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By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

By Grano S. R, Kilgariff B

The Renisun Tin concentrator treats an ore containing I's per cent till as cassiterite and 22 per cent sulphur in a range of sulphide minerals. predominantly pyrrhotite. The sulphide minerals are removed by flotation using copper sulphate (CuS

Jan 1, 1997

Coal is a very versatile resource, having variable characteristics and having potential for a wide variety of mar- kets. Australia has extensive deposits of black coal, although they are concentrated mainly in Eastern Australia. Assessments of the currently known reserves are related to the qualities of these reserves. Markets available to black coal fall into the broad groupings of metallurgical, fuel, conversion and miscellaneous markets and the requirements of these markets are related to coal characteristics. Market trends in Australia and on the export market are discussed and projected forward. By the end of this century Australian consumption of black coal could well be 100 million tonnes per annum, and, in the absence of any export restriction, a similar amount is likely to be exported. Currently defined black coal resources in Australia will last at least 600 years at these projected rates of consumption. Although the position appears satisfactory in considering the projected life of the black coal resources, there is a serious lack of detailed information on reserves, mining and preparation yields, quality and possible environmental restrictions. Action is required on three parallel courses: (1) a consistent, systematic and extensive survey of current coal resources in Australia, (2) accelerated exploration activity to define poorly prospected and potential areas, and (3) regular updating and extension of the knowledge of Australia's coal resources. This information would be of tremendous assistance for the formulation of a national energy policy on coal.

Jan 1, 1975

THIS paper deals with the handling of the various materials used in the 100-ton zinc plant at Risdon, and, in view of the magnitude of the works, the configuration of the ground covered by these works, the variety of the rnaterials used, and the large quantities, a very attractive and interesting subject is opened.The works are situated on the right bank of the River Derwent, about four miles above Hobart, the capital city of Tasmania. The Risdon works cover a space of 149 acres, the area being :3800 yards long by 2800 yards wide, and the elevations vary from 6 ft. above high-water mark at the wharf and foreshore to 163 ft. above high-water mark at the power station, these being the limiting points as regards elevation which are considered in this paper. Throughout the paper elevations are given in feet above high-water mark. Fig. 1 shows a general view of the works taken from the opposite bank of the River Derwent. The wharf is clearly shown, with SS Kekerangu loading residue; behind the wharf is seen the inclined conveyor leading to the cakine bin; further up the hill is the leaching division. No. 1 haulage runs to the left of this up to a point on the left of the power station, the large reinforced concrete building at the top of the hill. Below this is the cell room, the largest building on the plant. The roasting division, not very clearly seen, lies at the foot of the main stack, and the casting division lies to the left of this, between the leaching division and the cell room. A large wharf has been construl'ted alongside the works. This wharf is 880 ft. long and 60 ft. wide. It is capable of berthing large overseas steamers, as at low tide there is a depth of :30 ft. of water. The rise and fall of the tide at the wharf is 4 ft. 6in., and the river is navigable at all states of the tide. Just above the company's wharf...

Jan 1, 1923

For the past five years the University of Queenslandhas, through its various workshops, been preaching to Australia that there was a potentially hazardous situation from earthquakes for urban Australia. A few people outside The University accepted this, but largely the warnings fell on deaf ears.The 1989 Newcastle earthquake changed that per-ception. The most important lessons to emerge from Newcastle were (i)the realization that in continental areas small earthquakes cause widespread damage:(ii)the local geology of an area is of great importance in the damage done by an earthquake.These two factors clearly indicate that, in the future, we must take far greater account of the "Urban Geology" of an area. This paper discusses the need for urban geology and its impact on seismic risk and compares that with the traditional methods of assessing seismic risk.

Jan 1, 1990

In any strip coal mining operation the aosL important single operating unit is the dragline. Because the capital and operating costs of a dragline are high, it is desirable to operate these machines at their maximum efficiency. Thiess Bros. Pty. Limited operate a Bucyrus-Erie 1350 Walking dragline at their Callide coal mine. The operating conditions at the Callide Mine are different from those of other coal mines situated in Central Queens ,nd. The topography is rugged, the coal seam is thick, and the overburden is hard and inter- HH,inded. Several different operating techniques for a large dragline working under these con- ditinns arc discrossmd it tt

Jan 1, 1978

By Preston JC, Richards DJ

A multicommodity exploration programme was mounted in the 1970s by CRA Exploration Pty. Limited over a major part of the southern Murray Basin in Victoria. Commodities sought were brown and black coal, gold, uranium, diamonds, titanium and zirconium rich heavy minerals, and base metals. An area of 40 000 km2 was held under exploration licences by the Company. Exploration techniques used were literature research, airborne magnetics and gamma ray spectrometry, drilling, and geophysical well logging. Targets were defined in both the Tertiary basin sediments and the underlying Palaeozoic sedimentary and igneous rocks. Although exploration is continuing, large resources of brown coal and low grade titanium rich heavy minerals have already been discovered. Exploration for uranium was abandoned in accordance with statutory requirements. The search for significant resources of the other commodities has not been successful.

Jan 1, 1986

Trial ore production began at the Hilton Mine in 1987 with ore being trucked into Mount Isa for treatment at the Lead/zinc Concentrator. The expansion of output from the Hilton mine required additional concentrator capacity which led to the design and construction of the Hilton Concentrator. Systematic laboratory and Pilot Plant testwork dating back to 1968 to develop a flowsheet and reagent regime suited to the varied and generally complex mineralogy of the Hilton ore was successfully concluded with a Pilot Plant trial using a sulphoxy based sphalerite depression system in early 1988.In May 1988, a decision was made to build a 750 000 t/y concentrator with some novel technological and capital-efficient features. The Hilton Concentrator commenced operations in December 1989 reaching target grinding rates and metallurgical performance by mid-1990. Current ore treatment rate is 800 000 t/y.Lead concentrates assaying 43 - 48 per cent Pb are combined with the Lead/Zinc Concentrator lead concentrates and smelted at Mount Isa. Zinc and Low Grade Middlings (LGM) concentrates are filtered in the zinc filter plant at Isa with those from the Lead/Zinc Concentrator and then railed to Townsville for export or treatment in Australia.

Jan 1, 1993

Although developed primarily for sintering tantalum, the unit to be described can be used to heat-treat metals in the form ofa bar, wire or strip, by passing a current through them. The upper temperature limit with this type of heating is the melting point of the metal being heated.The unit was designed for vacuum work, but. various gases can be used if required.Briefly, the vacuum sintering furnace consists of a bell which is counter-balanced and may be lowered onto the brass base plate which holds the electrodes. A rubber ring seal is used for vacuum work. The lower flexible grips are bolted to the brass base plate which is at earth 'potential, while the other electrode passes through the plate by way of an electrically insulated vacuum seal. This upper electrode, the height of which can be altered as desired, the lower grips, and the bell are water cooled. The vacuum line to the pumps and a line to the vacuum gauges also lead from the base plate. The more important sections of the unit are described below.THE BELLThe unit was designed so that the bell could be lifted clear of the base plate and the electrodes, thus facilitating adjustment of the latter and the mounting of the specimen to be heated. A double walled steel bell, 20 in. high, with t in. cavity was used. The bell was fabricated from 10 gauge mild steel sheet using a double overlapping run of arc welding for all seams. A water inlet and outlet...

Jan 1, 1946

In open cut gold mining at Mt Magnet and Reedy, grade control sampling is done with inclined RC drilling using one metre samples. In the small open cuts at Rothsay blasthole sampling was successfully used. Underground sampling for gold and copper grades at Rothsay is done using chip sampling. At the Youanmi open pits both Ditchwitch Earthsawing and RC drilling are used.All assay data are interpreted on sections and plans using a customised SURPAC system. Reconciliations of the grade control predictions of tonnes and grade against initial ore reserves, mining production and milling results are carried out monthly.

Jan 1, 1990

By Bogie I, White P. J

Active geothermal systems occur widely in Sumatra and in the Taupo Volcanic Zone (TVZ) of New Zealand. There are also many occurrences of epithermal gold mineralisation in Sumatra, some of which are economic. Minor sub-economic occurrences of gold have been reported in the TVZ but none have yet been mined. There are both similarities and differences in the nature of the active geothermal systems and mineral deposits in Sumatra and New Zealand, which can be systematically related to the tectonic setting. The thicker crust and consequent predominance of silicic volcanism in New Zealand leads to hydrothermal. systems which are little eroded and with limited lateral outflows. The systems in Sumatra are of mixed character, with some of the characteristics of those in andesitic island arcs such as Java or the Philippines, eg a higher proportion of systems with identifiable acid magmatic volatiles, a greater potential for deep erosion and lateral outflows than in New Zealand; but modified by the more oblique component of subduction and thickened crust so that some are localised in volcano-tectonic depressions and consequently have high piezometric levels of primary hydrothermal fluid. The unusual occurrence of calcic zeolites in veins associated with gold mineralisation in Sumatra is thought to be indicative of "satellite" boiling zones along de-gassed hydrothermal outflows.

Jan 1, 1995

By E ¦iftti, A Koenig

Natural sphalerite associated with copper, silver, lead-zinc, tin and tungsten deposits from various world-famous mineral deposits have been studied by cathodoluminescence (CL), laser ablasion inductively coupled plasma mass spectrometry (LA-ICP-MS), electron probe microanalysis (EPMA) and electron paramagnetic resonance (EPR) to determine the relationship between trace element type and content and the CL properties of sphalerite. In general, sphalerite produces a spectrum of CL colour under electron bombardment that includes deep blue, turquoise, lime green, yellow-orange, orange-red and dull dark red depending on the type and concentration of trace quantities of activator ions. Sphalerite from most deposits shows a bright yellow-orange CL colour with lmax centred at 585 nm due to Mn2+ ion, and the intensity of CL is strongly dependent primarily on Fe2+ concentration. The blue emission band with lmax centred at 470 - 490 nm correlates with Ga and Ag at the Tsumeb, Horn Silver, Balmat and Kankoy mines. Colloform sphalerite from older well-known European lead-zinc deposits and late Cretaceous Kuroko-type VMS deposits of Turkey shows intense yellowish CL colour and their CL spectra are characterised by extremely broad emission bands ranging from 450 to 750 nm. These samples are characterised by low Mn (<10 ppm) and Ag (<1 ppm), and they are enriched in Tl (1 - 30 ppm) and Pb (80 - 1500 ppm). Strong green CL is produced by sphalerite from the Balmat-Edwards district. Amber, lime-green and red-orange sphalerite produced weak orange-red CL at room temperatures, with several emission bands centred at 490, 580, 630, 680, 745, with lmax at 630 nm being the strongest. These emission bands are well correlated with trace quantities of Sn, In, Cu and Mn activators. Sphalerite from the famous Ogdensburg and Franklin mines exhibited brilliant deep blue and orange CL colours and the blue CL may be related to Se. Cathodoluminescence behaviour of sphalerite serves to characterise ore types and help detect technologically important trace elements.

Jan 1, 2008

The paper presents an overview of the mining industry of Papua New Guinea. Although the Bougainville problem is still unresolved, new mines like Ok Tedi, Misima and Porgera, which have come on stream during recent past, have raised hopes of sustained growth period in the industry. Kutubu Oilfield is also being developed in the Southern Highlands and the oil production has commenced from July 1992. Government revenue from these mega projects will increase five-fold during 1993 and 1994. A new mine which is being planned is the fabulous Lihir Deposit, on an island renowned to be full of gold. Gold occurs within a volcano which still contains high temperature ground water because the system which created the deposit is still geothermally active.In Papua New Guinea, problems of environmental management are far easier to tackle than those of a socio-political and economic nature involving compensation payments to the landowners and the distribution of royalties and taxes between the national and provincial governments. At the socio-political level, the country has not been able to resolve the problems of land rights versus mining rights. Whenever mining starts in a big way, it raises people's expectations to a very high level, which then becomes the focal point of dispute between landowners, provincial governments, national government and mining companies. A new system called 'Forum' has been tried to bring all parties together and son out the issues. The system appears to be working well in new mines like Ok Icdi, Porgera, Misima and Kutubu Oilfields.

Jan 1, 1993

By Nilsson C

Man has always been and will always be part of his environment, in ,a good, bad or indifferent manner. Until quite recently, this environment has been the atmospheric boundary layer above the land masses, and to a limited extent the air-sea interface of the oceans. Since the days when he lived in caves, he has built up a wealth of observations on these two environments,-with ever-increasing scientific precision which unfortunately until quite recently was completely insufficient for modern capabilities of data analysis. Consequently, in a sense, he has left in his wake thousands of years of missed, opportunities for making exact observations and increasing his understanding. The data of the past are lost and he has to be satisfied with what he can assemble from now on when his environ- ment, largely as a result of his actions, is exhibiting more and more rapid variations in time; in other words, time series of observations of phenomena are required, the length of which is critical for most purposes of analysis.

Jan 1, 1970

Mt. Whaleback is in the Pilbara region of Western Australia approximately 1200 kilometers north of Perth, the State capital. In this deposit the Mt. Newman Joint Venturers are mining ore reserves totalling 1500 million tonnes of high grade hematite averaging 64.0% Fe. In addition to Mt. Whaleback, 38 ore bodies have so far been identified outside Mt. Whaleback on the Company's remaining 75,000 hectares of lease area. These ore bodies contain major tonnages of iron ore. Extraction at present is planned at a rate of 37 million tonnes per annum at an ore-to-waste ratio of approximately 1 to 1.4. The ore is railed north to Port Hedland on the Indian Ocean where the different products are screened, crushed and blended prior to shipping. The purpose of this paper is to acquaint the reader with the facilities installed in the Mt. Newman operation to form a background to the sampling techniques employed, describe the precisions which were achieved in experiments conducted February through June, 1976 and also to assess the degree of blending which takes place during the various processes and to put a quantitative measure to the degree of blending. There have been many excellent papers written on the more theoretical aspects

Jan 1, 1976

By Amanatidis A

In this paper, the kinetics of iron precipitation as sodium jarosite from aqueous solution is investigated. The determination of the reaction mechanism is attempted based on the experimental data of iron removal as a function of time, without using the characteristics of the precipitate.Experiments at the temperature range from 50° to 95°C were carried out with initial conditions of iron concentration IQ g/L, sodium sulphate concentration 25.44 g/L, sulphuric acid concentration 3.68 g/L, pH = 1.5 and agitation rate 600 rpm. Temperature greatly and positively influences iron precipitation from the solution and this is accompanied by pH decrease. The activation energy was determined using the maximum values of the precipitation rate, which were evaluated by polynomial fitting of the sigmoidal shape experimental curves, and it was found to be 44.37 kcallmole. The determination of the rate-controll ing mechanism was based on some criteria used for the discrimination among the three probable mechanisms of precipitation (diffusion, mononuclear nucleation, polynuclear nucleation). These criteria utilise various funetions of the recovery 'a' of iron precipitated versus time, the most important of which are the chronomals. The results of the kinetic analysis procedure showed that the polynuclear nucleation growth mechanism controls the precipitation of iron as sodium jarosite. This was confirmed by the high value of activation energy, excluding diffusion as the controlling mechanism.

Jan 1, 1993

By de Lassar de Pressigny Y

IRSID has in its laboratories two experi mental counter-current reduction furnaces allo- wing the simulation of the physico-chemical conditions of reduction in any gas-solid coun- ter-current process, including the blast furnace and direct-reduction shaft-furnaces. The counter current is realized by an electric furnace mo- ving along a laboratory tube filled with the material to be tested. The reducing gas stream in the tube travels in the same direction as the furnace After reduction, twenty samples, with dif- ferent degrees of reduction and which can be related to different levels of an industrial furnace, are taken from the tube and subjected to various quality tests. Experiments were realized to determine the behaviour of various types of industrial pellets when reduced under either blast furnace or shaft furnace conditions. The results show the large influence of the reducing conditions on any pa- rameter characteristic of the quality of the pellets : reduction efficiency, swelling, cru- shing strength and disintegration.

Jan 1, 1974

By Francis R. S, Campbell J. J

Aberfoyle's Hellyer Division has filtered very fine flotation concentrates using two different makes of pressure filter. At the Luina concentrator a Larox pressure filter was used to treat a combined Pb + Zn or bulk concentrate. At the Hellyer concentrator two Lasta pressure filters are being used to filter copper/silver, lead, zinc and bulk concentrates. Operating parameters and performance at both operations are described. In both concentrators it was found that correct cloth selection was critical and that cloth failures contributed significantly to downtime. Thorough preventative maintenance progammes were required to ensure adequate availability of both makes of filter.

Jan 1, 1989

The Lower Proterozoic metasediments of the Pine Creek Geosyncline form a chrono- stratigraphic sequence of mainly greenschist- and amphibolite-grade shallow-marine to supratidal pelites, psammites, carbonate rocks, and volcaniclastics which in places rests unconformably on Archaean basement. Granite and later dolerite intrude the sequence, and are associated with the major orogenic 1800-m.y. event which regionally metamorphosed the sediments. Most mineralisation is stratabound, and can be related at least partly to volcanic activity. Uranium mineralisation is mainly confined to particular carbonate-rich horizons near basement. Other metals are mainly in small hydrothermal deposits near intrusive granite. Specialist studies indicate that uranium was leached from its source rock, and probably carried as carbonate complexes in highly saline fluids at between 100 and 3500 C. Precipitation took place by redox reactions in breccia zones in carbonate rocks; these zones were formed by carbonate solution or diapiric movement of evaporites which preceded the carbonate. Extensive chloritisation in the ore zones suggests metasomatism by Fe- and Mg-rich fluids which may have evolved during dewatering of the evaporites. The main mineralising event took place after the 1800 m.y. metamorphism, and was probably

Jan 1, 1979

The standard charge weight scaling laws imply that only one particular delay (that possessing the maximum instantaneous charge) contributes to the ppv. However, the present analysis clearly demonstrates that a varying number of blastholes contributes to the ppv. This number also increases with distance, x, between the blast source and the detector, and is caused by waveform broadening due to attenuation. Thus the operative charge weight, itself, is also a function of the distance, and so makes the standard charge weight laws difficult to implement. If the delay time scatter is neglected, then, under certain conditions, relatively simple expressions can be derived for the ppv magnification, FN, as a function of the number, N, of blastholes. When the influence of delay scatter and random fluctuations in each blasthole vibration is included using Monte Carlo simulations, then, to a first approximation, the condition FN=KNx applies, where KN is a constant dependent upon N. Unfortunately, however, for any particular blast this condition cannot be distinguished from the standard charge weight scaling law. The dependence of ppv on N would only be apparent if blasts of differing N were to be compared in an otherwise identical environment. Since this situation is very difficult (if not impossible) to realise, then the influence due to N, although significant, goes largely undetected. Another problem associated with standard charge weight scaling laws is the difficulty of accurately assessing the appropriate charge weight, even if attenuation broadening is neglected. For example, if a number of blastholes are very close, then they experience a vibration interaction which is non-linear. However, if the same blastholes were to be widely spaced, then the separate vibration signatures add linearly. The standard charge weight scaling law fails to distinguish between such linear and non-linear regimes. Unfortunately, in many production blasts, both regimes exist throughout various portions of the blast spatial pattern and so makes it difficult to determine the operative charge weight. The solution to the combined influence of waveform broadening and linear/non-linear interactions will obviously require substantial future research. A possible solution may be found in the use of numerical dynamic codes.

Jan 1, 1990