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By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

By J. Dong

"A “green” collector project has been initiated at Vale Base Metals Technology Development to replace xanthate. Bench and miniplant testwork showed comparable metallurgical results between xanthate and DTC (sodium dibutyl dithiocarbamate), a “greener” collector. During the first DTC plant trial, a strong interaction between the process water and DTC negatively impacted the metallurgy. The subsequent investigation showed that the quality of process water including suspended solids and dissolved metal ions had a significant impact on the performance with DTC, while less so with PAX. This paper explains these differences using UV spectrophotometry and batch flotation tests. INTRODUCTIONVale Base Metals is dedicated to sustainable mining and mineral processing. One of the key activities is to find a “greener” collector to replace xanthate (PAX: potassium amyl xanthate), which decomposes during storage and flotation causing CS2 emissions in the work place. As the most promising candidate, DTC (sodium dibutyl dithiocarbamate) was evaluated in the lab and miniplant (Dong & Xu, 2011). Consequently, a plant trial was conducted in the winter of 2010. However, the results were not as good as expected. The subsequent investigation showed that the quality of process water played a significant role in the metallurgical performance with DTC but less so with xanthate.From test work in 1996 and 1997, a series of batch tests were performed at Clarabelle Mill to investigate the winter/summer metallurgical shift with xanthate. As shown in Figure 1, the winter metallurgy was considerably worse than the summer metallurgy (Xu & Wilson, 2000). At 80% pentlandite recovery, the concentrate (Cu+Ni) grade was 21% in the winter and 26% in the summer. At 23% (Cu+Ni) concentrate grade, pentlandite recovery was 85% in the summer and 70% in the winter. In the summer, the process water is much cleaner, with very low concentrations of dissolved metals ions and suspended solids; while in the winter, the water is yellow and cloudy, with much higher suspended solids. Based on these results, it was concluded that the process water in winter has a detrimental impact on metallurgy."

Jan 1, 2012

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By Stefan Planeta

On discute les performances techniques et économiques des méthodes d'exploitation à haut rendement dans les mines métallifères au Canada. L'accent est mis sur la dilution et pertes des réserves minières et sur les coûts opératoires et totaux. Une analyse technique de quelques opérations minières est également effectuée. Il ressort de cette analyse que les résultats réels des opérations minières en cours diffèrent souvent de ces planifiés suite à la dilution du minerai et aux pertes importantes des réserves minières. On propose, définit et discute un certain nombre des facteurs de performances technologiques et économiques pour pouvoir mieux apprécier les problèmes rencontrés dans plusieurs mines en opération. À l'aide des études de cas on démontre impact négatif de la dilution et des pertes additionnelles des réserves minières sur la rentabilité des opérations en cours et sur les nouveaux projets miniers. On conclut, que l'application des indicateurs proposés donnerait un outil valable, aux opérateurs miniers, aux niveaux de la planification, du suivi des travaux d'exploitation et d'éventuelles études comparatives entre les différentes situations minières. ABSTRACT The paper discusses technical and cost performance of bulk mining methods in Canadian U/G metal mines. It focuses on ore dilution, ore reserves losses as well as on operational and total cost. Technical analysis of some mining operations has been performed. It indicates that due to dilution and significant reserves losses, the actual results of mining operations often differ substantially from those planned. The paper proposes, defines and discusses several indicators quantifying technical and economical performance in order to assess better the problems encountered in several operating mines. The case studies presented here have demonstrated an adverse effect of dilution and additional reserves losses onto profitability of existing operations and new mining projects. It is concluded that the application of the above mentioned indicators may be beneficial for mine operators. They may become a very useful tool at the stages of planning, follow-up of mining works and with regards to comparative studies between different mining situations.

May 1, 2001

By P. Scinto, P. Hudson

"Modern day ore bodies are becoming increasingly harder, more abrasive and lower grade. The Mako deposit is located in Senegal and consists predominantly of primary mafic and felsic lithology that are both very competent and very abrasive ores (Axb < 30, BWi >20 and Ai >1.0). The deposit was initially discovery in 2010 and the Toro Gold management team fast tracked the Mako Project through development and into production to achieve its first gold pour in January 2018. The comminution circuit comprises primary crushing single stage SAG milling with recycle crusher (1oCR SS-SAC). The mill reached design throughput and grind size seven weeks after first ore. The Mako project marks another successful international application of single stage milling, which represents a simple and easy to operate comminution circuit for small-to-mid size projects with a low capital cost. This paper describes the ore interpretation, comminution modelling, grinding circuit selection and design, as well as an overview of the commissioning and ramp-up of the mill.INTRODUCTION The Mako Gold Project is operated by Toro Gold Ltd., which holds a 90% interest in the project. The project is located in south-eastern Senegal in the Kedougou region, close to the Gambia river and township of Mako. The Mako deposit lies in the “Kenieba Window” of eastern Senegal and western Mali, which hosts a number of gold mining operations and development projects. The Mako Gold Project has an estimated life of 8 years with overall recoverable gold estimated at 924 koz. The process plant is designed to treat 1.8Mt/a of ore and produce 128 – 143 koz of gold per annum. Lycopodium Minerals Pty Ltd (Lycopodium) was appointed to provide feasibility studies and EPCM services for the greenfield project. Forming part of consultancy services provided by Lycopodium, Orway Mineral Consultants (OMC), a subsidiary of Lycopodium, was involved in the design, commissioning, ramp up and ongoing post commissioning support of the comminution circuit."

Jan 1, 2019

By L. S. Almeida, U. A. Courbassier, C. T. Guimãaraes, M. N. Souza, V. L. Silva, H. P. Dias, G. A. Bicalho, B. S. Rocha, P. N. Rodrigues, A. Carnevale

During primary aluminum production the anode changing is a very important task. So improvements on it will be essential to avoid disturbance and have a better operational control. After anode changing a good current distribution will be guaranteed using a cavity cleaner and precise anode setting. Albras switching a manually anode setting to an automatic one solved the setting problems. In this paper it will be shown some pot line results and the improvements on workers ergonomic and safety conditions. The device was developed in a partnership between Albras and Pesto.

Jan 1, 2006

By Ben Habermann

"The object of the work described in this paper was to increase the understanding of the relation that capillary pressure of a rock, hydro-dynamics, and accumulation of oil in stratigraphie traps have to one an-other. The hydrodynamic oil-water tilt equation is derived by considering the two vector gradients involved: (1) buoyancy of oil in water and (2) hydraulic gradient.Recent theories show the necessity for oil to have a continuons phase in the reservoir rock in order to mi-grate; this fact applies to hydro-static as well as to hydrodynamic conditions. Hydrostatically, the displacement pressure of the rock deter-mines the amount of oil that can be trapped behind a permeability barrier. If the buoyancy of oil in water exceeds the displacement pressure, oil will migrate up-dip; an oil trap will be formed where displacement pressure is greater.In stratigraphie traps the pressure drop caused by moving water is positive when its direction is down-dip, helping accumulation; and it is negative when its direction is up-dip, forcing the oil into the tighter section of the reservoir. Theoretically, pro-vided we have data such as: (1) the displacement pressure of an up-dip permeability pinchout, (2) density difference between the oil and water in place, and (3) the direction and magnitude of the hydrodynamic gradient (if any), the possible extent of a stratigraphie oil accumulation down-dip can be predicted.To test the above theory sample cores from three wells in the Denver Basin were analyzed and the oil column that could be held under hydro-static conditions was calculated. After the hydrodynamic influence was considered, the results were compared with actual field data.The significant fact shown by this investigation is that the calculated oil column in one reservoir very closely approximates the actual extent of the oil column in a well. Also in accordance with the theory, the capillary pressure caused by the buoyancy of the oil column exceeded the measured displacement pressure on core samples from another productive field. For very tight shaly sand and questionable oil shows, the interpretation of data is very critical, as shown by experiments on core samples from a third field."

Jan 1, 1960

By The Staff

"THE property of Red Mountain Mines Limited is located 11/2 miles north and west of the town of Rossland, in southern British Columbia. The mine is situated on the flank of Red mountain, famous in pioneer days as the site of a number of profitable gold-copper producers. Mining and milling commenced in May, 1966, and by the first of July the concentrator was treating close to its average design capacity of 400 tons per day. The following description of the property and its operations is divided into three parts, dealing respectively with geology, mining and milling.GeologyAll the known ore reserves of Red Mountain Mines occur on the Coxey claim, on the west slope of Red mountain. Although there are indications of molybdenite mineralization elsewhere on the Company's property, these have not been developed.The Coxey and adjoining areas are underlain by the Mount Roberts formation of the Rossland volca-nics. This formation consists of an interbedded series of volcanic and sedimentary rocks, mostly brecciated and silicified near the ore zone, and all intruded by igneous rocks which occur in various forms, and vary in composition from basic to acid. The country rock in the vicinity of the mineralization seems to be mostly a volcanic, approximately andesitic in composition, and possibly a surface flow. There is much banding, some of which is undoubtedly due to tuff and agglomerate layers, and some to narrow, siliceous, sedimentary horizons such as the surface exposure of the main ""A"" orebody, much of which was a thin capping of greyish banded rock that looked like quartzite. The drill holes also intersected occasional layers of black, argillaceous quartzite, sometimes altered to a greenish colour. The whole assemblage has been silicified with varied intensity, sometimes to such an extent as to have obscured or obliterated the original characteristics. The mineralized zone has also been strongly brecciated, the fragments varying in size from less than an inch up to large masses, best described as a mega-breccia. Anomalous results obtained in drilling, such as sedimentary sections that do not appear in adjoining holes, may sometimes be due to the presence of these large blocks, no longer in their original position. The whole volcanic unit is thus very complex and confusing. For practical purposes, the ore may be said to occur in a greenstone formation with minor sedimentary interbeds and considerable later igneous material."

Jan 1, 1967

By Pritii Tam Wai Yin, Tony Leong, Neetu Bansal, James Vaughan, Amiel Boullemant

Mercury is a toxic element that is associated with many industrial activities including the Bayer process. Mercury is known to enter the Bayer process with the bauxite feed material and has the potential to accumulate as the process solution is recycled. This paper explores the speciation of mercury in Bayer process streams. The process parameters considered are the oxidising-reducing potential, basicity and temperature. The results of a refinery circuit survey are presented and compared with the thermodynamic predictions. Electrochemical measurements on relevant synthetic systems are also included.

Jan 1, 2014

By C S. Stevens

This paper describes the problems encountered and the steps taken to solve them in milling an ore containing relatively large amounts of pyrrhotite. A complex and greatly lengthened flotation circuit was required to recover the pyrrhotite. A very low pH had to be maintained in the cyanide circuit in order to get good recovery of the gold and maintain reasonable cyanide recovery. Introduction D ELNITE Mines Ltd., a gold mine situated about 5 miles by road south and east of the town of Timmins, Ontario, is serviced by two shafts. No. 2 shaft extends from surface to the 2875-ft. level, and No. 3 shaft, an internal winze, extends from the 2875-to the 5275-ft. level. No. 2 shaft was stopped at the 2875-ft. level because of a heavy band of chloritic schist which necessitated a drive to the north for 1000 feet, where No. 3 shaft was sunk. The latter bottomed in the schist at the 5275-ft. level. From the 2500 to the 2875-ft. level in No. 2 shaft, the ore was

Jan 1, 1965

By M. J. Steffens

ESPLIM is a novel separation technique that combines the advantages of solvent extraction and electrostatic dispersion but its application in the extraction of nickel by the direct solvent extraction route and the effect of high electrostatic field on the stability of organics have not been explored. These were investigated in this study and it was found that the technique allows 97% extraction of the nickel in a single stage compared with 3 stages by the conventional solvent extraction. Also, three months of exposure to 5.0 kV under simulated operational conditions had no adverse effect on the stability of organics.

Jan 1, 2005

By R. L. Alexander

"Madawaska Mines Limited, incorporated in 1975 is the successor to Faraday Uranium Mines Limited. The history of the latter's mine development and corporate changes are outlined. This paper describes the geology of the Bancroft area and the rock types found in the mine, particularly the pegmatite which is the host rock for the uranium. The structure, mineralogy and distribution of the ore shoots are described with the method of grade control and mine development. The paper concludes with a summary of the production and mineral reserves.Location, Access, and PropertyMadawaska Mines Limited is located in Faraday Township, Hastings County, Ontario. The mine is in the N.T.S. quadrant 31 F/ 4, Bancroft sheet and near 46 degrees 01 minute latitude, 77 degrees 46 minutes longitude. The mine is one-half mile north of Highway 28, five miles (8 km) west of Bancroft, and is accessible by various highways from Toronto, Ottawa, Peterborough, and Belleville. (Fig. 1). A landing strip for small aircraft is located at the northwestern edge of Bancroft. Bancroft is a modern community with a population of 2,400. The company has the mineral rights to 2982 acres (1207 hectares) surrounding the mine workings and plant which are situated in the north parts of Lots 16 and 17, Concession XI, Faraday Township."

Jan 1, 1986

The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of &apos;water carrying rate&apos;. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By Michael E. Charles, Jaroslav J. Vocadlo

"The hydraulic transport of solids through pipelines can have many advantages over other modes of transport. Numerous successful applications both within plants and over longer distances have demonstrated the technical and economic feasibility of slurry pipelining. Solids successfully transported include kaolin, coal, iron ore, gilsonite and limestone, and others, such as sulphur and potash, are likely to be transported in Canada in the near future. However, though the technology of solids pipelining is quite advanced the underlying principles have not yet been formulated past the semi-empirical stage. The main objective of this paper is to present a discussion of the important technical and economic considerations in the design of so lids pipeline systems by reference to typical data. The Worthington slurry pumps and pilot facilities are briefly described."

Jan 1, 1972

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By I. Tinto

"IntroductionEnvironmental pollution problems, caused by gases or effluents, by high noise levels or from air borne dust, are placing increasing demands of the operators, from statutory authorities, and from the general public, to adopt more stringent dust control measures. This requires that a successful plant dust control program be an integral part of any plant operation. While a successful environmental program is a key factor in maintaining productivity and good labour relations, anticipation of future environmental regulations during the plant design phase can avoid the high cost of plant upgrading, or dealing with pulmonary conditions in the work force in subsequent years.Particulate removal, conventionally called dust collection, involves the removal of coarse- and fine-particulates from the airstream. Although generally limited to that required for contro!Hng plant generated air emissions, particulate control equipment also has a wide application for air cleaning and filtration inside the plant, as well as for recovery of usable products.In the late 1950s and early 1960s the public became more concerned with the problems of air pollution. This increasing concern was stirred by an awareness of the extremes to which water pollution had progressed in many of the rivers and lakes, by increasing perception of air pollution as detected by visible smog and harsh chemical odors, by the alarming rate of increase of smog plagued cities and communities, and by specific incidents where ill health could be traced to specific episodes of air pollution. Particle size is perhaps the most important single factor affecting particulate control. Large particles (over 5 microns) constitute the major mass fraction of most sources of emission and economical control equipment dqes exist for their efficient control. However, while these larger particles frequently represent the source of soiling and unsightly smoke plumes, they are not a major health problem as they tend to settle relatively quickly, are more easily scrubbed from the atmosphere by rain, and are not able to penetrate the respiratory system. By far the most important form of particulate air pollution is the fine particulate, (below 3 microns) which is harmful to the pulmonary system. The adverse effects caused by this particulate matter on human health are for the most part related to injury to the surfaces of the respiratory system. Particulate material in the respiratory tract may produce injury itself, or it may act in conjunction with gases, altering their sites or their modes of action. A combination of particulates and gases may produce an effect that is greater than the sum of the effects caused by either individually (i.e. synergistic effect)."

Jan 1, 1989

By H. W. Smith, R. D. Fournier

This paper presents the results of an investigation of a full-scale rod mill. Appropriate numerical techniques are developed for the experimental determination of the parameters of a dynamic mathematical model from steady state data. The results confirm that this full-scale rod mill behaves similarly to laboratory-scale ball mills for which results have previously been obtained. It is noted, however, that although the model presented is adequate for predicting over-all particle size distributions, the size distributions of individual components of a multicomponent ore cannot be predicted.

Jan 1, 1972

By F. S. Thurner

"This paper describes the engineering and construction activities of the ""design-build"" project awarded to the joint venture of Foundation-Comstock-Janin for the construction of the plant and wharf facilities, camp site, power plant and all supporting services. As a member of the Foundation Group of companies at that time, Fenco actecl as consulting and design engineers for the project. Particular emphasis is given to the problems which adversely affected design and construction activities due to prevailing arctic conditions and the remote location of the project. The paper also describes the approach taken in the investigation of the site and soil conditions as well as the selection of the special structures for the 225,000-toncapacity fibre storage building, the wharf structure for 50,000-dwt vessels, and the 1,000-tph-capacity reclaiming and ship-loading facilities . It further covers the logistics problems and the scheduling activities related to the short duration of the shipping season, and the transportation of equipment and mate1•ials by sea as well as by air."

Jan 1, 1976

By D. R. Spink

An historical background is presented to provide a basis for the lack of normally expected developmental effort over the first 20-25 years of viable zirconium production operations. This is followed by a description of developing technology, which is the result of years of research and piloting effort directed to the development of a more economical method to produce high-grade metallic zirconium. It is predicted that many of the process improvements described will have a significant impact on future zirconium production methods and consequently on future prices and markets.

Jan 1, 1977

By R. J. Craig

Introduction All mining operations produce rock dust. Inhalation of rock dust, particularly if it has a high silica content, causes silicosis. Silicosis is, therefore, recognized as a hazard of the mining industry and has been made compensable throughout most of Canada. Most of the dust in any mining operation is caused by rock drilling and blasting operations and the movement and transportation of broken rock. Dust from blasting cannot be eliminated, but it can be controlled by means of increased ventilation, the use of water sprays, and the control of blasting hours. Dust from ore movement can be reduced by keeping the broken rock in a moist condition at all times. The dust from the rock drilling operation has been found to be the most difficult to control. Concentrations of dust caused by rock drills in stopes can usually be reduced to the safe minimum of 300 particles per cubic centimeter (p.p.c.c.) by diluting the air with increased ventilation. In development headings, where the machines are more confined, this is not always practicable. Therefore, the dust must be eliminated at its source. This paper deals with the reduction of dust from Leyner machines by adopting improved designs.

Jan 1, 1947