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Jan 1, 1970

By V. Carlson, J. A. Rowe, E. O. Bennett

This report concerns the microbial flora found throughout the surface facilities of six water-injection systems in Texas and Oklahoma. Each system is described in detail and water quality data are presented when available. Pseudomonads and sulfate-reducers (Desulfovibrio) were the predominate organisms found in the systems. The genera Sphaerotilus, Bacillus, Achromobacter, Minococcus, Clostridium, Flavobacteriurn, and Sarcina were also isolated in significant numbers. Molds, iron bacteria, sulfur bacteria and soil bacteria were found less frequently in the systems. It is concluded that a complex microbiological flora exists in oilfield water-injection systems. A tendency for waters to deteriorate in passage through solid bed filters is also noted. INTRODUCTION The injection of water into a subsurface formation is often accompanied by numerous problems, the origin and nature of which are only partially understood. During the past few years, investigators have indicated that bacteria are involved in some of these problems even though very little specific information is available concerning this matter. It is surprising that investigators working on microbiological problems in water injection have never made a complete study of the flora of these systems. The logical course to pursue is that of identifying the microbial flora and then examining each organism individually and in combination with others to determine if they produce a particular problem. The objective of the present investigation is to identify the microbial flora in water-injection systems. In addition. the quality of the water in most of the systems was determined and some observations made on the extent to which passage through surface-handling facilities affects water quality. The information derived from this study can serve as a foundation for additional basic investigations. EXPERIMENTAL PROCEDURE The microbial flora of six water-injection systems were studied at 50 sampling points. These systems are experiencing problems which may be attributable to micro-organisms, and two were being treated with antimicrobial agents at the time of this study. The samples were obtained by inoculating 1.0 ml of the water onto the different media at the sampling point. The media used for primary isolation included nutrient agar, Strokes agar, M-10-E medium and semi-solid thioglycollate medium. The cultures were returned to the laboratory, incubated at 30°C until growth occured; then, pure cultures were obtained from individual colonies. The pure cultures were identified according to standardbacteriologica1 procedures. Those organisms not fitting identification criteria exactly, even though exhibiting close similarities to known species, are listed as unidentified organisms. Membrane filters were used to make water-quality tests at intervals before and after collection of the microbiological samples. The filter discs were 47 mm in diameter with a 0.45-micron particle-size retention, and the tests were done under closed conditions at 20) psi. Membrane flow rates are plotted as increasing filtrate volumes, and the total solids contents arcs given when available. An effort was made to sample at each place in a system where a change in environment occurred. In this manner, the effect of passage through filters, tanks, hay sections, etc., on the microbial flora and water quality could be observed. RESULTS SYSTEM A This waterflood system (Fig. 1) is about four years old and daily pumps approx&ately 110,000 bbl of oil-free sour water from a 3,700-ft deep reef. The

By J. W. Goss, M. J. Coolbaugh

Most grouting has been done to stop water flaw in mines and for stabilizing foundations of various man-made structures, a survey of the U.S. literature reveals. Apparently Sun Manuel is one of the first mines in this country to use grout extensively underground for strengthening and stabilizing ground in drifts, shafts, and stations. A comparison with other procedures as well as details of the Sun Manuel program are covered. The employment of pressure grouting as a ground stabilizer at the San Manuel Copper Corp. mine reduces delays in both development and production, lowers costs, and makes possible safer working conditions. It specifically reduces delays in haulage operations and permits the maintenance of normal ventilation. In development work this grouting allows faster excavation by cementing together highly fractured or broken ground that otherwise would require extensive cribbing or spiling. In drift repair, it consolidates the loose or fractured rock over the timber or steel drift supports, thus decreasing the frequency of repair, lessening the hazards from falling rock, and curtailing delays due to blockage of drifts by muckpiles and repair operations. Pressure grouting is the process of pumping an accurately controlled mixture of cement and water into loose, fractured, or porous rock. The ratio of water to cement varies according to the nature of the rock encountered, from the thinnest mixture of 30 gal of water per sack of cement, used to fill very fine fissures, to very thick grout of 5 gal of water per sack of cement, used to fill large fissures or extensive areas of loose, broken rock. The pumping pressures at San Manuel vary from about 100 to 1000 psi, depending upon the compactness of the rock, while at other mines the pressures sometimes go as high as 5000 psi. In order to grout an area in which ground water is encountered, the pumping pressure of the grout must be increased by an amount equal to the pressure of the ground water. GROUTING IN DEVELOPMENT WORK The areas under development at San Manuel include many sections of loose, highly fractured rock. Prior to the advent of the grouting program, drifts, shafts, and stations in these areas could not be excavated without utilizing extensive support such as cribbing, spiling, and breast boarding. This slowed down the development work and increased the costs considerably over that required for excavating in more competent ground. Now, when a particularly bad area is contacted, the mining is temporarily stopped while the bad portion of drift or shaft is grouted. After the grouting is completed, the excavating is resumed with an approximate decrease of 50 pct in lost time and costs. Grouting in Drifts and Turnouts: The grouting procedures and patterns used in drifts and turnouts are very similar. The standard procedure for grouting such a turnout is shown in Fig. 1. After the ground is supported as well as possible with cribbing or lagging, the gaps between the back lagging and side lagging are plugged with empty cement sacks or additional timber, if necessary. The ground surrounding the proposed turnout is then grouted in two stages. In the first stage, the broken and caved rock is drilled and grouted to a depth of 5 to 10 ft, depending on the depth of the broken rock. This stage forms a grouted seal that allows higher pressures to be used at depths beyond 10 ft without developing excessive leaks at the face. After a grout hole is drilled, a 10-ft long pipe is wedged tightly into it with empty cement sacks. Grout is then pumped into the hole until the pressure reaches 200 to 300 psi, and the pipe is subsequently removed if it hasn't become cemented in. No more than one hole at a time is drilled and grouted because the grout has a tendency to go from one hole into another, plugging up the latter. Five or six holes are usually adequate for the first 10 ft of grouting. Experience has shown bentonite to be a useful admixture to the grout, particularly when it is indicated that the grout is being lost into large fissures or voids. Bentonite increases the plasticity of the grout enabling it to remain in place more easily until it has begun to set. In the second stage, the longer holes are drilled through the previously grouted rock, after which the

Jan 1, 1961

By Howard J. Smith

For several years this Institute has recorded in its Transactions the various discoveries of potash‡ in America, and the successive stages in the development of an independent domestic potash industry. This paper is intended primarily to continue the record through the year 1935. In retrospect it is not inappropriate to note that public interest aroused in 1910 resulted in the production of some 1090 tons of pure potash in 1915, as a small beginning in the domestic inorganic potash industry, and that the infant industry thus begun reaches its majority this year, following a record production in 1935 of about 600,000 tons of potash salts and exports to no less than 22 foreign countries, including six countries in Europe. This production, with an estimated 200,000 tons of pure potash, may be compared with a production in 1934 of 430,157 tons of salts with an equivalent of 144,342 tons of pure potash. Mine and Plant Improvement During 1935, the American Potash & Chemical Co., at Searles Lake, Calif., began to reap the benefits of its previously enlarged plant facilities, which increased its productive capacity to 180,000 tons of muriate annually. The United States Potash Co., at Carlsbad, N. Mex., improved its operations by installing trolley locomotives and other haulage facilities and is maintaining its development headings two years in advance of operations, with projected plans for orderly mining for years to come. The hoisting shaft at its mine is now equipped to hoist at the rate of 1,000,000 tons annually, and the refinery to produce 150,000 tons of muriate containing less than one per cent of impurities. The Potash Co. of America, at Carlsbad, N. Mex., completed the conversion of its plant from a prospecting to an operating basis late in 1935. The coarse-crushing plant, with a capacity of 150 tons an hour, formerly on the surface, was installed underground, with ore pockets

Jan 1, 1938

By Howard J. Smith

For several years this Institute has recorded in its Transactions the various discoveries of potash‡ in America, and the successive stages in the development of an independent domestic potash industry. This paper is intended primarily to continue the record through the year 1935. In retrospect it is not inappropriate to note that public interest aroused in 1910 resulted in the production of some 1090 tons of pure potash in 1915, as a small beginning in the domestic inorganic potash industry, and that the infant industry thus begun reaches its majority this year, following a record production in 1935 of about 600,000 tons of potash salts and exports to no less than 22 foreign countries, including six countries in Europe. This production, with an estimated 200,000 tons of pure potash, may be compared with a production in 1934 of 430,157 tons of salts with an equivalent of 144,342 tons of pure potash. Mine and Plant Improvement During 1935, the American Potash & Chemical Co., at Searles Lake, Calif., began to reap the benefits of its previously enlarged plant facilities, which increased its productive capacity to 180,000 tons of muriate annually. The United States Potash Co., at Carlsbad, N. Mex., improved its operations by installing trolley locomotives and other haulage facilities and is maintaining its development headings two years in advance of operations, with projected plans for orderly mining for years to come. The hoisting shaft at its mine is now equipped to hoist at the rate of 1,000,000 tons annually, and the refinery to produce 150,000 tons of muriate containing less than one per cent of impurities. The Potash Co. of America, at Carlsbad, N. Mex., completed the conversion of its plant from a prospecting to an operating basis late in 1935. The coarse-crushing plant, with a capacity of 150 tons an hour, formerly on the surface, was installed underground, with ore pockets

Jan 1, 1938

By B. Ball, D. W. Fuerstenau, P. C. Kapur

A two-phase distributed-parameter model of the flotation process has been extended to allow consideration of the important process parameter, concentrate grade. A simple expression is presented for the grade of concentrate in terms of the zeroth and first moments of the concentrate distribution. An example is given for a binary ore containing two pure minerals each having nondistributed rate constants. For extend-ing the model to the distributed rate constant case, a cubic polynomial zoas utilized to simulate the feed distribution. One particular example is considered and grade-recovery curves are generated to show the dependence of such curves on the initial feed distribution. Operating flotation plant engineers have traditionally evaluated plant performance in terms of the recovery of valuable mineral and the grade of the concentrate. In both operation and research, grade-recovery relationships have been used as a guide for selecting flotation conditions. Weissl illustrated the use of grade-recovery curves in plant operation and considered the grade-recovery relationship to be a metallurgical one. The extensive experimental work of Chi" using standard batch flotation tests on iron ores shows that, even with extensive statistical correlation of data, little insight can be gained into the basic fundamentals of these relations. Such relations must depend on the kinetic behavior of the various mineral species in the flotation circuit. In his flotation text book, Gaudin3 considered the relationship of recovery and of product grade to flotation kinetic indices, but he did not extend his calculations to yield grade-recovery relations. Although Gaudin used a simplistic model for his analysis, he did recognize that variations in flotation rates must result from variations in locking, surface heterogeneity, particle size and shape, among other things. In a recent paper,' we presented a model of the flotation process that could be readily analyzed with an analog computer. This model combines the concept of a distributed set of rate constants"" with that of the two-phase flotation model,8" resulting in a model more powerful and flexible than previous ones. The purpose of the present paper is to show how this model can be used to generate grade-recovery curves and to determine the dependence of such curves on the various kinetic parameters. In this paper, the model will be limited to the semi-batch case, but extension to the continuous case is a straightforward step.

Jan 1, 1971

By F. H. Bunge, W. H. Jr. Dailey

This paper covers an investigation of the magnetic roasting characteristics of several iron ores when treated in the form of small pebbles (1/8" to 1/2" in size), and in the form of balled fines. The roasting treatment was carried out with apparatus capable of very close control of time, temperature, face velocity, and per cent combustible in the reaction gas. The effect of rapid initial heating was not studied although it is believed that this has a major effect on the results when processing solid pebbles. The test equipment is a fixed bed type, with such a wide range of gas velocities, temperature, combustible content and etc., that the results obtained can be made to approximate those from various commercial roasting processes. The data presented in this report covers reaction rates, effect of processing variables on silica in the concentrate, flow resistance of beds, and to a limited extent, the effect of particle size. The work is far from complete and raises many more problems than it gives answers for. We believe, however, that much of the information will be useful to those engaged in investigation of magnetic roasting processes. We measured the time required for various degrees of completion of the reaction of hematite to magnetite, for finely pound material in balled form and for carefully sized crushed ore. Measurements were made for a variety of Minnesota and Labrador ores. This report covers an ore requiring fine ginding (-325 M) for liberation (Lower Kevin) and an ore requiring coarser grinding (-100 M) for liberation (Upper Olson). These ores represent approximately the range of characteristics for a group in the west end of the Mesabi Range. Our data shows that the reaction rate is very fast for the finely ground material and that tests are readily reproducible. The reaction rate of the larger size material, in the range of 1/8" to 1/2", is much slower and the results more erratic. We found that for the ores tested, the percentage of silica in the Davis tube magnetic concentrate was a function of iron recovery. Normally the concentrate had a low and relatively uniform percentage of silica up to a critical value of recovery. Above this critical recovery value the percentage of silica increased very rapidly. For example, for one particular ore roasted in the form of 3/8" diameter balls made from -28 mesh fines, the silica remained at about 7% to 8% until the recovery exceeded about 93%. Increasing the recovery beyond 93% resulted in over 25% silica with the additional recovery. The degree of conversion of hematite to magnetite (% completion of roast) required to obtain 93% recovery for balled material, varied inversely with the gas flow rate. Percentage silica in the concentrate resulting from roasting 3/16" and 1/2" solid material was relatively erratic. However, for varying degrees of iron recovery the lowest silica percentages corresponded to those obtainable when roasting fines. It is thought the probable reason for the erratic values was the variation in shattering or cracking of the pebbles during initial heating and roasting. There is some indication that very fast initial heating will greatly increase the permeability of the individual particles of ore to gas flow so that the reaction rate for coarse sizes will approach that obtainable with balled fine material.

Jan 1, 1961

By P. F. Gnirk, J. B. Cheatham

An experimental investigation has been made to study the effects of tooth angle and confining pressure on the force required for indentation of dry rock samples under confining pressure. In these experiments static single-tooth indentations were made on two standstones, a limestone, a schist and a slate under confining pressures of 5,000 to 15,000 psi. Sharp wedge-shaped teeth with included angles ranging from 30°to 105°were used. In all cases the force-displarenzent curves are approxinlately linear for rocks tested under confining pressure, as contrmted with the discontinuous curves obtained for silnilar rocks at atmospheric conditions. Photonzicrographs of thin sections through the craters indicate very little evidence of chip formation during indentation. In general the experimental data lie between calculated values for perfectly rough and perfectly smooth tooth-rock interfaces. INTRODUCTION The variables associated with ctrilling at depth are numerous and, in many instances, are not easity isolated and controlled. Also, many of these variables are interdependent; however, if the variables which are sufficiently independent of each other are held constant and are appropriately introduced, the dependent variables can be more easily studied and evaluated. It is the purpose of the present investigation to study experimentally the simplest case of bit tooth-rock interaction. In essence, the experiments have involved the static loading of sharp wedge-shaped tools on the surfaces of effectively semi-infinite dry rock samples subjected to confining pressures. During this investigation the following quantities have been maintained constant: 1. Pore pressure: atmospheric (i.e., the rock is dry). 2. permeability: although the rocks may be permeable, they are "jacketed" in such a manner that the fluid is not permitted to flow through them. 3. Temperature: 75F. 4. Rate of loading: essentially static (approximately 0.002 in./second). 5. Bit tooth: a sharp wedge-shaped tooth loaded normal to the rock surface. 6. Rock surface: smooth and flat. 7. Drilling fluid: hydraulic oil. In addition to the above conditions, the rock surface was free of a layer of cuttings. There was no indexing to previously indented surfaces, and the influence of corners of the borehole was neglected because the rock samples were effectively semi-infinite. The following quantities have been varied, and the resulting effects have been studied: 1. Rock a) Type (e.g., limestone, sandstone, etc.). b) Mechanical properties ) Necessarily dependent c) Porosity on type of rock. 2. Bit tooth (included angle of wedge-shaped tooth). 3. Depth of penetration. 4. cobfining pressure. On the basis of laboratory experiments which have shown that many rocks exhibit ductile behavior at confining pressures corresponding to depths usually reached during drilling,'.' a theory has previously been advanced which predicts the force required for penetration by a single sharp wedge tooth into a ductile* material.' The material is assumed to be isotropic, homogeneous and rigidly plastic (no elastic deformation) and to obey the Coubomb yield criterion (Figs. 1 and 2). Equations governing the force required for penelration are given for two extreme cases:** 1. A smooth, perfectly lubricated tooth-rock interface (fridionless boundary), in which the solution gives a minimum value for the penetrating force: in which F = force of the tooth, b = length of tooth edge,

By G. Chesneau

Two great discoveries of this century have diminished the dangers of fiery coal-mines,—the sifety-lamp, conceived in 1815 by Sir Humphrey Davy and successively improved by many engineers, such as Clanny, Marsaut, Mueseler, Fumat, etc., and safety-explosives, the appearance of which is comparatively recent, hut which, thanks to the persevering labors of several technical commissions (especially the French commission on explosives), and of the manufacturers and experimental users of these powders, appear likely to play, in the protection of the miner, a part as important as that of the safetylamp itself. Brit while it is true that by the use of a safety-lamp of approved form, and the exclusive employment, with all prescribed precautions, of these new explosives, complete security should be assured, even in highly fiery atmospheres, experience has shown that the imprudence of workmen, or the bad condition of a lamp, may nullify these protective means, so that it ought to be the constant care of the engineers of fiery mines to dilute the fire-damp by good ventilation so far as to maintain always and in all parts of a mine a proportion of this gas below the lower limit of explosiveness belonging to a mixture of air and methane. Good ventilation still remains the best preventive of explosions from fire-damp, and since, even with a rational and well-controlled mine-ventilation, the volumes of air traversing galleries and rooms are liable to vary within wide limits by reason of open doors, falls of rock, or other accidental causes, it follows that but a few thousandths of fire-damp should be left in the normal atmosphere of the mine-workings, so that a considerable

Jan 1, 1894

By S. R. Mitchell, M. Weissman, J. H. Brown

It has been demonstrated that for fine grinding operations, the energy input (E) and the product size modulus (k) are related by an equation of the form E = Ak1-n (1) where "A " and "n" are constants.(1) Also, it was suggested that "A" is determined by the comminuting device and that "n" depends primarily on the rock. It was the purpose of this investigation to study these constants by determining the form of an energy-size reduction relationship over an extreme range of energy inputs, and at the same time, to evaluate the minimum particle size produced during grinding. The comminution system consisted of a stainless steel laboratory ball mill in which quartz was ground at 60% solids for times ranging from 1 minute to 700 hours. The mill which measured 10" diameter by 12" long was loaded with about 60 pounds of balls ranging in diameter from 3/8" to 1-1/8" and was driven at 55 r.p.m. Quartz was selected for the tests because it is a brittle material for which size distribution data were expected to show a constant distribution coefficient regardless of product size.(1) This permitted specification of product size by a size modulus alone. The quantities measured were the time of grind (measure of energy input) and the specific surfaces of the products. Since no accurate method is available yet for determining particle size directly in the very fine size ranges specific surface data were used for this purpose. The relationship between these two quantities may be expressed as where Cis a constant which includes a shape factor, p is the specific gravity of the solid,_S is the specific surface and D is an equivalent particle diameter. For a material in which the distribution coefficient does not change with size the term (l/S) may be substituted for k in equation L if the proportionality constant "A" is changed correspondingly. This substitution was made in this work but in addition, screen analyses were made on several products to verify the equivalence of the two methods of size specification. EXPERIMENTAL DETAIL QUARTZ Quartz from two sources was tested. One series of tests was made on a clear, high purity crystalline quartz from Brazil and Arkansas, and another series was run on massive quartz fromNewHampshire. Grinding charges of the high purity material consisted of 2000 gram samples of -3-8 mesh particles, while the charges of the New Hampshire quartz were 500 gram samples of a -35+48 mesh screen fraction. The difference in the sizes of these two series of charges was not significant in view of the extreme size reduction accomplished, and the New Hampshire samples were smaller to permit ginding to finer sizes in shorter times than required for 2000 gram lots. SAMPLING AND ANALYSIS Separate charges were ground for all tests in which the grinding times were less than one hour and for all tests on New Hampshire quartz since these products were difficult to sample accurately without affecting the entire charge. During the long time grinding tests the mill was

Jan 1, 1961

By H. B. Pulsifer

One of the most common basic open-hearth furnace products is a simple carbon steel with a carbon range from 0.05 to 0.15 per cent. The material is widely used for sheets, tubes, bars, wire and the innumerable special objects of secondary fabrication. The properties of the material vary over wide ranges, depending on the more exact composition and details of manufacture or treatment that affect its structure. The present paper is a review of those properties and structures that have been found by studying this steel as used in the cap screw industry. At first glance this might be thought a narrow application of the steel, but, since the industry uses the material in the cold-worked, annealed and heat-treated conditions, the title of the paper may be excused for its comprehensiveness. Yet, in studying the wide ranges of properties and structures that preclude a more specific title, there can be no suggestion of completeness or finality. Even a summary of a few years' work is no more than a preliminary survey of a field that will be fertile in scientific data and industrial products for many years to come. An outline of the structures will be given first, then a list of the previous contributions that are at hand and finally some details of the work and related problems, especially concerning this low-carbon steel in the surface-hardened condition. Wire Used in Manufacture of Cap Screws The wire that is used for making cold-upset and roll-threaded cap screws has been cold-drawn from hot-rolled rods that were pickled and limed. The common sizes used in the industry range from 0.185 to 0.750 in. dia., the exact diameters depending on the plant practice and having the usual tolerances of 0.002 in. for the smaller sizes and 0.003 in. for the larger sizes. The carbon range, by pit analysis, is usually between 0.07 and 0.12 per cent. Manganese should be within the usual 0.30 to 0.50 per cent. range. Sulfur rarely exceeds 0.045 per cent. and phosphorus seldom exceeds 0.030 per cent. Silicon is usually below 0.03 per cent. but in the silicon-killed steels may be in the customary 0.10 to 0.25 per cent. range. Rimmed steel is not considered most suitable for cap screws that are cold-headed or for parts that are to be surface-hardened.

Jan 1, 1931

By Arnulf Muan, Hobart M. Kraner

Ferromanganese alloys react with aluminu-silica brick in blast furnace hearths and cause the formation of new phases with low refractoriness and consequent failure of the refractory lining. The nature of these reactions is explained on the basis of petrographic observations, thermodynamic data, and Phase equilibrium considerations. Animproued hearth design resulted from these findings. The production of ferromanganese in blast furnaces presents many problems which are not encountered in the production of iron in the same furnaces. One of the most serious of these problems is the rapid failure of refractories caused by their reaction with the ferromanganese metal. The present paper describes such a "hearth attack", its symptoms, causes, and cure. Following an introductory discussion of operating practice in ferromanganese blast furnaces, results are presented of a petrographic examination of samples from a furnace which had to be shut down because of refractory failure. The causes of this failure are then analyzed on the basis of petrographic observations combined with thermodynamic and phase equilibrium data available in the literature. The latter type of data were subsequently used as a guide in recommending improvements in hearth designs which have since proven themselves successful in practical operations. I) FERROMANGANESE BLAST FURNACE PRACTICE It is considered good practice to blow in a furnace on iron and operate it in this way for a period of time preliminary to producing ferrornanganese. During this time, iron generally penetrates the bottom refractories six or more feet below the original working surface of the hearth. Not only does this metal pervade the joints to these depths, but the pores of the refractories are usually also filled by molten iron. The high throughput of the iron furnace provides ample heat to maintain a high temperature in the hearth refractories. This, together with a high ferrostatic pressure, causes porous clay brick of the hearth to shrink. During subsequent use of such a furnace in ferromanganese production, the iron in the pores of hearth brick if; replaced to some extent by ferromanganese. The replacement is usually not complete. This is probably due to the lower metal throughput and lower prevailing temperatures resulting from this in the brick of the hearth bottom. When the ferrornanganese furnace is banked—or when the temperature in the furnace falls due to a furnace delay—-manganese oxidizes even though the atmosphere is largely CO. Considerable expansion accompanies this oxidation of manganese from metal to oxide. The hearth refractories are then subjected to the disintegrating forces of the volume expansion. These forces may in extreme cases be large enough to lift the furnace off its mantle supports as was described in a previous paper.' When cooling takes place slowly, however, and the temperature remains at a fairly high level, the refractories undergo fluxing action by the MnO. This latter reaction and the reduction of SiO2 of the clay brick is the general subject of the present paper. The observations to be described herein were made on a ferromanganese furnace located at the Johnstown plant of Bethlehem Steel Co. The furnace was lined entirely with clay refractories and had operated on iron for 266 days and on ferromanganese for 96 days prior to being taken off because of a hearth wall failure. II) PETROGRAPHIC EXAMINATION AND CHEMICAL ANALYSIS The photograph reproduced in Fig. 1 shws a cross section of the upper part of an 18 by 9 by 4-1/2 in. bottom block removed from the blast furnace. This brick came from a depth of approximately 6 ft below the original working face of the bottom. It will be noted that the 4-1/2 in. dimension is almost the same as when the brick entered the furnace. Three characteristically different zones marked I, II, and III on the print of Fig. 1 are apparent. Results of chemical analyses of the original brick and samples from each of these zones are listed in Table I. Petrographically the various zones were characterized as follows: The central zone marked I was essentially un-reacted brick. The microstructure consisted of fine needles of mullite, and the pores in this entire area were filled with iron. This is characteristic of

Jan 1, 1962

By John Shelton

ONE of the heaviest burdens uselessly cast by our mineral land laws upon the holder of the title conveyed by a patent from the United States is due to the provision excepting known veins from land patented as placer. In many instances the expense of defending such titles from the assaults of the owners of lode locations made upon the theory that the veins so located were known to exist at the date of the placer application for patent has exceeded many times the value of the land in question. Neither the lapse of time, however long after the issuance of the patent nor repeated adjudications by the courts serve to quiet such titles or to prevent them from being questioned. In the passage of laws providing for the acquisition of title to the mineral lands of the United States, Congress provided that the title to known veins should not pass from the United States by a patent based upon a placer location. As construed by the courts, the law (Sec. 2333 R.S.U.S.) provides that the applicant for a patent upon a placer claim may, if any vein of sufficient value to justify the expenditure of money in its development is known by him to exist within the boundaries thereof, include in his patent application an application for patent upon the vein as a lode claim; and failure to do so is to be deemed a conclusive declaration that the applicant makes no claim to the vein nor to an area of surface ground extending for 25 ft. (7.6 m.) on each side of its middle or center. As to such vein and, such area of enclosing surface ground under the circumstances stated, the title remains in, the United States notwithstanding the issuance of a patent that purports to convey the entire surface of a described area and everything beneath it, excepting only the segments of veins the apices of which lie outside of such area. Such known veins with such area of enclosing surface ground are, of course, at any time, so long as they remain unlocated, subject to location and appropriation in the same manner as other veins upon the public domain. The history of the operation of this law in one district will serve to illustrate its effect generally throughout the mining regions of the United States. In the Butte district, the mineral that first attracted the atten-

Jan 8, 1919

By E. S. Leaver

THE purpose of this paper is to describe, in a general way, gold-dredg-ing operations in California, with particular reference to unusual features, including types of deposits and recent attempts to improve the recovery of the gold. DREDGING AREAS The gold-bearing formations that traversed the western slope of the Sierra Nevadas for a north and south distance of some 300 miles furnished the immediate source of the gold found in most of the placer deposits of California.. Erosion through a long period carried the gold, together with various forms of partly disintegrated material, to lower elevations and formed placer deposits. Through the classifying action of water in motion, the coarser gold and heavier material of various kinds were deposited relatively near the source; consequently, in' the higher moun-tain country, old river channels were worked feverishly during the early California gold-rush days because of their high gold content. With the working out of these known high-grade channels, and from the knowledge thus obtained of prehistoric stream beds, drift mining was started and flourished until about 1890. Even today many drift mines are operating with the objective of opening other old Tertiary river channels that have been covered by volcanic flows.

Jan 1, 1937

By Henry S. Munroe

THE earliest accounts we have of Japan represent the country as having great mineral wealth, especially of precious and useful metals. Marco Polo, the Venetian traveller, in the thirteenth century, writes of "Zipangu:” "They have gold in greatest abundance, its sources being inexhaustible. The king does not allow of its being exported. To this circumstance we are to attribute the extraordinary richness of the sovereign's palace. The entire roof is covered with a plating of gold. . . . The ceilings of the halls are of the same precious metal ; many of the apartments have tables of pure gold of considerable thickness, and the windows also have golden ornaments." Marco Polo also gives an account of an unsuccessful Tartar expedition against Japan, prompted by the supposed great wealth of the country. Columbus also, as well as many other explorers, were attracted and encouraged by these prevalent reports of the wealth of the islands of Zipangu. Kaempfer, writing in 1727, speaks of the great mineral wealth of Japan, and especially of the abundance of gold, which, he says, is found in many provinces. The Portuguese and Dutch, while they had trading-posts in Japan, furnished tangible evidence of the truth of the early reports. Between 1550 and 1639 the Portuguese merchants sent home from Japan nearly three hundred million dollars' worth of bullion, most of which was gold. As the relative value of equal weights of gold and silver was then six to one, while in Europe, at the same time, it was nearly twelve to one, the exchange of silver bullion for gold was by no means an unimportant part of their business. After the Portuguese, the Dutch continued the exportation of bullion, and the exchange of silver for gold, though with less profit, as the relative value of gold increased with the demand. Between 1649 and 1671 the Dutch traders sent home over two hundred million dollars in bullion, of which, however, nearly two-thirds was silver. In 1671 the Japanese government, alarmed at the rapid rate at which the precious metals were leaving the country, issued an edict forbidding the exportation of gold or silver, under heavy penalties, which had the immediate effect of stopping this trade. Besides bullion, copper formed at this time a most important article of export. According to Dr. Geerts,* who has examined the old * Transactions Asiatic Society of Japan, vol. iii, p. 41.

Jan 1, 1877

By V.K. Zworykin

Throughout its development the science of electronics, like so many other branches of science and industry, has been indebted to the metallurgist. Metallurgy has provided the electronic engineer with conductors to furnish passage for electrons outside of his evacuated tubes: it has developed tungsten and tantalum wires for emitting electrons and various refractory metals and alloys suitable for electrodes, which receive them and guide them within the tube; finally it has supplied ferromagnetic materials both for shielding electronic apparatus from magnetic fields and for forming highly concentrated fields for deflecting electron . Today I hope to show you that electronics has not been altogether ungrateful for this assistance. More specifically, I wish to indicate the role that the electron microscope, a relatively recent product of electronic engineering, is playing even now in the study of metals. Every metallographer is aware that his standard metallographic microscope will not reveal structural detail involving separations smaller than a certain fraction —at the very best a tenth—of a micron. This limitation, he knows, is a consequence of the fact that the wave length of the light employed for forming the image has this order of magnitude. It is, thus, a property of all light microscopes. TO overcome it, a different imaging medium must be employed, The existence of such a medium became evident when it was demonstrated1 that electrons were affected by magnetic and electric fields with axial symmetry just as light is affected by glass lenses; these fields, or "electron lenses," curve the paths of electrons reaching them from an object located on the axis of symmetry in such a manner that, at some distance from the lens, a true image of the object is formed. Furthermore, although a wave length may . be ascribed to electron beams just as to light, this wave length is much shorter; for electrons accelerated through a difference of potential of 50 kilovolts, the wave length is only about one hundred-thousandth of that of visible light. Actually, the elcctron microscopes of today resolve detail one hundred times as fine as light microscopes; if the maximum useful magnification of the latter is taken to be a thousand, that of electron microscopes is one hundred thousand. The Electron Microscope Since electrons are readily scattered and absorbed by matter, specimens to be observed in the electron microscope must be prepared to be less than one micron in thickness; furthermore, the interior of the microscope must be carefully evacuated to prevent collisions between the clectrons and the molecules of the air. Finally, as already mentioned, the lenses are formed by axially symmetric magnetic or electric fields, and not by any material medium such as glass. Apart from these basic differences, the electron microscope closely

Jan 1, 1943

By V. K. Zworykin

Throughout its development the science of electronics, like so many other branches of science and industry, has been indebted to the metallurgist. Metallurgy has provided the electronic engineer with conductors to furnish passage for electrons outside of his evacuated tubes: it has developed tungsten and tantalum wires for emitting electrons and various refractory metals and alloys suitable for electrodes, which receive them and guide them within the tube; finally it has supplied ferromagnetic materials both for shielding electronic apparatus from magnetic fields and for forming highly concentrated fields for deflecting electron . Today I hope to show you that electronics has not been altogether ungrateful for this assistance. More specifically, I wish to indicate the role that the electron microscope, a relatively recent product of electronic engineering, is playing even now in the study of metals. Every metallographer is aware that his standard metallographic microscope will not reveal structural detail involving separations smaller than a certain fraction —at the very best a tenth—of a micron. This limitation, he knows, is a consequence of the fact that the wave length of the light employed for forming the image has this order of magnitude. It is, thus, a property of all light microscopes. TO overcome it, a different imaging medium must be employed, The existence of such a medium became evident when it was demonstrated1 that electrons were affected by magnetic and electric fields with axial symmetry just as light is affected by glass lenses; these fields, or "electron lenses," curve the paths of electrons reaching them from an object located on the axis of symmetry in such a manner that, at some distance from the lens, a true image of the object is formed. Furthermore, although a wave length may . be ascribed to electron beams just as to light, this wave length is much shorter; for electrons accelerated through a difference of potential of 50 kilovolts, the wave length is only about one hundred-thousandth of that of visible light. Actually, the elcctron microscopes of today resolve detail one hundred times as fine as light microscopes; if the maximum useful magnification of the latter is taken to be a thousand, that of electron microscopes is one hundred thousand. The Electron Microscope Since electrons are readily scattered and absorbed by matter, specimens to be observed in the electron microscope must be prepared to be less than one micron in thickness; furthermore, the interior of the microscope must be carefully evacuated to prevent collisions between the clectrons and the molecules of the air. Finally, as already mentioned, the lenses are formed by axially symmetric magnetic or electric fields, and not by any material medium such as glass. Apart from these basic differences, the electron microscope closely

Jan 1, 1943

By C. A. Stickels

A heat of electrolytic iron, to whzch alunzinutn and nitrogen had been added, was hot-rolled, cold-rolled 90 pct, and recrystallized at temperatures from 500" to 700°C. Primary recrystallization textures appear to arise from competitive growth of two types of nuclei: 1) those having orientations belonging to the "usual" primary recrystallization texture found in riming steel, and 2) those with the {111} (110) ovientation. Development of a (111}(1 10) component in the primary recrystallization texture occurs only over a certain interval of isothermal recrystallizatzon temperatures when the material is supersaturated with respect to the precipitation of AlN. Lowering the degree of supersaturation depresses the temperature interval in which a (111)(110) component occurs. An elongated, 'pancake-shaped" recrystallized pain structure and a marked delay in the start of recrystallization were found in all specimens which were supersaturated with respect to A1N precipitation after cold work, regardless of their recrystallization texture. ONE of the consequences of killing low-carbon steel with aluminum is a significant change in recrystallization behavior. About 15 years ago, Solter and eatttiel showed that this behavior was largely controlled by aluminum and nitrogen in the steel. If complete precipitation of A1N was prevented before cold rolling, an increased "recrystallization temperature" was observed in subsequent. annealing, and the recrystal-lized grains were not equiaxed. Leslie et a1.2 studied this phenomenon in some detail and clearly demonstrated the relationship between A1N precipitation, recrystallization kinetics, and the development of "pancake-shaped" grains. It has also been known for some time that aluminum-killed steels, processed to produce elongated "pancake" grains, develop a (11 I}( 110) primary recrystallization texture. This texture has not been found in iron or low-carbon rimming steel as a primary texture4j5 but has been observed following grain growth in electrolytic iron.5 The present work was undertaken to study in more detail the effect of A1N supersaturation on recrystallization textures in iron. LITERATURE REVIEW The deformation texture in heavily rolled iron has been studied in detail by Bennewitz.~ The texture consists primarily of a partial fiber texture about a (110) axis in the rolling direction, designated here as fiber texture A. It includes the range of orienta- tions (111)[110] - (001)[ 110] - (11l)[110]. A weak secondary texture also is present.6 This is a duplex partial fiber texture about two (110) fiber axes located 60 deg from the rolling direction and 30 deg from the sheet normal. The range of this texture, designated here as fiber texture B, about the [101} fiber axis is (112)[110] - near (545)[252] - (211:1[011] *The range given here follows Bennewit~.~ A few pole figures from re-crystallized material indicate a broader range than this.' However, the components which are strongest in the recrystallization texture are in this range.'________________________________________________________ Primary recrystallization textures in unkilled steels can be accounted for by growth of members of fiber texture B present in the deformed metal.5 However, while members of fiber texture B dominate the primary texture, other orientations survive primary recrystallization as well. In particular, some {111}(110) members of fiber texture A must also grow during primary recrystallization, because a well-defined {1ll)( 110) texture develops during subsequent grain growth at 700°C.5 The unusual recrystallization behavior of deformed supersaturated solid solutions has been attributed to: 1) retention of the solute in solution,' 2) formation of coherent, preprecipitation solute clusters prior to and during re~r~stallization,~ and 3) formation of a precipitate prior to and concurrent with recrystallization.'~-'~ When aluminum is supersaturated with iron, the difference in grain boundary mobility between general high-angle boundaries and certain special coincidence site boundaries is apparently eliminated.' In aluminum-killed steels, precipitation of A1N can take place at ordinary subcritical recrystallization temperatures. The rate of precipitation increases with increasing aluminum or nitrogen contents.2'13 There is some doubt, however, as to whether true precipitates form during the time at temperature needed to complete recrystallization. Leslie ef a1.2 found that precipitation in one steel was complete after about 100 min at 700GC, or after about 1000 min at 650GC, as measured by chemical analysis for AlN. Aoki et a1.,13 using internal friction for dissolved nitrogen, showed that a large fraction of the dissolved nitrogen was removed from solution within a few minutes annealing time at temperatures from 400" to 800°C. However , the rate of formation of AlN, as detected bv chemical analvsis. was much slower than the apparent rate of nitrogen removal. Hasebe,'~~ using carbon extraction replicas, has identified A1N precipitates by electron diffraction in a 0.2 C steel, solution-treated at 1300°C and annealed 2 hr at 700°C. Borchers and kim,I6 also using a replication technique, observed precipitates after annealing treatments as short as 2 min at 640°C. However, Leslie et a1.' state that no A1N precipitate can be seen while recrystallization is being inhibited in aluminum-killed steel.

Jan 1, 1967

By J. A. Elias, R. H. Heyer, J. H. Smith

Plastic anisotropy determined by the ratio of width strain to thickness strain in tensile specimens of low-carbon steels is strongly related to crystallographic preferred orientation. Using(222) Pole figures, a method was developed which permits rapid Predictions of plastic anisotropy for any crystallographic texture or orientation. The method is applied to low-carbon steel sheets in which four different crystallographic orientations were produced by variations in cold rolling and annealing treatments. AnISOTROPIC behavior of metal sheets during plastic deformation has long been evident. A familiar example is earing in cup type draws. During tension testing of sheet specimens, anisotropy results in a difference in width strain as compared with thickness strain. Carpenter and Elam1 observed this phenomenon in single crystals of aluminum for both sheet and rod samples. Lankford, Snyder, and Bauscher2 made tension tests on sheet samples of aluminum-killed low-carbon steel to determine the ratio of the width-to-thickness strains, and showed that this ratio was related to drawing performance. Burns and Heyer3 calculated theoretical ratios of width strain to thickness strain for two specific orientations of the bee system, using <111> as the operative slip direction. These calculated values were in fairly good agreement with the ratios determined by tension tests of low-carbon steel sheets in which these preferred orientations existed. The high degree of plastic anisotropy of silicon steel sheets could also be predicted from their crystallographic structure by these calculations. The present study has been made to show that the anisotropy observed in plastic tensile straining is strongly orientation dependent and can be adequately predicted for many orientations and textures. PLASTIC STRAIN RATIO R In the region of uniform elongation of a tension test specimen the plastic deformation may proceed at different rates in the width and thickness directions. Such anisotropy has been described in the past by the plastic strain ratioR:

Jan 1, 1962

By W. A. Schaeffer, Sidney A. Justin, Jr. H. D. Easton

Restriction and proration of petroleum production have increased materially the difficulties attendant upon the estimation of reserves, particularly in large, "flush" fields. Such practices preclude the use of decline or other curves, from which, under capacity production conditions formerly prevalent, much could be learned as to the ultimate recovery to be expected from a given field or lcase therein. In restricted fields that would produce at many times the low rate allowed by the regulations in force if allowed to flow without restraint, one is forced to use other information than production performance to predict the volume of oil recoverable. Examples are: at Kettleman Hills, California; the Conroc, Van and East Texas fields, Texas; the Iowa field, Louisiana. It is beyond the scope of this paper to apply a definite method to the determination of the reserves in any actual field, therefore the discussion will be limited to a consideration of available methods and an enumeration of important factors governing the accuracy of such estimates. The problem is to determine not only oil in place but recoverable oil in place, for a given field or tract, which is complex and depends not only on the characteristics of the reservoir but also on the plan of development, the production allocation scheme, the rate of production and many other factors. Many data must necessarily be considered, weighed as to inportance, and assigned quantitative values. Estimates of recovery in prorated fields have been discussed by Brace&apos;, Shaw2, Snider3 and others. The wide difference in estimates of ultimate recovery from a number of important recently developed fields demonstrates the inadequacy of

Jan 1, 1935