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By Xiaolin Cheng, A. J. Sinclair

"Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeo chemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:<equation>where all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemico-mineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By Mark Sherman

"One of the main functions of a process technology and engineering services provider is to select grinding equipment that will meet the client’s throughput rate target. Prudent risk mitigation strategies would suggest that throughput rate estimates be cross-checked using a variety of techniques.Whilst some comminution circuit designers have estimated specific energy requirements via the manipulation of the Bond specific power equation e.g. Barratt’s Grindpower and OMC’s FSAG approach, other designers have opined that the Bond Indices have no role to play in the calculation of SAG mill specific power. As a result, they have developed their own specific energy estimating methodologies, e.g. SMCC’s Drop Weight based power methodology, SPI, SAGDesign, etc. Each method has its supporters and its critics.The challenge facing the engineering provider is how to nominate an SAG mill based circuit throughput rate estimate when faced with significantly disparate specific energies calculated by the different methodologies. This challenge is exacerbated via the continuing evolution of contemporary circuit configurations such as two stage pebble crushing some of which incorporate HPGR technology as the second stage of pebble crushing.The methodology presented in this paper shows that the Bond Indices are an excellent tool for estimating the specific energy requirements for SAG mills in SAB, SABC and SSS circuits. The method accommodates primary crushed feeds, partial and or fully secondary crushed SAG mill feeds, and emulates the impact of pebble crushing on SAG specific energy. As a result, the new Bond Index based method has provided an additional tool for increasing Fluor’s confidence when predicting SAG mill based circuit throughput rates. Based on this outcome, the author proposes that the decades old conundrum of using Bond Indices to calculate SAG specific energies for SAG mill based circuits has been solved."

Jan 1, 2012

By Garston Blackwell

Abstract - During geostatistical estimation of block grades, the kriging process produces a measure of error, the kriging variance or the kriging standard deviation. Estimation of the block error depends on the semi-variogram model for a deposit, which reflects fundamental characteristics of a deposit such as (1) nugget effect, (2) range of influence of grades, (3) different local spreads of data as a function of average grade (proportional effect), (4) nested structures, and (5) underlying anisotropies in the data; this model may be affected by sampling or assaying limitations, however. Because the kriging error incorporates so many features of both the deposit and data to be used for estimation, it may offer a substantial improvement on block classification over traditional procedures such as data density. Practice indicates that the relative kriging standard deviation (RKSD) is particularly useful for block classification in measured, indicated and inferred categories. Plots of RKSD in plan and section also can be used to demonstrate where extra drilling and sampling would be most advantageous for upgrading the class of some blocks. Moreover, the use of grade and RKSD filters can show where material near cut-off grade is poorly defined, indicating sampling target areas to improve block classification in the vicinity of the ore-waste boundary.

Jan 1, 1998

By Peter Rubie

"For many years, optimising the relining of hard rock grinding mills has been complicated by:?? the large number of variables;?? the low frequency of relines (slow feedback loop);?? the potential economic risk associated with some changesA technology that has its roots in the automotive manufacturing industry is being utilised to construct a statistically accurate, configurable, and dynamic simulation of the mill relining process. The effects of various mechanisation and process changes can be rapidly modelled and compared.This technology will provide mill maintenance managers and contract relining companies with the opportunity to benchmark current performance against world’s best practice. It will also provide an opportunity for concentrator plant designers and mill manufacturers to plan for maximum plant efficiency, by designing an infrastructure and equipment combination that maximises annual plant availability.This simulation tool and its associated data set, has been developed using recent grinding mill performance data from mills of varying dimensions, liner configurations, mill relining equipment, operator and tool variables.The simulation will provide an output that the various stakeholders can utilise to make optimal decisions within the given financial, physical and technological constraints of the individual concentrator plant."

Jan 1, 2012

By A. Vervoort, A. Govaerts

Geostatistical concepts are often difficult for students to understand, even those with a strong mathematical background. One of the main problems is the link between the variation of the parameter value in space or time and the calculated experimental semivariogram. Another challenge is differentiating between directional and omnidirectional semivariograms and their interpretation. For these reasons, interactive tools were developed based on the free public domain software R. The use of these interactive tools is limited to educational situations only (i.e., to visualize basic concepts). The interactive modules can be accessed at www.bwk.kuleuven.be/geostatistics.

Jan 1, 2014

By A. A. Ruitenberg, L. R. Fyffe

"This paper compares several distinct types of mineral deposits associated with different families of granitoid rocks in the New Brunswick Appalachians. Porphyry copper deposit s are associated with late-stage differentiates of Lower to Middle Devonian I-type igneous complexes. Contact metasomatic deposits were formed where these plutons intrude carbonate rocks and they gave rise to vein deposits in fracture zones near wrench faults. The I-type granitoids were emplaced mainly in areas of thin continental crust and locally along prominent faults in areas of thick continental crust.In contrast, tin-tungsten-molybdenum-bearing greisen deposits and skarns, and antimony-bearing quartz veins are associated with predominantly S-stype granitoid complexes ranging in age from Middle Devonian to early Carboniferous. The mineral deposits occur within or along the contacts of very fractionated (specialized) late phases of these intrusive complexes, which are characterized by high K2O/Na2O, Rb/Sr and Rb/Ba, and low Fe, Mg, Zr and Ti contents. These specialized granitoids are in a large wrench fault zone that cuts across thick continental crust in southwestern and central New Brunswick.IntroductionA great variety of igneous intrusions and subvolcanic stocks were emplaced in the New Brunswick Appalachians during the latter stages of and immediately after the Acadian Orogeny (late Lower to Middle Devonian) and during the subsequent Hercynian Orogeny (Carboniferous). The presence or absence and characteristics of mineral deposits associated with these intrusions reflect the level of intrusion, the composition of the associated igneous rocks and the composition of the invaded sequences.Nickel-copper sulphide deposits occur in mafic intrusions in the St. Stephen area of the southwestern Magaguadavic - St. Croix Zone and in the Goodwin Lake area of the northeastern Mirarnichi Zone. Contact metasomatic and vein-type copper-rich base metal sulphide deposits and porphyry copper deposits with or without molybdenum are related mainly to high-level granitoid stocks of intermediate composition in the Matapedia-Tobique and northwest Miramichi zones. Tintungsten - molybdenum deposits with or without base metal sulphide minerals and antimony-uranium deposits are mainly associated with Upper Devonian and Lower Carboniferous biotite-muscovite granites and related &apos;subvolcanic intrusions that occur in an arc-shaped belt extending from the southwestern Magagaudavic - St. Croix Zone into the central Mirarnichi Zone."

Jan 1, 1982

By T. J. Bruce, G. E. Agar, R. Stratton-Crawley

"A technique by which the design of a flotation circuit may be optimized is described and examples of the application of this methodology are given.Three interrelated criteria are defined and the application of these criteria to the selection of the optimum residence time for each stage of a flotation circuit is demonstrated. The criteria are:(1) Add no material to the concentrate that is lower in grade than the feed to that separation stage.(2) Maximize the difference in recovery between the desired mineral and the gangue.(3) Maximize the separation efficiency.Three independent systems were examined experimentally and it was shown that application of any of the criteria yielded similar results.It was demonstrated how the application of rate measurements (Criterion #2) could lead to the selection of a set of optimized times for several stages in a flotation circuit and that these could in turn be used to simulate the results of a locked cycle test. The predictions were checked against the experimental results from a locked cycle test and there was substantial agreement between the predicted and observed results."

Jan 1, 1980

By Harvey McLeod

M3 -Technology HOWEVER:In practice we have limitations ?Clients: aggressive or cost based; inexperienced ?Consultants: ?expanding market w/training limitations ?Prescriptive designs ?Lack of senior oversight ?Regulators: difficult to retain technical capacity ?Stakeholders: perceptions and expectations ?Physical settings: challenging terrain, climate, soils/rock Do M3?s Perform? YES?Generally M3?s since mid-1960 do perform ?BC Closed Mines: Afton, Highmont, Trojan, Bethlehem, Cheni, SNIP, NO?ARD/ML issues?e.g. Equity Silver, Samatosum; selenium, cadmium, sulphate

May 1, 2010

By E. Ghali, C. Su, G. Houlachi

"The influence of lead ions on zinc electrowinning process was investigated by means of electrochemical noise measurements (ENMs) and cyclic voltammetry in conjunction with scanning electron microscopy and X-ray diffraction. All electrochemical experiments were performed in sulphuric acid electrolyte containing different lead ion concentrations as impurity. Lead was added in six trace levels between 0.05–0.8 mg/L in the bath. The lead content of the zinc deposits was dependent on the introduced lead concentrations. The overpotential associated with zinc electrodeposition shifted to higher values with the increase of lead concentration in the solution. An appropriate correlation was found between the different concentrations of lead in the electrolyte and the morphology of zinc deposit by ENM. The results showed that the increase of lead ion concentrations is generally accompanied with the decrease of skew and increase of kurtosis values that could be related to the morphology of zinc deposit. Effectively, the morphology changes from well-defined hexagonal platelets to large hexagonal, layered platelets and finally to non-symmetric refined crystalline structure, respectively.INTRODUCTION In commercial zinc electrowinning, zinc oxide is leached from the roasted calcine with an aqueous acid sulfate electrolyte. Then the zinc-rich solution is purified and transferred into an electrolytic cell. During electrolysis, zinc is deposited on aluminum cathode where lead-silver or pure lead is served as anode. Electrodeposition of zinc could be influenced by several parameters such as bath acidity, temperature, current density, the nature and concentration of impurities as well as additives in electrolyte. Metallic impurities play a complex role during zinc electrowinning and they can adversely"

Jan 1, 2016

By Chuanhui Cao, Shimei Liu, Xiaojing Li, Yueyuan Zhou

"Force analysis on weakly-magnetic particles and non-magnetic particles in magnetic field are presented, using a kind of permanent magnetic drum magnetic separator, which is designed with strong specific magnetic force and open magnetic system. Its surface peak intensity reaches to 1.0T, and the distribution density of capture line is 1.25×103/dm2. Qualitative analysis on the particles including its magnetic property, particle size, motion speed, magnetic field intensity, etc. is also presented to calculate the separating parameters for the drum separator. Experiment was conducted for the separation of fine weakly magnetic minerals for example ilmenite. The practicability to separate the minerals using separator designed with open magnetic system has been proved, providing an economic way for efficient separation of micro-fine weakly magnetic minerals and upgrading of non-metallic minerals. INTRODUCTIONMagnetic separation is a mineral processing method based on the differences of magnetic properties between minerals in inhomogeneous magnetic field (Sun, 2007). Currently for separation of micro-disseminated weakly magnetic iron ore, electromagnetic high intensity magnetic separators with closed structure of magnet system are often used. And for the separation of strongly magnetic minerals such as magnetite, low intensity drum magnetic separators with open magnet system are often used. In order to lower the operation costs and improve energy efficiency, it is important to develop efficient high intensity permanent magnetic separator with open magnet system, to some extent replacing high intensity electromagnetic separator.Oberteuffer (1974) discussed the magnetic force and competing forces in magnetic separators which compete with the magnetic forces and act on all of the particles which travel through the separator are those of gravity, hydrodynamic drag, fraction, and inertia in magnetic separation."

Jan 1, 2016

By K. J. K. Weglo, M. U. Savich

"At the Falconbridge Limited, Canadian Nickel Division, Sudbury Operations, we investigated the ""NO NOISE"" ear muffs model NN3-F which is a Swedish product with foam-filled sealing rings (the Hellberg Standard Volume Hearing Protector). It is used extensively at Falconbridge mines in Sudbury.The research which was carried out in the four Falconbridge mines was conducted under three different headings: manufacturer&apos;s attenuation data (psychophysical method), clamping force and head size (bizygomatic diameter), and attenuation tests (physical methods) under working conditions.Manufacturers of hearing protectors claim their products offer noise reductions of 23 decibels (NRR) or more, but they fail to point out that this reduction is obtainable only under ideal conditions. The reality of attenuation under working conditions, as several studies have found, is quite different.Methods for using short measurements to determine the noise exposure index, and for controlling muff-wearing habits, were developed at the Elliot Lake Laboratory. Measurements taken at Falconbridge on ""NO NOISE"" ear muffs revealed that they have a practical attenuation of some IO to 13 decibels. It is important to note here that measurements also revealed that clamping force (thus attenuation) was in an inverse relationship with ear muff comfort. Measuring attenuation using noise dosimeters was a difficult job. Not a single surveyor would accept these measurements (physical method) for absolute accuracy. Apart from that, it was impossible to measure, in one shift, more than two work stations. Because of this, we sought a solution: measuring head size and clamping force in relation to actual attenuations.A detailed analysis of the relationship between attenuation and head size/clamping force was done at four mines. Standard deviation ellipses (standard error ellipses) for head size versus clamping force are in close agreement with measurements that were carried out. In order to measure clamping force an apparatus was constructed and a method for measuring suspension system durability is described in Appendices Band C of this report. At the same time we sought to reduce deterioration of ear muffs in mines as well as to put in place a system whereby attenuation can be controlled and improved. The clamping force apparatus can be operated automatically. The proposed control system is quick, simple and efficient . This system is equally applicable in small and large mining operations, and it can be totally automated and the data computerized for audit of the results. This control system is a new step in controlling ear muff attenuation in working environments.From these measurements of NN3-F ""NO NOISE"" muffs it can be concluded that ear muffs are not the total solution to protect the worker from noise.As the results were evaluated folio wing measurement, Falconbridge switched from the NN3-F ""NO NOISE"" muffs to approximately 90% Mark V ""NO NOISE"" muffs and 10% Mark V MSA muffs. These new muffs showed much better head size versus clamping force relationship and can be expected to produce 14 dBA or better attenuation of noise. RESUMEUne étude des casques antibruit ""NO NOISE"" modèle NN3-F, de fabrication suédoise, avec anneaux d&apos;étanchéité en mousse (dispositif de protection contre le bruit ""Hellberg "" pour volume ordinaire)a été effectuée Ii la Falconbridge Ltd. , Division canadienne du nickel aux installations de Sudbury . Ces casques sont largement utilisés dans les mines de la Falconbridge Ii Sudbury.Cette étude aeu lieuen milieu de travail dans les quatre mines de la Falconbridge sous trois rubriques différentes soit: les données d&apos;atténuation du bruit du fabricant (méthode psychophysique), la force de serrage et la taille de la tète (diamètre bizygomatique), et les essais d’atténuation de bruit (méthodes physiques). Les fabricants de dispositifs de protection contre le bruit prétendent que leurs produits offrent une réduction du bruit s&apos;élevant Ii"

Jan 1, 1986

By Robert B. Parsons

"Effective January 1, 1990, mines in British Columbia are subject to a new provincial mining tax statute, the Mineral Tax Act. Under this Act, mines are subject to a two-tier tax system, with a minimum tax payable on ""net current proceeds"" and a higher tax paid on net income. For many mines, the present value of tax paid under the new rules should be comparable to the amount paid under the old rules. Earlier cash payments could pose difficulties, particularly for smaller mines, but existing producing mines could benefit in the short-term.IntroductionEffective January 1, 1990, British Columbia has replaced the provincial mining tax regime under the Mineral Resources Tax Act with a new system under the Mineral Tax Act. The new rules borrow some ideas from other provinces (New Brunswick&apos;s two-tier concept, and Saskatchewan&apos;s indexed costs) with a view to levying a tax that is fairer to both the producer and the province."

Jan 1, 1990

By J. G. Schofield, C. G. Tan, R. J. Ord

"Most electric furnaces in the nickel and copper smelting industries are still fitted with conventional electrode holders which consist of water-cooled electrical contact clamps and a pressure ring. The water cooling exerts a significant cooling effect on the electrode column. The importance of controlling the temperature of the Soderberg electrode paste at the contact clamp area is examined, using in-plant experience and computer simulation of the paste melting and baking process. In addition to the effect of water-cooling, the effect of other variables, including the mantle air temperature, the electrode current, the furnace freeboard temperature and the electrode slipping rate are discussed. Ways in which the variable heating conditions in the paste melting zone can be controlled are outlined.IntroductionIn most non-ferrous electric smelting operations, the breakage of Soderberg electrodes is an infrequent, isolated occurrence. Occasionally, however, a rash of breakages may be experienced on a particular furnace for what appears to be no obvious reasons. The extent of the breaks may not exhibit a uniform pattern; sometimes the break may be less than half a metre above the electrode tip; at other times it may be at or just below the roof level. The latter type of break is, of course, the most dangerous since it is closest to the non-baked, weak portion of the electrode paste column. No matter where the breaks occur, they result in abnormal furnace power, charging and tapping conditions and loss of production while the new electrode section is slipped and baked. On a six-electrode furnace, breakage on one electrode has the immediate effect of reducing the total furnace power by one-third. On a three-electrode furnace, the effect is more drastic, one half of the power being lost."

Jan 1, 1995

By Michel Ruel

Most plants do not track how their systems perform. Optimization is the easiest way to benefit from your control systems. We suggest an approach in four phases. The first phase is to assess all equipment to determine the performances for instruments, valves, variable speed drives, and other equipment. The second phase is to remediate instrumentation problems, including the ones pertaining to valves, variable speed drives, analyzers, transmitters. When equipment is in order, loops are put back in automatic mode. If a loop oscillates, use standard default values for this type of loop. The third phase consists in validating the control strategies, properly configuring the systems (control system, programs and parameters, HMI, alarms), and then tuning the loops and control strategies. The fourth phase consists in analyzing the process and expected performances in order to optimize the control loops and control strategies. If performance is not sufficient, a decision tree will be presented to determine the right approach: advanced regulatory control, model predictive control, or fuzzy logic control. Once all steps have been completed, control performance monitoring software is used to sustain the results and pinpoint equipment or loops not performing as stated. Alarm management and rationalization could also be performed after auditing the alarm system, if needed. Examples from plants will be used to demonstrate how this step-by-step method is applied and produces results. INTRODUCTION Maximizing what you already have is the best investment to remain competitive. This article aims to show the benefits of a systematic approach using modern tools to improve plant performance. We at BBA suggest dividing the work in four phases, and a subsequent phase can begin when the previous one has progressed: Assess, Remediate, Stabilize, Optimize, or add advanced control. This approach has been successfully applied to several sites. Examples and illustrations from these plants demonstrate how this step-by-step method is applied and produces results. Under the BBA method, there are four questions to answer before proceeding to the next step. For each control strategy, you should ask the following questions: Assessment: Does it work? Remediation: Do you use it? Stabilization: Is it stable? Optimization: Does it perform? Do you need advanced control?

Jan 1, 2019

By J. Bruce See

INTRODUCTION This symposium at Cu 2019 has been organised to honour and celebrate the career and achievements of Dr Phillip John Mackey, an internationally recognised expert in the production of non-ferrous metals, especially copper and nickel smelting and refining. Phillip was born in Epping, a suburb of Sydney, New South Wales, Australia on 19 April 1941 and is one of 4 children of Gilbert and Philomena (nee Bartlett) Mackey. After completing Primary School in Epping, he attended Marist Brothers High School in Eastwood, Sydney and graduated in 1957 as the Dux of the School. Phillip’s father, being on the staff of the Sydney Technical College, in Ultimo, Sydney had the opportunity in the early 1950s to meet the late Professor Sir Rupert Myers, Foundation Professor of the School of Metallurgy at the New South Wales University of Technology (later called the University of New South Wales or UNSW). Gilbert Mackey was impressed by the new young Professor of Metallurgy and encouraged his son to study metallurgy - at the time an expanding industry in post-war Australia. EDUCATION AT THE UNIVERSITY OF NEW SOUTH WALES Phillip commenced at UNSW in 1958, graduating with honours in 1963. His undergraduate education and training included a few years of part-time study while working at British Motor Corporation on sheet metal forming of car bodies. At University Phillip developed his talent for teamwork. He was a contributing writer to the University newspaper, Secretary of the UNSW Students’ Union and was active in the UNSW Metallurgical Society and co-editor in 1963 of “Metallurgical Review,” the annual journal of the UNSW Metallurgical Society. His diverse interests and curiosity about the world around him were likely nourished while at University. Upon completing his Bachelor’s degree, Phillip was awarded a Commonwealth of Australia Postgraduate Research Scholarship. He began his PhD in 1964 on the thesis topic “Studies in Heat Transfer between Dispersed Liquid Metals and Gaseous Atmospheres” working under the supervision of then Associate Professor Noel Warner, an outstanding Professor at the University. Professor Warner is now an Emeritus Professor at the University of Birmingham and is internationally respected for his pioneering theoretical and practical work on established and innovative smelting processes.

Jan 1, 2019

By M. Elmadagli

Wear mechanisms of two commercial aluminum alloys, namely a spray formed and extruded Al-25%Si alloy, and a sand cast A390 alloy (18.5 %Si) that are known to be successful in cylinder bore technology were studied to have a better understanding of the requirements for wear resistant aluminum alloy design. From durability point of view these alloys are known to be successful for engine bore applications. It is interesting to compare the wear mechanisms in these alloys because they have significantly different silicon content and microstructures, and were produced using different techniques. The wear tests were done using a block-on-ring configuration, in controlled air atmospheres (5 % relative humidity). In spite of the differences in silicon content and microstructure, the wear mechanisms were similar and consisted of formation and destruction of hard tribolayers that are either formed by either mechanical or chemical interactions on contact surfaces. The differences in the wear rates between the two alloys arose from the differences in the hardness of the worn surfaces, and the alloy&apos;s ability to sustain the tribolayers on the worn surfaces.

Jan 1, 2004

By B. J. Fryer, R. P. Taylor

"As a monitor of the processes involved in the formation of granitoid mineral deposits the coherent group behaviour of the rare earth elements (REE) actively reflects changing fluid characteristics. For example, in the porphyry environment, magmatic-hydrothermal fluids produce potassic alteration with strong enrichment in the light rare earth element s (LREE), reflecting their high pH, low fluid/rock ratios, and the dominant role of CI- complexing in metal (i.e. Cu, Au) transport. With increasing fluid/rock ratios and decreasing pH accompanying the progressive involvement of meteoric fluids (and the production of propylitic, argillic, and phyllic alteration) anionic species such as F - and CO, 2- become important in metal (e.g. Mo, W,) transport through complexing, and their activity in the hydro thermal fluids is illustrated by mobilization of the heavy rare earth elements (HREE).The relative involvement of CI- versus F - versus CO32- in metal transport in other granite-related systems can also be monitored through REE behaviour. Hence granitoid tin-tungsten mineralization and associated greisenization typically exhibit heavy rare earth enrichment and evidence the importance of F&apos; and CO32- in metal transport. Similarly, heavy rare earth element enrichment in hydrothermal uranium deposits can be related to the transport of uranium as carbonate complexes. REE are widely accepted as powerful tools in the study of rock petrogenesis, but their use has been neglected in the investigation of mineral deposits. The recognition of the systematic variation of REE distributions in granitoid mineral deposits suggests that the application of REE geo chemistry, particularly when integrated with fluid inclusion and isotope studies, can provide (1) an effective method for identifying the physicochemical controls of metal transport and (2) a useful criterion for elucidating metal distribution."

Jan 1, 1983

By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2&apos;-bipyridine (bipy) (1), 6-alkyl-2,2&apos;-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2&apos;-bipyridine (bipyR&apos;) (3), R&apos; = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By L Munholand, G. Soucy, P. Quintal

This work presents early results from the first study to optimize the hydrodynamics of a Plasma Lift Reactor (PLR). The PLR is designed to break down organic contaminants in aqueous solutions. New experimental results are presented for air/water tests and for plasma degradation of organic contaminants in Bayer liquor. In addition, a multiphase Computational Fluid Dynamics (CFD) model has been developed which predicts the hydrodynamic behavior in the PLR. These results of this work suggest the PLR is effective at reducing contaminants in the Bayer liquor and that the CFD model adequately describes the hydrodynamic flow.

Jan 1, 2005