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Thermal Processing of Petroleum Fly Ash for Vanadium Recovery

Sep 13, 2010

By Braithwaite J. C

A brief summary is given of the applications of geochemistry on two areas in North West Nelson. It has been found to be an effective method for reconnaissance prospecting. Its particular advantage lies in areas which due to thick bush cover or ru

Jan 1, 1980

By Johnson N. W, Quast K. B

Over the years there have been occasional references in the literature to the activating effect of cyanide in galena flotation with xanthates. These have usually been associated with the processing of lead-zinc or copper-lead-zinc ores. Bubble contact curves for the pure galena-xanthate system show a flotation edge at pH 10.4 independent of sodium cyanide concentration which was thought due to hydroxyl ion, not cyanide ion.Flotation tests were conducted on samples of Mount Isa lead-zinc ore using varying concentrations of sodium ethyl xanthate and sodium cyanide. At low collector concentrations, galena recovery kinetics improved with sodium cyanide addition, and the higher the cyanide concentration, the higher the galena recovery rate. At higher collector concentrations, galena recovery rate was independent of sodium cyanide addition.For a given collector addition, the lead grade-recovery curve shifted to an improved position with increasing sodium cyanide level. For the same recovery there was an increase in the lead grade with increased sodium cyanide addition, and this increase was most dramatic at high sodium cyanide concentrations.The presence of sodium cyanide during the grinding of Mount Isa ore caused surface passivation of the iron sulphides and possibly the sphalerite.These sulphides, therefore, reacted with less of the oxygen present in the pulp, hence more oxygen was directed to the surface of the galena. This resulted in an enhancement in the total amount of xanthate adsorbed on the galena that is reflected in the improved flotation response of that mineral.

Jan 1, 1990

By Corbett GJ, Leach TM

A continued exploration programme has further defined the geology of the Tolukuma vein system, verified the resource indicated by Newmont, and identified potential for additional mineralisation. The resource at Tolukuma Hill, designated as zone C, is a mine recoverable 432,000 t at 18.1 g/t Au & 46 g/t Ag. Mining will be by a combination of open pit and underground at a rate of 100,000 t per annum. Processing will be by SAG mill, gravity circuit and CIL plant. A diatreme breccia, localised at an intersection of structures and a relationship of gold to base metal sulphides, are indicative of a strong porphyry association. Typical epithermal features such as crustiform banded quartz and quartz pseudomorphing platy calcite are also present and locally contain lesser gold mineralisation. Pre-existing dilatant structures have acted as a host to the ore fluids, resulting in the formation of the semi-continuous Tolukuma-Gulbadi veins over a 1100 in strike. A fluid flow model suggests that mineralizing fluids were sourced from a diatreme margin and migrated laterally along dilatant structures. Bonanza gold grades are interpreted to be derived through fluid quenching in the flexure between a hanging wall split, which hosts much of the Tolukuma Hill resource, and the feeder graben structure. Thus, the relationship between the pre-mineral structural geometry and fluid upflow at the margins of a diatreme breccia, controls the ore setting.

Jan 1, 1995

By Boyd G

This paper describes the planning, analysis, design and operational experience of highwall mining based on auger drilling techniques applied to thick coal seams exposed in an opencut highwall. Being the first time such technology has been used in Australia, a large commitment to technical design and logistics planning was given by Callide Coalfields Pty Ltd. This commitment included technical and operations management and supervision, mine services, and the retention of consultants to undertake geotechnical analysis, instrument preparation and instrument installation.

Jan 1, 1991

By Selby DW, Hamill J, Cauley ID, Thomas I, Thornton AJ

The main objective of sulphide flotation in a cassiterite concentrator is to remove sulphide minerals (pyrite, pyrrhotite and sometimes chalcopyrite) from the ore prior to gravity concentration. Tin losses in the sulphide flotation stage account for a significant proportion of the total tin loss. separate studies of the sulphide flotation circuits of Renison Ltd and Cleveland Tin Ltd were conducted to investigate reasons for the tin losses. Sampling surveys were conducted in the rougher-scavenger and also the regrind-cleaner sections of both plants. In both plants, the rougher circuits recover excessive quantities of liberated cassiterite, while recovery of the desired composite cassiterite-sulphide fraction is low. The regrind mills are successful in liberating the composite cassiterite in the rougher concentrate, but at the expense of increasing the proportion of very fine tin mineral. The cleaner circuits recover between 40 and 60% of the cassiterite received, and this is all lost.

Jan 1, 1978

Our ultimate resources come from the Sun and the Earth System. At this time we face a world crisis in energy, water and soil resources. Global pollution problems are increasing in almost all nations. There is an urgent need to use our vast knowledge with a new wisdom and this requires new integrated teams of experts to provide the best alternatives for the needed new development problems. These teams must include economists, engineers and a broad spectrum of scientists. Today it is possible to produce clean energy, stop soil erosion, clean water and reduce and use wastes of many types.

Jan 1, 1995

By Svensson J

The nickel segregation process is one of the methods for treating nickel oxide ores. In this process nickel oxide ores are heated together with a small amount of the carbonaceous reductants and halides to about 800-950¦C. The reduced nickel segregates onto the surface of the carbonaceous reductants in the form of metallic particles which are recovered by magnetic separation or flotation. Pilot plant tests for the extraction of nickel from nickel oxide ores have been made using nickel segregation process by means of a new roasting installation which is called the "Mechanical Kiln" (2.5m~ x 3m,') with autogenous heating. Nickel oxide ores containing about 2.5%Ni were mixed with 2.5%CaC12 and 2.7%coal, and continuously charged into this installation at the rate of 60kg/h in continuous operation for 30 days per trial.

Jan 1, 1980

By Amusin BZ

The concept of rigid or yielding bolts is discussed based upon support requirements for excavations of equivalent geomechanical behaviour. The concept of equivalent geomechanical behaviour is introduced for comparison purpose where the rock mass properties are varied for a given depth (stress) so that the deformation of the roof without any support remains constant = 300mm. A simple experimental theoretical analysis for a uniform stress field acting on an axi-symmetric excavation is conducted to establish roof bolt requirements under different conditions such as width of a given excavation, time of setting of support etc. Results are presented in graphical forms.

Jan 1, 1992

An ongoing research program into surface subsidence over Room and Pillar coal mining is described. A subsidence monitoring network has been established for one Room and Pillar mine in the West Moreton Coal Field of South East Queensland, at which pillar extraction is being conducted. The maximum measured subsidence to 28 January 1986 was 638 mm, with movement continuing. Analysis of the monitoring data with view to application of the subsidence pre- diction theory developed by Kowalczyk (1972) is discussed. The Kowalczyk theory provides predictions of subsidence depression, slope of surface, horizontal displacement, surface curvature and horizontal strain, for both the Partial and Total Settlement cases. The development of subsidence with time is also investigated and a preliminary analysis conducted.

Jan 1, 1986

The influence of strongly chemisorbed solutes such as oxygen and sulphur on the rates of reactions at the gas-liquid iron interface is briefly reviewed. Deductions from recent studies of the rates of decarbur- ization of carbon-saturated liquid iron indicate ideal adsorption behaviour for sulphur over a wide temperature and composition range. This is in fair accord with available infor- mation on surface tensions in the Fe-C-S system. Previously unpublished results for the kinetics of the 14C02-CO exchange reaction are in accord with ideal absorption of oxygen on liquid iron. The derived value for the ideal adsorption coefficient of oxygen at 1550¦C is in quantitative agreement with measurements of the depression of surface tension in the Fe-0 system. Consideration is given to the applicability of such results to the violently agitated systems of steelmaking.

Jan 1, 1980

By O. J. RICHARDS

The Wongawilli system of mining has been in use for over 30 years and has enabled high production rates and acceptable extraction ratios to be achieved in seams less than 4 m in thickness. A modification of the Wongawilli system has been developed to permit the use of a continuous miner and mobile equipment to extract a coal seam 6 m thick. Following physical and mathematical model studies the new mining method is now undergoing field trials at Collinsville, Queensland. Progress of the field trials to date has achieved 99% extraction of the upper slice by remote control operation of the continuous miner and established the feasibility of installing resin grouted wooden dowels in the coal floor to reinforce the coal septum. The method is explained in the text.

Jan 1, 1980

By Mitchell D

In recent years the need to provide increased ventilation to improve environmental conditions rather than to dilute firedamp has led to increasing interest in the use of recirculation. Present UK mining law prohibits recirculation in ventilation, but it has been permitted selectively by exemption granted by Hm Inspectorate of Mines and Quarries. The conditions of use imposed by these exemptions to safeguard the safety and health of miners are examined in detail, dealing separately with primary and auxiliary recirculation systems.

Jan 1, 1988

The evolution of Hall process alumina reduction technology is des- cribed with particular attention to the pot lines. Future directions of tech- nological change are considered. It is predicted that the Hall process will continue to be the avenue for aluminium production for some time to come.

Jan 1, 1982

By King RP, Kientzler P

In recent years, ultrasonic comminution technology has been developed at the Utah Comminution Center. An ultrasonic grinding device was assembled and investigated. An ultrasonic transducer system has been significantly improved by using a special type of piezoelectric ceramic and preloading to 4.1 x le kPa to obtain maximum strength. The improved system provides constant and rapid vibratory promotion of fatigue fracture resulting in more effective breakage. The design principles for an ultrasonic mill are developed in this paper. Size reduction was successfully achieved in the ultrasonic nip-roll device for a variety of materials. Ultrasonic comminution has repeatedly demonstrated the capability of producing fine particles from a variety of materials. A comparison between ultrasonic grinding and dry ball milling of limestone showed that the ultrasonic device produced much narrower size distributions than the ball mill. This trend is especially obvious in the coarse size range where few particles remain, and in the fine size range where overgrinding is prevented. This behavior might have some interesting applications in areas other than mineral processing like powder metallurgy or material science where narrow and controlled product sizes are required for the successful elaboration of high-technology ceramics and glasses. Ultrasonic comminution has a significant advantage in the accurate control of the product size.

Jan 1, 1993

By Singh RN

Monolithic packing systems have gained in popularity as a gate side packing method. However, there has been no detailed investigation to assess their underground strength behaviour. This work includes the laboratory and in situ investigation for strength behaviour determined on various monolithic packing materials namely Tekpak-XX, Hydropak-20, Hydropak-30, Astrapak-3R, Flashpak, Thyssen pack and Aquablends. A simple technique for assessing the pack strength was developed at the laboratory by using a penetrometer, of which penetration resistance can be directly correlated with the uniaxial strength of the pack. The in situ strength investigations were made on core samples obtained from three pipes inserted inside the pack, while the penetration test were made on the pack surface. The in situ results indicated that the packing material develops an inconsistent strength on various part of the pack which was mainly related to an inadequate mixing of grouts inside the pack.

Jan 1, 1992

By DAVID C LAURENCE

The richer, shallower sapphire deposits of the New England region of New South Wales which have been traditionally mined by the small miner are almost worked out. Larger mining and exploration companies are replacing the small miner and exploring for the primary source of sapphire or lower grade alluvial deposits.Although in recent years considerable exploration effort has been directed at locating the primary source, commercial exploitation of sapphire is still restricted to the working of alluvial deposits.If the Australian industry is to compete against Asian and African producers it must use cost effective exploration, mining, processing and marketing methods.

Jan 1, 1990

By Dimitrakopoulos R

Ore textures in base metal deposits are an important factor in the liberation of the economic components of the ore, metal recovery and reagent consumption during beneficiation. Optimising the mine profit requires knowing the relationship between ore texture and mineral processing behaviour, and the ability to predict the metal grade and the ore texture at a suitable scale. A new method that generates distributions of mesotextures for any mining block size or shape is proposed and includes: I . establishing a protocol for acquiring mesotexture data: 2. measuring the mesotexture spatial correlations using a multi-texture variogram; 3. generating multiple simulations of mesotextures; and 4. upscaling the simulations to generate the expected mining block/stope mesotexture distributions. Models of the ore textures built using the proposed methodology can be used to assess resources and reserves, enhance ore/waste discrimination and predict the metallurgical behaviour of parcels of ore.

Jan 1, 1997

The granulites and related "dry" igneous rocks tend to be passed over during exploration for metals. Preliminary data show that high trace concentrations of Cu, Ni and other metals of economic interest are common in orthopyroxene and some of the other granulite minerals. During retrograde metamorphism of granulites, pyroxenes are converted to amphiboles or phyllosilicates, and significant quantities of metals are released and become available for incorporat- ion into new mineral phases, or may be transported elsewhere. S--rich scapolite is the normal scapolite of granulites. Its retrogression to secondary plagioclase provides much S which scavenges Cu, Ni, etc., from pyroxenes undergoing retrogression, thus producing ore-fluids. A full analysis of a scapolite with 5.10 per cent S03 is given. Beryl is unstable in granulites but the rare Be mineral taaffeite (Al4Pf (Be,Fe)O3) with 5,50 per cent BeO occurs in central Australia as a pale green Tabular mineral easily confused for chloritoid in hand-specimen. Metamorphic differentiation and mobilization of primary ore concentrations are major factors controlling their post-granulite attitude and grade.

Jan 1, 1969

By Coppock BW

Sintering of lead and zinc concentrates is practised by Sulphide Corporation Pty. Limited to provide both desuiphurised lump sinter feed, for simultaneous reduction to zinc and lead in the Imperial Smelting Process blast furnace, and sulphur dioxide gas for sulphuric acid manufacture. From November, 1969 a 20 percent increase in production rate has been obtained through improvements in operating technique. A gradual increase in bed permeability was achieved by modifications to the feed mix conditioning equipment and by improving moisture control. However advantage could not be taken of the higher permeability to increase sulphur elimination because the hardness of the lump sinter decreased. Higher throughput, better quality sinter and more stable sintering conditions were however made possible by simultaneously: 1. reducing segregation and compaction in the sinter bed, by narrowing the discharge opening of the main layer feed hopper, 2. reducing the sizing of sinter returns to give a closer size spectrum of particles in the feed mix, and 3. increasing the sulphide sulphur content of the feed mix to give higher bed Temperatures.

Jan 1, 1972