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By E. T. Dumble

The domes of the Texas coastal plain are structural features, consisting of bosses or stocks of salt, gypsum or anhydrite, or of combinations of these, intruding into and occurring in connection with broken and uplifted sedimentary beds of Cretaceous and Tertiary age. Some of these domes show on the surface as mounds of greater or less elevation, while others are only known from drilling records. They may be divided into two classes: interior domes and coastal domes. The interior domes include those which occur in a zone 40 to 50 miles in width lying immediately east of the Cretaceous-Tertiary contact, and extending from the Sabine to the Colorado. With a single exception, these domes, so far as now known, occur in approximate alignment with the contact, but at irregular intervals. East of the Brazos, the domes are entirely surrounded by Eocene sediments. The coastal domes are found nearer the Gulf, lying entirely within Neocene territory and stretching from the Rio Grande to the Sabine. They are much more numerous than the interior domes, and, apparently, are ranged along several lines having a general northeast-southwest direction. No domes are known in the Oligocene belt. INTERIOR DOMES The interior domes so far, identified are Butler's, in Leon county, Palestine and Keechi in Anderson county, Brooks and Steen in Smith county, and Grand Saline in Van Zandt. In connection with these interior domes we must also consider the Sabine Peninsula,. of Harris, which is, without question, genetically connected with them. The Palestine and Keechi domes have been described recently by 0. B. Hopkins,1 who gives a clear idea of their corn position and structure. Others have been described at different times, and an excellent resume of the literature is given by De Golyer.2 _

Jan 10, 1918

THE record of the development of physical metallurgy since the founding of this Institute embraces by far the greater part of physical metallurgy as this subject is recognized today. Yet it is not to be supposed that the metallurgist interested in the properties and behavior of solid metals at the beginning of this period was without important and even fundamental information. He had an empirical knowledge of the behavior of solid metals which extended backward into prehistoric times and he had the early beginnings of many of the chapters in the science of metals. Industry was burgeoning in many directions, for methods had been developed, especially in the manufacture of steel that provided materials in extremely large tonnages, permitting applications of metallic materials on a very widespread scale. These multitudinous new uses of metals created an increased interest in the behavior of metals, and provided the basis for the rapid development of a science of metals. Indeed, the development of science generally that accompanied the industrial revolution reached a flood tide toward the end of the century, furnishing the metallurgist basic principles in chemistry, physics, mechanics, and crystallography that would shortly be extensively applied to metallic behavior. In this account, the early developments in the wide metallurgical field will be traced, in order that the status of physical metallurgy in 1871, when this Institute was founded, may be clearly seen. The subject of metallurgy in antiquity has been written upon frequently and at length. We shall here no more than indicate the main features that we need to define the position in 1871 and to provide a proper background for discussing subsequent developments. The writings of Pliny,1 23-79 A.D., to which Robex-ts-Austen3 fre-

Jan 1, 1948

By David A. Rice

This note describes a simple, rapid technique for measuring the apparent volume and density of individual bits of porous materials such as iron ore pellets or pieces of coke. The method consists of determining the weight recorded on a balance when a particle is depressed below the surface of mercury, and calculating the apparent volume from the known density of mercury. The apparent density is calculated after weighing the particle in air. The method is particularly well suited for applications where a great number of determinations are to be made. An additional benefit is the minimal handling of the mercury. In any event, the usual recommended safety precautions should be adhered to.

Jan 1, 1982

By L. C. Snider

NO important discoveries of petroleum during 1932 are reported from Canada. New Brunswick, which has a small production from one field, was inactive, and the production showed a decline from 6600 bbl. in 1931 to about 6300 bbl. for the year 1932. The old fields in Ontario increased from 123,000 to about 131,000 bbl. Alberta showed a decline of more than one-third, from 1,413,631 bbl. in 1931 to about 913,000 bbl. in 1932. This decline was due principally to the restrictions placed on the flow of gas wells in the Turner Valley field, from which the crude naphtha is obtained that accounted for more than 93 per cent of the production of Alberta and for more than 80 per cent of the production of all Canada in 1932. The starting of new wells to the limestone that produces the naphtha-bearing gas was prohibited late in 1931, and only wells started before that time were finished during 1932. One well was drilled in the Turner Valley field to a depth of 7555 ft., establishing a depth record for Canada. It passed out of the Madison limestone at 5560 ft., and encountered showings of oil in the underlying formations, probably of Devonian age. Commercial production had not been established by the end of the year. Commercial oil wells were brought in in two areas in Ontario which had previously been considered as productive of gas only— in the Dawn gas field, Lambton County, and in Raleigh Township, Kent County. The discovery wells had initial productions of about 50 bbl. per day, but no production of major importance is indicated. In Alberta, outside the Turner Valley district, two wildcats were drilled northwest. of Lethbridge in the Keho Lake vicinity. Both failed to make commercial producers in the Madison limestone, but one was testing upper sands at the close of the year. Good showings of oil are reported. A very small production was found in the Madison limestone in a wildcat well on the Twin River structure southeast of Lethbridge and another well has been started near by on what is considered on geophysical evidence to be a better location structurally. About 15 locations were made on the Canadian side of the border north of the Cut Bank development in Montana.

Jan 1, 1933

By Young C. Kim, William C. Cassun

A proper economic analysis of pit slope design must reflect the trade-off between the benefits and the increased risk of slope failure inherent in steeper slope angles. This paper describes the results of a case study in which a newly developed probabilistic economic analysis procedure was applied to the selection of a pit slope design at a large porphyry copper mine in the southwestern U.S. The paper also demonstrates the availability of the required data such as the probability of failure schedule and cost of failure models, under "real-life" conditions.

Jan 1, 1978

H. RIES, Ithaca, N. Y.-The part of Mr. Fiske's paper that interests me especially is that portion dealing with the raw materials, and the tests that were applied to the raw materials in order to determine their value in advance, if possible, because that, I believe, is a step in the right direction. For a number of years I have done my best to persuade different consumers of clay to develop standard methods for testing raw materials. We have in this country a large variety of clays which can be used for a great many different purposes, but in many cases the consumers either have no standard methods for determining the value of those clays in. advance, or if they have they do not publish them; consequently it often puts the clay miner at a disadvantage. If, for example, manufacturers of different types of refractory materials would state publicly just what physical tests their raw materials have to meet, it would, I believe, help them to find more easily the materials that they are looking for, and the clay producer would also be benefited. It would also encourage him to have his clays tested in advance, so that samples could be accompanied by certificates of physical tests that would be of convenience to the manufacturer. At the present time, in this country there are certain types of clay which seem to be rather scarce. There apparently are not many deposits of clay that are exactly suited for the manufacture of zinc refractories. So, too, there are not many deposits of clay that are suited for the manufacture of glass-pots, or the blocks for glass tank furnaces, or clays that can be used for graphite crucibles. Now, in many cases, no standard series of tests has been developed. I am also gratified to see that Mr. Fiske considers the tensile strength. tests of value. Some years ago the American Ceramic Society appointed a committee to draw up a series of recommendations covering standard tests. These recommendations were especially for the use of State geologists and the U., .S. Geological, Survey. Among the tests that were considered was the tensile-strength test, which Mr. Fiske has mentioned in his paper. Unfortunately, a majority of the committee turned it down, and the test was therefore not officially approved, but two of us, who formed the minority, believed in it. Since then the other members of the Committee have come to see that that is an important test to make and Mr. Fiske has emphasized it in his paper.

Jan 1, 1918

By J. B. Mackintosh

The general method which has been followed since the time of Heinrich Rose, and perhaps before, for the determination of phosphorus in iron and steel, is to dissolve the sample either in nitric acid, aqua regia, or some other oxidizing agent, in order to convert the phosphorus into phosphoric acid. In 1832 Rose* recommends HNO3, or aqua regia, preferably the former. Wohler, in 1854,† directs that the iron should be oxidized by burning in a stream of oxygen for the determination of carbon, and the resulting oxide of iron containing all the phosphorus as phosphoric acid be treated as an ore. In the fourth English edition of Fresenius' Quantitative Analysis,† pp. 666-667, we find directions to dissolve the iron in aqua regia or bromine; and, coming down to more recent times, we find F. A. Cairns § directing the employment of a boiling solution of potassium chlorate and hydrochloric acid for the oxidation and solution of the sample to be analyzed. It is unnecessary to multiply quotations from the literature of the subject, though they might be extended almost inclefinitely, since it would only be a repetition of the above mentioned series of methods in one form or another; and the references given have been selected to show how little essential variation there is in the type-methods of solution used. In fact it seems to be universally accepted as a necessary first step in the determination that some such method of solution should be followed. One chemist, however, struck out on a different line of thought, and to the Lest of my knowledge only one, M. V. Tantin, who, in

Jan 1, 1886

By R. B. G. Yeo

The effects of alloy additions on the M, and A, temperatures of an Fe-22.5 pct Ni alloy have been determined. Increasing amounts of titanium, colum-bium, vanadium, and silicon raise and then lower M,while raising A, cmtinuously. Cobalt raises both M, and A,. Aluminum has little effect on Ms but raises A,. Chromium md nickel lower M, and A,. It is proposed that elements raise M, in accordance with their effect on the Ae3 temperature of iron until the lattice becomes stiffened against the shear transformation so that M, is then lowered. An anomaly, first pointed out by Zener,1 arises in steels when the addition of elements, such as molybdenum and tungsten, which raise the Ae3 temperature, also lower the M, temperature.2'3 During the development of a series of martensitic precipitation-hardening (maraging) steels, the effect of several elements on the transformation of austenite to martensite was studied. The results show that under suitable conditions several elements which raise Ae3 also raise the M, and A, temperatures. PREPARATION OF MATERIALS STUDIED A series of alloys was made in which cobalt, titanium, columbium, vanadium, silicon, aluminum, molybdenum, chromium, and nickel were added to an iron base containing 22.5 pct Ni. The compositions of the alloys prepared are given in Table I. The residual manganese contents of the heats were in the range of 0.030 to 0.35 pct, silicon 0.05 to 0.1 pct, carbon 0.0008 to 0.009 pct, and nitrogen from 0 to 0.004 uct. The allois were made as 50-lb induction heats starting with electro-iron and electro-nickel, melted in air to oxidize impurities. Additions of silico-manganese and ferro-silicon were made after which the power was turned off to allow the products of deoxidation to rise and be skimmed from the surface of the melt. The furnace chamber was pumped down to a pressure of 5 p and the charge was heated to 2900°F for the addition of other alloying elements. The heats were poured into five 10-lb ingots, making successive alloy additions to each. The ingots were soaked for 2 hr at 2300°F and hot-worked to 3/4-in.-diam bars. This stock was heated to 1500°F for 1

Jan 1, 1963

By F. A. Forward, A. H. Ross, J. Halpern

IN treating carnotite ores by carbonate leaching it is often necessary to subject the ore to a prior roast. Among the advantages that may result from roasting are: 1) improvement in settling and filtering characteristics of the ore; 2) destruction of carbonaceous impurities that would otherwise contaminate the leach solution and consume carbonate reagent; and 3) substantial increase in extraction of vanadium, which is usually low when the un-roasted ore is leached. Recovery of vanadium may be an important factor in processing carnotite ores, and the fact that vanadium is usually recovered in good yield by acid leaching has often been an economic advantage over results obtained with carbonate leaching. It has been found that response of an ore to carbonate leaching, following roasting, depends primarily on its composition and on the conditions of the prior roast treatment, particularly with regard to the roasting temperature, the atmosphere maintained above the charge during roasting and cooling, and the presence of certain reagents. These factors, especially the last, virtually determine the extractions of uranium and vanadium attainable by carbonate leaching, as well as the reagent consumption on leaching, whereas adjustment of the leaching conditions has only a limited influence. These variables were examined systematically to elucidate roasting and carbonate leaching of carnotite ores and to establish a treatment yielding high recoveries of both uranium and vanadium. Tests were conducted on samples of four different Colorado Plateau ores, described in Table I. Roasting Procedure: The roasting tests were conducted in an electrically heated furnace in which the temperature was controlled to +15oC. The ore (usually a 500-g charge) was ground to —100 mesh, mixed with the desired reagent, and spread in a silica tray to a bed depth of about 1/2 in. During the roast the charge was rabbled at intervals of 15 min. To provide free access of air the furnace was usually ventilated; however, in a few experiments a controlled atmosphere such as carbon dioxide or hydrogen was maintained above the charge. Leaching Procedure: The pulp, generally comprising 500 g of ore and a 2000-cc solution containing 80 g per liter of Na2CO3 and 20 g per liter of NaHCO3, was agitated in an autoclave at 120°C, under 30 psi O2. Samples were withdrawn periodically, and the solution and ore residue were analyzed. Under the conditions employed, maximum attainable extractions were generally achieved in 4

Jan 1, 1958

By C. F. Dietz

WHEN thinking of industrial relations, we must not confine the term to what is ordinarily called "welfare work;" viz., organizing baseball teams, departmental parties, athletic contests, and such things. These are all of interest but not very helpful in solving the problems of industry. We must think of industrial relations as that understanding developed between workers and management that permits of harmonious progress because of a mutual understanding of each other's problems. Most of the industrial unrest, discontent, mistrust, or antagonism is due to misunderstanding; and that misunderstanding is the direct result of not having taken the workers into our confidence. If they are merely cogs in a machine, employed to do certain things, and have no interest in anything but the receipt of the pay envelope, we cannot expect intelligent harmonious progress. There are still some people who think that the interests of management, or capital invested in a business, and the interests of the worker are diametrically opposed. That is an unfortunate belief; the interests are identical. If the worker does not understand what his part of the work represents, what the management's part represents, and what the invested capital's part represents, he is bound to have a misconception, of the matter and will think only in terms of the pay envelope. The methods used for producing a better understanding between workers and management do not much matter so long as the end is attained. Some plants prefer shop committees; others attempt to work through the foremen in the various departments; others, by personal contact-between the management and the men, especially if a shop is small. It does not really matter how the end is attained as long as the object is accomplished. The best type of industrial relations can probably be attained when the mystery is taken out of industry-when the workers understand what they. are a part of, what their function is, what they are contributing. They should also understand something of fundamental economics-that it is not just a question of getting all they can and giving just as little as possible but that their contribution makes for expansion, progress, and permanence, and opens a field of activity for themselves that other-wise would probably be blocked.

Jan 6, 1925

By Robert Maddin

crystal prior to, polishing in order to eliminate coring. This treatment may be accomplished by wrapping the single crystal tightly in very thin, dead soft, brass foil and annealing in the presence of air for 20 hr at 800°C. Since the wrapping encircles the sptcimen three to four times, only a very slight amount of oxidation occurs on the specimen surface. On unwrapping one of these cylindrical single crystals. in. in diam by ro in. long (72.75 pct cu, 27.23 pct Zn, 0.01 pct P11, 0.01 pct re), mall light-gray depnrrits in the form of circular arcs werenoted on the part nf the foil which had been in contact with the single crystal, Fig r. (By superim- approximatetl). These deposits, which, from their color, suggest the appearance of sublimated zinc, were found to coincide roughly with a set of octahedral planes nearly perpendicular to the rod axis. The pattern shorn in the figure held no relation to the profle of the sample since the markin~s on the crystal More annealing werc attributed to traces of cube planes. It seems very likely that the deposits were formed by sutllimation of zinc diffusing from octahrdral planes since diffusian would Eogically take place along planes of maximum atomic spacing. However, it is difficult to understand why a continuous sublimation of zinc should occur from a single crystat in contact with a wrapping roil OF the same composition, and why diffusion would take place along specific octahedral planes and in a regular pattern.

Jan 1, 1949

By John J. Borkert, Carl E. Gerity

In situ mining offers a new and proven method of exploiting sedimentary uranium deposits. The feasibility and economic evaluation of exploiting a uranium reserve by either open pit or underground mining should also include a similar study for in situ mining. This report compares the economics of mining several hypothetical uranium deposits at various depths, grades and reserve sizes by open pit and in situ mining. The evaluation process evolved establishing, where possible, common geological and logistical parameters to both methods of mining. The various assumptions that are unique to either open pit or in situ mining were also drafted, where possible, as equal and common functions to be used in each economic evaluation of the reserve models. After the various parameters were defined, they were programmed to an economic analysis of the various hypothetical uranium deposits by the selected mining method. From the vast array of cost evaluations, total capital and operating cost per pound U308 produced, DCF-ROI, and total net profits before State and Federal taxes were selected as the most meaningful results to compare. From the various geologic parameters used, it was determined that the economic viability of a mining venture is most sensitive to a depth-grade thickness ratio. The three selected evaluation products were plotted against the various depth-grade thickness ratios of the hypothetical uranium deposits. The results of the economic cost analyses show in situ mining generally to be a better method to maximize total net profits and to maximize return on investment.

Jan 1, 1979

By B. Alexander, G. Derge W. Peifer

This is part of a research project in the Metals Research Laboratory of Carnegie Institute of Technology, sponsored by the Carnegie-Illinois Steel Corporation. In organizing our program it became apparent that the problem of analyzing molten steel for hydrogen must be divided into two parts: (I) the correct analysis of a given sample, and (2) the correct sampling of the bath. Emphasis has been placed upon these divisions in the order named because methods of sampling cannot be evaluated until a satisfactory method of analysis is available. Vacuum fusion was selected from the list of possible analytical methods because it seemed to us to offer the best possibilities for giving rapid, accurate results on solid steel samples. A number of objections have been raised against this method as usually practiced. We have sought to meet some of these by proper design of the apparatus. Experiments will be described which show that others are not valid. In the conventional apparatus the sample is held under high vacuum for a period of several hours before it is actually analyzed and one might expect considerable hydrogen to escape during this period. We have provided a means of introducing the sample to the vacuum just before analysis. Another difficulty has been that the entire apparatus has been designed primarily for the purpose of analyzing for oxygen, which constitutes upward of go per cent of the total gases evolved from the sample The volume and pressure measurements have therefore been insensitive to the relatively small amounts of hydrogen present. This difficulty obviously can be taken into account in any apparatus designed especially for the amounts of hydrogen expected. Analysis in Vacuum-fusion Apparatus A number of experiments were carried out to determine the importance of several factors that have been stated as possible sources of error or uncertainty in vacuum-fusion analysis for hydrogen; namely, that hot graphite will absorb some of the gases, that metal vapor will cause discrepancies, and that low results may be obtained as a result of the water vapor (produced by the oxidation of the hydrogen) dissolving in the butyl phthalate of the manometer, or that the blanks obtained from the apparatus are so great as to make the method inaccurate. The experiments also checked on the accuracy and feasibility of using differential freezing as a method of gas analysis in a vacuum-fusion apparatus.

Jan 1, 1945

By M. R. Geer Olds, H. F. Yancey

.I. S. Huckaba (Western Machinery Co., Spokane, Wash.)—It has been my pleasure and privilege to be able to follow this work with the H.M.S. pilot plant very closely. This has been a very thorough and painstaking piece of work and will be of great value to the dense-media operators and manufacturers. Unfortunately time was not available to make an accurate comparison between this pilot plant and the commercial plant at Bellingham Coal Mines, both plants having Wemco drum separators. Briefly I would like to point out what I consider the most interesting finding of this work. Capacity: Very good results were obtained at a feed mte of 5.2 tons per hr in a 30-in diam by 24-in. long drum separator. The maximum capacity of this drum is not known but it is something over 5.2 tons per hr for the available area of 2.08 sq ft. Medium Preparation: The importance of proper medium preparation is well demonstrated. A "tailored" or

Jan 1, 1954

By R. G. Jones, W. L. Kinney, R. E. Schilson, R. S. Wilson, G. A. Clark, H. Suralo

This paper describes the field opeturluns at the Fry in situ combustion project in Crawford County, 111. Field operations may be divided into three phases—-preliminary engineering studies of 1960 and 1961, ignition, and, finally, operation of the test. The Fry combustion project was a pilot test of cocur-rent in situ combustion on a 3.3-acre inverted five-spot. In the summer of 1960, air injection tests were conducted using old wells in the area and a new air injection well drilled especially for the test. In the summer of 1961, four new oil wells were drilled on a 3.3-acre pattern for the pilot test. All old wells in the near vicinity of the pilot test were abandoned to preclude any possibility of gas escaping to adjacent formations. A compressor plant was also installed at the test site in 1961. Air injection tests and other engineering studies were made. At the conclusion of these tests, ignition was accomplished with a 40 kw electrical igniter. Operation of the Fry combustion test was little different from the usual oilfield operation with the exception of the high rate of air injection. No difficulty was found with the openhole completion. There were no unusual corrosion or emulsion problems until bottom-hole temperatures exceeded 150F. Four cores were drilled into the burned-out portion of the reservoir with no mechanical difficulties. INTRODUCTION A cocurrent or conventional in situ combustion test was conducted on the Fry unit of the Marathon Oil Co., in Crawford County, Ill. Besides testing combustion in the Fry type of reservoir, the test was intended to evaluate various operating procedures. This paper presents a discussion of the Fry combustion test field operations. The geology of the reservoir and the test performance are discussed in other papers.'.' HISTORY OF THE FRY UNIT The Fry unit consists of 11 leases totaling 337 acres in an area in which oil was originally discovered in 1906. Production from this reservoir, as from all Robinson sand reservoirs in the area, was very high during the first few years. As the dissolved-gas energy was dissipated, early attempts to retard the decline consisted of vacuum, air, and gas repressuring, and recently, most of the area has been subjected to water flooding. Following early air repressuring, the Fry waterflood unit was formed and water flooding initiated in July, 1952. In the area in which the Fry combustion test was conducted, a peripheral water flood of a 160-acre area was developed as shown in Fig. 1. Between 1956 and 1960, it became apparent that the water flood was unsuccessfd. In looking for a suitable site for an in situ combustion test, the Marathon Oil Co. selected the Fry unit as possessing those features most desirable for such a research project. Field operations associated with the Fry combustion test began in the spring of 1960.

Jan 1, 1966

By David Cornell, D. L. Katz

Procedures for computing turbulent flow of gas in steady state near the well bore and a graphical method for predicting unsteady state laminar flow at distances from the well have been combined to compute pressure gradients in gas reservoirs. Methods are discussed for predicting single and multiple transients at constant flow rate in an infinite reservoir, predicting constant How rate. in a finite reservoir, reproducing and interpreting back pressure test data, and prediction of the behavior of a closed-in gas well. An example of the graphical method is given for a single transient and the results are compared to a published analytical solution. A typical calculation of the pressure gradient in a reservoir and the production of gas is made .starting with data from a hack pressure test. INTRODUCTION The calculation of pressure gradients throughouse a ga-reservoir at any point in its production history is a complex problem involving turbulent flow near the well bore and unsteady state flow of the gas from the reservoir. The problem is complicated further by the variety of boundary conditions that may be imposed upon the flow. Such boundary conditions include finite or infinite reservoirs. constant or variable rates of production, constant or varying bottom hole pressures, complex initial pressure distributions throughout the reservoir, and pressure maintenance through cycling. In addition to these problems there are the practical difficulties associated with natural gas reservoir analysis These might include: (1) variation. in the permeability and porosity throughout the formation. (2) variations in the thickness of the formation, (3) communication of the producing formation with other producing zones. (4) radial variations in permeability due to influx of drilling fluid. acidizing. or the buildup of liquid in the formation around the well, (5) partial penetration of the producing zone. (6) water flood, and many others. These problems will be considered eventually. In the mean- time, it is necessary to present methods of handling the case of radial flow through a homogeneous, regular, producing stratum to a single well uncomplicated by other factors. The idealized case of steady state, radial flow from a natural gas reservoir was studied by Elenbaas and Katz5 and by Mac-Koberts.' An analysis of the unsteady flow of gases through porous media has been made by Aronofsky and Jenkins' for the one dimensional laminar case with the boundary conditions of constant downstream pressure and uniform initial pressure. Solutions for the partial differential equation for unsteady state radial flow of liquids through porous media have been given by Van Everdingen and Hurst" for the constant bottom hole pressure and constant production rate cases for laminar flow in a reservoir initially at a constant pressure. The analogous heat transfer equation has been treated by Perry and Berggren9 for the case of quenching a cylindrical hole in an infinite medium to a constant temperature. The back pressure curve, which involves the variation of the bottom hole pressure as it is determined by the behavior of the reservoir as a whole. has been studied by Rawlins and Schellhardt,10 Binck-lev,' Baumel and Breitung,' and others. No complete. adequate treatment has been given for the unsteady state, radial flow of gases into a cylindrical hole from a porous medium with or without the presence of turbulent flow and for any set of boundary conditions. If one relies only on analytical solutions of the basic equations, a new solution must be obtained for each new boundary condition. Furthermore, the complexity of the mathematical expressions for boundary conditions other than the very simple cases limits the use of analytical solutions. Graphical methods exist, however. that are general in nature, accurate, and readily employed. The analysis of steady and unsteady, laminar and turbulent, radial flow for various boundary conditions with application to specific natural gas well problems by means of graphical procedures forms the content of this paper. STEADY STATE RADIAL FLOW EQUATION FOR LAMINAR AND TURBULENT FLOW A steady state radial flow equation for laminar and turbulent flow through unconsolidated sands has been given by Muskat as discussion of the work by Elenbaas and Katz.5 This equation is based on the properties of unconsolidated

Jan 1, 1953

ROBERT M. KEENEY,* Portsmouth, Ohio (written discussion?).- Mr. Coffin has written a most interesting paper that covers most of the uses to which water-cooled devices are subjected; but to meet with the operating department's approval, these devices must effect a saving in cost per ton of ingots produced in the furnace. The making of steel in the open-hearth furnace is dependent entirely on the personal element. It is not possible to charge the furnace with so much raw material, turn on a valve for heat, and by use of recording thermometers, clocks, etc. empty the furnace when a steel is made. Competent men trained to the work must be in charge all the time, and the quality and quantity of steel produced is quite as dependent on the care and working qualities of the furnaces as on the raw material and working of the charge itself. Steel making is hot, hard work and the inducement offered to technical men to take up this work is not sufficient to induce many to enter the field. The result is that most of the workmen in an open-hearth plant, the men who actually operate the furnace and make the steel, are not technical men and do not understand the "whys" and "wherefores " and care less. All this means that a furnace must be built as nearly fool-proof as possible. By this I mean that it is necessary to protect those parts of a furnace most subject to abuse by water-cooled devices whenever possible, and these water-cooled appliances must he as nearly fool-proof as they can be made. The control of the gas entering a furnace is of the utmost importance. This means a properly designed port must have the same design throughout the whole run of the furnace. This is not possible with the ordinary

Jan 6, 1919

By C. A. Wert, M. G. Coleman

The Zener relaxation in alloys in the a! solid-solution region of the Cu-Ni-Zn ternary system has bear investigated. Of the binary solid solutions that bound this region, Cu-Zn and Ni-Zn exhibit measurable Zener peaks whereas Cu-Ni does not. At constant atomic percent copper, the Peak height drops uni.forinly from the value in the Cu-ZTL binary to zero in CIA-Ali. The cariation of peak ternperatuve with composition is linear. At constant atomic percent zinc, the peak height in the ternary alloys goes through a large maximum as compared with the binary values. The temperature of these peaks varies smoothly with composition. The half-width of the peaks in the ter nary alloys, however, are much larger than those in the binaries. A large enhancement of the relaxation strength of the Zener relaxation in ternary Au-Ag-Zn alloys as compared to the relaxation strengths in Au-Zn and Ag-Zn binary alloys was observed by Firson and ert.' Since this effect was unexpected, the present study was devised to investigate whether enhancement of the Zener relaxation in ternary alloys is a general feature or is particular to the Au-Ag-Zn system. We have chosen the Cu-Ni-Zn alloy system for this investigation. Measurable Zener relaxations are observed in both the Cu-Zn and the Ni-Zn binary systems, but not in the Cu-Ni binary system. A large solid-solution region extends to large concentrations of zinc, making it possible to vary composition of the alloys over a wide range without crossing phase boundaries. EXPERIMENTAL PROCEDURE Two series of alloys were prepared. the first at constant atomic percent copper, the second at constant atomic percent zinc. The compositions of these alloys are shown by the circles in Fig. 1. The alloys were prepared by melting the individual components, each of which had previously been vacuum-melted, in an evacuated quartz capsule in an induction furnace at 1500 C. The capsules containing the molten alloys were quenched in water to reduce coring. Any individual melt which exceeded 0.001 pct weight loss was discarded. The ingots were swaged to a 50 pct reduction of area and annealed for 1 week in an evacuated quartz capsule to aid homogenization. The alloys were then

Jan 1, 1967

By E. H. Crabtree, Neil S. Parker

THE custom milling plant of the Eagle-Picher Mining and Smelting Co. is at Sahuarita, Arizona, approximately 20 miles south of Tucson. It is connected by a 2-mile railroad spur to the main line of the Southern Pacific Railroad between Tucson and Nogales. The capacity of the plant is 500 tons per day. The mill is conventional except perhaps in the rather wide variety of ores treated. These vary from straight copper ores, from which only one concentrate is produced, and lead-zinc or copper-zinc ores from which two concentrates are produced, to complex gold-silver-copper-lead-zinc ores, which require the simultaneous production of three or four concentrates. Custom ores are received in lots varying in size from a few truckloads to several carloads. Similar ores, after crushing and sampling, may be commingled, or individual lots may be milled individually. The ores are first dumped either into one of two 200-ton railroad bins, or into one of the two 75-ton truck bins. From these bins the lot of ore is individually crushed in a 24 by 16-in. jaw crusher to 3-in. size, and then to 1/2-in. size in a 3-ft Symons shorthead crusher. After crushing to 1/2-in., the ore is conveyed to the automatic sampling plant. This consists of three Vezin samplers in series, each successively cutting out 10 pct, to pct and 5 pct of its feed. After No. 1 sampler, the material passes through a mixing barrel and is then crushed to 1/4-in. in a set of rolls before passing to No. 2 sampler. Between No. 2 and No. 3 samplers, the ore is again mixed in a mixing barrel. The final sample, consisting of one pound per ton of ore, is taken to the laboratory, where it is further crushed to 1/8-in. in a coffeemill, and then riffled down to the size required for grinding in a pulverizer. The capacity of the crushing and sampling plant is up to too tons per hour, depending upon the character of the ore. After sampling, the ore is stored in five ore-storage bins, consisting of four 200-ton bins and one 175-ton bin. Each of these bins is discharged by means of belt feeders and conveyor to the ball mills, so that ores may be composited for milling in any required ratio, or milled separately by themselves. Fine grinding is done in one 6 by 4-ft Allis-Chalmers ball mill and one 8-ft by 36-in. Hardinge mill. These two mills both discharge to one 54-in. Akins Simplex Highweir classifier. The classifier sands can be returned to either or both mills, so that flexibility in grinding for different ores is easily obtained. Flotation equipment consists of four 66-in. Fagergren machines for copper-lead roughing and six similar machines for zinc roughing. Lead-copper bulk concentrate is cleaned and recleaned in eight No. 18-S Denver machines, and zinc concentrate is cleaned in three 66-in. Fagergrens. Copper-lead differential separation

Jan 1, 1947

By E. Topanelian

In recent years considerable progress has been made in the development and application of mathematical techniques for the solution of certain problems involving economic "strategies". Such a problem might involve, for example, the scheduling of shipments of a commodity from a number of sources to a number of destinations. The object would be to schedule the shipments in a manner so as to satisfy the destination requirements and at the same time minimize the transportation costs. The solution to such a problem is not necessarily intuitively obvious. The "obvious" solution is frequently far from optimum. If the shipments are to be made from, for example, only two sources to four destinations, the optimum schedule is readily found. However, if shipments are to be made from, say, 10 sources to several hundred destinations, even a competent and experienced scheduler may spend considerable time in finding a reasonable answer. Even then he is not sure that he has the optimum solution. Furthermore, he has no way of knowing how far from optimum the answer is. Consequently, he does not know whether he should accept this solution or seek a better one. Prior to the advent of large high-speed digital computers, little more could be done with such problems because of their great size and multiplicity of possible solutions. A problem involving 20 sources and 50 destinations would require choosing, from a very large number of possible combinations, the optimum combination of 1,000 variables. The best one could do was to utilize intuition, extrapolation from past experience, and other non-exact approaches. With a high-speed computer, however, such problems can be solved providing a reasonable computational procedure (or algorithm) can be utilized. The purpose of this paper is to describe such a procedure (linear programming) and to apply this procedure to a production scheduling problem. THE RESERVOIR PROBLEM A simple reservoir model is used throughout this analysis to illustrate the use of linear programming. Even the simplest reservoir behavior problem is nonlinear in both space and time, but if the geometry is fixed for a particular study and the time variable is quantized, the resultant system may be described by linear constraints on the variable production rates. Crude oil is available from five separate sources and is delivered to a pipeline. Sources 1, 2, 3 and 4 are ideal reservoirs and therefore are subjected to reservoir flow restrictions. Source 5 is labeled "Outside Source" and crude oil from this source is assumed to be available in unlimited quantities without considering reservoir conditions. The general problem is to determine the schedule of crude oil production from five sources which, over an eight-year period and subject to certain restrictions, will result in maximum profit. "Profit" is defined to encompass all economic factors and expenses involved in producing and selling crude oil to a pipeline facility. Such economic factors are lumped to the extent that the term represents the dollars profit from one barrel of crude oil from any of the five sources entering the pipeline system. Table 1 presents the assumed profit per barrel for oil from any of the five sources over each of the four time periods. In this chart the eight years is broken into four equal intervals of two years. The selection of four time periods of two years each and the values representing the potential profit are completely arbitrary selections for the purpose of illustrating this idealized reservoir problem. In any practical application of this work a careful economic study would have to be made in order to estimate potential unit profits for time periods as far in the future as eight years. In this particular study it is assumed that all of the potential unit profits (C) are known and fixed before the production schedule is attempted. For each reservoir arbitrary values are assigned for