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By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By Y. Zedan

In this study, the statistical design of experiments (DOE) was applied to study and regulate the properties of near-eutectic Al-11%Si alloys. Develop regression equations for such response variables as hardness, yield stress, ultimate tensile stress, percent elongation, total cutting force, cutting power, and tool life together with other factors which, include the percentage composition of the alloying elements, and the requisite modification (Sr) level. These equations may be analyzed quantitatively to acquire an understating of the effects which the main variables and their interactions may have on the mechanical behaviour and the machinability of the alloy under investigation. The results reveal that increasing the levels of Cu and Fe content results in an increase in hardness, yield stress, and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the percentage elongation adversely, whereas the Sr-level has a positive effect on this parameter. It was found that Sr-levels have the most significant effect on the cutting forces and cutting power followed by the content in Fe and Cu. The results also reveal that the interaction coefficients of these variables have a significant effect on tool life compared to the main independent variables. This fact may be attributed to the formation of complex insoluble phases between Cu, Fe, Si, and Al as investigated using Scanning Electron Microscopy (SEM) attached to an EDX analysis system. The accuracy of the regression equations in predicting the expected properties has been verified by carrying out random experiments in the range of variation of these variables.

Jan 1, 2011

By R. Bainbridge

"IntroductionTHE LEAD SMELTING Department of The Consolidated Mining •and Smelting Company of Canada, Limited (Cominco), at Trail, B.C. treats materials from numerous sources for the recovery of lead, •and, of secondary importance, for the .recovery of sulphur as S02• The Department's sintering section has a .capacity of 1,500 tons daily. This section is being replaced by •a new charge-•handling and sintering plant with a daily capacity of 2,000 tons of finished sinter. Materials handled in the sintering section comprise concentrates, ores, and fluxes from Company mines and from 'custom' (independent) producers, together with intermediate products from various plants of Cominco'•s Metallurgical Division, all of which must be treated to, make up a chemically balanced charge of a predetermined lead content for the sintering plant.As received, 80 •per .cent of these materials are finer than 200 mesh, and one-quarter of the tonnage (dry basis) is a slurry .at 30 to 40 per cent moisture. This slurry, a -residue from the electrolytic zinc operation, was, for many years, partially dried before being mixed with other dry materials to make up the sinterplant charge.Some experimental work carried out in 1937 indicated that the metallurgy of the sintering operation could be improved by adopting a technique of 'wet-mixing' followed by controlled drying and nodulizing."

Jan 1, 1953

By G. A. Pinsky, Pickard M. K

"IntroductionTWO METHODS of mucking have been used in sinking C shaft, the five-compartment production shaft of the Yellowknife property of Giant Yellowknife Gold Mines, Limited:(a) Band mucking during the original sinking in 1949 and 1950 (l); and(b) Mechanical mucking with the Cryderman shaft mucker during the recent deepening in 1954.This paper briefly describes the recent deepening and compares the performance figures of the two sinking operations.PlanningProduction planning in 1952 showed that it would be advisable to deepen C shaft in 1954 to provide for three new production levels and the installation of an underground crusher. To complete the required shaft work it would be necessary for a shaft crew to deepen the shaft about 500 feet, to partly excavate three level stations and a crusher station, and to cut a station for the loading pocket. Figure 1, a vertical section of the lower part of the shaft, shows the details of the deepening programme.During the planning period, Giant had a rather small supervisory staff and at the same time was experiencing a heavy labour turnover. As it was obvious that production would suffer if the sinking crew were recruited at the mine, it was decided that the merits of contracting-the shaft sinking to an independent contractor should be investigated."

Jan 1, 1955

By R. White, C. Doyle, B. Martin, C. Díaz, J. Hrepic, G. Cuthbert

"A program initiated to improve the service life of the magnesite-chrome refractory in the top blown rotary converters at INCO’s Copper Cliff Nickel Refinery identified slag corrosion as a major wear mechanism. Target slag compositions were established to produce a non corrosive slag. A plant program to achieve this target slag by the addition of controlled amounts of do lime and MgO was instituted. Addition to rates of the slag modifiers was optimized based on the slag composition assays achieved and the requirement to address corrosion effects on the high alumina content ladle refractory. A60% gain in TBRC refractory performance was eventually achieved and has been maintained yielding a net annual savings of $700,000. A significant gain in available converter operating time has also been realized.IntroductionINCO’s Copper Cliff Nickel Refinery utilizes two top blown rotary converters (Fig. 1) to smelt a blend of semi-refined nickel concentrates, producing a granulated nickel matte suitable for the adjacent carbonyl based nickel refining operation. The converter, or TBRC, operation is a batch process composed of feed charging and melting, oxidation of the excess sulphur in the matte, and reduction of residual nickel oxide. The final matte, containing about 78% nickel, is tapped at 1600°C from the converter and is granulated in a sluice equipped with high pressure water jets."

Jan 1, 1997

By Jamal Jafari, Abbas Sam

"The concentration of the fourth production line at Golgohar includes 66% iron with Blaine number of 500 cm2/g. For pelletizing process, the feed iron grade should be greater than 68% with minimum Blaine number of 1800 cm2/g. In this study, the low intensity magnetic Separators, particularly the feed particle size distribution of LIMS were considered. The feed particle size distribution of the separators was optimized to prepare an appropriate concentrate (as mill pelletizing feed). The samples were performed from the LIMS feed and after grinding, four d80 (64, 103, 132, and 15 3µm) were prepared. Then, laboratory magnetic separation experiments were conducted on these samples. The best results obtained using d80 of 132µm. In this particle fraction, the iron grade and Blaine number were 70.3% and 1571 cm2/g, respectively. Therefore, it seems necessary to include a grinding and classification systems before LIMS stage. According to the presence of a high amount of -132 µm particles in the initial feed, an inverse closed circuit was selected. The hydrocyclone was designed in three units as the classification system with 62 cm (diameter), 22 cm (overflow outlet) and 11 cm (apex diameter). By simulation of hydrocyclone with USIMPAC software, the size distribution of underflow was determined. Based on these results, a ball mill with dimensions of 6.7 m (length) and 5 m (diameter) was designed as grinding system.INTRODUCTIONGole-Gohar iron ore concentration plant No.4 (Polycom Plant) in Gole-Gohar Industrial and Mining Complex was installed to increase production capacity as well as treating the circulating load from AG and SAG mills of the main concentration plant of the complex. The load from the mine is crushed using jaw and cone crushers. The crushed ore is then combined with the circulated load and the combination is then grounded using HPGR and ball mills respectively.After comminution, there is a magnetic separation plant which includes a medium intensity magnetic separator (MIMS) followed by three low intensity magnetic separators (LIMS). Final concentrate dewatering is done using three belt filters. After the primary magnetic separation, the ore is upgraded to 62% Fe content and final concentrate which is the product of LIMS has 66% Fe content."

Jan 1, 2016

Concentrator Improvements -1990-1995Back to Basics ?pilot plant versus plant opportunities identified ?understand process fundamentals & baseline -1996-2000Point ?C?Projects ?strategy to improve global competitiveness ?structure implemented to generate & drive ideas ?capital investment for life of mine asset renewal - 2001-200?Six Sigma Methodologies ?emphasis on data, measurements & analyses ?dedicated, highly trained personnel on projects 1990-1995 Improvement Phase??Philosophy??back to basics?approach?understand what each piece equipment needed to do?understand reagents, control variables?confirm operating strategies ??probe, stabilize, institutionalize??test theories, confirm with lab and plant trials?process stability (equipment reliability, controls)?enhanced operator guidelines, operator training?focus on continuous improvement?optimize existing equipment capability?stop looking for ?magic?solutions 1990-1995 Improvement Phase??Technical?finer grind, same equipment?optimize media size/shape to grinding application?balanced available ball mill power to applications?lowered cyclone feed densities where possible?improved selectivity, same equipment?balanced available cells to applications?streamlined process (eliminate process steps)?added cleaning stages where required?understanding pulp/mineral surface chemistry?lowered flotation pulp densities 1990-1995 Improvement Phase??Effort?numerous studies to understand process?liberation and mineralogical characterization?pulp and mineral surface chemistry?flotation kinetics and entrainment?extensive internal and external manpower?Brunswick, Noranda Technology Centre?CanMet, AMTEL, MinnovEx, Lakefield Research, McGill University?small capital expenditure

May 1, 2002

By J. M. Harrison

FIELD PARTIES of the Geological Survey of Canada have, in recent years, mapped several areas east and northeast of Flin Flon (9, 10, 12, 13, 14, 15, 118) (1). In all these areas the mineral deposits show a close geographical relation to faults although the immediate control of most of the known ore deposits appears to be folded structures in the rocks (8, 11, 18, 19). Air photographs and published geological maps were studied in order to ascertain whether or not the mineral deposits in the Flin Flon-Snow Lake mineral belt as a whole show any spatial relationship to faults. It was found that most of them do show a distinct geographical association with faults, or with topographic features that may be faults. It is further apparent on air photographs that a major lineament, for composite of lineaments, follows approximately the contact between gneisses and schists of the Kisseynew complex on the north, and Amisk volcanic rocks on the south. However, this Kisseynew lineament is not continuous and, especially in the eastern half of the district, it is exceedingly irregular in plan. Parts of this lineament have been mapped as faults (9, 10, 12, 14), other parts have been shown as stratigraphic contacts (1, 2, 21, 27), and still other parts have not been studied except by reconnaissance methods. It is suggested that the Kisseynew lineament may be due to a deformed fault that extends easterly from a point about 25 miles west-northwest of Flin Flon to a point at least 10 miles northeast of Wekusko lake and that the mineral deposits.

Jan 1, 1951

By W. Graham

"IntroductionEFFLORESCENCE is herein considered to be any deposit of salts on the surface of a masonry structure that is brought from within or through the structure by capillarity and deposited by evaporation. Usually, efflorescence is white although green, yellow, and brown efflorescence is sometimes observed.The common white efflorescence almost always consists of sulphates of the alkali and alkaline earth metals and calcium carbonate, although sodium chloride is frequently present in structures erected near the sea shore.The first and most obvious result of the presence of soluble salts in masonry is the unsightly accumulation of these salts on the surface. This is particularly noticeable early in its life and is frequently fugitive ( 1), as much of the salt is soluble and is gradually washed away by rain. This removal can usually be facilitated by scrubbing; the structure with dilute hydrochloric acid.A more serious effect is the continuous accumulation of soluble salts as a result of ingress of sulphur acids in rain water or water from the ground. This may eventually cause spalling and disintegration by crystallization of salts in the pores of brick and mortar. An example of this type of failure, resulting from the crystallization of calcium sulphate, is discussed by Hardesty (2). Butterworth (3) describes similar failure resulting from •crystallization of magnesium sulphate."

Jan 1, 1954

By S. Steinlechner, G. Schneeberger, J. Antrekowitsch

The recycling of steel mill dusts is getting more and more important. The costs and requirements of land filling are rising and companies are interested in new recycling strategies. The rising of sustaina¬bility hand in hand with the high rate of valuable metals in these residues supports new research activities on the recycling sector. Especially zinc but also iron and lead are economical factors due to the treatment of steel mill dusts. This paper gives a small overview of fundamental studies concerning the chemical and physical composition of these dusts. Furthermore aggregates for the reduction of these dusts in the liquid phase are introduced and compared. The Flash-Reactor, the TBRC-Technology (Top Blown Rotary Converter) and submerged arc furnaces and there use for melting and treatment of these dusts are in the center of interest of this paper. The final conclusion gives an overview of possibilities for reduction of filter dusts in the liquid phase.

Jan 1, 2011

By Daniel Gendron, Luc Morin

"Concentrate sampling is a growing concern in the world's mining and smelting industry. The main modes of transportation for concentrate to the smelter are by truck or rail car in a bulk form, thereby limiting access to sample extraction equipment. In many cases, concentrate is shipped to a smelter by several suppliers therefore requiring individual manipulation of different customer samples in a safe and reliable manner. The Heath & Sherwood Bulk Product Sampler offers this feature as well as an economical and effortless way of obtaining samples in rail cars or truck boxes.In 1994, Noranda Metallurgie in Rouyn-Noranda, Québec purchased a self contained Bulk Product Sampler to extract samples directly from inside rail cars before unloading the concentrate. After testing and comparing the results with the conventional sampling method, the bulk product sampler proved to be a practical and advantageous solution for concentrate sampling both for the customer and smelter. Since its installation at the Horne smelter in Rouyn-Noranda, the Bulk Product Sampler has been steadily used on rail cars which contain concentrates from around the world."

Jan 1, 1996

By R. Blazej

Machinery Systems Division (MSD) in the Institute of Mining Engineering at Wroclaw University of Technology specializes in belt conveying systems analyzing, calculating and design. Within the division operates the certified Laboratory of Belt Transportation (LTT) and Laboratory of Rollers. Since few years, a group of several people have begun work on developing a comprehensive system for the automatic evaluation of condition of conveyor belts working in the mines. Group uses both magnetic devices developed by specialized companies servicing belts and its own machine vision system developed for assessment of belts covers and edges during belt movement (up to 7 m / s) on the specially designed for this purpose the test conveyor. Recently they have got the research grant funded by the National Centre for Research and Development (NCBiR) for development of the system for automatic diagnosing of conveyor belts? condition and aiding of rational belt management. On the basis of previously created diagnostic tool called ABCDE (Automatic Belt Condition Diagnostic Equipment) the five modules: vision-A magnetic-B, preventive-C, forecasting?D, and determining safety factor-E will be developed. They will automatically interpret data about conveyor belts? condition to indicate the extent and timing of repairs, to prevent failures and to select the optimum moments for their replacements. The system will use results of ongoing research & development and planned research concerning modeling of belt wear using evolutionary genetic algorithms. The reached stage of research can not yet allow to start the implementation work by potential users. It is therefore necessary to pursuit research in real scale, the development of new modules (C-E) and intensive testing of the system in working condition with system calibration to optimize the economic effects.

Aug 1, 2013

By B. R. Maas

Processing material at a consistent rate through the continuous countercurrent decantation (CCD) thickeners presented a major bottle neck to unlocking additional value from one of the post-flotation streams at the Kansanshi processing plant. The manual operation of the thickeners making up the CCD train resulted in frequent imbalances and process upsets across units. The automation of CCD trains is notoriously tricky as the available manipulated variables are outnumbered by the parameters requiring regulation. The implementation of an advanced, auction-based, control philosophy to manage the movement of both slurry and solution inventory through the train addressed this parameter imbalance and lead to the stabilisation of the circuit. Since the commissioning of this control strategy: an additional 7 200 dmt/day (+36% throughput) of material can reliably be processed through the train, the number of monthly downtime events has reduced, and a saving of $354 000/month in reagent cost has been achieved. INTRODUCTION CCD operation Agitated leaching is a common method used in hydrometallurgy to extract a metal from its host ore. The host ore is initially finely ground to liberate the surfaces of the valued minerals and improve the kinetics of the leaching process. The ore is then contacted in an agitated tank with a lixiviant to dissolve the desired metal into the aqueous phase. The resultant slurry from the leaching process comprises of a solution pregnant in the metal salt and a barren ore. The first purification step taken after leaching is to wash the pregnant liquor solution (PLS) from the depleted ore. On the industrial scale, a set of between two to ten thickeners arranged in a countercurrent configuration is often used to carry out this separation (Perry & Chilton, 1973). The slurry is introduced at the head of the train and a wash solution at the tail. The two streams are pumped through each thickener countercurrent to one other. At each stage the residual PLS in the slurry is mixed and diluted down with the countercurrent overflow solution from the downstream thickener. The diluted slurry is fed into the thickener where the solids separate out through gravity sedimentation. The settled solids are channelled towards the underflow of the thickener by a rake mechanism and pumped downstream to the next thickener in the train. The outcome is the recovery of a PLS from the overflow of the lead thickener and a slurry of washed solids from the underflow of the tails thickener.

Jan 1, 2019

By G. H. McKay

AT the Eagle mine, near Gilman, Colorado, where the Empire Zinc Company have installed an underground mill, transportation problems were comparatively simple. A railway siding on the Denver and Rio Grande railway is equipped with an unloading dock or platform at the portal of their service incline adit to the mill. This 18-degree incline is approximately 600 feet long from the unloading track to the head of the mill skipway. For the Big Missouri mill, upwards of 2,500 tons of material and equipment had to be trucked from tidewater at Stewart, B.C., a distance of 21 miles to the Big Missouri camp at elevation 2,800. From that point, this freight had to be moved either over or through the Big Missouri ridge, rising to elevation 3,450, to its final location 800 feet from the surface between elevations 2,150 and 2,350. Immediately after leaving the government dock at Stewart, the road crosses the International boundary line into Hyder, Alaska, and then follows a water grade for eleven miles along the lower stretches of the Salmon river. leaving the river, the road climbs for two miles before crossing back into British Columbia territory at Silver Heights, and then continues for another mile and a half to where the Big Missouri road branches off from the main road to the Premier mine. For a distance of four miles from the junction of the roads, the Missouri road is very narrow, with many sharp curves and with irregular up and down pitches and grades up to 25 per cent until it reaches the Summit. From there on, a fairly easy grade leads a mile and a half to the end of the road on Joker Plats. In winter, the last stretch of road is subject to heavy snow drifting, especially through a narrow funnel-shaped gulch, known as 'The Gap', where the snow may pile up to a depth of over twenty feet.

Jan 1, 1938

By M. Goto, F. Kubota

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."

Jan 1, 2012

By Gordon E. Forward

Sustainable development in the mining and metallurgical industrial sectors can be implemented by two distinct groups: 1. The managers and operators of existing facilities ? working with industrial processes and systems that have been operating for many years, in some cases several decades 2. Those who are engineering and building new facilities or upgrades of existing plants. The focus of this paper is to look at approaches and tools available to bring sustainable development thinking and action to these two distinct areas. The paper will discuss: 1. The concept of working with existing facilities and processes to minimize waste and maximize product from a regional raw material/resource consumption perspective using By-product Synergy. The BPS concept has been carried out in Texas (TXI-Chaparral?s STAR Example), in Calgary, Alberta with Suncor assistance, in Montreal, Quebec with Noranda as project leader and currently in Ontario with Dofasco as industry champion. Successful outcomes are presented. 2. A new approach to designing greenfield facilities or upgrades to existing plants using a sustainable development review process. Undertaking the review early in every project can institutionalize the concept of discussing and implementing waste elimination, design for environment, eco-efficiency, risk minimization and community awareness and involvement in the future capital stock. The review process has been developed as an excellent tool for measuring and reporting on a corporation?s sustainable development progress. Examples of how this approach has been adopted in the mining and metallurgical industry, and the resultant outcomes are given.

May 1, 2002

By T. H. Etsell, P. Kerr, Qi Liu

"The objective of this investigation was to study the reaction mechanisms during the reduction of iron oxides in the presence of calcium chloride and carbon black as a simplified iron segregation process. The gas phase was analyzed by mass spectroscopy and the solid reaction products were analyzed by scanning electron microscopy. Mass spectroscopy, combined with thermogravimetric analysis and differential scanning calorimetry, revealed the presence of several gases at elevated temperatures over time, and the scanning electron microscope in combination with energy dispersive X-ray analysis illustrated the growth of a metallic iron phase on or near the carbon substrate. The results correlated well with similar copper and nickel segregation processes, but also introduced new insights that challenge the simplicity of the current models. The formation and transport of gaseous iron species to the carbon substrate in the presence of steam and hydrogen were evident during the reduction process that was studied; however, there is more happening at a mineralogical level, based on evidence of a liquid phase resulting in substantial growth due to an apparent fluxing effect created by the calcium chloride.These results help to better explain the chemical reactions and, in turn, the thermodynamics and kinetics of iron segregation processes related to the beneficiation of low grade complex iron ores. The results are also applicable to the production of metallic iron and concentrated titanium dioxide from ilmenite ores. The benefit of this process is that it allows ores in which the iron minerals are intimately associated with gangue minerals to be processed in circumstances where conventional mineral processing techniques are unsuitable or incapable of upgrading the material."

Jan 1, 2016

By L. T. Loe, A. S. Norsk, Mo i. Rana

High production rate and good stability demand the optimization of all phases of electric pig iron smelting. This is important with respect to slag chemistry, which to a large extent regulates the process temperature in electric smelting. Controlled basicity and slag volume. and a satisfactory screen analysis of the reduction material and sinter, are of the utmost importance for smooth furnace operation. Large variations in slag volume and in B/ A and C/Fe ratio will have an influence on the furnace resistance and thus the specific energy development in the furnace, which lead to variable reduction of SiO.. The result will be variable hot -metal quality and un-stable furnace operation.

Jan 1, 1970

By A. Zangooi, J. A. Finch

"A frother analysis technique based on the formation of a colored solution with UV-VIS absorbance proportional to frother concentration over a certain range has been developed. The calculation of concentration requires the comparison of the sample absorbance at a selected wavelength with a linear calibration (frother concentration vs. absorbance) constructed with values collected from solutions of known concentration (standards) at the same wavelength. It has been found that concentration ranges for preparation of standards can vary widely. An integration of our experiences into a databank can offer some guidance on the selection of standard concentrations. The databank includes results from the analysis of 37 chemical reagents, commercial frothers, and natural oils used in research work or at industrial sites. Grouping frothers by similar chemical structure or origin provides a good basis for selecting the standards to approach the maximum absorbance range for the spectrophotometer in use.INTRODUCTIONA technique to determine frother concentration on samples of industrial milling streams based on formation of a colored solution with UV-VIS absorbance proportional to frother concentration has been developed. The concentration is determined by comparison of its absorbance, at some selected wavelength, with those obtained by processing a series of solutions of known concentration (standards), at the same wavelength. It is desirable to have linear calibration (frother concentration vs. absorbance) over the widest concentration range. The upper concentration can be restricted by the instrument, as there is a maximum detectable absorbance (minimum transmittance), which can be reliably sensed by the UV-VIS detector (in most cases maximum absorbance is 3)."

Jan 1, 2016

By J. P. Harrison, G. F. Gambino

"This paper examines unpredictability in the parameters governing hydraulic fracturing (HF) as used in stress amelioration for underground excavations, with the aim of showing how this unpredictability may affect design decisions. Using uncertainty models that are appropriate to particular levels of information and degrees of uncertainty, this paper demonstrates how these can aid in decision-making related to feasibility assessments of HF arrays for stress amelioration.Cave mining operations produce large underground voids and high stress concentrations around critical mine locations. These stress concentrations increase the potential for rock burst events. Although de-stress blasting has a long history for redistributing high stress concentrations, to improve safety and reliability HF is now being trialled as an alternative.Unfortunately the HF process is extremely uncertain, and so predicting fracture propagation geometry is difficult. Although the major parameters governing HF propagation have been previously identified, no indication has been given regarding the contribution that uncertainty in these makes to unpredictability in the overall HF system. Using simplified models of HF and referencing a recently proposed characterization of unpredictability, we relate unpredictability in the various governing parameters to the effect it has on strain energy density (SED) in the surrounding rock. Within these models we analyse SED as well as the stress intensity factor (KIc) when investigating the effect of parameter uncertainty and its influence on various crack propagation criteria (Sih & Macdonald, 1974). These models are applicable to unpredictability associated with the development of new fractures; the case of pre-existing fractures is the subject of on-going work.The paper will assess in greater detail the various governing parameters, and investigate the appropriate use of other uncertainty models. As a result, we will show how assessment of uncertainty in HF parameters can be used to both guide feasibility studies and determine the optimal allocation of resources to improve the final design."

Jan 1, 2015