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By J L. Bos, D J. Readett

As mining progressed through the Girilambone oxide orebodies, down to the primary sulphide zones, each successive stratiform layer yielded copper bearing ores of changing mineralogy and grade. Constant changes, innovations and optimisation were required to be applied to the heap leach, solvent extraction and electrowinning operations, to efficiently produce LME Grade A quality copper cathodes from this ore. The changing ore types required various crushing, stacking and heap leach irrigation methods to ensure that optimum recovery from the predominantly low-grade copper ores was efficiently achieved. Subsequently, innovations such as heap aeration and heap rejuvenation techniques were implemented. The constant selective removal of copper from the maturing heap leach liquors, coupled with an increase in iron(III) concentration, required solvent extraction optimisation. Changes to the original solvent extraction circuit configuration, combined with changes in operating parameters and procedures, allowed effective processing with changing heap liquor compositions. The electrowinning tankhouse was also upgraded and optimised through continued testwork and monitoring, to maximise cathode production and quality

Jan 1, 2000

By G T. Hefter, P Singh

Sulphur dioxide oxidation is an attractive alternative anodic reaction to the evolution of oxygen in copper electrowinning. Accordingly, the electrochemical oxidation of SO2 in aqueous 1.0 x 10-1 mol/L NaClO4 has been studied at pH 2.3 using platinum and glassy carbon electrodes. On the platinum electrode SO2 oxidation occurred on the forward scan at 0.96 V and on the reverse scan at 0.63 V. For GC, a single SO2 oxidation peak occurred at 1.40 V on the forward scan. SO2 oxidation on both electrode substrates was hampered by oxide layer formation. The electrode could be reactivated however, by oxide layer reduction. Although reactivation was most successful for platinum, SO2 oxidation on platinum is quite complex, with this evidenced by the reverse scan anodic peak. Glassy carbon shows simpler behaviour and thus, is the preferred substrate for SO2 oxidation.

Jan 1, 1998

By M W. Chen, I Canbulat, S Saydam, C G. Zhang

The height of fracturing (HoF) measures the propagation distance of continuous fracturing from the mining horizon and is also termed the height of cracking (Hebblewhite, 2020; Khanal et al, 2019) or hydrologically the height of groundwater drainage (Tammetta, 2013). In longwall practice, HoF is an important predictive indicator for assessing the dewatering effect of panel extraction on the shallow aquifer and surface flows. The HoF determination is basically dependent on field measurement works, typically using surface extensometer, borehole televiewer imaging, piezometer monitoring, packer testing, borehole breakout logging, and isotopic tracer monitoring (Brown and Walsh, 2022; Corbett, 2022; Hebblewhite, 2020; Holla and Armstrong, 1986; Mills and O’Grady, 1998; Walsh et al, 2022a, 2022b). These methods or tools have been widely applied to observe rock fracturing and groundwater responses to longwalls at Australian coalmines, for example, Dendrobium Mine (Brown and Walsh, 2022; Walsh et al, 2022b), Appin Mine (Walsh et al, 2022a), and Springvale Mine (Corbett, 2022). In Chinese mines, borehole televiewer imaging and packer testing are more frequently used due to convenient instrumentation, quick testing, and not requiring long-term maintenance of the instrumentation boreholes. The HoF determination also involves further raw data interpretations, for which specialist software for data extraction and quantitative criteria for bounding the fracture transition and termination are necessary. By combining the measured fracture distribution and longwall parameters regarding panel geometry and geological settings, several HoF models have been developed for conceptualising the understanding of strata depressurisation and providing mine engineers fast calculation tools for HoF prediction. The Mackie model considered the height of fracturing as the upper bound of fractured zone and revealed that within the fractured zone there are highly connected fractures and accordingly porosity enhancement and groundwater depressurisation, where the fracture network can be less transmissive from the mining horizon up (Hebblewhite, 2020). The fractured zone shares similar fracturing regime but different heights in varying models: HoF is 30 to 58 times of the mining height (t) based on Australian, Soviet and UK experience (Kendorski, 1993, 2006), and 21 to 33 t according to the field measurements in NSW Central Coast, Australia (Galvin, 2016). Some Australian longwall mines adopt Ditton model (Ditton and Merrick, 2014) (Equations 1.1 and 1.2 in Table 1) sourcing from NSW coalfield experience for HoF prediction, while Liu model (Liu, 1981) (Equations 2.1 to 2.4 in Table 1) developed from 27 coalmines in China is frequently used by Chinese coalmines.

Nov 29, 2022

The rights of nations to explore and exploit minerals in the continental shelf were recognized by the 1958 Convention on the Continental Shelf. The Commonwealth Government has expressed the view that, as a party to the Convention, it has, by virtue of its foreign affairs power, full rights to legislate with respect to offshore minerals. States have taken the view that the rights recognized as extending into the continental shelf are land mineral rights, which belong to the States, and the Commonwealth legislative power in this field is strictly limited. Without prejudice to each other's rights, Commonwealth and States agreed to "mirror" legislation in relation to offshore petroleum. Commonwealth and State legislation, of which the operative parts are in identical terms, are both administered, in relation to areas adjacent to each State, by State Ministers of Mines. The legislation has functioned well in practice, though difficulties are encountered by the Commonwealth Government due to lack of direct accountability to Commonwealth Parliament. An alternative scheme designed to overcome this problem is outlined.

Jan 1, 1974

The Project Financing Industry is currently being expanded en- compassing greater competition due to the improved worldwide economy. This has meant that money is in greater supply than demand for both loan and equity investment and is available for larger and higher risk ventures. The consequence of this is that the Project Financing Industry should be better able to provide more innovative forms of financing to meet the needs of mining and petroleum companies, regardless of size. Large mining and petroleum companies in Papua New Guinea should therefore be looking for ways to raise equity funds for exploration in greenfield areas, diversifying their risks through acquisition, and seeking to reduce their costs of borrowings. The small to medium sized mining sector should be looking to raise equity for increased ex- ploration on tenements and, where possible, to raise borrowings to fund expansion and further development of their projects. In summary, it is a period during which companies should take ad- vantage of available funding to augment their strategic plans and increase their long term returns to shareholders.

Jan 1, 1997

By Oliveira JF

Thiourea is an alternative reagent for cyanide in gold leaching. The recovery of gold from acidic thiourea solutions by adsorption on activated carbon is based on methods similar to those applied for the extracting of gold from cyanide solutions, but the mechanism involved in the process is not completely understood. In the present work, studies were carried out to evaluate the adsorption of gold onto activated carbon. Experimental data showed good agreement with both the Freundlich and Langmuir isotherms. The adsorption of gold from acidic thiourea solutions proved to be an endothermic process, while the adsorption from cyanide is known to be exothermic. The isosteric heat of adsorption of -11.3 kcal/mol in the early stages of the adsorption is an indication of a process involving chemisorption. The effect of temperature was studied between 15¦C and 55¦C. An activation energy of 3.5 kcal/mol was determined by the Arrhenius plot, which indicates that the controlling step in the kinetics of adsorption is the diffusion onto the porous structure of the activated carbon.

Jan 1, 1993

Mine dewatering has long been a problem with mines and some of the shallowest mines have the biggest problems. Machinery was developed by the ancients for raising water by rope buckets with treadmills or by horse whim. From the 1700's on into the early part of this century, massive cornish pumps or equivalent were the vogue powered by steam. One Australian mine pumping system was claimed to be the largest in the world just after the turn of the century. It was installed at Beaconsfield in Tasmania and the mine, like so many other mines of the period, were beaten by problems and cost associated with mine dewatering. The owners of that mine are looking at the feasibility of dewatering using surface drilled wells. Much simpler and smaller pumps are the order now and it is feasible to use boreholes instead of shafts to contain the pumps or else to use the holes to convey discharge waters to the surface from pumps located in drives or stopes.

Jan 1, 1988

By D Brennan, S Jahanshahi, F Jorgensen

The recycling of metals can be very efficient with careful selection of the material being recycled. The volume and value of recycled ferrous scrap has lead to the development of steel mini-mills which in turn has caused major changes to the steel industry. Although much smaller in volume, the recycling of lead is very significant, with battery recycling accounting for 60 per cent of annual world production. This high recycle rate can be attributed to the relatively uniform feed-stock from lead-acid batteries. The recycling rates of other metals are considerably lower due to longer use and non-uniform product usage that results in less efficient segregation and processing. It is clear that recycling of metals has advantages but its sustainability is uncertain. What are the key benefits of metal recycling? Metal recycling has technical, economic and social impacts. It is relatively easy to assess recycling on a technical basis, but the social impacts are harder to evaluate. This paper examines some of the issues in evaluating the sustainability of metal recycling.

Jan 1, 2002

By J H. Heo, J H. Park, M J. Lee

In this paper, the challenging points regarding the high temperature physical chemistry of slags to achieve the improved and stable electric arc furnace (EAF) or electric smelting furnace (ESF) technology on the way to green steel will be reviewed, and the recent experimental and modelling research will be discussed. For example, the initial melting phenomena of hot briquetted iron (HBI) and the slag formation behaviour was observed using a high-frequency induction furnace. Main component of gangue oxides in HBI was SiO2, Al2O3, and CaO in conjunction with unreduced iron oxide. To increase the dephosphorisation efficiency, the distribution ratio of phosphorus between metal and slag was calculated using FactSage™ software, version 8.2 (CRCT ThermFact, Inc., Montreal, Canada) and was compared to the measured results. The optimisation of slag chemistry is required not only for maximum dephosphorisation efficiency with good slag foamability but also for minimum slag volume with less refractory corrosion in EAF process. The slag chemistry is also one of key parameters affecting the operation efficiency in ESF in view of FeO reduction behaviour, viscosity, sulfide capacity, etc.

Jun 19, 2024

The T33-34 blast, the first major blast at Mount Isa Mines, broke 1,360,000 tonnes of copper ore using 349 tonnes of explosives. The original concept of firing T33, T34, T35 and U37 separately was changed during the life of the project due to adverse ground conditions. These conditions also caused the stoping method to be modified after the firing of the stopes had started. To stabilise the two stopes T33 and T34 where large fall off was occurring, rib pillars were left in the original slot. This caused the blast design to be more complex as these rib pillars had to "lead" the blast. The implication of such a large blast on the underground and surface environment was thoroughly investigated and precautions taken. The charging time of the blast was six weeks. Hook-up was started four days before the blast and continued until two hours prior to the blast. Detailed scheduling was carried out of other work that had to be done in the 24 hours before the blast to ensure that there were no delays in the firing.

Jan 1, 1977

Computer programs for the storage, retrieval and use of basic thermodynamic and physical property data for chemical substances are described. Methods are presented for the collection, critical assessment and pre- processing of source data for files containing enthalpy, entropy and heat capacity data for 3000 compounds, enthalpy and excess entropy for 200 dilute solutions and critical propert- ies and vapour pressure for 600 compounds. Retrieval programs are discussed which allow the tabulation or plotting of many basic and derived thermodynamic properties for chemical substances or balanced reactions. Examples are given of the use of such data to infer the stability or corrosion resistance of materials and the feasibility, yield and heat release of reactions. A general purpose calculation program is discussed which allows the equilibrium compos- ition to be found for complex systems with many species and phases, using the method of Gibbs energy minimization. Methods of correction for non-ideal behaviour in these systems are discussed, as well as methods for fixing, maximizing or minimizing any desired property of the system. Examples are given of the simulation of various laboratory Experiments and industrial processes by this method.

Jan 1, 1977

This paper reviews an analytical model that defines the relationship of weight-weighted or volume-weighted average haulage distance with bench height and other related parameters; presents the optimum bench heights under various conditions in terms of minimising the weighted average haulage distance of ore/waste during the full lifetime of an open pit mine, and discusses the truck-haulage economics of mining open pits by high bench, specifically by 15 m, 18 m and 20 m bench through marginal analysis. The observations from these analyses disprove the previous conflicting assertions that the overall weighted average haulage distance either increases or decreases monotonically with bench height. It is concluded that: (i) an increase of bench height to 15 m from 12 m is likely to be viable under the general conditions of large-scale deep open-pit mines; (ii) the reduction of haulage cost is limited with the case of increasing bench height to 18 m from 15 m; and (iii) the feasibility of mining open pits by 20 m benches is generally questionable. These conclusions may serve as a useful guide for those who advocate open pit mining by high benches.

Jan 1, 1995

By Spark R. F

The copper deposits at Pernatty Lagoon are predominately djurleite-digenite bodies beneath the permanent water table, and chrysocolla-atacamite-malachite above the permanent water table. The minerals havebeen deposited as sheets, lobes, and pods in zones suggestive of permeability channels or permeability basius with respect to groundwater circulation.Pyrite is deposited in the form of framboids, which reflects its biogenic origin. Copper-iron sulphides deposit by replacement of pre-existent pyrite, and rarely by direct deposition. The latter mode of formation results in complex crustification bandings of chalcopyrite, bornite, sulphur rich bornites, digenite, and blue remaining covellites. The copper-iron sulphides appear to reequilibrate under constrained oxidation, resulting in an iron depletion and associated copper enrichment, the final product of which is a djurleite-digenite assemblage and associated with goethite. Where copper mineralization/ host rock relationships have rendered the rocks entirely impermeable to post ore groundwater movement, then the copper-iron sulphides are preserved as the ore assemblages.Minor and trace minerals observed include sphalerite, carrollite, galena, wittichenite, and possibly tetrahedrite in the primary ores. In the oxidized ores cllprite, tenorite, and trace brochantite have been found.

Jan 1, 1976

By M E. Malmstr÷m

Quantification of site-specific sulfide oxidation rates is crucial to accuracy of prediction of, for example, the environmental impact of a mine site. Sulfide oxidation reactions are reportedly increased by bacterial mediation; determination of abiotic and biotic weathering rates thus requires the establishment of sterile control samples. However, sterilisation often involves exposure of samples to extreme conditions that may alter the physical, chemical, or mineralogical characteristics of the tailings and hence affect element release rates. The impact of various sterilisation techniques, common and novel, on the element release rates from tailings from the Kristineberg site, northern Sweden, has been investigated. Batch weathering experiments indicated that the different methods of sterilisation (autoclaving, heat treatment, ethanol/heat treatment, application of antibiotics, rinsing with distilled water, and γ-radiation) did not greatly affect long-term element release rates. Long-term experiments (>30 days) are thus to be recommended for establishment of weathering rates. Sterilised and untreated control samples showed similar element release rates after ~100 days of experiments; possible explanations include that microbial oxidation is not important under our experimental conditions (Po2 = 0.2 atm, pH ~2.3, 22¦C, 0.01 M HNO3, no additional nutrients).

Jan 1, 2003

While South Africa is well endowed with mineral resources, it is generally accepted that its future will be determined more by the development of its human resources than its mineral wealth. The country has throughout its modern history suffered from an over-supply of unskilled labour and a shortage of skilled and professional manpower. There has furthermore always been an over-reliance on Whites as an internal source of professional manpower, supplemented by immigration wherever possible. Better utilisation of other population groups in professional positions has been hampered by the general lack of education and training among such groups. Although many problems still remain, there are emerging trends which are likely to positively affect the training of professional manpower in the future. The direct and indirect influences that are likely to affect professional training at the macro level include 1. government policy and objectives in respect of manpower education and training, 2. the emergence of technikons as fully- fledged tertiary education institutions, 3. demographic trends in South Africa as they pertain to education, 4. political and statutory developments in the country, 5. industry involvement in tertiary education, and 6. professional registration.

Jan 1, 1986

More than ten seafloor massive sulfides (SMSs), which tend to be enriched in Au and Ag with varying amounts of Zn, Pb and Ba, have been reported in Japanese Exclusive Economic Zone (EEZ) including the Jade hydrothermal field in the Izena cauldron Okinawa, theSunrise deposit in Myojin knoll Izu-Ogasawara, and other active deposits found in the past 20 years. From the fiscal year 2008 some universities in Japan will begin development of sensing devices to delineate surface distributions of known SMSs and to find new ones. The devices would be deployed by an autonomous underwater vehicle (AUV) or remotely-operated underwater vehicle (ROV) later in active hydrothermal fields and potential areas in the EEZ. On the other hand, different laboratories are planning to research and evaluate SMSs with state-of-the-art methods such as the benthic multi-coring system and geophysical devices to collect information in deeper parts of the SMSs. In this session recent projects on exploration and evaluation of SMSs with some new trials including geophysical and geological surveys in Japan will be reported. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By L C. Thompson

This paper examines six sites in Northern Nevada where soils and groundwater have been contaminated with petroleum hydrocarbons and/or organochlorine compounds. All six of the sites studied are located in an arid, highly mineralised area of the Great Basin. As a part of the original geochemical investigation to determine the applicability of biodegradation in the remediation of petroleum impacted soils and aquifers extremely high levels of uranium, vanadium and molybdenum were detected in the anaerobic groundwaters associated with some of the hydrocarbon plumes. Some groundwater uranium concentrations exceeded 7 ppm while vanadium and molybdenum concentrations reached almost one ppm. The bioleaching appeared to be most effective under methanogenic conditions and was noted in both high sulfide and low sulfide environments. Background concentrations of uranium in the formation were measured between 6 ppm and 109 ppm and highly dependent upon depth with the highest levels being found in association with evaporites. Unlike uranium, vanadium tended to concentrate in free-floating organic fractions reaching levels as high as 2000 ppm in the layers of jet fuel floating above the groundwater. Molybdenum was the most resistant of the three metals to bioleaching.

Jan 1, 2004

By Ngai WCT

Over 90 per cent of the explosives in Hong Kong are used in civil engineering works. The Hong Kong Government controls all explosives and delivers on a daily basis to each site which it has licensed. Such deliveries need to be arranged the day before actual delivery. With the vagaries of the traffic in Hong Kong, contractors do not necessarily know the time of arrival of explosives. Contractors in general would like to reduce their exposure to these potential delays and the high cost of explosives deliveries. The high population density and urbanisation means that rock blasting has to be carried out in close proximity to other property. In order to protect life, property and utilities, it is not only necessary to employ proper blasting techniques but also to adopt effective safety measures. The Route 3 Advance Earthworks project is located on the north-west corner of Tsing Yi Island, Hong Kong. It is one of the Airport Core Programme projects for the new Chek Lap Kok Airport. Secured by Leighton Contractors (Asia) Ltd in early-1992, the work commenced in May of the same year, with completion and handover to the Hong Kong Government in May 1995.

Jan 1, 1995

The paper sets out the context for water and the challenges that have to be faced in the battle to alleviate global poverty. It acknowledges that the world has been blessed with abundant water but because of population and development pressures, and the projected changes in climate, avoiding serious water shortages in some places will be difficult. MiningÆs use of water is placed in context and the paper then considers the specific threats to the industry in terms of availability and price and the need to find mechanisms to deal with the issue of resource degradation caused by abandoned mines. Rio TintoÆs use of water is then set out and three examples are given of how different water challenges have been addressed. The paper goes on to consider each element of a water strategy designed to move Rio TintoÆs performance towards excellence. This strategy incorporates improved management procedures (policy, principles, standards and targets), performance enhancement (through use of the Rio Tinto Water diagnostic and technology changes) and working with others in the academic and NGO community who seek to address the same global issue.

Jan 1, 2003

By S Hapugoda, Y Tang, L Lu

The steel industry is one of the global leading CO2 emitters, accounting for approximately 7 per cent of global anthropogenic CO2 emissions. In 2022, the world produced 1878.5 Mt of crude steel. About 70.8 per cent of the world’s crude steel was produced by integrated steel mills through the blast furnace and basic oxygen furnace (BF-BOF) process, while the remainder was produced largely by mini mills using electrical arc furnaces (EAF). Compared with gas-based DRI and scrap-based EAF processes, the direct CO2 emissions from the BF-BOF process and the coal based DRI and EAF process are significantly more, as both the processes rely heavily on fossil fuels, such as coke and pulverised coal, to provide energy and reduce iron oxides. Hydrogen is very reactive and reduces iron oxides to metallic iron without generating CO2. Therefore, substitution of hydrogen for fossil fuels in these processes presents a good opportunity to significantly decarbonise the steel industry. This paper will first discuss the thermodynamic and kinetic characteristics of hydrogen and carbothermic reductions of iron oxides and then examine the behaviours of different ore types present in Australia iron ores during hydrogen reduction.

Sep 18, 2023