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By K. Harris, J. B. Wahl

Ni-base superalloy cast materials provide an outstanding balance of high temperature strength, fatigue resistance, oxidation resistance and coating performance and can be produced to very tight tolerances in extremely complex configurations, such as axial and centrifugal integral cast turbine wheels. As a result, cast superalloys are used in the most demanding applications of aero and industrial gas turbine engines. Use of these materials is expanding to smaller microturbine, turbojet, turbocharger and missile engine applications due to this unique combination of desirable properties. This paper will present an overview of the application of investment cast Ni-base superalloys and process capability to small turbine and missile engines.

Jan 1, 2010

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By O. K. Mahabadi, A. Lisjak, B. S. A. Tatone, N. Vlachopoulos

"Numerical simulations are widely adopted in the design of several types of rock structures, including tunnels, caverns, rock cuts, and open pit and underground mines. In recent years, analyses based on the hybrid finite-discrete element method (FDEM) have been shown to provide a realistic representation of rock mass deformation and fracturing processes. To date, the FDEM approach has successfully yielded qualitative and quantitative results for several practical rock engineering applications, yet it has lacked the ability to consider the implementation of rock-reinforcement measures. Since rock reinforcement is often used in civil and mining applications to improve the strength and deformational behaviour of a rock mass, the ability to incorporate such features into FDEM analyses is essential to extend its applicability to a broader range of problems. The work presented in this paper represents an important first step towards developing a simulation tool that can be used for practical rock engineering applications, including the design of underground excavations and rock slopes.INTRODUCTIONRock support and reinforcement measures are often employed in civil and mining rock engineering projects in order to maintain or improve the strength and deformational behaviour of rock masses. The preferred type of reinforcement or support elements along with the preferred layout and timing of installation depend on the in-situ ground conditions, the nature of the rock mass and excavation method. Over the last two decades, numerical modelling has been increasingly used to design and attempt to optimize rock reinforcement and support systems. As such, most rock engineering-specific modelling software now offers various approaches for modelling different rock reinforcement and support elements."

Jan 1, 2015

By G. H. Long, D. H. Magnusson

THE DEFINITION of the continental margin, as considered in this paper, is in the broad sense: " ... those provinces of the continents and of the oceans which are associated with the boundary between these two first-order features of the earth" (Heezen et aL, 1959, p. 17). The provinces in the area under con-sideration are: the Continental Shelf, the Continental Slope and the Continental Rise. The Continental Shelf extends from the shoreline to the shelf break, which lies at approximately the 200-meter isobath through-out the region (except north of the Grand Banks, where the break may be defined more properly by the 400-meter isobath). The Continental Slope and Rise occur between the shelf break and the 4,000-meter isobath. (The last figure was somewhat arbitrarily selected for the purpose of this paper.) The Atlantic Continental Margin as thus defined extends along the eastern coast of Canada from the International Boundary in the Gulf of Maine northward to approximately the 60°N latitude off the coast of Labrador. The area of study amounts to at }east 500,000 square miles -an area roughly equivalent to 13 per cent of Canada's total land surface.

Jan 1, 1970

By M. Rafieazad, P. Fathi, M. Mohammadi, A. M. Nasiri

This study examines the impact of low-temperature heat-treatment cycles on microstructure and corrosion performance of Direct Metal Laser Sintered (DMLS) AlSi10Mg_200C alloy. It is known that the morphology and the size of eutectic silicon are the two most critical factors affecting mechanical properties of the AlSi10Mg alloy. Although high-temperature heat-treatment cycles are common practice for the strengthening of the cast Al-Si-Mg alloys, in the case of DMLS fabricated AlSi10Mg alloy, high-temperature solutionizing and low temperature annealing cycles result in mechanical properties degradation primarily due to a dramatic decrease in the solubility of Si in the super-saturated a-Al matrix of the as-printed alloy. In this study, low-temperature heat-treatment cycles that only promote precipitation of Mg2Si accompanied by the interruption of the silicon network were investigated. SEM and XRD analysis were utilized to observe the evolution of microstructure after different annealing heat-treatments at 200, 250, 300, and 350°C for 3 h. Increasing the heat-treatment temperature contributed to the Si networks interruption and an increased precipitation of Mg2Si phase. Low-temperature annealing from 200 to 350°C was found to promote the homogeneity of the microstructure characterized by a uniform distribution of eutectic Si in ??-Al matrix. Additionally, in order to investigate the impact of different heat-treatment cycles on corrosion resistivity of DMLS-AlSi10Mg_200C, the potentiodynamic polarization testing and electrochemical impedance spectroscopy were performed in a 3.5 wt.% NaCl solution. The results revealed more uniformly distributed pitting attack on the corroded surface by further increase in the annealing temperature, which was attributed to the uniformity of Si dispersion. In comparison, low temperature annealing at 200°C led to a penetrating selective corrosion attack along the melt pool boundaries, resulting in a higher corrosion rate associated with the lower absolute value of impedance of the protective passive film on the surface.

Jan 1, 2018

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By John Stubbs

Sub-Surface Shaft excavation Mine development Headframes Surface Production facilities Product storage and loading Tailings area Infrastructure Discovery Lodge Utilities Operations complex Port Marine loading Rail unloading and storage

May 1, 2013

"This paper presents results of ongoing research being carried out at the University of New South Wales into improved methods for estimating rock mass strength. In this paper the rock mass strength of Hawkesbury Sandstone is assessed. An estimate is first made based on an extensive database of intact rock strength data being collated by the author and the assumption that the rock mass strength can be determined following the GSI approach. The resulting strength envelope is then compared with nine documented case studies where stress induced failure has occurred in tunnels excavated within Hawkesbury Sandstone. The case studies cover a range of conditions:• construction dates from 1880s to 2006• spans from 3.2 to 12.5 m• depths from 17 to 124 m• excavation methods of drill & blast, roadheader and TBM.Finite element modelling is used to assess the likely magnitudes of the stresses present at the time of failure. The finite element models are interrogated to provide the values of major and minor principal stresses in and around the mapped failure zone. Failure and stable points are then compared to the rock mass strength envelope(s) of Hawkesbury Sandstone derived using the Hoek-Brown criterion and spalling criteria. The Hoek-Brown rock mass strength envelope differentiates between the ‘failed’ and ‘stable’ zones remarkably well.INTRODUCTIONStress induced failures of rock masses are fortunately rare in civil tunnelling. However, when they occur they provide an opportunity to calibrate an assumed rock mass strength criterion. This paper compares an estimate of rock mass strength for the Hawkesbury Sandstone with the following cases where stress induced failure occurred in tunnels excavated within Hawkesbury Sandstone.• Cataract & Devines Tunnels of the Upper Canal (Upper Nepean Scheme)• Malabar Outfall Tunnel• Sydney liquefied petroleum gas (LPG) Storage Cavern• Northside Storage Tunnel• Cross City Tunnel• Lane Cove TunnelTwo-dimensional finite element modelling is used to assess the likely magnitudes of the stresses present at the time of the failures. The principal stresses are then compared to the assessed rock mass strength envelope(s) of Hawkesbury Sandstone derived using the 2002 Hoek-Brown criterion (Hoek et al., 2002) and the spalling criterion suggested by Diederichs (2007)."

Jan 1, 2015

By Lang Tao, Jun Wang, Wei Xiao, Wenqing Qin, Pan Cao, Guanzhou Qiu, Key Lab of Biohydrometallurgy of Ministry of Education, Central South University

"The effect of metal cations on the rutile flotation using styryl phosphoric acid (SPA) as the collector was investigated by micro-flotation test, bench scale flotation test, zeta-potential measurements and adsorption measurements. The micro-flotation results indicated that Fe (?) and Al (?) ions in low concentrations had obvious activation on the rutile flotation, and Pb (?) ions in low concentrations had smaller activation of rutile, but Fe (?), Al (?), Pb (?), Ca (?) and Mg (?) have strong inhibition of rutile flotation in high concentrations. The bench scale flotation results indicated ethylene diamine tetraacetic acid (EDTA), boracic acid, and sodium hexametaphospate can decrease the metal ions concentrations, and increase the recovery of rutile flotation. Adsorption measurements and zeta-potential measurements revealed that Fe (?), Al (?) and Pb (?) ions were adsorbed on the rutile surface, and had interaction with SPA. But when these ions concentration were over the largest adsorption capacity, residual metal ions could occur chemical reaction with SPA.INTRODUCTIONRutile is one of the favored minerals for production of titanium dioxide white pigment, primarily through the chloride manufacturing process (Stanaway 1994; Hou et al., 2013) However, the majority of rutile ores belong to refractory ores, while flotation is one of the most efficient methods to separate fine rutile from gangue (Dolbear et al., 1937). With the flotation development, many effective collectors were successfully applied in the oxide ore. Many reviews have indicated that organic phosphonic acid collectors showed good selectivity on oxide ores such as ilmenite and rutile (Bulatovic & Wyslouzil 1999; Liu & Peng 1999).It is inevitable that many types of metal cations are present in ore pulp. These metal cations significantly influence the flotation of minerals. Liu et al. (2015) showed that Ca2+ and Mg2+ could improve the floatability of spodumene at pH 12.5 and 10.0, respectively. The authors proposed that Ca2+ and Mg2+ ions readily form hydroxy complexes (CaOH(l) and MgOH(l)) and precipitates as (Ca(OH)2 and Mg(OH)2) in strongly alkaline solutions. Fan and Rowson (2000) investigated the effect of Pb(NO3)2 addition as an activator on ilmenite flotation and showed that it could improve ilmenite floatability. The addition of Pb(NO3)2 resulted in an increase of ilmenite zeta potential in both weakly alkaline and acidic aqueous solutions. Mehdilo, Irannajad, and Rezai (2015) studied three kinds of ilmenite of different origins and discovered that both Mg and V had a negative correlation with ilmenite flotation, while the Mn content seemed to correlate positively with flotation efficiency. A number of studies have also showed that Fe3+ can improve the floatability of ilmenite (Fan et al., 2009; Nuri, Mehdilo, & Irannajad, 2014)."

Jan 1, 2016

By C. G. Bruce

"ON NOVEMBER 15th, 1950, the Department of Mines and Technical Surveys announced the discovery of vermiculite near Perth, Ontario. The announcement followed nearly a month of study to determine so far as possible the potentialities of the deposit and quality of the material from surface indications. The mineral was identified by the writer in the field among samples submitted by Mr. Arthur Powers of Stanleyville or, September 22nd, 1950. Within a week of the announcement, mining rights to properties covering a major portion of the deposit had been acquired by commercial interests.Hitherto, Canada has had to import her entire requirements of vermiculite. Prospects of .a domestic supply gave promise of considerable benefit to many industries, particularly the building industry, and to the consumer public. Should the deposit •prove large enough there was also the possibility of exporting to centres in the United States.Field and laboratory studies were continued at the Mines Branch during the winter of 1950-51 as opportunity occurred. It is the purpose of this paper to describe the results of these •preliminary investigations, to attempt to present the Stanleyville occurrence in its proper perspective with regard to similar occurrences elsewhere, and to review the salient features of the vermiculite industry.Properties and UsesVermiculite is a hydrated magnesium aluminum silicate. In appearance it resembles mica, having the same micaceous cleavage, but it differs from that mineral in being very soft, pliable, and inelastic. Colours range from black through dark olive-green and brown to almost colourless."

Jan 1, 1952

By P. Mengé

The covering of a hydraulically filled goethite pond is discussed from a geotechnical point of view. The characteristics of the goethite were defined in order to allow a detailed study of the procedure for the construction of the cover on top of the soft material and a verification of the stability of the cover and side slopes after construction. These characteristics and the main results of the studies are given, as well as the experiences and observations made during the execution of the work. Finally, the monitoring plan, during and after construction, is also discussed and some results are given. The 'Design and Construct' contract form was used to allow the contractor to choose the optimum and most economical method to realize the closing of the pond, based on his experience with similar projects. The works were carried out between mid 2003 and the end of 2004. The paper will, amongst others, discuss the special method of working that had to be developed to allow the covering of the whole pond in a relatively short time period, without soil improvement methods such as vertical drains or stabilization by in situ treatment. Fill material was used to establish a platform on top of the soft material so that the cover liner and finishing layer could be installed on top of the fill layer. The 'floating roof' principle was used; subsidences were allowed to occur during the installation of the impermeable top liner and soil cover.

Jan 1, 2006

By J M. Gibbs

Craigmont Mines Limited mine 50,000 tons of ore and waste per day from the open pit at Merritt, British Columbia. An electric-powered "down-the-hole" drill, a diesel-powered rotary drill and two electric-powered rotary drills have been used. All primary drilling, as a result of cost and operating experience, is now performed with two electric-powered rotary drills. Trials with various loading techniques have increased the amount of AN-FO and decreased the amount of commercially prepared slurries used for primary blasting. Approximately 95 per cent of the primary blasting is accomplished with AN -FO, mixed at the hole. Introduction THE Craigmont mine is located near the village of Merritt, B.C., 240 miles northeast of Vancouver. The concentrator has been in production since September of 1961. Craigmont is a combined open-pit and underground operation. To date, slightly more than 95 per cent of the mill feed has been mined from the open pit. As underground development proceeds, the ore requirements from the open pit will decrease. The average milling rate from September, 1961, to April, 1964, was approximately 4,900 tons per day.

Jan 1, 1965

By Sazol Das, Hany Ahmed, Ganesh Bhaskaran, Zhuoru Wu

"Friction stir welding (FSW) process in lap configuration for dissimilar materials has been developed and tested for steel to aluminum joining. A novel cylindrical tool was designed for improved material flow. The joining of steel to high strength 5xxx and 6xxx aluminum was carried out by FSW technique using optimized process parameters. The microstructure, micro-hardness, joint strength and corrosion properties at the weld interface have been investigated. Optical and scanning electron microscopy reveled a well layered structure at the interface and lap shear tests of the welds showed excellent fracture resistance. Neutral salt spray tests for up to 500 hours (ASTM B117) were carried out on the bare steel to aluminum FSW joints, which did not show neither evidence of corrosion at the weld interface, nor any degradation of the weld strength. The FSW lap configuration was applied to prototype commercial vehicle structural component whereby a steel stiffener insert was friction stir welded to high strength 6xxx aluminum alloy. The interface microstructure showed layered root without any steel shattering in aluminum side. A finite element study was carried out to quantify the benefits where it was found that the stiffness increases by 76% under bending loads and 36% in torsion loads.INTRODUCTION Energy preservation and environmental issues, namely carbon footprint and legislation around emission in transportation industries has led to a growing need to use of lightweight materials such as aluminum and magnesium alloys along with various grades of steel in structural application, while still maintaining their strength and crashworthiness. Assembling dissimilar materials within integrated structure is thus a stringent requirement related to optimum performance. In order to achieve an efficient technology of joining dissimilar materials such as aluminum to steel, it remains difficult to select an effective welding process for a given joint configuration. The use of aluminum in transportation industries for structural component is not exclusive in a design and is almost always used along with various steel grades for a mixed materials solution, thus dissimilar aluminum/steel lap joining is of great interest since this is widely used in the assembly of parts (e.g. pillar, frame rails, chassis, body in white (BIW), CAB, etc.)."

Jan 1, 2018

By W. N. Wallinger

The mine and concentrator of Cyprus Anvil Mining Corporation are situated in south-central Yukon, some 120 miles north of Whitehorse. The large lead-zinc concentrator employs conventional crushing and grinding , followed by differential flotation, to produce selective lead and zinc concentrates, as well as a mixed lead-zinc (bulk) concentrate. Since the commencement of operations in 1969, the concentrator has undergone expansions and modifications which have increased the capacity to 10,000 tons per day, and afforded some metallurgical improvements.

Jan 1, 1978

By Jianwen Yang, Yucai Zhou, Yanhong Dong, Daixiong Chen

"The study of combined depressants for flotation separation of lead from copper has been carried out to solve the copper-lead separation problem. Test results show that the depressant of CMC (Carboxyl Methyl Cellulose) or sodium sulfite plays an important role on the selective depression of galena flotation. When the two reagents above are combined, the selective depression effect on galena is further enhanced. When the mass ratio of CMC to sodium sulfite is 1:4, galena was best depressed, with the lowest lead content in the copper concentrateClosed-circuit tests indicate that under a certain pH value of the slurry, with the best ratio of CMC to sodium sulfite as depressants, the copper concentrate with the grade of 28.23% copper and 4.12% lead is obtained, and the copper recovery is 84.87%; the lead concentrate with 68.12% lead and 0.86% copper is obtained, and the lead recovery reaches to 92.20%. An efficient separation of copper and lead is achieved with the combined depressants. INTRODUCTIONComplex copper-lead-zinc sulfide ore is abundant in China. With the rapid increase of mineral consumption, it has become one of the important sources to produce copper-lead-zinc metals. However, it is difficult to achieve effective separation of copper and lead, due to the complicated ore properties, such as fine dissemination, low copper grade, complex symbiotic relationship and similar floatability of copper and lead.Poisonous reagents of bichromate and cyanide are often used as depressants for copper lead separation. They have good separation efficiency, but pose serious pollution issues. As the environmental protection is becoming more and more important, it is a trend to replace traditional toxic reagents with new nontoxic efficient chemicals. Organic depressant FCLS studied by Liu has strong selectivity against galena, and does not depress chalcopyrite. A new type of galena depressant of CLS-01 discovered by Jin-lin Yang shows good results in the separation a mixed copper and lead concentrate. In addition, dextrin, chitosan and some other natural organic compounds (Drzymala, 2003; Huang, 2012; Qin, 2013) have also been studied to separate copper and lead."

Jan 1, 2016

By R. K. Rajamani

Discrete Element Method simulation of charge motion in ball, SAG and autogenous mills has become a standard for design of mill internals, power draft evaluation, etc. Both two-dimensional and three-dimensional codes are being used. The two-dimensional code dominates the user market since the code completes a simulation in one or two hours. On the other hand, three-dimensional codes have been in the domain of specialists who can handle the complexity of the code and have access to parallel computing hardware. For the first time, this barrier is overcome via computing with graphic processing units (GPU). Commodity graphics cards now allow parallel computation with hundreds of processors. It is shown that the computational time has been reduced by a factor of fifty using GPU computing. Hence, SAG charge simulation results in three dimensions are achievable in a few hours using affordable desktop machines. The GPU computing shown here enables the three dimensional simulation into a manageable daily task for mill designers and researchers. On the technical side, the simulations can be elevated to a higher level of complexity to simulate breakage and transport. First, the speedup factor of fifty is established for the Nvidia GeForce GTX 580 graphics card. Next, four simulation tasks, consisting of AG, SAG and ball mills are reported. The simulation of AG and SAG mills are completed in less than 8 hours. The ball mill simulation with 1.25 million spheres is completed in 27 hours. In the near future, as the graphic card hardware advances the compute time can be halved.

Jan 1, 2012

By B. M. Currell, M. J. Neate, P. W. Bowden

Historically the hydrogen fluoride laden fume emitted from the electrolytic cells in the aluminium reduction process is further treated in pulse jet dust collectors. These dust collectors act as dry scrubbers performing two duties: adsorbing the gaseous fluoride emitted from the cells onto alumina dust; and collecting the alumina dust minimising particulate and fluoride emissions to the environment.Patented StarBag (TM) technology has been used in aluminium smelters in Australia as a means of increasing the dust collection and fluoride scrubbing capacity of existing collectors. This technology provides an alternative to major capital equipment upgrade where increased capacity is required, and potentially lowers the production cost per tonne of aluminium where capacity limitations are being realised and production expansion is required. This paper presents the findings of on-site pilot scale, and full production scale comparative tests, highlighting the operational and variable differences observed utilising the Star-Bag(TM) technology at Boyne Smelters Ltd in Australia. The results illustrate how this technology can be utilised to increase the hydrogen fluoride scrubbing efficiency and dust collection capacity of existing capital equipment.

Jan 1, 2006

"The Waite-Amulet, an important copper-zinc mine, lies astride the Duprat-Dufresnoy township boundary about 8 miles northwest of Noranda, Quebec. It is an amalgamation of two properties, that of the former WaiteAckerman- Montgomery Mines to the north and that of Amulet Mines, Limited, to the south. This amalgamation took place in 1933. The description that follows is confined to the Amulet section.Ore was first discovered on the Amulet property in the autumn of 1924. The C Shaft and Upper A orebodies were found in 1925 and the F orebody in 1929, the latter by diamond drilling under a swamp. Under the present management, Lower A ore body was discovered by diamond drilling at a depth of 700 to 1,200 feet in 1938, and new ore was found from the old C Shaft workings between 1943 and 1945.From April 15th to October 20th, 1930, 60,291 tons of ore was produced from the Amulet. During the second half of this period, the ore averaged 4.2 per cent copper, 16.3 per cent zinc, and 0.02 oz. gold and 3.35 oz. silver per ton. Due to the prevailing low prices of metals, there was no further production until July, 1937. Output was greatly accelerated in 1940 when the newly found Lower A orebody assumed the main burden of production. Up to January 1st, 1946, mill reports indicate the treatment of the following ore: GENERAL GEOLOGYFig. 1 shows the geology of the entire property. To the east is the Lake Dufault granodiorite stock and to the west the Flavrian Lake granite mass. Around the granodiorite and separating the Waite from: the Amulet section is an older diorite intrusion. The ore occurs in a series of lavas that form a broad anticline pitching eastward at a relatively low angle into the Lake Dufault intrusives. There are several steep east-west faults. The late Powell diabase dyke is shown, also the general areas of strong dalmatianite alteration, a type closely associated with the sulphide mineralization."

Jan 1, 1954

By D. Yu, T. A. Utigard, M. Barati

"Sulfation roasting of nickel concentrate to generate water-soluble metal sulfates was investigated as an alternative process to smelting for the recovery of valuable metals. The kinetics of dissolution of various species of the calcine in three leachants was studied; hot water, dilute HCl, and concentrated HCl. The results indicated that dissolution of sulfates by hot water at 90 ºC is achieved within 30 minutes. In order to increase the recovery of the valuable metals, acid leaching is necessary due to the existence of ferrite in the calcine.INTRODUCTIONInvestigations on the sulfation roasting of nickeliferous sulfide ores or concentrates were mainly carried out in 1950’s to 1990’s to generate water soluble non-ferrous metal sulfates followed by metal recovery by leaching (Stephens, 1953; Thornhill, 1954, 1961; Fletcher and Shelef, 1964a, 1964b; Fletcher and Hester, 1964; Frankiewicz, 1977; Norrgran, 1983). Commercialization of the sulfation roasting process was only performed by Falconbridge Ltd. (Thornhill, 1961; Boldt, 1967), which employed a sulfation roast process on nickeliferous pyrrhotite at 680 oC where Ni, Cu, and Co were leached and Fe2O3 was produced for the iron industry. In 1965, 118,342 tons of pyrrhotite was processed, however because of the huge SO2 emissions (no acid plant) relative to the nickel production and the poor economics, this plant was shut down.Nickel production from sulfide ores via pyrometallurgical means, especially the electric furnace smelting process, is a major emitter of SO2 to the environment and a big energy consumer (Warner, Diaz, Dalvi, Mackey, Tarasov and Jones, 2007). Nowadays, due to the more stringent environmental regulations as well as the need to reduce energy consumption, metal production by sulfation roasting is gaining more attention as an alternative process to smelting. The main focus of this paper is to investigate the extent and rate of leaching of valuable metals from the sulfation roasted nickel calcine, aiming to maximize the metal recovery and minimize the dissolution of iron species."

Jan 1, 2012