goethite precipitation methods; the Electrolytic Zinc process (EZ) and the Vieille Montagne process (VM) (Lei Xiang, 2006; Xuguo-qiang, 2007;ZhaoYonget al.,2005). The EZ method hydrolyzes the Fe3+directly to FeOOH. The weakness of the EZ process is the low recovery rate of the associated minor metals. The VM method reduces the iron to the ferrous state and then oxidizes the Fe(II)to Fe(III),with simultaneous hydrolysis/precipitation of the Fe(III) as FeOOH. Before iron hydrolysis, the minor metals, such as indium, could be selectively precipitated, because Fe(II)requires a high pH for hydrolysis. So the VM method has a high recovery rate for the minor metals. There levant goethite precipitation reaction is:"

Jan 1, 2016

By E. M. De Souza, P. Lausch, D. O. DeGagné, J. F. Archibald

"The potential use of industrial and municipal waste glass as a partial pozzolanic replacement for Normal Portland cement in mine backfill has been investigated. Considerable quantities of glass are currently discarded into landfill sites at high cost to municipal and industrial users with no foreseeable environmental benefits being gained by such disposal. This research study was undertaken to assess the viability of using ground waste glass materials as partial binder replacement of Portland cement fractionswithin consolidated mine backfill materials. The program was implemented to review various factors that could influence successful incorporation of glass waste replacement of cement, these factors being the feasibility of glass waste procurement, determination of process economics and the physical and chemical suitability of ground waste glass materials to generate adequate backfill strength when replacing Normal Portland cement fractions. A series of laboratory assessment trials were established to evaluate backfill component characteristics and mixture strength properties for both standard Portland cement-consolidated and blended Portland cement/ground waste glass-consolidated backfill materials. Side-by-side review of the strength behaviour of various component backfill/cement mixtures was designed to permit comparative evaluation of the capabilities of ground waste glass and Portland cement products as backfill consolidating agents"

Jan 1, 1995

By M. Kuyumcu

With annual production of almost 3.5 million metric tonnes of K20, former East Germany (GDR) was the world?s third-largest producer of potash, ranking behind only the Soviet Union and Canada. More than 80 % of production was intended for export to earn urgently needed hard currency. For this reason, beginning in the 1970s, East Germany began to mine unprofitable hard-salt sources and carnallitite fields, which are geomechanically problematic. In the course of restructuring from a centrally planned to a market economy after German reunification, only two of the nine existing potash mines were classified as economically viable for privatization. All six potash mines in the South Harz Region were closed between 1991 and 1993. The orderly safekeeping of these potash and other decommissioned ore mines and the rededication of mining areas were assigned in 1992 to a German state-owned company GVV founded especially for this purpose. Elaboration in the present documentation covers the local necessity of the type and extent of filling and safeguarding measures. As a result of the remedial measures taken, it was possible to prevent the collapse of cavities and damage to surface facilities. This documentation describes the safeguarding successes to date, with appreciable reduction and stabilization of surface settlement and with significant lessening of seismic events. Also presented are concepts updated to the state of the art for safeguarding of numerous potash mining shafts for long-term effectiveness in separation of the workings and watercourse levels in the cap rock. In the course of 100 years of production, six mining dumps resulted with a total volume of approximately 170 million m3. They consist of up to 95 % of water-soluble salts. Every year, precipitation dissolves up to 500,000 tonnes of this salt, which enters as a highly concentrated solution into watercourses and ground water. Explanation follows of measures for minimization of environmental pollution by covering of dumps and controlled drainage of alkaline solutions from the dumps. Finally, presentation is made of the results of the successful work until now by GVV for reuse of decommissioned mining sites with settlement of new companies for creation of additional jobs and for revitalization of the monostructured South Harz Potash Mining Region.

Aug 1, 2013

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016