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The preeipitation of dissolved lead from a strong brine by metallic iron is a chemically controlled, first order reaction. The precipitation rate is sensitive to changes in chloride concentration and temperature. The precipitation of dissolved silver is a diffusion controlled, first order reaction. The precipitation rate is insensitive to changes in chloride concentration and temperature.INTRODUCTIONLead and silver sulphates can be extracted from electrolytic zinc plant tailings, or residues, by leaching with strong brine solutions, the lead and silver going into solution as complex chlorides. One of the methods which can then be used to recover the dissolved lead and silver is to precipitate them with metallic iron. The deposition reactions which take place are of the type Pb++ Fe - Fe++ Pb............ (a)To fit such a method of precipitation successfully into a practical flowsheet it is necessary to have some knowledge of the kinetics of the various reactions, Le. to know how the precipitation rates vary with temperature, brine and metal concentrations, and so on. Reaction rates are also needed to design suitable precipitation vessels. However, when examining the possibility of using a brine leaching process to extract the lead and silver from the residue produced at the Risdon plant of the Electrolytic Zinc Co. of Australasia, it was found that, although the use of metallic iron to recover lead and silver from the pregnant brine had been reported by Ralston (1924) and by TrumbulI, Hardiek and Lawford (1948), very little was known about the precipitation reactions. Consequently a laboratory investigation was undertaken, and this paper covers those aspects considered to be...

Jan 1, 1961

By Qi Shifu, Guo Tao, Liu Haoquan, Yao Chaogui, Zheng Li

Abstract: To excavate oil-gas pipeline ditches in a rocky region or area the explosive method is needed. When a parallel ditch is to be dug by blasting near or in the vicinity of an existing pipeline, a safe criterion must be determined to ensure safety for the latter. In this investigation, with the construction of the second phase of the West-East Gas Pipeline Project, we carried out real blasting tests and numerical simulations to explore the safety criteria for the existing pipeline. Through this investigation, we obtained the safe strain elasticity threshold es2000µe, blast vibration velocity calculation formula, and the maximum vibration velocity Vmax=14cm/s(5.51in./s) for the pipe under blast shock loading, and worked out how to determine the charge size in the follow-up blasting excavation. These results can be used to determine the maximum explosive weight per delay and decide delays for the initiation circuit network in blasting a parallel pipeline ditch, and to make safety assessments for the existing pipeline in service. Having successfully been applied in the second and third phases of the West-East Gas Pipeline Project, China-Russia Oil Pipeline Project and China-Myanmar Gas Pipeline Project, these findings are very significant for other similar pipeline construction.

Jan 1, 2014

By C. Chamberlain

The mining industry continues to underpin the regional economy. Australia, benefiting from a weak currency, receives 27% of the total goods export value from non-energy mining lead by aluminium, iron ore, gold and nickel. Consolidation has eliminated CRA, Comalco, North, Savage, Acacia, Ashton, Great Central, Aberfoyle, Placer Pacific, Plutonic, Normandy and RGC leaving Rio Tinto, BHP-Billiton, WMC, MIM and, increasingly, the South African companies Anglo, Gold Fields and Harmony as dominant players. Exploration stagnates with expenditure dropping 40% in Australia and 80% in PNG from peak levels. Major new regional developments include Rio’s West Angles iron ore project, Newcrest’s Ridgeway gold-copper mine and Inco’s Goro nickel-cobalt project in New Caledonia.

Jan 1, 2002

Electrochemical measurements are presented on electro-deoxidation of silica in molten calcium chloride at 900°C, with porous silica pellets as starting material. Measurements during pre-electrolysis (to remove water from the melt) showed electrochemical noise, which is consistent with the evolution of hydrogen. Throughout, the dominant anodic reaction appears to be CO2formation, based on the observed potential at the anode, and measured anode wear. Because of the presence of dissolved CaO in the melt, some of the CO2 candissolve in the melt; the resulting calcium carbonate formation was confirmed by electrolyte analysis after reduction runs. Reduction of dissolved CO2 at the cathode is likely to contribute to the background current during the reduction process. For the electrode and cell configuration used here, most of the over potential arises from polarization of the anode, and ohmic potential drop in the electrolyte.

Jan 1, 2006

Although not fully accepted in South Africa, the Theory of Sampling originally proposed by Pierre Gy is fast becoming the cornerstone of sampling practice throughout the world. The growing acceptance of Gy?s Theory of Sampling in South Africa can be attributed to a number of factors, chief amongst them being the development of a tradable mineral asset market, the promulgation of the Mineral and Petroleum Resources Development Act (MPRDA), the growing number of commercial and academic courses that are offered on sampling, and the regulation of the industry through internationally acceptable guidelines and rules for reporting and trading in mineral assets. The size of the South African minerals industry and the dependence of our economy on mineral production have also meant that correct sampling is of key importance to mineral trade. ISO standards have been the principal guides for producers of mineral bulk commodities who produce to customers? specifications, whereas Gy?s insights have been most readily accepted by precious and base metals producers whose product is sold into metal markets. Understanding of small-scale variability is essential in the precious and base-metal industries, but detailed studies of the effects of heterogeneity have not been as productive in the bulk commodities. Sampling practices at different stages of mineral development from exploration, face sampling and grade control, ore processing and handling, metallurgical sub-sampling, point of sale sampling, and sampling in the laboratory are considered in the gold, platinum, ferrous metal, and coal industries. A summary of the impact of poor sampling in these industries is presented. Generally it appears that poor sampling practice is most likely to erode mineral asset value at the early stages of mineral development. The benefits of good sampling are considered, especially with regard to the financial implications of bias and error on large and consistent consignments of bulk commodities. Keywords theory of sampling, sampling errors, ISO standards.

Jan 1, 2014

By Carlos Henrique Turolla Maia, Ulrich Maidl, Marc Comulada, Julio Claudio Di Dio Pierri

"Pure sands are typically the domain of slurry shields due to their high permeability and their granular characteristics. However, the Earth Pressure Balanced (EPB) shield machine technology has advanced in recent years with improved conditioning agents and shield machines that are equipped with slurry injection facilities and alternative mucking methods. These new so-called hybrid EPB machines have steadily increased the range of application of the EPB technology. The contribution discusses the capacities and operational features of hybrid EPB vs. slurry shield technology in pure sands. At the example of the Metro Line 4 in Rio de Janeiro (Brazil), the contribution shows that hybrid EPB tunneling in pure sands is possible and it is compared with a state-of-the-art slurry shield project as the KASIG project in Karlsruhe (Germany). Furthermore, the control of the support pressure by means of foam conditioning and slurry injection in conjunction with a close, real-time monitoring of machine parameters is discussed. INTRODUCTION Slurry shield and EPB technologies have both undergone significant developments in recent years, leading to the use of parts of one technology in the other and even to completely hybrid systems. Also the ranges of application (see recommendations by DAUB (DAUB 2010)) of both technologies have been shifted far beyond their original limits and are largely overlapping by now. Nevertheless, the basic principles of face support remain unchanged. Exploiting the possibilities of process data analysis (Maidl 2014), the interactions between the ground and the shield machine are a matter of research and have been intensely investigated. PRINCIPLES AND CALCULATION OF FACE SUPPORT PRESSURE Figure 1 shows the principles of two approaches for the determination of required support pressures: kinematic methods and numerical methods. Kinematic methods that are employed for the assessment of face stability only consider the situation in front of the TBM. The required face support force is determined by means of an assumed failure wedge that would form in ultimate limit state. Based on the ground properties, the vertical surcharge and the self-weight is transformed into a horizontal force along a virtual sliding surface. This horizontal force is to be balanced by the face support. The calculation results are amended by respective partial safety factors for water and earth pressure and the method-specific support pressure fluctuations are added."

Jan 1, 2016

By Kevin Connor

There was little change during 1988 in the production of minerals in Burundi. The Government of Burundi, which banned all commercial mining operations in the country in 1979, lifted the ban on mining of alluvial gold deposits and started a program of small-scale artisan gold mining in October. Along with the legal mining of gold, licensed gold trading counters were established. Other mineral commodities produced were kaolin clay, lime, and peat. In compliance with the Government ban, the only mineral wealth exploited for commercial sale and export was alluvial gold. Through financial assistance from the International Bank for Reconstruction and Development (World Bank) and the United Nations Development Program (UNDP), a study to inventory the country's mineral resources continued throughout the year. As part of this study, during the year, a West German company undertook a drilling program to further outline the nickel reserves of the Musongati area in central Burundi. Results of the work as of yearend were disappointing, with only 12 million tons of ore identified with better than 2% nickel content proven. Investigations also continued during the year regarding the centrally located deposits of vanadium-bearing titaniferous magnetite. A Norwegian company contracted to prepare a prefeasibility study for developing the deposit. The British Sulphur Corp. Ltd. was nearing completion of its $1.2 million2 study of the phosphatic limestone deposit at Matongo-Bandaga at yearend. Ore reserves of about 17 million tons grading 11% phosphorus pentoxide (P2O3) had been identified. The phosphate zone overlies a carbonatite rock, which could provide the basis for a cement industry. Additional drilling was planned for 1984. Exploration for gold was underway in 19S3 in northern Burundi through UNDP funding. Several primary deposits of shallow semimassive sulfides with gold values ranging from traces to 11 grams per ton had been discovered. With assistance from the Federal Republic of Germany, bastnasite reserves of 5,400 tons, with associated high europium oxide and cerium content, were verified, and the prospects for finding

Jan 1, 1985

By H. F. Niemand, C. J. Postma, P. L. Crouse

"SynopsisThe separation of zirconium and hafnium is essential in the nuclear industry, since zirconium alloys for this application require hafnium concentrations of less than 100 ppm. The separation is, however, very difficult due to the numerous similarities in the chemical and physical properties of these two elements.Traditional methods for separation of zirconium and hafnium rely predominantly on wet chemical techniques, e.g. solvent extraction. In contrast to the traditional aqueous chloride systems, the AMI zirconium metal process developed by Necsa focuses on dry fluoride-based processes. Dry processes have the advantage of producing much less hazardous chemical waste.In the proposed AMI process, separation is effected by selective sublimation of the two tetrafluorides in an inert atmosphere under controlled conditions, and subsequent selective desublimation. Estimates are made for the sublimation rates of the two tetrafluorides based on the equilibrium vapour pressures. A sublimation model, based on the sublimation rates, was developed to determine if the concept of separation by sublimation and subsequent desublimation is theoretically possible.IntroductionZirconium requires several purification steps to conform to nuclear-grade specifications. Little information is available on the sublimation separation of Zr and Hf compounds, especially in the fluoride form, the majority of which deals with sublimation under vacuum conditions. On the industrial scale, only vacuum sublimation of ZrF4 has been reported. No records were found for the sublimation of ZrF4 in an inert atmosphere. Information on the sublimation rate of ZrF4 or HfF4 in an inert atmosphere is also limited. The rate is assumed to be dependent on several factors, of which temperature, area, and composition are considered the most important."

Jan 1, 2015

The published liquidus data on the Pb-PbS system have been correlated on the basis of one-coefficient Margules equations. Thermodynamic properties of the components of this system have been obtained, and it has also been found that the calculated miscibility gap of this system exists over a very narrow range of temperature (1041 to 1058°C).

Jan 1, 1972

By M. McWha

Laboratory bias is a universal problem in all branches of analytical science. It results from differences in methods, techniques, equipment, and calibrations between laboratories. Notwithstanding that it is a property that can be measured by the use of standards or by inter-laboratory testing, laboratory bias remains a material issue for the mining industry. There is extensive literature and clear guidelines on measurement from the International Organization for Standardization (ISO) and its worldwide federation of national standards bodies (ISO member bodies) and from the science of metrology. ISO guides cover the manufacture and use of standards. An accessible source of literature covering laboratory quality control comes from the public health sector, particularly pathology. There is little doubt in financial reporting rules about the meaning of materiality. Public reporting guidelines are clear that material matters need to be disclosed for investors. Unfortunately there is currently no clear guidance what to do about biased assay results in mineral industry public reporting guidelines. This paper reviews the requirements for the manufacture and use of reference materials, public reporting requirements in the mining industry, and presents proposals to improve management and reporting of laboratory biases. Keywords laboratory bias, reference materials, ISO Guides, financial reporting, materiality.

Jan 1, 2014

By Antonio Nieto

According to the analysis of surface powered haulage accidents involving off-highway haul trucks in openpit mining, the U.S. Mine Safety and Health Administration (MSHA), reported 1,300 fatal accidents from 1990 to 2005. Of these, 163 were considered off-highway truck haulage accidents, and at least 23 involved collisions of an off-highway truck with a neighboring vehicle or a worker on foot (Nieto and Dagdelen, 2006). In general, an average of 18 nonfatal accidents and three fatal accidents occurred in openpit mining per year when equipment backed over the edge of an embankment, stockpile or dump point (Fessak, et al., 2003). The specific problems that need to be solved can be determined by carefully studying the accidents involving haulage trucks (Marrara, et al., 2004). Solutions to haulage truck safety must consider the human factors affecting each task even when engineering solutions seem most appropriate. In surface haulage, human performance becomes a critical issue because of the unusual demand the vehicle?s places on their human operators: ? Roadways and working areas change frequently in mining operations. ? The sheer mass of mining equipment such as trucks requires control inputs (e.g., braking) far in advance of the desired action. ? Rough roads, loading and unloading impacts can subject the driver to dangerous shocks and vibration. ? Visibility is sharply curtailed by the bulk of the vehicle generating large blind spots. All of the above issues can be attributed partially to the lack of visibility (Pyles et al., 2003). Driver visibility and communications are key issues to reduce mining truck accidents. Analysis of fatalities and injuries involving mining equipment demonstrates the need to develop new intervention and control strategies to mitigate the risks associated with mining equipment operation. Ongoing development of these and other new strategies is required to achieve a reduction of injury in the mining industry

Jan 2, 2010

It is a pleasure and a privilege to be with you for the Annual Conference of The Australasian Institute of Mining and Metallurgy.The inaugural meeting of The Institute was held in Adelaide in April, 1893. Through the kindness of your President, who passed on to me several publications concerning The Institutute I have been able to glance back over the eighty years in which The Institute has served both the profession and Australia.In that record, many names of great distinction caught my eyes. When one reads the list of past presidents of the The Institute since 1893 and the list of those to whom The Institute Medal has been awarded, one reads the headings of a biographical dictionary of the Australian mineral industries. Many famous names are there-men from the great mining companies, engineers, scientists, metallurgists and geologists. Simply to read the names is to recall great enterprise and great achievement. Going over those names one hears the echoes of the inspiring story of the establishment of the Australian steel industry, the electrolytic zinc inq.ustry, all the major developments in the mining of coal, gold, copper, silver and lead, the treatment of difficult ores, the geological exploration of a cqntinent, the discovery of uranium, bauxite, petroleum, nickel, the establishment of the alumina industry and finally the mammoth earthmoving operations of today. The list of names is a chronicle of great men who did a mighty work. They stand like milestones in the progress of a nation.When one reads further and runs down the titles of some of the papers published in the Proceedings of The Institute even a layman like myself can appreciate the dramatic developments in mining and metallurgy that have transformed the whole practice of the mineral industries in our land. Australians have made some notable innovations and discoveries both in mining techniques and in the processing of ores. The history of mining is not only a story of the discovery of the mineral resources of this continent but of adventurous steps taken to perfect new ways of mining the ore and extracting the metal.I read with great admiration the presidential address given by Sir Maurice Mawby in 1968 and wa...

Jan 1, 1973

By W. G. K. Fleming

The general history of piling is traced up to the present time with regard to the evolution of methods and materials. The processes have been strongly influenced by developments in basic equipment and industrial change. It is noticeable that in the twentieth century more progress has taken place than in the many previous centuries. It has been strongly influenced by the general development of Soil Mechanics. Test loading is probably the most effective way to assess the success of designs and many empirical relationships have been challenged through it. As we approach a new century it appears that it will be an age of rapid equipment development, with much enhancement of understanding of what has been done. Processes of automatic construction and testing will becoming commonplace. These changes will narrow the limits of conventional scatter that have come to be accepted and to a large extent will be driven by political efforts to curtail energy consumption, to raise standards of quality and reliability, and to conserve the environment. 1. Ancient history. Piling is an ancient art. Its first mention in history is from Herodotus, the first person to commit an account of his times to the written word in the years 557 to 479 BC. He evidently had a strong interest in engineering matters because he wrote of building, brick making, reinforced brickwork, river training, canal building, bridge construction, tunnelling and its acoustic detection and piling. The piling reference comes from Book 5 at paragraph 16.

Jan 1, 1999

By W. A. Calhoun

A method for treating high-iron Arkansas bauxites for recovering both abrasive and metal-grade bauxite has been developed by the Bureau of Mines. Present practice usually produces a reject containing appreciable quantities of metal-grade bauxite; however, the processing renders the alumina in the reject unsuitable for the Bayer extraction treatment. Thus the Arkansas abrasive bauxite industry has, in the past, produced little or no metal-grade bauxite. The present investigation was made to determine the possibilities of batter utilization of those particular bauxites through recovery of the wasted metal-grade portion. The large expansion of aluminum-production facilities planned for 1951-53 makes recovery of metal-grade bauxite from presently treated abrasive and marginal abrasive ores en especially timely objective and a welcome addition to our aluminum potential. The quality of the Arkansas bauxites and the inherently associated titania content have made this material particularly attractive to the abrasives industry. however, the gradual depletion of natural abrasive-grade bauxite reserves in this area, the comparative scarcity of high-grade ore, and the difficulty of maintaining adequate reserves have necessitated blending different grades of bauxite calculated to meet specifications. Production of abrasive-grade bauxite from tile, high-iron reserves 13 becoming, increasingly necessary. In one commercial operation, producing abrasive-grade from ores averaging slightly less than 10 percent Fe2O3, approximately 2.7 tons of ore are required to produce 1 ton of abrasive-grade bauxite. The reserves of ore of this grade, however, have been considered inadequate for a long-range production, and ultimately ores averaging 12 to 15 percent Fe2O3 will have to be treated to moot the continued demands of the abrasive industry.

Jan 1, 1952

By Moinpour M

The kinetics of reduction of copper (cuprous) sulphide with CO-CO2-He gas mixtures, using an excess of CaO(s) as a sulphur-scavenging substance were investigated in the temperature range 855° - 950°C by a thermogravimetric method. Several gas compositions were employed at each temperature. Potential carbon deposition was overcome by preheating the reducing gas mixture. The phase-composition and the morphology of partially reactedsamples were analysed by a SEMlEDAX unit. The reduction rates showed strong dependence on the bulk gas compositions (CO, CO2) and, in most cases, the rate declined with rising temperature. The rate-controlling step appears to be the diffusion of CO2 gaseous species through the micropores of the CaS(s) - product layer which builds up around the CaOcore.

Jan 1, 1989

By Timothy D. Stark

Jet grouting has increasingly become one of the ground improvement technologies used to address seepage concerns and to provide strength improvement of soils. The technique of jet grouting uses high pressure/velocity jet fluids to erode the existing soil and then to mix the cuttings with cement slurry to form soilcrete. Excess slurry or spoil is ejected to the surface. If the native soil is not completely mixed with slurry, the resulting columns will have soil inclusions which can reduce the strength of the column and/or increase the permeability of the column. A jet grout test program at Tuttle Creek Dam shows that the completed large diameter columns contain perhaps 40 to 50% or more of native soil that was not broken up and mixed during the jet grout process. The test program included excavation of full-scale columns to a depth of 35 ft (10.7 m) for visual inspection and testing. Additionally, six of the columns were cut or sectioned to investigate the interior of the columns. The observed inclusions include significant amounts of both fine grained (silts and clays) and coarse grained (fine sands and sands) soils. Evidence suggests at least two explanations: (1) fine grained soils can be difficult to erode and break up into small enough particles that can be ejected to the surface, especially if at low natural water content, and (2) when large diameter columns are being excavated, the excavated roof of the cylindrical cavity may be unstable and may collapse. With this roof instability large slabs of material can break off, fall into the slurry and escape the cutting and mixing action of the rotating jets. This paper describes the Tuttle Creek Dam test program, inclusions observed in the completed columns, and suggests potential causes of the inclusions.

Jan 1, 2009

Presented in this volume are the basic mining techniques and production operations associated with underground bituminous coal mining. Chapter 2, "Multiflow Process Charts", presents, in sketch form, a description of the various operations characteristic of conventional and continuous mining. In order to focus attention upon the major components and operations in each work cycle, certain items are not shown in the sketches, e. g., machine electrical cables, brattice, and rib posts. The elapsed time shown for each sketch is considered representative for the various work elements summarized by the sketch. More detailed work element times can be found in Chapter 3, "Typical Work Cycle Times", and Chapter 4. "Standard Time Data".

Jan 1, 1971

By I. Tsolas

This paper presents the use of non-parametric approach (i.e., data envelopment analysis, DEA) for the development of environmental sustainability indicators in mineral processing using environmental, economic and/or integrated indicators (i.e., indicators that interrelate two dimensions of sustainability). A case study based on real publicly available data is presented to illustrate how the proposed approach can be implemented in practice. The merit of this approach, which is based on the productive efficiency framework, is that it provides environmental sustainability indicators that can be used internally for benchmarking purposes and externally for sustainability reporting.

Jan 1, 2008

By Alec C. Bloem

A 55' deep excavation encompassing almost a city block in London, Ontario required a lateral earth retention system to provide both temporary excavation support and a permanent groundwater cut-off wall for a proposed office complex. The system selected was an interlocking Drilled Shaft wall with 3-4 levels of tiebacks. The specifications required the system to be designed for movements or settlements around the excavation of ¼" max. Design to be by the Contractor with design parameters and a comprehensive soils report provided. An extensive system of instrumentation in the form of inclinometers and survey targets were used to monitor vertical and horizontal movements of the shoring system and adjacent properties. Introduction The project, One London Place, is a two phase office tower development in downtown London, Ontario. Phase one consists of a 24 storey office tower on the northwest part of the site, with five levels of below ground parking over the entire site "Figure 1". A second office tower will be constructed at a future date.

Jan 1, 1991

By P. den Hoed, J. Nell

Tests were conducted on samples of rutile, titaniferous slag and ilmenite; each sample was mixed with coke and chlorinated in a bubbling fluidized bed at 1000°C. Profiles of the rates of chlorination of species were constructed from chemical compositions of the bed residues at different durations. From the start FeO and MnO are chlorinated quickly and all but entirely in a fraction of the time it takes to chlorinate all the TiO2. When the level of FeO is significant, as in slag and ilmenite, FeO is chlorinated faster than TiO2is. In these oxides, there is an inverse relationship between the rates of chlorination of FeO and TiO2during this first stage; the relationship, moreover, correlates linearly with the initial percentage of FeO in the oxide. We identify three stages in the chlorination process; a first, in slag and ilmenite, when FeO is being chlorinated; a second, when TiO2is most readily chlorinated; and a third, towards the end, when the levels of TiO2are reduced to those of other species. The rates at which individual species are chlorinated are analysed in terms of their appreciation or depreciation with respect toTiO2

Jan 1, 2003