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Effect of Spacer Chain Length on the Flotation of Kaolinite and Quartz by Using Gemini Surfactants as Collector

Sep 13, 2010

By R. C. Burton

One of the major problems encountered with recirculatory breathing apparatus presently used by mine rescue teams is that the inspired air becomes uncomfortably, and often dangerously, hot. This is also true with self-rescuers. It is well known that man can tolerate very high dry-bulb temperatures if the wet-bulb temperature is low, but not vice- versa. The maximum tolerable, wet-bulb temperature is about 42 °C (108 °F). A continuously inhaled wet-bulb temperature above this value can cause irreversible damage to the throat and lung tissue, and wet-bulb temperatures close to it cause extreme discomfort (1) and seriously retard the capability of the man to perform useful work. A theoretical analysis, combined with experimental results, has shown that it is the carbon dioxide absorbent that is the major cause of high wet-bulb temperatures of the inspired air in the Siebe Gorman Proto 4, and in the Draeger BG 174 apparatus, both of which are used by rescue teams on South African mines (2). In the Proto 4 apparatus, the absorbent for the carbon dioxide is soda lime (calcium hydroxide). The German Draeger BG 174 also uses this absorbent but under arduous conditions such as in hot environments (50 °C, 122 °F), the use of an alkali absorbent cartridge is recommended which consists mainly of caustic soda (sodium hydroxide). Lithium hydroxide is used in some apparatus in the United States. It is clear that different absorbents will produce different quantities of heat and moisture for a given rate of absorption of carbon dioxide. The proportion of this heat and moisture which is transferred to the user depends upon how much can be removed from the recirculating air between the absorbent and the mouthpiece. This paper discusses the present methods of heat removal and describes the design and test results of a prototype evaporative cooler.

Jan 1, 1980

With the continued implementation of stricter limitations on the discharge of excess process water from all existing and future mining and metallurgical operations, the design and operation of the entire process water circuit must form an integral part of any total operational package. It is far better to æanticipate and circumvent the problemÆ rather than be forced into an expensive remediation program after the event. By far the greatest problem relates to the treatment and disposal of what is generically known as acid drainage. In simple terms, an acidic metal sulfate solution is generated by a series of chemical and biological reactions as soon as most sulfide minerals are exposed to air and water. Treatment of this solution by one or more of a wide range of chemical and physical options can involve substantial capital and operating costs, although there are recent processing options that yield saleable by-products, thereby reducing the financial liability of what is effectively a waste stream. This presentation provides an overview of the Australian situation compared with the rest of the world and outlines the basic features of a number of the more advanced passive and active acid drainage options.

Jan 1, 2004

By C. M. McKinney

This report contains Bureau of Mines routine analyses of 492 samples of crude petroleum from 470 United States oilfields, each of which produced 2,500 barrels a day or more during at least 1 of the years 1946-56. The fields are listed alphabetically by State and field names in table 1, with information on the geographical and geological sources of the samples. Table 2 summarizes the general characteristics of the crude oils and analytical and computed data determined from the analyses. A previous report 4 contains similar analyses of 283 important United States oilfields; some of them are repeated in this report. Many fields for which analyses previously were published are represented by new analyses, which include data not previously reported. Refractive index nu and specific dispersion, ng minus nD divided by the density, for some of the distillate fractions are included in the analyses of 316 of the crude-oil samples. This is the first Bureau of Mines report on analysis of crude oils to contain such data, and their use in calculating hydrocarbon-type composition of the fractions is explained.

Jan 1, 1957

By P. F. Allen

WITH capacity of 51,000 tpd, the Morenci concentrator produces approximately 49,000 tons of tailing for final deposition. Disposal involves distribution of thickened tailing to dams in such a manner that solids can be used for dam construction and water can be impounded for reclamation. During early operation, although tonnage treated was lower, it was necessary to use orthodox disposal practices in the areas available for tailing. Trestles mounted on a series of dams, constructed of borrow material, carried the pipelines from which tailing were spigoted behind the dams. When adequate disposal areas were finally established, it became desirable to look for more efficient methods. The idea of placing the distribution pipe or manifold directly on the crest of the dam was advanced in 1945. After a period of testing, that procedure in modified form replaced the older trestle arrangement. Marked economies resulted, and time required to prepare dams for succeeding storage cycles was greatly reduced. The tailing disposal area for the Morenci concentrator lies south and southwest of the concentrator building. Ample storage space is available. A wide valley contains three sharply defined ravines lying on an average slope of 4 pct. The more central of these ravines, and the largest of the three, is known as Morenci canyon, which provides substantially more tailing storage area than the other two. Stargo canyon lies to the west; the other is appropriately named East canyon. Total area of the tailing disposal site is nearly 31/4 sq miles, or about 2000 acres. The storage area in use was somewhat more than 850 acres at the end of 1954, or 16 acres per 1000 tons of tailing to be stored daily. At the present time none of the east side dams are in regular use but they are available in emergency. There are five dams on the west side (in Morenci and Stargo canyons) as well as two auxiliary dams adjacent to No. 4 West and No. 5 West. This has made it possible to concentrate men and equipment in a smaller area with consequent savings in both manpower and machinery. Tailing Thickening: Tailing from the flotation process reaches the thickeners with a solid content of about 18 pct. The launder carrying this pulp is subdivided at a central point into seven launders carrying a proportional share to each of seven tailing thickeners, which are located in Morenci canyon close to the concentrator. Five of these thickeners are 300 ft diam and two are 325 ft diam. Thickeners are of the peripheral traction type and rakes travel at the rate of one revolution in 37 to 39 min. The entire installation provides 500,000 sq ft of settling area, or approximately 101/2 sq ft per ton of tailing to be thickened daily.

Jan 1, 1957

By R. Strandahl

As one of the largest private utilities globally, E.ON currently operates hard coal fired power stations in with a total installed capacity of some 20.000 MW: These thermal power plants consume domestic coals but are increasingly dependent on imported seaborne traded coal (in 2009 approx. 17 million t). Knowing that the company’s reputation and credibility depends in part on how E.ON lives up to the responsibilities along the entire energy value chain, E.ON takes a collaborative approach with the various suppliers. Hence, E.ON’s responsible policy also applies to the procurement of coal; the utility launched in 2009 a comprehensive Corporate Responsibility program with special focus on supply-chain audits. One of the first coal audits focussed on the Cerrejón coal mine in North Eastern Colombia. The authors will share the key learning’s and experience from the Colombian audit jointly conducted with an independent auditor and E.ON experts from the Corporate CR and E.ON Energy Trading.

Jan 1, 2011

By Hirokazu Narita

Keywords: solvent extraction, precious metals, thiodiglycolamide, rapid separation, hydrochloric acid The solvent extraction of some precious metals (Pd(II), Pt(IV), Rh(III) and Au(III)) and base metals (Fe(III), Cu(II) and Zn(II)) in a hydrochloric acid solution was carried out using N,N'-dimethyl-N,N'-dioctyl-thiodiglycolamide (MOTDA) dissolved in the mixed solution of 80 vol-% dodecane and 20 vol-% 2-ethylhexanol. The extraction percentages of Pd(II) and Au(III) in the 0.01 M MOTDA-1.0 M HCl solution system are 99.6% and 71.8%, respectively. In contrast, the other metal ions are hardly extracted under the studied conditions. The Au(III) and Pd(II) extracted in the organic phase are easily back-extracted with a 1.0 M thiourea/1.0 M HCl solution. A comparison with the conventional extractant for the Pd(II) separation, di-n-hexyl sulfide (DHS), revealed that the extraction rate of Pd(II) with MOTDA is much greater than that with DHS. The extraction percentage reached over 99% in less than a 2 min contact time. However, in the DHS-Pd(II) system, it takes about 240 min to achieve the extraction equilibrium. Furthermore, MOTDA can quantitatively extract Pd(II) up to half the molar amount of MOTDA. Therefore, MOTDA is a promising extractant for Pd(II) from the HCl solution after the removal of Au(III).

Jan 1, 2005

Inpit tailings disposal has been undertaken at a number of mining sites within Australia. This paper presents a brief history of the experience of inpit tailings disposal at the Marymia Gold Operation in Western Australia, including geotechnical aspects of the design. Regular monitoring of the inpit tailings disposal into the K1SE Pit at Marymia has allowed the operators of the mine to assess the performance of the tailings storage against its predicted performance during the design phase. Results of this monitoring indicated that the predicted performance was exceeded and the results have been incorporated into the design of another large inpit tailings disposal, the K1 Pit. Monitoring of tailings disposal to both the K1SE Pit and K1 Pit has allowed the mine operator to make substantial savings from inpit tailings storage when compared with above ground tailings storage facilities. The inpit method of tailings disposal at Marymia has proven to be acceptable from an environmental perspective by reducing the water resource requirements of the project, backfilling pits, which would otherwise collapse with time and eliminating the need for disturbing additional areas of mining leases, which usually accompanies construction of above ground tailings storage facilities.

Jan 1, 1999

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By Carrie Pourvahidi

The California High Speed Rail Authority (Authority) was created by the State of California through legislation in 1996. The purpose of the Authority is to plan, construct, finance and operate a statewide intercity high speed passenger rail system. In 2004 the Authority prepared a programmatic level environmental document in compliance with the California Environmental Quality and National Environmental Protection Acts (CEQA and NEPA).The Authority and Federal Railroad Administration (FRA) were the lead agencies overseeing the development of the environmental documentation. The resulting document includes two volumes and 64 supplemental technical reports analyzing the transportation needs for California and the selection of an approach to meeting the project transportation needs. The Programmatic Environmental Impact Report and Environmental Impact Statement (EIR/EIS) identified High Speed Rail as the most environ-mentally protective, sustainable and economical approach to meeting the state?s projected transportation needs.

Jan 1, 2008

By G. Ward Wilson

Waste rock and tailings may be combined through intimate blending to create new materials with superior physical and hydraulic properties. The new material, termed Co-Mix, has high shear strength characteristics, low compressibility, low hydraulic conductivity, and a high water retaining capacity. Co-Mixed tailings and waste rock may be used to construct cover systems, internal barriers and seals, confinement structures and full depth waste repositories. Field scale test trials using Co-Mixed blends of waste rock, tailings and slag have been constructed at the Copper Cliff Mine in Sudbury, Canad. These lysimeters will be used to evaluate the performance of the new material for cover systems that may potentially be constructed on the tailings impoundment upon closure. In this sense, the paper point out the construction of the lysimeters with respect to expected field performance during the spring snow melt period and summer to produce cover systems for closure.

Sep 12, 2005

By Sarma S. Kanchibotla

In overburden cast blasting the explosive energy is used to move a significant percentage of overburden from the high wall to the spoil pile thus reducing the amount of material to be handled by machinery. However, the obvious trade-off between the extra explosive energy in the cast blast versus reduced dragline effort is complicated by an increased risk of damage to the underlying coal. This damage may not be obvious but inevitably leads to reduced coal recovery and may negate much of the benefit sought from cast blasting.

Jan 1, 1999

By Willem Le Roux

Occupational health and safety is regulated by statute and common law. South Africa has, like many other countries, legislated extensively on occupational health and safety. Despite the body of legislation, the common law continues to play an important role as far as it concerns contractual, delictual and criminal liability. Two major Acts regulate occupational health and safety viz. the Occupational Health and Safety Act, No. 85 of 1993 (?OHASA?) and the Mine Health and Safety Act, No. 29 of 1996 (?MHSA?). The MHSA applies to mines and works as defined and related aspects. OHASA applies to other industries but does not apply to employers and workplaces to which the MHSA and certain matters covered by the Merchant Shipping Act, No. 57 of 1951 apply. See section 1(3) of OHASA. 2 The employer?s health and safety obligations in terms of the MHSA 2.1 Section 2(1) of the MHSA provides amongst others, as follows: ?The employer of every mine that is being worked must: (a) ensure, as far as reasonably practicable, that the mine is designed, constructed and equipped: (i) to provide conditions for safe operation and a healthy working environment (ii) ... (b) ensure, as far as reasonably practicable, that the mine is commissioned, operated, maintained and decommissioned in such away that employees can perform their work without endangering the health and safety of themselves or of any other person?.

Jan 1, 2011

By Robert P. Vinson

This Bureau of Mines report presents the results of tracer gas studies conducted at three facilities where bagger hoods had been installed several years ago to remove airborne silica dust from the vicinity of the bagging operator. The studies indicated that for optimum benefits makeup air must be evenly dispersed, the hood enclosures and duct systems must be as airtight as possible, the average intake air velocity of each hood should be at least 200 fpm, and the hoods and duct systems must be properly maintained.

Jan 1, 1981

By Kazuyuki Matsuzawa

A series of plate loading tests were carried out on a loam ground in order to investigate the influences of the plate size and the loading rate on the observed load-settlement relations. Two circular plates having diameters of 0.3 m and 1.0 m were used. Three types of loading methods were employed; 1) static cyclic maintained load test, 2) static continuous load test, and 3) rapid (dynamic) plate load test. An interpretation method called non-linear damping method was used to estimate a static load-settlement relation from the rapid plate load test signals. The derived static load-settlement relations match well with the measured results from the static load tests.

Jan 1, 2006

By T. Gerritsen, A. Matyas, F. Stober, I. Candy

This paper describes developments in ferro-nickel furnace technology, specifically improvements to cooling methods, furnace controls, and high voltage furnace operating regime. The evolution of these technologies is briefly presented, as context for describing the current state of the art that has enabled ferro-nickel furnace operation at over 75 MW and specific energy consumption of less than 400 kWh/t dry ore. Examples from existing operations are used to illustrate present best practices, and potential future trends are discussed. The paper begins with an overview of the fundamental aspects of pyrometallurgical treatment of lateritic ores that drive ferro-nickel furnace design. Furnace wall cooling methods are related to the requirements resulting from specific furnace process conditions, including slag and metal compositions, as well as arc and bath power. The benefits of high productivity and low specific energy consumption resulting from high voltage (shielded-arc) operating practice are discussed, along with the furnace controls and electrical power train that enable such operation even with captive power generation.

Jan 1, 2004

By P. K. Sen, Mrinal K. Ghose

Tailing slurry is usually abrasive and possesses high viscosity. This paper examines the existing iron ore beneficiation process and focuses on some of the key environmental issues related to the disposal of tailings. It identifies that almost 32% of the iron ore extracted ends up as tailings and they are usually disposed in slurry form in tailing ponds. By the year 2000, 27 Mt of iron ore tailings were generated in India, which has become one of the biggest waste handling problems to the industry. Characteristics of the tailings vary widely. So the physical nature of tailings cannot be considered separately in isolation without considering the mill effluent from the beneficiation plant. In the present investigation, studies were carried out in three iron ore mines in India to evaluate the characteristics of tailings from the beneficiation plant. The tailing samples were collected from different locations during a time period of one year and analyzed. The results will be discussed and the characteristics of the tailings have been evaluated. The disposal system of tailings at the three mines was evaluated. The research on the settling characteristics of tailings indicates that the area provided in the existing tailing ponds in India is much more than that of the experimental results. This paper concludes that sedimentation tests are essential to design appropriate tailings pond with respect to size. In the proposed scheme it is suggested that an additional unit process, i.e. sedimentation tank be added to the process before the disposal of tailings to the tailing pond.

Jan 1, 2003

By Yum Xiaoquan, Turgut Yalcin

"A laboratory study was carried out to determine the potential role and effect of ultrasonic irradiation in the flotation of a Sudbury copper-nickel sulphide ore. The use of ultrasound was tested separately at the pulp preconditioning, collector conditioning and flotation stages. While no significant benefits were evident in the latter two cases, ultrasonic preconditioning of pulp improved the grade-recovery performance and had the prospect of reducing reagent consumption rates. Tests were conducted on both the normal and oxidized ore samples, and several variables were investigated, including ultrasound frequency (25 kHz and 45 kHz), ultrasonic power (up to 1.6 W/cm2), duration of ultrasonic treatment (up to 60 minutes), and the intensity of pulp agitation employed during the application of ultrasound. Ultrasound frequency of 25 kHz and duration of 15 minutes yielded satisfactory results. Changes were found to occur in the temperature, pH and Eh of the pulp during ultrasonic processing. The favorable effects of ultrasound observed in this study were attributed primarily to its surface cleaning capability.INTRODUCTIONThe use of ultrasound for the surface cleaning of objects is well known. Ore flotation is based essentially on the surface properties of minerals, and hence stands to benefit from ultrasonic treatment which may help restore mineral surface characteristics that might have been lost or modified through oxidation, etc. Expected outcomes of this method of treatment include improved flotation kinetics, higher recovery, better selectivity, and savings in reagent consumption, as has been demonstrated by various researchers (Aldrich and Feng 1999, Celik 1989, Ozkan 2002, Letmathe et al. 2002, Nicol et al. 1986)."

Jan 1, 2005

By W. J. Birch, A. Wetherelt

The scaled-distance model for blast vibration analysis is the standard method employed throughout the surface mining and quarrying industries to model Peak Particle Velocity (PPV) data. Although empirical, the method is widely accepted and through the simplicity of its application and ease of graphical verification is set to remain a popular option. The validity of the technique relies principally on the fundamental parametric assumption that blasting data is normally distributed. Throughout the evolution of scaled-distance modelling, this is an issue that has most often been presumed rather than proven (most likely due to the tediousness of the calculations involved). In the few cases when normality has been given some degree of consideration, the result has been the product of a simple visual inspection of frequency distributions: clearly unsatisfactory. However recently the soundness of this assumption has been brought into question, with obvious connotations for blast modelling in general. This paper considers this fundamental issue and seeks to investigate the normality hypothesis within the blasting context through an in-depth statistical analysis of what possibly can be described as an ‘ideal’ blasting dataset. This being a rare case study concerning an opencast coal site in England, where for the entire life of the site every single blast was monitored and recorded through the use of permanent monitoring stations. This has provided a unique ‘total population’ dataset of considerable size from which the assumptions of normality are put to the test.

Jan 1, 2005

By Radford B. Langston, John A. Marjerison, Graham C. Howell, Hendrik A. D. Kirsten

Probabilistic design is gaining wider acceptance in the rock engineering community since it allows more rigorous determination of risk relating to ground fall or excavation instability. Risk analysis can be conducted by various means, but the basis is formed by either objectively or subjectively determining probability of occurrence of an event. In the case of rock engineering, this event is either instability or excavation failure. Rock mass classification systems provide objective analysis of data collected on a typically subjective basis that also relate closely to excavation stability. A probabilistic analysis technique is presented that uses statistical distributions of rock mass and material properties, ground support fixture specifications, stress conditions, opening geometry, and ground support installation quality to more rigorously determine probability of failure for an underground opening and the subsequent risk to personnel.

Jan 5, 2007