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By C. Bourgoin

"The factors constraining productivity in the mining of narrow vein ore deposits are numerous and often interdependent. This paper concerns mining techniques capable of reducing some of these constraints in the case of vein deposits whose dip is less than 45 degrees. Modifications of conventional mining methods as well as suggested new developments are presented, as are matters pertaining to the mechanization of operations as a mean of increasing both productivity and work safety. IntroductionThe mining of vein deposits, whose width (thickness) is generally less than 2 metres and whose dip is often variable, calls for the use of varying stoping procedures as well as appropriate infrastructure and equipment. In the case of intermediate dips (15 degrees to 45 degrees), it is generally conceded that the degree of mechanization is limited and that ore removal via gravity is impossible. This paper proposes certain innovations in matters of equipment use and stoping methods, together with certain technical data pertaining to the application of these new procedures Stoping MethodsTo mine vein deposits, one must choose a method that can adapt to irregular ore limits and allow, as well, for good ore recovery with as little dilution as possible. In addition, it is important to minimize development work in waste rock. In principle, one selects a method that is both safe and profitable; this method will be defined mainly by the nature of the vein deposit and its dip, by the competency of the rock formations and by certain technical considerations. Moreover, the stoping procedure in a given deposit may well change with time as a function of new layouts or new equipment."

Jan 1, 1994

By Vincent Doyon

For several years, the GDD SSW EM Probe is being used in nickel?s mines in Canada and Brazil to define ore limits, reduce dilution and predict nickel grades. It is used with success to test most if not all percussion blast holes at all Falconbridge Mines in Sudbury and Raglan and all Inco?s Thompson mines. However, after testing the SSW Probe in other metal mines, we realized that EM conductivity does not define ore limits by testing blast holes for copper, zinc or gold. For non-conductive ores, no instrumentation is yet available on the market to reduce dilution, by outlining quickly and inexpensively the real shape of an orebody. To that effect, Instrumentation GDD Inc has developed a new revolutionary photonic probe that will make the reduction of dilution possible by probing blast holes. Once surveyed with the probe, a computer draws graphs of the ore grade as a function of depth for each blast hole. A contribution by Canada Economic Development made possible the development of this new technology. Canmet and Soredem also cautioned this technology developed by Instrumentation GDD Inc. This new photonic probe will allow: 1) to better understand the shape of the orebody 2) to raise the grade of the ore fed to the mill 3) a more complete extraction of the ore 4) to raise the competitiveness of mines

Oct 1, 2004

By K. Reipas

"Westmin Resources Ltd. operates the 3300 TPD H-W underground copper/zinc mine on Vancouver Island. Ore storage underground is handled in a 6000 tonne coarse ore bin and a 3000 tonne fine ore bin. Both of these bins have experienced significant wear since excavation and construction in 1985. Wear problems have included both deteriorating rock walls as well as worn out steel liners and concrete at the discharge points from the bins. Extensive rehabilitation work was completed in 1993.The basis o/this paper is the rehabilitation work done on the coarse ore bin. The design and installation of ground control measures are discussed. The bin access methods used to allow the work to proceed quickly and safely are also presented. This involved the use of a Tekfoam safety bulkhead to protect workers.IntroductionMine DescriptionThe H-W mine was commissioned in 1985. Mine access is by vertical shaft with most production areas at a depth of about 500 m. Host rocks are composed of andesite and rhyolite. Mine capacity of 3300 tonnes per day is achieved mainly by longhole open stoping methods, complemented by room and pillar mining. Metals recovered from the massive sulphide ore are copper, zinc, gold, and silver. Mineable reserves at January I, 1994 were 9.7 million tonnes."

Jan 1, 1995

By M. Hozayen, E. S. Radwan, P. A. Nawrocki, A. Jebbouri

"A major geomechanical study was conducted for one of the UAE onshore oil fields with the purpose of studying reservoir rock properties and stress distribution, based on which a 3D coupled reservoir geomechanical model was built. This model was later used for wellbore stability analysis and for analyzing the effect of fractures on future reservoir production performance, including fracture deformation and permeability evolution occurring due to reservoir depletion and resulting changes in local stress field. The subject of this study was a complex fractured Upper Cretaceous carbonate reservoir characterized by high degree of heterogeneity, both vertically and laterally. Wellbore instability related drilling problems were encountered while drilling the wells in this field. The problems were mainly in drilling the horizontal wells, including breakouts and mud losses. Experimental results of laboratory tests are summarized in this paper whereas wellbore stability analysis and formulation of a 3D geomechanical model that was built for that purpose is summarized in a sister paper (Part II).A suite of tests reported includes tensile strength, uniaxial and triaxial compression and permeability under stress at simulated reservoir conditions. All tested rocks have been grouped into twelve test units and reservoir geology, rock types and challenges related to designing a viable sampling and testing program for a big reservoir are discussed first followed by sample selection criteria and details of the testing program. All test units showed brittle behavior at zero confinement and some samples showed similar behavior at low confining stresses. With confining stress increase, the behavior gradually turned to plastic but some samples showed features of ductile behavior even at low confinement.Obtained experimental data have been summarized in the form of strength criteria and correlations. The Mohr-Coulomb strength equations were obtained for each test unit and also for the averaged values. It was noticed that triaxial compressive strength (TCS) increases with decreasing porosity or increasing density but their influence on TCS is getting smaller with confining pressure increase. Good correlation of porosity and density with Young’s modulus, Poisson’s ratio, unconfined compressive strength (UCS), friction angle, cohesion and tensile strength has been noticed and there was an increasing trend between the confining pressure and TCS. Rock type (mud or grain supported) was not influencing the TCS as much as porosity and density and the two lithologies encountered affected TCS approximately in the same way. These results and correlations are summarized and explained in this paper. They were further used in the numerical modelling part (Part II) of this paper, Hozayen et al. (2015). It is also concluded that rock lithology is not a decisive factor and mechanical properties of tested rocks should be rather considered dependent on porosity and permeability. This helped greatly in reducing the number of tests that had to be performed."

Jan 1, 2015

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to assist the mining industry in implementing continual improvement in management of major unwanted events so maximising health and safety performance. A comprehensive body of knowledge has been compiled from diverse mining industry experts for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This paper presents an overview of the RISKGATE body of knowledge captured specifically for the management of unwanted events that stem from the handling and use of explosives (drill and blast) within surface coal mining operations. The knowledge presented is divided into a series of initiating events (listed below) within which there are further degrees of classification based on design, operation, and management concerns. Initiating events: ? Loss of control of explosives and associated chemicals in storage on site ? Loss of control of explosives and associated chemicals during transport ? Loss of control of explosives and associated chemicals during manufacture ? Loss of control of explosives and associated chemicals during handling and blast operations ? Loss of control of explosives and associated chemicals during disposal The system guides the user in generating substantive and leading-edge controls to assist in the design, management and reporting of drill and blast operations to meet stringent internal and external requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry.

Aug 1, 2013

By P. D. Soares, H. R. Bullis, R. A. Hureau

"Echo Bay's Lupin Operation has produced more than 2.15 million ounces of gold since start-up in 1982. The mining method used to the£ present time has been longhole open stoping using trackless equipment. Because direct measurement of the open stopes has not been possible until recently determining the exact quantity of unplanned dilution in previously mined stopes has not been possible. Estimates of dilution hove been mode using comparisons between production tons and grades against ore reserve tons and grades.This paper discusses tracking of grade and tonnage measurements from reserve estimation through production. Comparisons between estimated and actual tons and grade are presented~ along with a brief description of methods used at the Lupin operation to control dilution."

Jan 1, 1994

By C. A. Born

This paper describes the rejuvenation of a molybdenum mine mill complex at the head of Alice Arm, 500 miles north of Vancouver and 85 miles north of Prince Rupert, British Columbia. It includes a description of the property history of the deposits and of the previous operations, together with details of the project for re-opening the mine.

Jan 1, 1979

By Tom Shumka

Introduction ?This technique detects 100% of all gear tooth surface indications, providing comprehensive data, and has the ability to size indications accurately. ?The remarkable advantages of ECA technology, is improved inspection capabilities and significant time-savings. ?The advantage of using EMCD is its ability to size indications accurately. ?This technique does not require the gear teeth to be wiped down by hand after cleaning as in MT, LT or UT inspections. (Figure 1) ?This technique will inspect one gear tooth in 30 seconds. ?All of the data can be archived for future comparisons in an electronic report. Methodology ?This technique utilizes Eddy Current Array (ECA) as the principle inspection technique. ?What has been added are specialty scanner probes with multiple coils, a multiplexer and a software package. ?With 2 and 3D dimensional isometric displays, the defect can be seen electronically as it is on the gear tooth surface, thus, reducing the reliance on human interpretation.

May 1, 2011

By D. Neely, D. Milne, L. R. Feldman

"Resin-anchored rebar is commonly used for rock support in mining. The rock properties and environment determine the average bond strength, allowing mine engineers to select the appropriate length and installation pattern for the support. In weak material such as potash, the average bond strength tends to be lower than for a typical hard-rock installation. Determining the failure mechanism by which the support fails in soft-rock applications could lead to improved bond strength and better calculated installed support capacity. This paper reports on research conducted at a potash mine in Saskatchewan and analyzes the failure mechanism of the support.RÉSUMÉ Dans les mines, les barres d’armature enduites de résine sont fréquemment utilisées pour soutenir le roc. L’environnement et les propriétés du roc déterminent la résistance moyenne d’adhésion, permettant ainsi aux ingénieurs miniers de choisir la longueur de barre appropriée et le diagramme d’installation du soutien. Dans des matériaux faibles, tels que la potasse, la résistance moyenne d’adhésion tend à être plus faible que pour une installation typique dans de la roche dure. La détermination du mécanisme de rupture selon lequel le soutien fait défaillance dans des roches tendres pourrait conduire à une meilleure force d’adhésion et à un meilleur calcul du soutien installé. Le présent article fait état de la recherche effectuée dans une mine de potasse en Saskatchewan et analyse le mécanisme de défaillance du soutien. ,"

Jan 1, 2016

By Li. L.

Backfilling has become a popular solution in underground mines around the world. It reduces environmental impact of mining industry and improves ground stability. In most cases, backfill has a high water content so that it can be delivered by pipes from a backfill plant on ground surface to underground stopes. Upon deposition in the stope, the backfill tends to consolidate under its own weight, leading to a generation of excess pore-water pressure. To avoid excessive pressure and protect the backfill barricade installed at the base of the stope, the backfilling of the stopes is usually divided into two stages: plug pour and backfill body pour. The interruption of backfilling operation is undesirable as it slowdowns the mining productivity, and sometimes causes pipe clogging, leading to unexpected increase in manpower cost and further reduction in mining productivity. The backfilling interruption time may be reduced, even eliminated if the drainage of backfilled stopes is sufficiently improved. This paper presents an application of wick drains, a material commonly used in civil engineering, to mine backfilled stopes to help accelerating the drainage. A protocol is proposed for installing the wick drains in a mine stope to be backfilled. Numerical simulations were made, showing that the drainage of the backfill can significantly be improved by the introduction of wick drains. The application of wick drains in mine backfill can thus be considered as a promising technique and merits deeper and more detailed investigation.

Aug 1, 2013

By William D. Swank, Prabhat K. Tripathy, Tedd E. Lister, Eric S. Peterson, Delon C. Haggerd

More than half of the primary neodymium, produced directly from ores, is being used to manufacture neo magnets. Neodymium, being a critical element in supply, has attracted considerable interest worldwide to recover this metal from a variety of waste streams. From among different recycling processes, hydriding-dehydriding can prove to be highly effective in recycling discarded neo magnets present in consumer electronics. In the present study, manually removed magnets from discarded Hard Disk Drives (HDDs) were subjected to the hydriding-dehydriding process in order to evaluate the resultant products for the re-fabrication of the magnets. The paper describes the effect of experimental parameters on both the hydriding and dehydriding processes as applied to different magnet chemistries.

Jan 1, 2014

By Greg M. Hollyer

The search for minerals in the future will be dominated by deeper exploration and the need to accurately target ?blind? deposits as more and more of the ?easy? near surface targets are exhausted. In this context, key technologies are emerging for deep exploration both in grassroots and minesite exploration, including the Titan 24 Deep Penetrating geophysical technology. Introduced in 2001, this technology has grown rapidly into an accepted approach for exploration in a variety of geologic environments, including brownfield environments where discovering additional reserves would most quickly benefit companies. Titan 24 belongs to a new class of sophisticated Distributed Acquisition Systems (DAS) which record high-volume, high-quality data simultaneously at multiple receiver stations. This data is then processed digitally, modeled using specialized inverse modeling software, and interpreted according to geologic and other parameters. The result is a robust, high-quality, high-volume data sets which provide a basis for improved imaging to depth. In this paper, the Titan 24 distributed technology is discussed. Illustrations of the vast improvement to overall exploration are showcased through results in several case studies. These include examples from two gold deposits, a porphyry deposit and a minesite. These examples show the range of applicability of the technology and the ability to effectively image mineralization, lithology, structure and alteration to depth as an aid to understanding prospective mineral deposits and targeting drills more accurately.

May 1, 2008

By H. Henao, F. Canales

The present work evaluated the use of copper ore flotation tails as flux in the process of smelting copper concentrates. For this purpose, experimental and simulated liquidus lines were obtained at different ratios of tail/flux. Experimental variables included temperature, partial pressure of oxygen and sulfur dioxide and the conditions of tridymite or spinel saturation. The results indicate the feasibility of replacing the flux by increasing the temperature of the smelting process by 20°C. Results of simulation using FactSage and HSC confirm that the required increase in temperature can be achieved by increasing the flow of concentrate, enrichment of oxygen or increasing the matte grade. INTRODUCTION In the pyro-metallurgical process of copper production, the smelting stage produces two liquid phases, a sulphide phase rich in copper and another composed mainly of oxides called slag. The slag phase is the product of oxidation of the iron contained in the flotation concentrate. The smelting process which is carried out at temperatures of 1250°C, require the addition of silica as a flux and the injection of air enriched in oxygen (Schlesinger 2011). Currently, one of the most important aspects of the mining industry is the minimization of costs, the optimization of the use of available resources and the reduction of environmental impact. Under this context, the use of flotation tails from as a flux in the copper smelting process has the potential of reduced production costs and generate an environmental benefit by reduce the disposal amount of this waste material Regarding the use of copper tails as flux in the copper smelting process, a thermodynamic simulation study using the FactSage software had been reported in the literature (Parra et al., 2011). The results indicated an increase of 35°C in the temperature the liquidus for the equilibrium matte/spinel and a subsequent requirement of energy in the process of approximately 350 [MJ/ton slag]. Given that the calculated viscosity remains in the same order of magnitude, the melting temperature is a more relevant parameter for the evaluation of the use of tailings as flux.

Jan 1, 2019

By Jan Butra

In copper ore mines located in the Pre-Sudeten Monocline the deposit mining using room and pillar systems has been carried out for more than forty years. When implementing mining systems in deep copper ore mines it appeared to be necessary to adapt them to variable geological conditions and natural hazards. In the initial period of exploitation there were mainly caving and rockburst hazards. The adaptation of room and pillar system was connected with a state of knowledge in the scope of identifying, forecasting and controlling rock mass hazards. The new solutions allowed the safe and efficient exploitation of a blanket deposit of variable thickness from about 2 to 15m, seated on progressively increasing depth. They included exploitation in constrained conditions, such as in protective pillars. In the exploitation period, technical and organisational activities aimed at rockburst hazard control were introduced including active methods for controlling rockburst hazard and procedures for conducting mining works in the rockburst hazard conditions. When mining at a depth exceeding 1,200 m, the exploitation method and technique are additionally affected by thermal hazard and by gas and rock breakout hazard. New solutions of the room and pillar system and a longwall system with mechanical mining have been developed for exploitation in the associated hazard conditions. The require application of many innovative solutions in the scope of mining process and ore haulage mechanisation, excavation support and forecasting and control of existing hazards. The main purpose of these solutions is to conduct the safe and economically effective exploitation of the deposit.

Aug 1, 2013

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By T. P. Lim, N. K. Davé

"A modified accumulator method was devised to measure surface radon flux from porous media. It consists of a collector hood type of accumulator with a homogenizer pump and a pressure balancer. The latter was used to compensate any pressure changes produced during sample withdrawal and hence eliminate additional radon transport from the media. Errors resulting from radon back diffusion due to decreasing concentration gradient with time across the interface were also eliminated by measuring radon concentrations in the accumulator for two different periods of time and calculating the true radon flux, J(o), from the solution of a time-dependent radon transport equation in the absence of any pressure and temperature gradients.Core samples from the observation site were also withdrawn for laboratory determination of porosity, moisture content, bulk and grain densities, Ra-226 source concentration and the fraction of Rn-222 produced in the void volume. The data were used to calculate the radon diffusion coefficient for the media.Using the present method, the true value of surface radon flux for an abandoned uranium tailings pile was obtained as J(o) = 2020.2 mBq/m2/sec (54.6 pCi/m2/sec) compared to the value J = 1406.0 mBq/m2/sec (38.0 pCi/m2/sec) obtained by the conventional method. The bulk diffusion coefficient of radon for the media was obtained as 1.2 x 10-7 m2/sec.IntroductionRadon-222 (hereafter called radon) released from uranium mill tailings is a continuous source of environment radioactivity in terms of its transport as an airborne gas and its decay products. The particulate daughter products readily attach to aerosols or dust particles and can further be transported by various other environmental pathways. Typical radon release rates from existing tailings piles vary between 740 and 14,800 mBq/m2/sec (20-400 pCilm2/sec), depending on the nature of the tailings material, moisture content, etc. The United States Nuclear Regulatory Commission (NRC) is proposing radon release rates of 74 mBq/m2/sec (2 pCi/m2/sec) above that of background."

Jan 1, 1982

By Gonzalo Bernstein, David G. Meadows, German Naranjo, Edgardo Tapia

"During the last decade Antofagasta Minerals’ Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.INTRODUCTIONMinera Los Pelambres is a world class copper-molybdenum operation located in the Salamanca area in Chile, in region four, approximately 500 km north east of Santiago, the capital of Chile. In the late 1990s Antofagasta Minerals developed the Minera Los Pelambres project in Chile at an investment cost of approximately $1.3 billion USDs. The project construction was successfully led and completed by Bechtel Corporation in 1999 and within a matter of months the plant was already exceeding the nameplate capacity of 85,000 mtpd. In 2001 a pebble crushing circuit was added to raise the capacity to 114,000 mtpd. In the early part of 2003-2004, it was recognized that the hardness profile was changing with depth and that in order to maintain the plant capacity additional power would be needed in the SAG mills together with upgrading of the primary crusher. In conjunction with these changes a fifth ball mill and a second primary crusher station would also need to be installed. A further detailed engineering study and evaluation was initiated by Minera Los Pelambres. This was lead by Bechtel Corporation with major design contributions from FLSmidth and Siemens in order to establish the re-powering requirements for the SAG mills. These re-powering changes together with the inclusion of a pebble crushing circuit took the plant to up to 125,000 mtpd even with harder more competent ores. Finally in the last two years an additional grinding line has been added to take the capacity to consistently over 175,000 mtpd. The third line was installed in a record time of 256 days. A schematic of the current comminution circuit, discussed in this paper, is shown in Figure 2."

Jan 1, 2012

By G. R. Sadowski

"Large subhorizontal joints have been found in the foundation excavations in basalt and granite of Brazilian Dams. Some spread for hundreds of square meters showed slickensides—polished surfaces plus striations—and laminations interpreted as related to shear displacement, what substantially reduced their shear strength and imposed special reinforcement measures against the potential sliding of overlying concrete structures. The geological characteristics of these discontinuities have raised speculations related to their origin, be it related to mechanisms of bulging, cambering or to some tectonic or primary geological event.Several geologists and engineers from the northern hemisphere including Terzaghi already showed to be concerned with their role in granite foundations while in the southern regions Brazilian authors have found similar occurrences but also affecting individual lava flows of continental flood basalts in the foundations of major dams of the Parana Basin, which they designated under the particular name of “fault-joints”. This double-standard designation is self-explanatory of the difficulties involving their origin and related geomechanical properties: faults or just shear joints?Recently, similar features were encountered in the foundations of large dam constructions in anorogenic granites inserted in the realm of the Brazilian Amazon, where some of these discontinuities exhibit features common to tectonic thrusting combined with deep tropical weathering.The evidence of preshearing along the surfaces of such fractures, also associated to products of deep weathering, reduces their geomechanical strength substantially, suggesting values of ultimate phi spanning 12 to 28°. The detection of these descontinuities during initial investigation phases continues to be a major complex task in geological risk evaluations surveys. Trenching associated to some geophysical exploration techniques, although considered to be very basic exploration techniques are still the suggested methods for their forecast and previous determination."

Jan 1, 2015

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

By Golaleh Riahi

An original method is used to obtain stable nanoparticles of gold-based mono- and bimetallic systems supported on an acidic zeolite. This approach has been applied to PtHY (1wt% Pt) and to bimetallic Pt-AuHY containing 1% of platinum to which is added the amount of gold required to give Au/Pt molar ratios of 20,40,60 and 80%. Metal clusters of Au or Pt-AuHY are formed inside the supercages of the zeolite framework by the thermal reduction of cations by the ligands (en = H2N-CH2-CH2-NH2) under inert gas flow at a temperature depending on the metal. The use of acidic zeolites favours the dispersion of the metal and the thermal stability of the particles. This stability is explained by chemical anchoring of metal clusters by the Brønsted sites of the support. Several techniques have proved that for a molar ratio of 20% metal particles of Pt-AuHY are bimetallic. The segregation of Pt and Au starts for molar ratio =?40%. The catalysts tested on the methylcyclopentane hydroconversion reaction reveal that the addition of gold to platinum leads to an increase in the activity and an improvement in the selectivity for isomerization of the skeleton (cyclohexane and benzene) to the detriment of hydrogenolysis. Similar results were obtained for the dodecane isomerisation to isododecane. These catalysts were also tested in CO, propene and propane oxidation. The activity of fresh catalysts is rather low. It increases after their pretreatment in oxygen or hydrogen atmosphere. In propene oxidation in the reaction mixture O2 ? H2, beside total oxidation of propene to CO2, also propene hydrogenation was observed, particularly at low temperatures. The presence of Au enhances the hydrogenation properties: high selectivities (> 90%) to propane and high propane yields on PtAu HY are observed up to ~150oC, whereas for Pt HY catalyst the selectivity and yield to C3H8 decreases rapidly with the temperature beginning from ~100oC.

Oct 1, 2003