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By J. S. Brock

Magnetic, electromagnetic and gravimetric surveys have played an important role in the mineral exploration leading to the discovery of three major massive sulphide deposits in the Anvil-Vangorda area of the Yukon Territory. During 1964 and 1965 a saturation prospecting program, relying heavily on the integrated use of airborne and ground geophysical survey techniques, led to the discovery of the Faro deposit, which was subsequently proven to be a 63-millionton lead-zinc orebody. Locating the Faro deposit, the largest found to date in this overburden-covered region, involved an exploration sequence requiring the selection of a favourable geologic environment, aeromagnetic and electromagnetic surveys, property acquisition of anomalous areas and detailed ground geophysical surveys, followed by rotary drill testing, detailed gravimetric surveys and diamond core drilling.

Jan 1, 1973

By T. Vovan, A. Galibois, M. Fiset

"In order to establish some links between the 22 specimens found on the site of Les Forges du St. Maurice, their slag inclusions have been analyzed by electron microprobe. Comparison between their contents of various specific oxides allowed us to segregate them into two major groups and even to isolate two sub-groups possibly characterized by some equilibrium between their oxides and/or the type of ores used.In all probability, limes/one coupled systematically with a soil rich in hydrated aluminum silicates was used as a flux.Based upon the existence of a pseudo equilibrium between the slag and the metal, the elaboration of the bulk of the specimens can be ascribed to the indirect rather than the direct method whereas the process temperature can be estimated at at least /400°C.RESUMEDans le but d'etablir des liens entre les 22 objects provenant des Forges du St-Maurice, leurs inclusions de scories ont été analysées par microsonde. La comparison des teneurs en divers oxydes a permis de les séparer en deux groupes majeurs et même d'y distinguer deux sous-groupes pouvant être reliés à la forme d'équilibre entre certains oxydes et/ou au type de minerai utilisé. Selon toute vraisemblance, le fondant utilisé était de la pierre à chaux à laquelle on ajoutait systématiquement une terre riche en silicates hydratés d 'aluminium.Des considérations sur l'existence d'un certain équilibre entre les scories ei le métallaisset croire que la plupart des objets ont été élaborés plutôt par la méthode indirecte que directe et que la température d'élaboration se situait à au maint 1400°C."

Jan 1, 1984

By G. B. Harris, C. W. White

A study to investigate the recovery of base metals, notably copper, nickel, cobalt, zinc and manganese from iron-free concentrated chloride solutions using ion exchange was undertaken. In such solutions, apart from nickel and, to a lesser extent manganese, these metals are present predominantly as complex anions, and therefore conventional separation techniques based on cationic resins are not applicable. The results demonstrated that zinc, copper and cobalt can all be separately recovered leaving nickel and manganese behind. Specifically, zinc is a major nuisance element in nickel and cobalt processing, and the testwork showed that it can be preferentially removed prior to copper and cobalt. Selective resins for both copper and cobalt were identified, and it was demonstrated that the strength of the chloride background matrix has a significant effect on the efficiency of separation. An additional major advantage in such systems is that stripping can mostly be effected with water. Finally, some observations are made on the hurdles that must be overcome when attempting to introduce and commercialise new technologies.

Jan 1, 2015

By Richard W. Hutchinson, Christopher Osterman

Abstract -The Selebi-Phikwe deposits are hosted by amphibolite to granulite facies gneisses of the Limpopo belt. The sulfide orebodies are generally stratiform and conformable to the foliation of the wallrock gneiss. Sulfide remobilization has occurred during metamorphism and has produced discordant sulfide veins, called piercement structures, which project into the hanging wall and foot­ wall gneisses. These piercement structures are compositionally similar to the stratiform sulfides, consisting mainly of pyrrhotite, pentlandite and chalcopyrite. However, texturally the piercement sulfides are coarse grained and inclusion-free, whereas the stratiform sulfides are fine grained and packed with tectonically produced wallrock inclusions. The piercement structure sulfides and adjacent stratabound sulfides were sampled and analyzed for major base metals and PGE's for comparative purposes. Most of the piercement structures were enriched in Cu, Ag and Au, whereas they were generally depleted in Ni, Co, Fe and PGE's. Changing elemental associations were observed from the stratabound sulfides and along the length of the piercement structures. This and the degree of depletion or enrichment of various major and minor elements in the sulfide piercement structures may reflect the relative mobilities of metals under metamorphic conditions. The similarities between sulfide piercement structures and the footwall Cu-POE veins in some Sudbury deposits are reviewed.

Jan 1, 1994

By Roger D. Plouffe

In today's mining industry, it is possible to retrieve, from small-diameter holes, geophysical data for qualitative interpretation in exploration and quantitative interpretation in the development of orebodies. The primary objectives in the exploration stage are to identify where, within a hole, economic minerals are, and to help in lithological interpretations. Other aspects, which are more quantitative, are the interpretation of downhole logs for parameters which can be used in surface geophysical methods (i.e. density for gravity surveys, acoustic velocities for seismic surveys, and magnetic susceptibility for airborne and ground magnetic surveys). Recent advances in equipment design, portability and durability have made downhole logging in exploration more inexpensive and reliable. This new equipment is being used to generate very precise quantitative results. This is especially true on uranium development projects. The interpretation of gamma logs for eUJOS values has finally become precise enough that they have begun to replace chemical values in reserve calculations. Another part of development data is density and equilibrium information, which, with today's technology, is being derived from downhole probing. In the years to come, the trends for many metals are toward neutron activation techniques, or "in-situ assaying", and the use of multiple logs for better lithological and physical rock property determinations.

Jan 1, 1981

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By J. Ander

About fifteen years age some mines in western Canada commenced using Diesel engines, partly for development work but also for operations on quite a large scale. In the Eastern mining field, the Diesel engine made its appearance some eight years ago and has since, at quite a number of mining plants, proved to be a reliable and economical prime mover. As a result, it is today used more extensively than could have been foreseen only a few years ago, and it is reasonably safe to predict that the next few years will see the Diesel engine utilized to a still greater extent in the Canadian mining industry. It is not much more than thirty years since the first Diesel engine was put in operation. During the early years of this century, the Diesel engine took, so to say, its first faltering steps in public service. Since then it has reached a high state of perfection, and its importance has grown in a most remarkable way, until today it is used in practically every field where power is required. It is slowly but surely superceding steam for a great many purposes, as, for instance, for ship propulsion. While in 1921 only about 8 per cent of all tonnage launched was motor-driven, the proportion had grown to 38 per cent in 1927, and for 1929 it was slightly over 45 per cent. Some of the finest passenger liners afloat are Diesel-driven. In the early days, Diesel engines were built only in comparatively small units. Today engines with a capacity per unit of up to 10,000 horsepower, or even more, are being built for marine and stationary purposes.

Jan 1, 1930

By S. C. Radopoulou

Pavement condition assessment is an indispensable constituent in maintaining roadway infrastructure. Current practices for pavement condition assessment are labor intensive which introduce subjectivity in pavement rating and are time consuming. Automated methods rely on full 3D reconstruction of the pavement surface which introduces high equipment and computation costs. This paper presents a methodology for detection of patch type distresses in asphalt pavement images. This method uses filtering and histogram equalization for clearing and enhancing the image accordingly. It continues by applying the morphological process of closing, along with some rules based on the characteristics of a patch when captured in an image, to finally detect the area it occupies. Criteria for area, length, and width of a patch as seen in an image are taken into account to decide whether a probable patch is actually a patch. The method has been implemented in C#. The preliminary experiments demonstrate it produces promising recognition results

Aug 1, 2013

By The Staff

WE were requested to make a digest of our original grinding report, Fine Grinding Investigations at Lake Shore Mines. This digest is much easier to read than the original report, but it lacks the experimental 'evidence' found in the first report which, in many cases, is much more interesting and educational than the conclusions derived from it. In the course of rewriting the paper, we noticed several new angles on the test data which had not occurred to us previously. From the data included in the report and other tests not published, calculations were made which indicated a line of new test work. These tests, among other things, more than suggest a technique for designing the length of mills, the position and number of classifiers, and the total loads a mill should carry.

Jan 1, 1941

By N. Tounsi

The use of analytical modeling of continuous chip formation in conjunction with orthogonal cutting experiments was presented in the open literature to identify the coefficients of material constitutive equation within the practical range of stress, strain, strain rate, and temperature encountered in metal cutting. Identification of reliable constitutive data was hampered by a lack of a reliable model for the prediction of the primary shear zone thickness that affects directly the effective strain rate field. An original analytical model to determine the primary shear zone thickness is proposed in this paper. It is based on the mechanics governing the material flow in the primary shear zone. Based on the distribution of the hydrostatic pressure and the forces measured from orthogonal cutting tests, the model that describes the thickness of the primary shear zone is derived. To validate the model, FE simulations of chip formation using DEFORM3D were carried out for different materials and cutting conditions. The results of the analytical model are in reasonable agreement with FEM results.

Jan 1, 2006

By G. H. K. Pearse

Sulphur is derived from both 'voluntary' and 'involuntary' production. The former category includes sulphur obtained from elemental sulphur deposits and from pyrite and gypsumanhydrite deposits. Sulphur in the latter category is produced by pollution abatement at fossil Juel plants and from treatment of metallic sulphides. Canada is the world's largest sulphur exporter and third largest producer. Main resources of Canadian sulphur are sulphurous fossil fuels, metallic sulphides and native sulphur. Only the first two sources have produced sulphur in Canada 10 date; the first source accounts for over 85% of total Canadian production. Future sulphur sources will be derived increasingly through pollution abatement and decreasingly through voluntary production.

Jan 1, 1984

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By R. Lovat, J. A. Hunter

"The design, development, and verification of the Lovat 7.6metre diameter full-face tunnel-boring machine is reviewed. Programmatic and technical challenges are outlined with a review of the specifications and the design to meet these requirements. Subsystem designs are presented for the waste material removal, ventilation, cutter head, structural support, advance technique, water removal, and interfaces with the Donkin-Morien Mine. The techniques used to verify that the design meets the requirements is by testing in the Lovat factory and in the field. Certification of the machine for use in a methane environment is discussed.IntroductionStudies have concluded that the average annual worldwide tunnel construction is 500 kilometres at an estimated average co st of $3,400 U.S . per linear metre. The total market value of the tunnelling industry is estimated as approximately $1.7 billion U.S. per annum. Of this, the current market for tunnelboring machine excavation is approximately $270 million U.S. per annum worldwide with a further potential of $250 million if more contractors are convinced that Tunnel-Boring Machines (TBM) are more suitable than conventional techniques. The worldwide civil tunnelling market has the potential to double each year in the next 5 to 15 years. Growth has been identified in the energy and mineral resources sectors of the economies of many nations and a significant volume of machine tunnelling studies and trials are presently underway for the extraction of coal, uranium , heavy oil or oil sand fuels, metallic and non-metallic industrial minerals and base metal or rare earth ores. Further tunnel projects for regional transportation, waterpower, irrigation , high density urban transportation, storm water sewers and water supply purposes are continually being implemented with new concepts like military security facilities and underground storage schemes being considered.Lo vat Tunnel Equipment of Rexdale, Ontario, the only Canadian manufacturer of TBMs was incorporated in 1973 to manufacture so ft ground tunnel-boring machines to satisfy this growing market demand. Lovat has produced an average of 5 machines per annum during the period 1972 - 1982 and has established an international reputation for competitive costs, quality of construction, after-sales service, and reliability. As of June 1982 Lovat TBM's have been used to tunnel over 240 km in projects throughout the world."

Jan 1, 1984

By L. Lamothe, C. H. The

"Pilot precipitator tests were conducted at Noranda's Horne Smelter in late 1978 to evaluate methods of improving converter dust collection efficiency. A bout 35 Nms/min. of converter off-gas were isokineticatly diverted from the converter flue to the pilot precipitator leased from Flakt (Canada) Ltd., consisting of three fields, one transformer-rectifier set per field and 77-m2 total collecting plate area. The effects of gas volume flow rate and conditioning the gas with sulphur trioxide and/or additional moisture were tested. II was found that gas flow rate and moisture level had the most pronounced effect on collection efficiency. Based on a techno-economic assessment of different options for improving converter Courell efficiency, waffle hoods and water sprays were installed on the converters to reduce air infiltration and increase the moisture level in the gas.BackgroundThe Horne Smelter of Noranda Inc. is situated in northwestern Quebec and, since the closure o f the min e in 1976, has been operating as a custom smelter. The concentrates treated at the smelter come from various mines with mixed sulphide ores , many o f them containing significant amounts of lead and zinc which makes dust collection in electrostatic precipitators mo re difficult than normal.As part of a continuing program on reducing smelter dust emissions, the No . 6 Cottrell was installed in 1972 up stream of Nos. 2 and 4 Cottrells (in parallel) in a n attempt to improve dust collection by increasing the over- all precipitator capacity ( Fig. I). However, it has never per formed a t its designed efficiency o f 94%. The average efficiency established in various test s was in the range of 60 – 65%."

Jan 1, 1985

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By Eugene (Gene) Bounds

The Mining industry faces many challenges, one of which is the demand to communicate over a variety of media, be it visual, sound, voice, data or any combination. Over the years multiple infrastructures have been put in place to overcome environmental obstacles and address these communication needs. A mine is an aggressive environment for electronic equipment and as such only the best quality equipment can perform under those special conditions of e.g. temperature, dust and humidity. Siemens Canada and its partner LComm will discuss a mining solution using a unique combination of technologies based on fibre optics, standard communication interfaces, passive antenna infrastructure and wireless services. The presentation looks at maximizing the use of infrastructure, reducing costs, addressing difficulty of communications coverage above and below the surface and the capability to future proof the capital investment as new requirements and applications are identified. Discussion will address: Wireless voice, high speed data Data acquisition for process control from sensors Video for remote control and security Miner safety and location Timely receipt of large volumes of information

Apr 1, 2005

By A. H. Harvey, M. Delangen, A. D. Fernie

"A large-scale expansion to Pacific Coast Bulk Terminals Ltd. has now been completed and placed in operation. The original plant, built approximately eight years ago, consists of the direct rail-car to ship transfer of bulk commodities. The extension includes additional rail-car unloading, a transfer house system for directing commodities to storage or ship, major storage and reclaim facilities, a second shiploader and a second deep-sea berth. In addition to the facilities for overseas shipments, a wood-chip loader and a barge berth have been installed for domestic shipments of wood chips and, occasionally, for other local commodities. The design considerations imposed by the nature of the products to be handled are covered in this paper."

Jan 1, 1969

By G. Bonin, R. P. Preston

"This paper presents a series of case studies where spherical camera photographs were used to generate 3D shaft models using photogrammetric methods. The shaft models were, checked for accuracy by comparing them to overlapping laser scan data, provided survey data or idealized shaft models. Short lengths of model were found to more accurately reproduce the shaft surface, with a best observed accuracy of 8 mm. Longer models encountered errors with accumulated errors as exhibited by slight deviations from vertical or slightly conical model shape. At present, the models are considered acceptable for general documentation and gross change detection. INTRODUCTION Shaft inspections are required by mining regulations in many jurisdictions and are commonly completed by trained mine personnel via visual inspections. This can be time consuming and prone to errors due to lapses in attention and the rapid travel rate required to inspect an entire shaft in a reasonable amount of time. Similarly, because of the time requirements, there can be impacts on other aspects of mining as a result of occupying the shaft for inspections. Spherical cameras with supplemental light systems offer a modern addition or alternative to conventional inspections. These cameras can be lowered relatively quickly to collect high definition, fully illuminated videos of the shaft that can be reviewed in detail later while the shaft returns to service (Gillis et.al., 2019). The use of cameras offers a further opportunity for valuable survey data generation from the same original data stream. The video data can be processed into three-dimensional (3D) models using Structure-from-Motion (Westoby et al., 2012) based photogrammetric methods. Depending on the quality of the source video and availability of survey control (required for all photogrammetry models) these models can be very accurate. Shaft surveying can be conducted with traditional theodolite methods but such surveys are time consuming and limited in their data density. Similarly, scans can be completed using conventional terrestrial laser scanners, but this requires a significant number of distinct setups to provide sufficient overlap between scans. Work is being conducted both on the laser scanning (SLAM, Durrant-Whyte & Bailey, 2006) and photogrammetry fronts towards kinetic scanning (Benecke, 2017) systems. The major advancement which is permitting these kinetic systems is Inertial Measurement Units (IMUs) which can provide localization in GPS denied environments and reduce errors associated with the open traverse format associated with shaft scanning."

Jan 1, 2019

By D. Yuan, L. Yan, R. Kalanchey, M. J. Collins, I. M. Masters

Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project located in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Since the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The "lime boil" process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95 to 98%; silver extraction was up to 94%.

Jan 1, 2011

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is con-?ned by tectonic shear zones between marble and metapelites, extending laterally into the marble astabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical pro?les across mineralized zones con?rm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the in-situ supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly in?uenced by seasonal ?uctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent ?ooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2~10-3.8 to 10-1.4) and oxygenated (fO2~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sul?des and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+was transportedinto karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997