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For the year ending February, 1936 PRESIDENT AND DIRECTOR HENRY A. BUEHLER ROLLA, Mo. PAST PRESIDENTS AND DIRECTORS FREDERICK M. BECKET NEW YORK, N.Y. HOWARD N. EAVENSON PITTSBURGH, PA. VICE-PRESIDENT, TREASURER AND DIRECTOR KARL EILERS NEW YORK, N. Y.

Jan 1, 1934

PRESIDENTS DAVID THOMAS 1871 R W RAYMOND 1872-1874 A L HOLLEY1875 ABRAM S HEWITT 1876 T STERRY HUNT 1877 ECKLEY B COXE 1878 - 1879 WILLIAM P SHINN 1880 WILLIAM METCALF 1881 RICHARD P ROTHWELL 1882 RICHARD W HUNT 1883

Jan 1, 1917

PRESIDENTS DAVID THOMAS 1871 R W RAYMOND 1872-1874 A L HOLLEY1875 ABRAM S HEWITT 1876 T STERRY HUNT 1877 ECKLEY B COXE 1878 - 1879 WILLIAM P SHINN 1880 WILLIAM METCALF 1881 RICHARD P ROTHWELL 1882 RICHARD W HUNT 1883

Jan 1, 1917

By Conrad W. Stellar, John L. Paynich

Design/Build concept that provides for earliest possible completion and lowest cost is presented. Elements of the program include: joint cooperation between owner, designer and builder; schedule construction sequence; and a line budget. Benefits over lump sum contracts are reviewed.

Jan 1, 1979

The University of Colorado, Boulder, Colo. The University has published a volume, "Geology and Natura Resources of Colorado," by R D George The price is $2 and the volume may be had from the Campus Bookstore, University of Colorado, Boulder, Colorado.

Jan 1, 1933

A well=planned, useful little book on how to prospect for and find the ores of the different metals, with illustrations of the lay of the terrain and an appendix of mining terms, which will prove most useful to young miners. [ ]

Jan 1, 1949

By P. H. Brace

THE study of the relations between gases and metals is one of perennial interest to all who are connected with the production of high-grade metallurgical products. The data reported here are the outcome of work of which the object is to determine the effects of dissolved gases upon the properties of metals and to gain a more detailed knowledge of the reactions between gases and molten metals, particularly iron, under definitely controlled conditions. We have attempted to reduce our margin of error by dealing with relatively large quantities of metal, from 4 to 13 lb. (2 to 6 kg.), and keeping the ratio of refractories to metal as small as practicable. The ingots produced are large enough to provide adequate material for making determinations of magnetic and other physical properties. In choosing the bell-jar type of furnace we were influenced by the results of considerable experimentation along the same general line which indicated that, for the scale or which we were to work, it was important to have the furnace structure independent of the vacuum enclosure. The use of a bell-jar surrounding the entire furnace accomplishes this and also gives great freedom of observation during operation and ready accessibility for the replacements which are necessary after each run. Our choice of analytical method was made in the light of the results secured by H. M. Ryder, who used a method similar in principle for the analysis of very small quantities of gas extracted from strips of metal heated electrically in high vacuum. We have presented some selected preliminary experimental data as being illustrative of the quantity and nature of the gases which occur in iron of different origins, but do not urge any hypothesis at this time.

Jan 1, 1928

By Barry K. McMahon

The fundamental problem in rock mechanics is accounting for the discontinuous and anisotropic nature of the jointed rock mass. It is this problem that makes rock mechanics distinct from the mechanics of steel, glass, or concrete. Existing mathematical models explain much of the behavior of rock cores in the laboratory but, in civil engineering at least, the rocks that matter are the ones that are already broken. On the other hand, the basically descriptive methods now used in engineering geology do not lend themselves easily to mathematical analysis. A set of indices of geological properties related to the strength and deformation characteristics of jointed rock is needed. Like the index properties used in soil mechanics these will probably not have precise mathematical meaning, but once correlations are established with large scale tests they can form a basis for the transfer of test results, obtained in one area under one set of conditions, to the prediction of rock behavior in another area under another set of conditions. Indices of rock properties are even more important in rock mechanics than in soil mechanics as the cost of testing is much higher. To be useful, these indices must be easily and quickly measured and give reproducible results when measurements are made by different people. In this paper the word "joint" means all naturally occurring rock fractures with less than 3 in. of clay or other soft coating material. EXISTING INDICES OF ROCK PROPERTIES A comprehensive review of indices of rock properties for intact rock is given by Deere and Miller.' They provide charts ". . . for estimating the strength or modulus properties for intact rock from the numerical indices obtained by either the Schmidt hammer, the Shore Scleroscope,

Jan 1, 1968

By H. W. Imholz

Considerable stimulation was given to the interest in the lower producing zones of the North Central Texas area when several wildcat wells developed production in these formations. The Iron Mountain and Humble-Olander well in sec. 196, B.B.B. and C. survey, Jones County, Texas, had a potential of 7500 bbl. (after a 3000-gal. acid treatment) from the Palo Pinto limestone encountered from 3238 to 3250 ft. This well heightened the prospects for oil in commercial quantities in the Canyon, Strawn, Bend and Ellenburger formations in the adjoining counties of Shackelford, Haskell, Throckmorton and others. The Hickok-Van Parmer well in sec. 477 S.P.R.R. Co. survey, Eastland County, Texas, was good for 1040 bbl., natural, from the Ellen-burger limestone, encountered from 4024 to 4033 feet. The Hal Hughes-Cook and Jordan (Poindexter) well in sec. 350, block 6, S.P.R.R. Co. survey, Callahan County, flowed 890 bbl. in 9 hr., after acid treatment, from the Ellenburger limestone, encountered from 4369 to 4388 feet. Both of the Ellenburger wells apparently are maintaining the pressure and volume of their original potential tests, and will no doubt open up considerable area in the adjoining counties for prospecting to the Ellen-burger limestone. Production increased in the district from 12,081,871 bbl. in 1936 to 15,384,500 bbl. The increase was due to developments in Jones and Jack Counties. Jack County production increased from 896,680 bbl. in 1936 to 3,117,063 in 1937, while Jones County increased from 1,596,743 bbl. in 1936 to 2,289,322 in 1937. The remaining counties of the district showed a slight decrease in the amount of oil produced.

Jan 1, 1938

By T. P. Floridis

It was deemed desirable to obtain an understanding of the vacuum desulfurization process. McKechnie1 has reported that the sulfur content of nickel- and cobalt-base alloys is reduced in vacuo. Keverian and Taylor2 have observed that vacuum melting causes desulfurization of iron-carbon-silicon alloys. Garnyk and samarin3 have desulfurized transformer steel by vacuum treatment. Experiments were conducted in order to investigate the desulfurization of liquid iron under reduced pressures, and to establish the effect of some alloying elements, and various crucible materials. A vacuum-induction furnace of 50-lb capacity was used. The charge was Armco iron. Silicon was added as 90 pct ferrosilicon, carbon as electrode graphite, and aluminum as high-purity aluminum metal. Magnesia and silica crucibles were used, their inside diameters were 5 1/2 and 5 3/8 in., respectively. The temperature was measured with an optical pyrometer and it was held at 1600 1 15°C. Samples were withdrawn with quartz tubes of 6 mm ID, without disturbing the furnace atmosphere. Pressures were measured with an alphatron gage. The experimental results are shown in Fig. 1. They indicate that: 1) Sulfur can be removed from liquid iron alloys by vacuum treatment; 2) The desulfurization is enhanced by the presence of silicon, carbon, and aluminum, all these elements increase the activity of sulfur dissolved in liquid iron;4 3) The pronounced effect of silicon indicates that probably a volatile silicon sulfide is formed, Alcock and Richardson5 have observed a similar phenomenon; 4) The same rate of desulfurization was obtained when the metal was contained in either magnesia or silica crucibles. Dr. J. Keverian has contributed many discussions and recommendations. M. S. Sutliff has helped in conducting the heats. The permission of General Electric Co. for this publication is gratefully acknowledged.

Jan 1, 1960

By Clarence Zener

Theoretical considerations by one of the authors have ledl to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have verified2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are presented to test this extended theory. The physical basis for the type of internal friction that is being investigated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so likewise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal currents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,³ and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal currents accompanying transverse vibrations. Of more fundamental importance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adjacent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

By Clarence Zener

Theoretical considerations by one of the authors have ledl to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have verified2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are presented to test this extended theory. The physical basis for the type of internal friction that is being investigated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so likewise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal currents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,³ and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal currents accompanying transverse vibrations. Of more fundamental importance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adjacent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

John J. Porter, Cincinnati, Ohio (communication to the Secretary *):—The remarks of Mr. Firmstone concerning the presence of nickel in Oriskany ores, call to my mind some additional evidence on this point. In 1903, while engaged in the determination of zinc in a number of samples of ore from the Oriskany mine of the Alleghany Ore & Iron Co., I was surprised to discover the presence of nickel and cobalt. As far as I was then able to discover, their present;! had up to this time remained unnoticed. The amounts ranged from 0.05 up to 0.10 per cent. of the combined oxides, and while no attempt was made to separate the metals, the presence of both nickel and cobalt was conclusively proven. Since that time I have learned that traces of these metals are of quite general occurrence in Virginia iron-ores, and more especially in the ores of the Potsdam formation from the western slopes of the Blue Ridge. In certain manganese-ores from this formation, I have found as high as 0.50 per cent. of nickel and cobalt oxides. Any one interested in this subject will find further information in a volume l written by Andrew 8. McCreath, and printed in 1884 for distribution by the Norfolk & Western railway. A number of complete and accurate analyses of Virginia iron-and manganese-ores are given, and practically all show nickel and cobalt in appreciable quantity. Still another source of information on the occurrence of nickel in iron-ores in the United States, for which I am indebted to Charles Catlett, is found in the Tenth Census. Several analyses of Oriskany ores are given: all of which show the presence of nickel, with less cobalt, while the single representative from the Potsdam formation shows nickel, with no cobalt.

Jan 1, 1909

AS you have seen, I have hitherto demonstrated to you the methods for bringing to their proper and pure bodies all metals of any kind of ore that you have found and mined. If these did not now serve human needs all these operations with so much expense and labor would have been profitless and in vain. Therefore I recognize that it is necessary in speaking to touch upon all their operations and to teach you to ma& use of the metals according to the works needed. There are, for instance, some metals that would serve poorly for certain works when reduced to their fineness and perfection. Also, many artificers, in order to avoid expense, are content with having a larger quantity of metals and do not care so much about their perfection. For this reason they willingly accept mixtures of one metal with another, for example, of silver or copper with gold, of copper with silver, and likewise of tin or lead with copper. Tin is accompanied by lead to avoid spoiling its nature completely. All this, however, is done with a definite proportion by weight and not by chance. These admixtures, as I have told you in another place, are called in gold, carats, and in silver, leghe. This, in fact, means nothing but the association of one metal with another, indeed, a soiling of their purity and fineness, to which they have been brought with so much hard effort and labor. But now leaving this discussion, I shall tell you in the present book as briefly as I can, in order, first of the alloying of gold with silver or copper, and then of that of silver with copper.

Jan 1, 1942

By A. D. David

The object of this paper is to reduce to the simplest possiblc discussion the recent developments in refinery technology without resorting to detailed technical descriptions of the various items. During the year 1929, the most noteworthy tendencies have been towards the installation of more flexible plants, more unified operations, more balanced performance and greater fuel economy. In no other year in the history of petroleum refining has the industry witnessed to as great a degree the crystallization of so rnany developments in almost every phase of the art. Economic pressure has been the controlling factor, supplemented however by a market demand for more volatile anti-knock gasoline and higher quality of lubricating oils, resulting from the extended use of high-compression motors. Catalytic Hydrogenation Possibly the outstanding achievement during the year has been the beginning of construction of plants by the Standard Oil Co. of New Jersey for the catalytic hydrogenation of the so-called heavier and inferior petroleum oils to produce therefrom not only high yields of anti-knock gasoline, but also lubricating oils equal in quality to the best grades obtainable. It is reported that the plants will operate at a pressure of 4000 lb. or higher and temperatures in excess of 900" F. will be used. The hydrogen required for the conversion will be produced from refinery gases. This type of processing will doubtless be an important factor in balancing future operations; in other words, it can be used to eliminate present waste products and permit production of high-grade products from low-grade crude. Improvements in Lubricating Oils Another important development during the past year has been the extended use of vacuum stills, making possible the production of lubricating oils from what was formerly classed as "fuel-oil crude," or crude from

Jan 1, 1930

By G. W. Tuffnell, S. Floreen

Three Fe-18 pet Ni-base ternary alloys cortaining carbon, molybdenum, or cobalt were aged to pgroduce hardening by carbides, Ni3Mo, or ordering, respectively. Each alloy was tested in rotating-beam fatigue tests after hardening to 195 ksi ultim.ate tensile strength. The fatigue properties of three alloys soere essentially identical. The results suggest that tlze fatigae strength of an igron-base alloy should depend primarily upon the tensile strength, and not iipon the hardening mecaanisrn. THE fatigue strengths of many steels have been found to be directly related to their ultimate tensile strengths. For ultimate strengths below 200 ksi, the fatigue endurance limit at 107 to 10' cycles is approximately half the ultimate strength. Essen- tially all of the steels that have been tested, however, have been hardened by carbon. Thus it is not certain whether the relationship between fatigue and ultimate strengths is a general one that applies for other types of hardening in steels, or whether it applies only for the particular method of hardening by carbon. The recent developments of the martensitic precipitation-hardened stainless steels and the marag-ing steels have shown that it is possible to achieve high strengths in iron-base alloys by other hardening mechanisms than that due to carbon. Therefore, it is now possible to compare the fatigue properties of several iron alloys having the same ultimate strengths but hardened by different mechanisms. For the present study a binary Fe-18 pct Ni martensite was selected as a base material. This particular matrix composition has been found to have deformation characteristics very similar to pure iron.' Three ternary alloys were prepared by adding either 0.23 wt pct C, 5 wt pct Mo, or 20 wt pct Co to this base composition. After suitable heat

Jan 1, 1965

By K. C. Gilbart, Edgar Stansfield

When plants decay in a peat bog the woody parts form a brown pasty mass, or peat muck, largely soluble in alkalis. This brown matter has been termed "ulmin." The same material, but commonly black in color, is found in coal, and there is evidence of the similarity between the material forming the main bulk of the coal and the bulk of the more recently decayed material in peat bogs. The more recent or low-rank coals, such as lignite, little removed from the peat stage, contain notable percentages of alkali-soluble ulmins, but the percentage decreases with increased degree of coalification and is negligible in bituminous or higher rank coals. The determination of the alkali-soluble ulmins in any coal gives, therefore, an indication of its degree of coalification or rank. Coals which contain few or no ulmins soluble in alkalis do contain ulmins which can be rendered soluble by oxidation. The higher the rank of the coal, the more difficult it is to oxidize the insoluble ulmins and make them soluble. High-rank coals can be differentiated by oxidation tests on the insoluble ulmins; but low-rank coals can be characterized by both their soluble and insoluble ulmins. This paper deals with the determination and significance of the alkali-soluble ulmins present as such in the coal. The chemical nature and composition of ulmins are not discussed. Review of Literature The history of the study of ulmin is well given by Stopes and Wheeler.' The action of potash on coal has long been known, as Braconnot in 1819 distinguished between lignites and bituminous coals by stating that the former gave colored solutions with potash. Later the intensity of color was used to give a fuller differentiation. Hoffman2 distinguished between lignites and lignitic coals by the darker color given by the

Jan 1, 1932

By Joseph H. Taylor

The Ducktown district is in the extreme southeastern corner of Tennessee, its principal railroad point being Copperhill, on the Blue Ridge division of the Louisville & Nashville Railroad, midway between Knoxville, Tenn., and Atlanta, Ga. The ore deposits were discovered about 1849 and development work was begun in the early fifties. Only the "black copper" ores, products of secondary enrichment, from beneath the gossan outcrops and overlying the massive sulphide deposits, were then mined and smelted for their copper content. Upon their exhaustion, attention was directed to the treatment of the pyritic ore remaining, resulting in the devising of a process consisting of open-heap roasting, followed by blast-furnace smelting, which was practised until 1903, when semi-pyritic smelting was adopted. In 1908, the companies operating in the district, on account of litigation brought about by alleged smoke damage to forests and vegetation in the adjoining counties of Georgia, were compelled to erect enormous acid plants to prevent the escape of the sulphur dioxide produced in the smelting operations. The utilization of this sulphur dioxide in the manufacture of sulphuric acid as a byproduct has added to the revenues of the companies, and at the same time has furnished a valuable source of supply of sulphuric acid to the fertilizer trade of the South, and more recently to the manufacturers of eyplosives for use in the production of war munitions. The steadily increasing demand for sulphuric acid for the manufacture of fertilizers and explosives, together with the decreasing imports of pyrites, from which the acid is generally produced, now makes it imperative that greatly extended resources of pyrite be developed. While the Ducktown deposits do not predominate in pyrite, they do contain an inexhaustible supply of pyrrhotite, admixed with pyrite, which can be satisfactorily employed to supplement or substitute for pyrite in acid making.

Jan 1, 1918

By H. W. Knott, M. H. Mueller, P. A. Beck

The rolling and recrystallization textures in 300°C rolled uranium sheet were investigated using a Geiger counter diffractometer with the modified Schulz reflection technique. Seven sections of sheet material were used in order to obtain sufficient data for quantitative pole figures by the reflection technique. A special integrating specimen table was used for obtaining and recording the data automatically. The rolling texture was described in terms of several "ideal orientations" in which the stronger orientations have either the (1103 or (010) poles in the vicinity of the rolling direction. The recrystallization texture of the sheet uranium was also described by several "ideal orientations" which are somewhat different, except in one case, than the as-rolled "ideal orientations." RESULTS of an X-ray study of the deformation texture in rolled uranium rods were reported by Harris' in which a concentration of (010) and (110) poles was found in the rolling direction. More recently Seymour," Mitchell 'and Rowland,3 and Adam and Stephenson4 reported results obtained on uranium sheet rolled under various conditions of tem- perature and amount of reduction. Since the results of Seymour as opposed to those of the two other groups of investigators are not in full agreement, it seemed justifiable to publish the present data, obtained concurrently with the previously mentioned investigations.'-' The results with rolled and re-crystallized uranium sheet were also included in the paper, since they appear to be more complete than the only previously published texture data on recrystallized sheeL3 In the present investigation great care was taken to maintain complete separation of the reflections from different crystal planes, even in cases where the 20 angles differed from each other by less than

Jan 1, 1956

By H. Landsberg

MANY of the sedimentary rocks contain small amounts of radioactive constituents. These vary in quantity in different layers. Some recent deposits show rather high activity as; for example, the deep sea oozes and some lake deposits.1,2. Measurements made in boreholes have also shown considerable changes in activity from horizon to horizon. The first to publish data on this fact was Ambronn,3 and recently Russian geophysicists have shown remarkable variations of activity from one layer to the next in various wells. Spak4 felt even that he was able to line up horizons from data measured in two neighboring wells. ? The measuring of radioactive radiation is fairly difficult. Large errors are possible by the circulation of gaseous emanations in the well and porous strata. It is, therefore, never certain whether the activity of the layer where the instrumental device or collector is located will be measured, or that of some adjacent layer, For this reason it seemed to be advantageous to take samples of rocks into the laboratory and test them therefor their contents of radioactive material, Such a method has been followed in the past to distinguish radioactive ore from other rocks. Radioactivity of rocks, especially of the igneous type, was also deter-mined in the laboratory by numerous authors for absolute age investi-gations.6 Corresponding data from studies of sedimentary formations are scarce. Specimens taken from a core of the Bradford oil sandstone were tested by Landsberg and Ingham,7 with the results illustrated in Fig. 1, which shows that within relatively small vertical distances the differences of relative activity were considerable. If one assumes that the distribution of radioactive material is fairly uniform throughout a layer, measurements of radioactive radiation in various horizons would offer additional information for stratigraphic

Jan 1, 1939