Search Documents

By M. W. Bartley

DURING the field season of 1938, the Ontario Department of Mines assigned a combined geological and geophysical survey patty to the investigation of the location, genesis, structural relationships, and economic possibilities of the hematite deposits at Steeprock lake. The investigation was carried out by detailed mapping of the rock exposures and a magneto-metric survey of the drift-covered portions of the area. This was supplemented during the winter of 1938-39 by further geophysical work conducted on the ice. Dr. A. A. Brant, of the Department of Physics, University of Toronto, was in charge of the geophysical work for the Department of Mines in the summer and for the Sterola Exploration Company in the winter. The writer supervised the geological examination. Scope of the Paper The present paper is an attempt to acquaint the members of the Institute with the structure and mode of occurrence of the deposits, since many people are of the erroneous opinion that they are analogous to the Mesaba and Michigan deposits. It is hoped that, from this discussion, they may be able to draw some conclusions of their own regarding the nature of the deposits, and the importance and future possibilities of the region.

Jan 1, 1939

By Nader Golchinfar

The V-shaped breakout zones around excavation boundary have been captured by a variety of numerical methods such as FEM and DEM methods and failure criteria such as linear Mohr-Coulomb and non-linear Hoek-Brown failure criteria. Diederichs (2007) used Hoek-Brown parameters in his spalling parameter approach; however, it is convenient to use the Mohr-Coulomb failure criterion in numerical modeling because the material parameters can easily be determined from triaxial tests. It is shown in this study that when peak and residual strength parameters as well as dilation angle are properly defined, the brittle Mohr-Coulomb failure criterion can be used to model depth of failure near underground excavations satisfactorily.

Jun 1, 2012

By G. F. Colborne, A. Thunaes

"When the Canadian uranium milling plants went into operation during the early 1950's, they utilized flowsheets developed at the Radioactivity Division of the Federal Mines Branch in Ottawa. Since then, numerous process improvements have been made by the Mines Branch, by the operating companies themselves and by other research organizations. This paper will consider uranium milling technology from the standpoint of a new mine operator charged with the responsibility for the design of an economic flowsheet, and will indicate the range of process elements available to him and the testwork required to enable an intelligent decision to be made."

Jan 1, 1968

By J E. Curfman

This paper deals with using track-type and rubber-tired machines in the ripping and handling of overburden and ores. The techniques and proper attachments pertaining to the ripping of materials are covered in some detail. Production and relative costs of ripping, as against other methods, are covered in cases pertaining to the mining industry. The use of the refraction seismograph in predetermining the rippability of materials, including a chart relat-ing velocity to rippability, is covered. This operates on the principle that sound waves travel through subsurface materials at different velocities, depending upon the degree of consolidation of the material. It is known that the same factors that affect consolidation also affect rippability. Proper equipping of the tractor to insure maximum efficiency is also covered in some detail. Introduction T HE idea of loosening consolidated materials prior to further handling and processing is probably as old as man. The purpose of ripping is to provide fragmentation of rock and loosening of consolidated materials.

Jan 1, 1965

By William J. Davis, R. Blair Hrabi, Sally Pehrsson, Amelia V. Logan, Ross Sherlock

"Abstract - The Meadowbank gold deposits are hosted by a series of polydeformed and metamorphosed auriferous iron formations located in the Neoarchean Woodburn Lake group, western Churchill province, Nunavut. The supracrustal rocks in the Meadowbank area consist of a thick sequence of intermediate-composition volcanic rocks with intercalated iron formation, ultramafic volcanic rocks, and quartzite to quartz arenite. U-Pb geochronology gives an interpreted age of 2711 ± 3 Ma for the host strata at Meadowbank.The intermediate volcanic rocks are predominately volcaniclastic and have a geochemical composition that is consistent with an active continental margin setting. Iron formation deposition was coeval with the intermediate volcanism, as indicated by incorporation of volcanic detritus in the chemical precipitate. The geochemistry of the iron formation indicates that it precipitated from a fluid that at one time was at high temperature (>250°C), reducing, and likely acidic. Intercalated ultramafic rocks rarely show spinifex textures and have trace element ratios that are consistent with mantle plume-related undepleted mantle asthenosphere, likely recording episodic mantle upwelling associated with rifting in an active continental margin. The contact between the ultramafic volcanic rocks and the overlying quartz arenite is a disconformity marked by a quartz pebble conglomerate. However, similar geology on the structural hanging wall and footwall of the contact suggests that the conglomerate does not represent a significant hiatus in deposition, and is more likely a prograding terriginous siliciclastic unit.Three metamorphic events are recognized. The first, M1, is a cryptic greenschist facies event that is pre-D2. The second event, M2, is a mid-greenschist to amphibolite facies, syn-D2 event. M3 is the last event recognized, and is a post-tectonic greenschist facies event that is regional but inhomogeneous in extent, possibly reflecting thermal aureoles around post-tectonic 1.7 to 1.8 Ga Nueltin granites. The structural geology of the area is complex with four phases of deformation recognized, two of which had a significant effect on the geometry of the deposit. All of these regional events are interpreted as Paleoproterozoic in age. Relationships between deformation fabrics and mineralization, as well as the overall geometry of the mineralized envelopes, suggest that the deposit formed during syn- to late-D2. Superimposed on the mineralization are D4 structural elements that postdate gold mineralization.The main control on gold mineralization is replacement of magnetite by pyrrhotite and pyrite in high-strain corridors. The composition of amphiboles and chlorites associated with gold mineralization is remarkably consistent and shows no spatial or temporal variation, suggesting that it was buffered by the iron-rich nature of the host rocks. The bulk metasomatic effect on the intermediate volcanic rocks is characterized by the addition of K2O and the loss of CaO, Na2O, and MgO, with little variation in the total iron content. The elemental losses are likely the result of destruction of feldspars, stilpnomelane, and ferroactinolite, which are relatively common in the unmineralized rocks, and the formation of sericite, chlorite, and grunerite."

Jan 1, 2004

By David G. Meadows

During the last decade Antofagasta Minerals? Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.

Jan 1, 2012

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By Mark Weidenbach

OZ Minerals owns and operates the Prominent Hill copper-gold concentrator in South Australia, built in 2008 and commissioned in early 2009. The concentrator operates via semi autogenous grinding in a thirty four foot ThyssenKrupp Polysius mill followed by a twenty four foot Polysius ball mill in closed circuit with hydro cyclones, designed for an ore throughput of eight million tonnes per annum. The main aspects of designing the circuit are discussed along with the issues faced in the early stages of operation. A review of the optimization strategy applied to the milling circuit such as cyclone optimization, advanced process control strategy implementation and reline management to improve availability is then discussed highlighting areas of significant process improvement that have seen the plant exceed nameplate throughputs above nine million tonnes per annum.

Jan 1, 2012

By P. A. Riveros

The literature on the arsenic disposal practices of the metallurgical industry and the long term stability of the disposed arsenic compounds were reviewed from a Canadian perspective. The review was complemented with visits to selected operating metallurgical sites to obtain information on their specific arsenic disposal practices and the behaviour of their impounded residues. The arsenic disposal procedure currently favoured by the industry involves the formation of an insoluble ferric arsenate compound which is allowed to sediment at the bottom of tailings or residue ponds. It has been shown recently that this poorly formed crystalline compound is similar to ?arsenical ferrihydrite? which is ferrihydrite containing strongly adsorbed arsenate anions. Despite concerns about its long term stability on thermodynamic grounds, arsenical ferrihydrite appears to be stable for many years in the proper environment which includes a slightly acidic pH and oxidizing conditions. A high Fe/As ratio and the presence of heavy metals appear to increase the stability of arsenical ferrihydrite. High temperature operations, such as those encountered in the autoclave treatment of refractory gold ores, are conducive to the formation of scorodite, FeAsO42H2O, and/or a series of ferric arseno-hydroxy-sulphate compounds depending on the solution composition. Scorodite has several advantages over arsenical ferrihydrite as a disposal compound including a lower iron demand, a higher density and a greater thermodynamic stability. New procedures have been developed to generate scorodite at ambient pressure. These procedures would offer significant reductions in capital cost because of the elimination of the need for autoclaves. Lime precipitation which was widely used in the past is being abandoned as a result of strong evidence showing that calcium arsenate compounds decompose slowly in contact with atmospheric CO2 to form calcium carbonate and soluble arsenic acid. In all cases, the long term stability of the disposed arsenic compounds depends on a number of factors including disposal site characteristics, particle crystallinity and size distribution, the presence of complexing agents and the effect of bacterial activity.

May 1, 2002

By J. Stiksma, J. Dennett, R. Kalanchey, J. Ji, M. Collins, T. Chan, R. Berezowsky

A pilot plant campaign has been conducted by Sherritt Technologies in support of Eldorado Gold Corporation’s evaluation of pressure oxidation technology for the treatment of refractory gold concentrates from the Certej deposit in Romania. Four separate concentrates, containing 3.5 to 5.4 g/t Au, 13.0 to 14.5% S2- and 12.0 to 32.5 g/t Ag, were tested in the eight-day campaign. The major gold-bearing mineral was pyrite. Preliminary batch tests indicated that gold extraction from the oxidized concentrates in subsequent cyanide leaching was adversely affected by the presence of organic carbon in the pressure oxidation feed when chloride in solution was at an elevated level. As such, the process conditions that were tested during the pilot plant operation were selected to either counteract the negative impact of the organic carbon, or to deactivate it during pressure oxidation. Both process routes proved feasible, yielding gold extraction of 95 to 98% in cyanide leaching of the oxidized concentrates. Silver extraction was typically in the range of 80 to 90%, provided that the oxidized concentrates were also processed in a lime boil step prior to cyanide leaching.

Jan 1, 2014

By D. R. BUDINSKI

Clinton Creek Mine in west-central Yukon produced 0.94 million tonnes of fibre from 15 million tonnes of asbestos ore between 1968 and 1978. The mine closed in 1978. The deposit lies along the margin of a medium sized ultramafic pluton that intrudes schistose and gneissic rocks of the Yukon Metamorphic Complex. Country rocks are metamorphic equivalents of a mixed sedimentary and volcanic assemblage deposited during Precambrian or early Paleozaic time. Movement along the north west-trending Tintina Fault System probably caused the fairly high meromorphic grade that altered the original rocks to schists and gneisses. The ultramafic pluton hosting Clinton Creek Mine is one of several bodies that were emplaced along a deep seated imbricate fault system parallel to the Tintina Trench. Most of rhe intrusions were hydrothermally altered to serpentinite, bur apparently only the one at Clinton Creek contains commercial quantities of asbestos. The Clinton Creek pluton was probably injecred slowly at relatively low temperatures into the crustal rocks as a "mush" that cooled gradually, allowing sufficient time for serpentinization and chrysotile fibre crystallizarion.

Jan 1, 1984

By B. B. Meadows

"The Minto-Chipman Strip Mining Reclamation Project was initiated to re-vegetate the spoil piles remaining from strip mining operations.All available information was studied by the team responsible, and areas being reclaimed in the U. S. were visited, Methods applicable to the N. B. Project were noted for future use.We have both surface and underground mining operations in New Brunswick, Both deface the natural landscape and reclamation varies in difficulty, Surface operation disturbances are the most difficult to correct.Some of the surface mining is carried out next to two main highways and the results are definite eyesores, With this in mind, it was decided to landscape the spoil ground next to the highways and plant “as is"" the ground remote from the public view.The landscaping entailed various degrees of bulldozing from complete levelling to contouring, smoothing and topping, Bulldozing is, of course, the most expensive part of any reclamation project.There are two phases to the planting program; experimental and operational--experimental both prior and, later, in conjunction with the operational planting.Initially in the experimental project, the pH and composition of the spoil was determined using a grid sampling system. Soil samples were tested in a laboratory at the University of New Brunswick."

Jan 1, 1970

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By A. E. M. Warner, P. J. Mackey

Copper metal is produced in large or small tonnages in almost all countries of the world—handling raw materials in the form of either as-mined or milled ores, custom concentrates, or other custom materials including scrap and recycled copper. The scale of operations and type of technologies used around the world varies widely. There is a certain concentration of both mining and smelter-refinery production as a total of ten countries produce some 80% of world mined copper, while ten countries—mostly different ones— produce about 80% of smelted and refined copper. As a result, international copper trade is significant. The present paper takes the reader on a virtual tour of the copper plants throughout the world with a focus on smelter facilities. Operations and technology employed at each plant visited are discussed including a brief historical sketch. Future trends identified during the world tour are also discussed. The present authors considered sufficient time was required for a thorough study tour and settled on eighty days—the same as that for the celebrated fictional story of world circumnavigation in the 1870s. INTRODUCTION The celebrated French writer Jules Verne published his book “Around the world in 80 days” in English in1873 and it is the story of Phileas Fogg and his French valet Passepartout circumnavigating the world in 80 days in the fall of 1872 on a £20,000 wager (equivalent to over 2 million pounds today) from the exclusive Reform club in London. This is an interesting period for copper as it started trading on the London metals Exchange in 1876 and the start of global copper production chains started to take off at this time with the rapidly increasing electrification of the world. The production chain includes mining, mineral processing, smelting, refining and fabrication. Since 1880 annual world copper production has increased by over 150 times from 154,000 tonnes in 1880 (nominally considered as smelted copper—essentially the only route at the time to marketable copper) to over 23 million tonnes today (including total refined copper of 19 million tonnes of smelted copper including scrap and 4 million tonnes by solvent extraction-electrowinning), in tandem with increased electricity usage, along with significant transportation usage and for manufactured products (Figure 1).

Jan 1, 2019

By W. H. S. McFarland

THE Yukon Consolidated Gold Corporation, Limited, a Canadian company, operates alluvial gold dredges in the Klondike goldfields of Yukon Territory. Its operations are of unique interest to Canadian mining as it is the only large-scale placer mining operation of this type in Canada. Its properties lie in the valley of the Klondike river and its tributaries, Bonanza, Hunker, Bear, Last Chance, and All Gold creeks, and in the valley of Indian river and its tributaries, Dominion, Gold Run, Sulphur, Eureka, Montana, and Quartz creeks. At the end of 1938, they consisted of 1,650 placer mining claims and 9 leases or concessions. They cover a belt with an area of approximately 1,000 square miles. This vast area covers in part claims which have been previously worked by other methods such as 'drift' and 'open-cut' mining, and areas which were too low grade for such methods. The ground held by the Company is not held in freehold but in the form of mining claims and mining leases granted by the Dominion Government under the provisions of the Yukon Placer Mining Act. Full-size creek claims are 500 feet in length by 1,000 feet on either side of the base-line. Hill and bench claims are 500 feet up and clown the valley and 1,000 feet at right angles to the valley. All claims are held on the basis of an annual renewal fee of $10 for each claim plus 'representation work' of an assessed value of $200 per claim per annum. For the purpose of such representation work, claims may be 'grouped'. This means that work done by one dredge is sufficient to 'represent' a comparatively large block of claims. It is only in this way that it becomes possible to consider operations on a large scale over a term of years, for such operations would obviously be impossible on law-grade ground if representation work had to be done separately on each individual claim in each year.

Jan 1, 1939

By J. S. Godard

The mining developments in western Quebec have shown the ores of this district to be more complex in character than was at first expected. When the initial discoveries were made it was thought that the ores would be similar in character to those of Kirkland Lake and Porcupine areas. Developments have since shown that although the ores along the southern margin of the belt are somewhat similar, those within the belt, constituting by far the greater proportion, are vastly different, being complex mixtures of base-metal sulphides carrying values in the precious metals. These mixtures of base-metal sulphides of copper, zinc, and iron, present several problems to the metallurgist, especially in their concentration into marketable products. For the purpose .of this paper the following classification may be made of the ores of the district. Group I. - Milling Ores: (a) Ores in which~ arsenopyrite is the predominating sulphide. In this class of ore the gold occurs in fractures in the quartz and is associated to a lesser extent with the arsenopyrite and pyrite. Examples of this class of ore are the Granada, south of Pelletier lake, and the O'Brien and the Thompson in Cadillac township. (b) Ores in which iron pyrite is the predominating sulphide and gold is the valuable constituent. This may also be classed as a concentrating ore-Group III.

Jan 1, 1928

By Colleagues from Process and Operation departments, Guy Chevalier

"QCM's pellet plant, located in Port-Cartier, Quebec, produces up to 8.6 million tons of iron ore pellets annually. Four different types are produced: three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the installation of new process equipment to improve the reducibility of direct reduction pellets (DR pellet). The findings, the equipment selection and some post start-up modifications are presented.This low silica DR pellet is used in Midrex and HyL shaft furnaces. A good DR pellet has to meet strict chemical, physical and metallurgical specifications. An important metallurgical property is its ability to release oxygen when exposed to reducing gases. Considering that the market for DR pellets is expanding and being aware that reducibility is critical for our clients, a program to improve the latter was undertaken. Test work showed that one factor which has a negative effect on reducibility is the proportion of particles larger than 75 microns. Knowing that the best way to reduce the amount of coarse particles was to close our open grinding circuits, we began evaluating the most suitable classification equipment applicable to our process operations. We settled on hydro-classifiers based on their very sharp cut and their low operating costs. In light of the hydro-classifiers performance it was also decided to replace the hydro-cyclones of an already closed circuit.INTRODUCTIONAt the Québec Cartier Mining pellet plant, continuous improvement programs are aimed at increasing levels of consistency and improved chemical, physical and metallurgical properties. This is being accomplished while still maintaining pellet plant production volumes to satisfy market demands.QCM produces three types of pellets for blast furnace use: acid pellets, designated as ""BHF"", fluxed pellets, designated as ""BAF"", and low silica fluxed pellets, designated as ""BSA"". For direct reduction, a low silica acid pellet or DR pellet, designated as ""BBS"" is produced. This low silica DR pellet is used in Midrex and HyL shaft furnaces.The demand for DR pellets has been increasing during the last few years and is believed to continue so in the future. Wanting to be present in this growing market QCM found that it would be essential to work at improving its DR pellets quality. Efforts have been focused on improvements in three areas: SiO2 reduction, elimination of sticking and increasing reducibility. Improvement programs have begun with laboratory research followed by plant trials and full-scale implementation as a cooperative effort among QCM, COREM, and key customers."

Jan 1, 2002

By R. W. Nice

"For many decades the incidence of a highly active graphite-like ore has plagued the McIntyre mine. This ore acts as a precipitant of the gold complex immediately upon formation of this complex. The gold is subsequently discharged with the tailings.Many different methods have been devised by various researchers all of which proved inapplicable for the McIntyre problem.Recently, McIntyre personnel, through their own research, developed a flowsheet. This circuit should give an overall recovery of 36% which is below the 94% experienced in the mill at present. Therefore, less revenue would arise from treatment of these ores. On the other hand there exists a possibility of more efficient mining methods in some of this ore thus allowing more economic recovery.INTRODUCTION This paper has been prepared to serve two purposes:i) To propose a method of recoverying gold from a sizeable orebody at the McIntyre mine at Schumacher.ii) To summarize and present the many methods suggested to solve a very old but very real mineral dressing problem familiar to the industry as long as cyanidation itself."

Jan 1, 1971

By J. E. Shigley

The gemological properties that allow natural emeralds and blue sapphires to be distinguished from other gemstones are summarized in this paper. A variety of synthetic and laboratory-treated emeralds and blue sapphires are also encountered in the jewelry industry today. Gemologists distinguish these latter materials from their natural counterparts based primarily upon features seen with magnification, such as inclusions and/or growth zoning. In some cases, however, these observations and standard gem-testing methods are insufficient, and the use of non-destructive analytical methods, such as optical spectroscopy and chemical analysis, are required for positive identification. The commercial value of synthetic and treated gems are much less, and can be insignificant in comparison to that of an important untreated natural gemstone. Identification of synthetic and treated gem material is essential to maintaining integrity in the jewelry industry. Loss of consumer confidence in the gemstones sold at the jewelry counter could have a negative impact on the exploration and mining of natural emerald and blue sapphire.

Jan 1, 1998

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016