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By Forsén. O.

In this ?paper practical solidification of anodes containing nickel, arsenic, antimony and bismuth is compared with the equilibrium? diagrams and kinetic ?factors. In order to clarify the distribution of the impurity elements in the anode the structures were studied after the solidification and also after the electrolysis of anodes. This examination was carried out with optical microscope, scanning electron microscope and electrochemical measurements. All the nickel is remaining metallic in the copper matrix during the solidification and therefore nickel is dissolved in the electrolysis at all oxygen contents, when the nickel content is 0.25 wt-% or less in the anode. The practical .solidification mechanism of the anodes, when the nickel content exceeds 0.25 wt-%, proceeds by the crystallization of nickel oxides. In oxygen containing copper anodes nickel oxide is verified to crystallize together with antimony in certain conditions and to form a micaceous compound (3Cu2O?4NiO?Sb2O5), which may build up a very harmful floating slime in the electrolyte. Arsenic is strongly enriched along the phase boundaries in oxygen free copper anodes. An intermetallic compound Cu3As is formed when the amount of arsenic in the anode. exceeds 0.7 wt-%. This compound is more noble than the copper matrix. This means 'that a selective dissolution of copper-arsenic compounds takes place. The copper matrix dissolves more strongly than the grain boundaries. The solidification structures of oxygen free bismuth containing copper anodes show clearly the influence of bismuth. Thin bismuth films which are less .noble than the metallic copper matrix, are formed during the solid1ficatton process. As a result of this the?grain boundaries are dissolved faster than the copper matrix.

Jan 1, 1987

By C. Frias, M. Garcia, G. Diaz

Advances in hydrometallurgy promoted by Tecnicas Reunidas are providing increasingly simple and clean means for controlling the entire lead recycling chain. Used in parallel with pyrometallurgy, these processes allow furnace temperatures to be reduced and fumes and atmospheric pollution to be minimised. Furnace slags are digested, and residues (mainly gypsum) are non-toxic and convertible into marketable products. In addition, the global economy of the process is substantially improved by reducing the operating cost, increasing the lead recovery above 99% and obtaining a 99.99% pure lead product. These new PLACID and PLINT processes may provide the cleanest and healthiest practicable means for recycling lead from batteries.

Jan 1, 2000

By David J. Howard, Christine Broadbridge, David C. Paine

"High pressure vapor/solid reactions offer an opportunity for novel synthesis and processing of thin film materials and structures for electronic, optical, and magnetic applications. In this paper we review the use of two high pressure techniques that operate from 25 to 1000 atm (2.5 to 100 MPa) to fabricate thin film oxide structures from Si1-xGex deposited on Si wafers. High pressure synthesis enables temperature-independent control of reaction rates in the oxidation of this multicomponent semiconductor system and hence offers the opportunity to form thennodynamically metastable Si1-xGex<h from the alloy. The thermodynamics of the Si-Ge-0 system are reviewed and a method is described that utilizes selective chemical reduction (via H2 gas) of Si1-xGcx<h to form Ge precipitates in an SiO2 matrix. IntroductionAlloys of Si1-xGex grown epitaxially on Si substrates by chemical vapor deposition (CYD) and molecular beam epitaxy (MBE) have been used to create high performance microelectronic devices1. These devices show improved performance over conventional Si technology because they exploit the Si/Si 1-xGex band-gap discontinuity and take advantage of higher hole mobilities in the Ge containing alloys. While a range of devices based on heteroepitaxial systems have been demonstrated, the Si1_xGex alloys are of particular interest because they are most closely compatable with standard Si device processing. One disadvantage of Si-based materials systems is that they are not typically useful emitters of light. This is important since the use of light (rather than electrons) for transmitting and processing signals into, out of, and within Si-based microelectronics would represent a major technological advance in microelectronics-based communication and computer technologies. Nevertheless, through the use of innovative processing techniques it may be possible to use the Si1_xGex/Si heteroepitaxial system in integrated microelectronic/light-wave technologies."

Jan 1, 1994

By James Vaughan

Ionic liquids are solvents of interest for applications such as electro- plating, winning and refining of metals. Of particular interest is the possibility of processing reactive metals such as aluminium, magnesium and titanium that cannot be deposited from aqueous solutions. Aluminium has been electro deposited from AlCl3 : ionic liquid mixtures at low temperatures relative to conventional Hall-Héroult smelting. Imidazolium ionic liquids are have been used in the past due to their relatively high ionic conductivity and cation stability. The less studied and less expensive phosphonium ionic liquids systems may provide a viable alternative to imidazolium ionic liquids for certain applications. New information regarding the physical properties and electrochemical behaviour of phosphonium ionic liquid systems is presented.

Jan 1, 2006

By Weida Guo, Sangsang Liao, Bart Blanpain, Muxing Guo, Qing Liu, Lingling Cao, Keshe Ren, Yannan Wang, Lefei Sun

The interaction between a supersonic oxygen jet and liquid metal is a dominant factor affecting transport phenomena during the converter process. A systematic description of the interaction is of significant importance for a quantitative understanding of the transport phenomena. In this paper, cold model experiments and the corresponding numerical simulations were carried out to investigate the gas-slag-metal interaction inside an 80 t BOF converter. The effects of the operation parameters, such as inlet pressure, slag thickness and slag viscosity on the multiphase interaction have been studied. It has been found that the cavity profile is closely related to the operational conditions. The cavity depth increases with an increase in oxygen inlet pressure, whereas the cavity width is much less affected. The cavity profile is also clearly influenced by the thickness of the slag layer. The influence of slag viscosity on cavity profile is not significant under the present simulation conditions.

Mar 1, 2018

By Jian Pan, Zhen He, Deqing Zhu, Shouyan Yue

"The differences of raw material characteristic among six kind of iron concentrates and the influences on ballability were studied from the aspect of the size distribution, specific surface area and particles morphology. The results show that the specific surface area of iron concentrates has crucial influence on ballability, and the effective method of improving ballability for weak ballability iron concentrate has been found. It is of important guidance for Chinese steel mills to import and use iron concentrate from the whole world.IntroductionChina's steel industry has developed rapidly in recent years, crude steel production in 2011 is an unprecedented 683 million tons, which is almost half of the world crude steel production, and it is equivalent to the total sum production of the nations which rank at 2,3,4,5 and 6 in the world [1]. In order to match the development of steel industry, the blast furnaces are becoming larger and more modernization, therefore charging burden of higher quality is requested, and the reasonable blast furnace burden structure is more and more important, at the same time, for iron ore powder sintering process's continuous improvement and development, another method providing ""concentrate"" for blast fumace-pelletizing is also taken seriously. The grate-kiln method of pelletizing has achieved great development for its unique advantage, and in just a few years, there are over 60 rotary kiln production lines have built or being built in China, the sum of pellets has reached to more than 140 million [2, 3]. The rapidly growth of pelletizing yield demands diverse source of pellet, which include not only domestic magnetite concentrate, but also imported hematite which is high in iron and low in silicon. Usually the ratio of imported hematite concentrate increased gradually. The imported hematite concentrate has high grade and fine particle size (the content of -0.074 mm mostly higher than 90%), but the ballability of part of the concentrates is poor."

Jan 1, 2013

By Martin Reyes, Juan Hernández, Julio Cesar Juárez, Isauro Rivera, Ma. de los Ángeles Hernández, Francisco Patiño

The dissolution of Ag contained in metallurgical tailings was studied by adding ions Cu2+ and Zn2+ in S2O3 2- medium. Chemical analysis of mine tailings by cupellation revealed a Ag concentration of 71 g/ton. The XRF and XRD analysis confirmed the preponderance of SiO2 in the mineral matrix. The experimental dissolution process was conducted in alkaline solution using six concentrations of NaOH and five of S2O3 2-, at different temperatures, also using five concentrations of Cu2+ and Zn2+ as a catalyst. The results showed similar values for both systems (96.8% and 97.13%). The ion Cu2+ and Zn2+ increases the dissolution of Ag, and decrease the reaction time of dissolution. Under the conditions used, pH and stirring rate did not affect the dissolution of Ag.

Jan 1, 2015

By Yuanbo Zhang, Zhixiong You, Daoxian Duan, Guanghui Li, Tao Jiang, Xiaohui Fan

"Presently, high-grade manganese oxide ores are usually utilized by a coal-based reduction roasting process. However, there were some obvious drawbacks, including serious environmental pollution, high energy consumption, etc. The reduction temperature is relatively high (850-900 °C). In this study, a kind of biomass, pine black charcoal, was used as a reductant to reduce low-grade manganese oxide ores. Under the optimal conditions of reduction temperature of 600~650 °C, roasting time of 30~45 min and ratio of ore to reductant 5:1, the leaching efficiency of manganese reached more than 98%. Compared with the traditional coal-based reduction process, the reduction temperature is reduced by 250-300 °C.IntroductionManganese plays a very important strategic role in the national economy, and it is widely used not only in the metallurgical industry, but also in the light industry, chemical industry, medicine, agriculture, etc [1]. The average grade of manganese ores in China is evenly about 21%, which belongs to typical low-grade manganese ores [2]. Therefore, large quantity of high-grade manganese ores is required to import in order to meet the rapid development of Chinese manganese industry. As reported, the conventional treatment of reduction roasting has been widely applied for processing manganese oxide ores, in which coals or reducing gases (CO, H2 or CHi) were usually used as reducers [3]. However, there were some insuperable problems, such as high energy consumption, poor operating conditions, serious environmental pollution, etc [ 4-9]."

Jan 1, 2013

By A. N. Lasseigne

Hydrogenation behavior of the NaAlH4 intermetallics is investigated utilizing thermoelectric power and magnetic analyses. Using both thermoelectric power and magnetic susceptibility measurements on these intermetallics allows for confirmation and further insight into hydrogen&apos;s role in altering the material&apos;s electronic structure. The electronic and magnetic property correlations will indicate the direction for further alloy development to optimize hydrogen storage.

Jan 1, 2006

By Yan Wen

For the impurities in the copper smelting waste acid, SO3, Cu, As, Pb, Zn, Re and other elements enter the waste acid and generate a lot of arsenic residue, gypsum and neutralized residue, in which Cu, Zn and Re metals have not been recycled. Cu, Re and As are separated by step-wise vulcanization. The valuable metals of Cu, Zn and Re are recovered by separating zinc through pH adjustment. Calcium injection is conducted for boiler for reducing the amount of SO3. The residues generated in the form of arsenate and hydroxide will be returned together with arsenic filter cake for smelting treatment so as to achieve the purpose of valuable metal recycling and solid waste reduction and harmless treatment.

By Kazusuke Sato, Takahiro Uno, Koji Hoshino

"A novel Ni coating technique of Ni(OH)2 powders was developed to improve the positive-electrode performance· of the Ni-MH batteries. It was found out that Ni(OH)2 powder was reduced by N2H4 without any catalysts in an alkaline - solution at high temperatures. In result of observation of pH and potential changes in the solution during the reaction, it was found that the reduced species was HNio2- ion dissociated from Ni(OH)2 in the alkaline solution. The molar fraction of reduced Ni of the Ni(OH)2 was increased in proportion to the amount of added N2H4. At the small Ni fraction, a porous Ni layer was formed on the surface of Ni(OH)2 powder. Open cell tests were carried out with the paste type electrodes made of either the Ni coated Ni(OH)2 powder or non-coat powder, and cell performances were compared. In result, it was found that the Ni coating technique is effective on improvement in the utilization of Ni(OH); as a positive-electrode active material under high current densities.IntroductionNi-MH rechargeable battery is generally used for the power source of portable machines and electric vehicles because of its good performance at high energy density and. long term cyclical life as well as cleanness and good safety. Cell component materials have been improved respectively, and as concerns ·the positive-electrode reducing 'the internal resistance is a principal problem to improve the discharging performance at higher current densities.In recent years, improved Ni(OH)2 powders coated with conductive materials as NI. or CoOOH have been developed for the· positive-electrode active materials in order to· reduce the internal resistance of the electrode1)· 2) The Ni coated Ni(OH)2, however, is costly because it is fabricated by .the -non-electrode plate technique which needs a expensive precious ·metal catalyst as PdC12We found that Ni(OH)2 powder was reduced by N2H4 without any cryatalysts in an alkaline solution at high temperatures. After the treatment, Ni(OH)2 powder become gray color like Ni powder from light-green color; and. turned into a magnetic. In this study, the mechanism of the -reducing reaction was investigated to apply the reactions .to a novel Ni coating technique of Ni(OH)2 powders, · and the performance of the Ni coated Ni(OH)2 powder obtained by the reducing process was evaluated as an -positive-electrode active material of Ni-MH batteries."

Jan 1, 2000

By Afshin Sadri

Acousto Ultrasonic-Echo (AU-E) is a technique developed to provide accurate measurements of the refractory lining wear in operating smelters based on the principles of stress wave propagation. The objective of the system is to provide feedback for the continuous optimization of the overall smelter operation. In some cases, the AU-E refractory lining measurements have allowed clients to extend their smelter campaigns and operate safely for several years beyond their planned reline schedule. In other cases, AU-E results inform clients of serious issues within their furnace allowing them to shut down their smelters ahead of predicted failures and possible disasters. This paper presents the results of several smelter AU-E inspections of the hearth and sidewall. These case studies demonstrate how the AU-E results were used to positively affect the smelter operation.

By Yuanbo Zhang, Zijian Su, Bingbing Liu, Guanghui Li, Manman Lu, Tao Jiang

Acid wastewater containing toxic metal ions has become increasingly important global environmental concern and lead (Pb) is one of the prime toxic heavy metal ions. Humic acid (HA), a kind of natural organic matter, has been proventohaveagreatadsorptioncapacityformetalcations(Pb2+,Cu2+,etc.).Our previous study has verified that HA has excellent adsorbing ability on vanadium titanium-bearing magnetite(VTM) particles. In this study, VTM-HA complex magneticparticles werepreparedfor removing Pb(II)fromacidwastewater,which could be easily recycled by magnetic separation. The effects of pH value, ionic strength and VTM-HA concentration on the removal ratio of Pb(II) were deter- mined by isothermal adsorption tests. The results indicated that Pb(II) adsorption was subject topHand ionic strength. When initial Pb(II) concentration is 100 mg/ L, the residual concentration and removal ratio of Pb(II) reach 0.17 mg/L and 99.83%, respectively, which are much lower than the discharge standard. (cid:1) (cid:1)

Mar 1, 2018

By C. R. Palmer

The Bureau of Mines investigated the use of ion-exchange technology for the recovery of precious metals from cyanide leach and spent electrolytic solutions. This research included adsorption of gold and silver on both weak-and strong-base anion-exchange resins. The effects of nickel, mercury. and iron on precious metal loading of strong-base resins were also determined. Due to the nonselectlvity of strong-base resins, selective elution also was investigated. Both commercially available and experimental weak-base anion-exchange resins were tested. None of the commercial weak-base resins tested were suitable for a caustic-cyanide system owing to their low recovery of precious metals at pH 10 or above; however, three experimental resins have possible application. Continuous tests conducted with mill cyanide solution in a multicompartmented ion-exchange column using strong-base anion-exchange resins adsorbed nearly 100 pct of the precious metals as well as the iron and nickel. During the elution of this loaded resin the iron was first removed with NaCI plus NaOH; then nickel with dilute H2S04 or HCl; finally gold and silver with thiourea in dilute HCl.

Jan 1, 1988

By L. J. Lutz

The U.S. Bureau of Mines has developed an electrorefining process to recover Ni, Co, Cr, and other metals from mixed and contaminated superalloy scrap. The superalloy scrap is cleaned then directly electrodeposited as a Ni -Co deposit. The process recovers approximately 90 pct of the Ni-Co available from the scrap as a 99t pct pure Ni-Co alloy. During electrorefining the electrolyte undergoes a purification process which results in Cr and other refractory metals reporting to the purification residue. Operating data is given for a 3-L compartmented electrolytic cell. Techniques for the removal of Fe, Cr, and trace impurities from the recycled electrolyte are outlined. The economics of a facility producing 15 mt/d of a Ni-Co alloy are also discussed.

Jan 1, 1993

By Shinya Hodoshima

A catalysis pair of tetralin dehydrogenation / naphthalene hydrogenation has been proposed in the present paper as a liquid organic hydride for operating stationary fuel cells. Catalytic naphthalene hydrogenation, having been commercialized since the 1940s, proceeds to generate decalin via tetralin as an intermediate. The storage capacities of tetralin (3.0 wt%, 28.2 kg-H2 / m3) are lower than decalin (7.3 wt%, 64.8 kg-H2 / m3) but both tetralin dehydrogenation and naphthalene hydrogenation are much faster than the decalin / naphthalene pair. Moreover, existing infrastructures such as gas stations, chemical tankers and tank lorries are available for storage, transportation and supply of hydrogen. With respect to the stationary fuel cells with large space for hydrogen storage, tetralin as a hydrogen carrier is superior to decalin in terms of fast hydrogen supply or power density. Rapid hydrogen supply from tetralin under mild conditions was only accomplished with the carbon-supported metal catalysts in the ?superheated liquid-film states? under reactive distillation conditions. In contrast to the ordinary suspended states, the catalyst layers superheated in the liquid-film state gave high catalytic performances at around 250OC. As a consequence, both serious coke formation over the catalyst surface and excessive consumption of exergy were prevented simultaneously.

Jan 1, 2006

By Xia Hong-ying, Peng Jin-hui, Zheng Zhao-qiang, Zhang Li-bo

"Preparation of activated carbon from the walnut shell by microwave assisted steam activation was studied. Influences of the three parameters, activation temperature, activation duration and steam flow rate on the adsorption capacity and yield of walnut shell activated carbon(WSAC) were investigated,optimization process was obtained by the Response Surface Methodology (RSM). The optimum preparation conditions were as follows: activation temperature of 980°C, activation duration of 41 min and steam flow rate of 1.66 ml/min. The optimum conditions resulted in an activation carbon with an iodine number of 1025 mg/g and a yield of 52.17%, while the BET surface area, total pore volume and average pore diameter of WSAC were 1328m2/g, 0.72ml/g and 2.2nm respectively. The study supported the potentiality of comprehensive utilization ofWalnut shell and the benefits of the microwave heating.IntroductionActivated carbons are one of the most important adsorbent materials in modern society because of its abundantly developed pore structure, strong adsorption ability, high surface area and thermo stability. They have extensive application in many industries fields which include gas purification [1], catalyst supports [2] and other pollutants [3]. However, in recent years, the industrial production of activated carbon is facing the problem of raw material scarcity and high cost, which limit to be widely used. Therefore, the selection of an appropriate precursor plays an important role and it has become hot sport to seek cheap raw material to lower preparation cost. As a kind of reproducible resource, the waste from agriculture and forestry is a high-grade raw material for preparing activated carbon due to is high carbon content, such as palm shell [4], rice hull [5], and coconut shell [6]. At present Walnut shell is widely accepted to be a renewable source of biomass. According to statistics, there is more than 1000,000 tonnes of walnut shells are produced in China annually [7]. As a good precursor for activated carbon production, Walnut shell is a major agricultural waste, to make better use of the cheap and abundant agricultural waste, it is proposed for activated carbon production."

Jan 1, 2014

By Kazuyuki Kakegawa

The sintering characteristics and the change in the compositional distribution in the PbTiO3-PbZrO3-Pb(Mg1/3Nb2/3)O3) system during the sintering process by spark plasma sintering (SPS) method were examined. They were compared with those by a normal sintering method. The densifieation by the normal sintering was slow even at high temperatures. When SPS method was employed, much lower temperature and shorter period resulted in sintered bodies having almost the theoretical density. As expected in normal sintering, the compositional distribution decreased as the sintered density increased. On the contrary, the change in the compositional distribution by SPS was much smaller than that in the normal sintering. This sintering characteristic of SPS suggested a possibility of fabrication of sintered material having a desired compositional distribution.

Jan 1, 2003

By Xun Zhang, ZhiLong ZHAO, Lifeng Zhang, Huiqing Tang

A two-dimensional gas-solid model has been developed for examination of the blast furnace (BF) performance under hot charge operation. Simulation conditions were obtained from the actual operation conditions of the BF with inner volume of 2500 m3 and molten iron output of 6250 ton hot metal (THM) per day. The simulation results indicate that hot charge operation could change the thermal state of the BF in the region above cohesive zone (CZ) and has little influence on the thermal state of CZ zone and the region below CZ; it could intensify both the indirect reduction of the ore and the gasification of the coke in the region above the CZ. The optimum temperature for hot charge operation is 750 K, under which, a coke rate reduction of 25 kg/THM could be obtained.

Mar 1, 2017

By Vinay Kumar, Jae-Chun Lee, Rakesh Kumar, Manis Kumar Jha, Archana Kumari, Pankaj Choubey

Present work is a part of developing novel recycling technique for waste printed circuit boards (PCBs) i.e. the liberation of metals from PCBs by organic swelling followed by the treatment of resin to remove/ recover hazardous soldering materials. In order to recover the hazardous metallic constituent lead from the liberated resin, initially the leaching studies were made using fresh solder containing 63.9% Pb and remaining tin. Experimental results obtained in different conditions viz. time, temperature and acidity showed -97.20% of lead dissolution with 6M HNO3 at solid to liquid (S:L) ratio 1:10 (g/mL) and temperature 90°C in 75 minutes. The result of the studies validated with crushed PCBs shows that almost total lead and tin was leached out with 6M HNO3 and 6M HC1 respectively at S:L ratio 1:10 (g/mL) and temperature 90°C within 50 minutes. The results will be useful for the treatment and safe disposal of PCBs resin.

Jan 1, 2011