Search Documents

By V. Prabhu, D. Mantha, R. Reddy

Secondary copper blast furnace slag was treated with carbon to derive the conditions for maximum recovery of copper with a minimum simultaneous reduction of iron oxide. Experiments were carried out to study the effect of temperature, carbon and CaO additions to the slag on the efficient recovery of copper. A two-stage reduction process was also employed to study the efficiency of copper recovery and the results were compared with those of single-stage reduction. The maximum recovery of copper in alloy phase was obtained with 5 % initial carbon in the slag, 2% CaO addition to the slag and at a reducing temperature of 1573 K. Higher grade of the alloy phase with respect to copper was obtained by employing a two-stage reduction process. The results obtained in this study are comparable to those of the earlier research on the recovery of copper from reverberatory furnace discard slags.

Jan 1, 2004

By P. C. Kapur

The hierarchical relationship between three broad kinds of grinding models for a spatially homogeneous, linear, time-invariant batch grinding system are first established. Limiting and asymptotic arguments for arriving at approximate but simpler models are employed in all three cases. These parsimonious models -provide alternate and, in some respects, more incisive and convenient tools for the analyses of grinding processes and simulation of comminution circuits. In the discrete-size, discrete- time class of models, a reduced mill matrix is derived, which is seemingly adequate for those grinding circuits whose identification otherwise is difficult because of limitations on the quantity of data and its quality. In discrete-size, continuous-time types of models, parameter lumping has been employed for obtaining a G-H solution which is quite accurate and exceptionally useful for graphical display of data, model verification, and parameter estimation and simulation. In continuous-size, continuous-time models, a similarity transformation is used for solving the integrodifferential equation of grinding. This solution provides a unified framework for a number of apparently diverse empirical grinding phenomena such as self-preserving behavior of ground particle size distributions and energy laws.

Jan 1, 1987

By R. A. Metz, Willard C. Lacy

Rather than attempting to present a summary of the many and highly varied papers that have been presented at this symposium on sampling and grade control, I will attempt to extract the general philosophy of analysis and approach, and attempt to identify the trend of future developments. First, the term "sampling" is used with its broadest connotations. A sample consists of a representative portion of a larger mass, and must represent the mass not only in the grade of contained metals or minerals, but also in all other respects in terms of mineralogy and mineral quality (1, 5), deleterious materials, recoverability of economic components, physical behavior, geophysical response (1), and even archaeological and environmental aspects (7, 11). The sample must be taken from a locality and in such a manner and quantity that it is representative of the larger rock mass. This calls for complete and accurate geological control and an understanding of the nature and distribution of the contained chemical and physical elements and a record of the effectiveness of the different sampling methods. Second, value of a given mass of ore material is based upon its profitability - the difference between recoverable value and costs to achieve recovery, beneficiation and sale. There is a strong movement in mining geology control toward more complete analysis in determining cutoff grades and in grade control, as illustrated by the kriging of metallurgical recovery factors as well as grade at the Mercur Mine (8). To achieve a "profitability factor" as a guide for economic mining practice requires further integration of: 1) the value of contained metal or mineral, 2) percentage recovery of values, 3) dilution of ore with waste rock, 4) addition to, or loss of value as a consequence of by-product materials or deleterious components, 5) cost of producing a saleable product plus minimum profit to justify the effort (cutoff), and 6) cost of land restoration (7, 11). All these parameters vary with the rock type, rock structure, mineralogy, depth, geometry, mining and metallurgical methods, but they must be sampled and analyzed if sampling and grade control are to reflect profitability. A wide variety of deposits has been presented at this symposium; each deposit with its own problems and special solutions. Deposits containing high unit-value components, e.g. precious metals and diamonds, present special problems in the obtaining of accurate samples and generally require statistical analysis control methods or may disregard or modify occasional high or occasional low values, based upon experience (12). Grade control may be accurate for the long term but may vary for the short term. Bulk sampling is always essential. Deposits containing metals or minerals with low unit value are very sensitive to transport costs, and they are often very sensitive to small amounts of deleterious components or differences in physical or chemical behavior. Problems of sampling and grade control change with the genetic type of deposit, with the stage of deposit development and with the size of the information base. Precious metal epithermal deposits (2, 6, 8), because of rapid vertical zonation and erratic lateral distribution of values, have always been difficult to evaluate and maintain grade control and ore reserves. On the other hand, evaluation and grade control are relatively easy in bulk-lowgrade deposits (4, 13). However, these deposits generally have a low margin of profit and are sensitive to mining and beneficiaton costs, price fluctuations and political costs. Industrial mineral deposits (5) often must be evaluated on the basis of their behavior, rather than by chemical analysis. Environmental impact generally increases with the scale of the operation, but certain elements or minerals have especially high impact effects (7, 11). In the exploration phase there is no production control of sampling procedures and careful geological observations are particularly essential. The greatest number of problems is related to the oxidized outcrop where the chemical environment of the ore body has changed and the contained values may have been enriched, depleted or values left unchanged (2, 6). Present evidence suggests that gold values may be very mobile under certain conditions (2, 6) and stable under others. Everything must be sampled in detail. Principal values and by-product or deleterious elements may vary dependent upon their position within the soil profile. Such factors as geomorphic position, erosion rate, vegetation, climate, etc., may affect the interpretation (1, 3). During the development phase it is equally easy to overtest, to have "paralysis by analysis," as to undertest (3, 6). Bulk samplng and testing are

Jan 1, 1992

By C. O. Hamilton

Poor plant start-up performance is usually blamed on poor design and unsatisfactory equipment. But, in most cases, the real cause of poor performance is inadequate preparation for operations and maintenance. Inadequate maintenance preparation, unlike inadequate operations preparation, will not immediately manifest itself in a new plant. However, not taking advantage of the window of opportunity afforded a new plant to organize the maintenance operation ensures that the new equipment honeymoon is unexpectedly short. Also, once a plant has entered a “breakdown mode,” it is extremely difficult to turn around.

Jan 1, 1991

By J. P. Barbosa, R. V. V. Araújo, R. B. E. Trindade

Bromide stabilizes the auric or aurous ion by forming a stable complex in acidic aqueous solution. The oxidizing agent normally used for the process is bromine, which is a corrosive liquid with high vapour pressure. This is, in fact, the main reason why it has not found acceptance yet as an industrial oxidant for gold. Ferric ion with hydrogen peroxide and/or sodium hypochlorite have already proved to be effective oxidants for the dissolution of gold from a rotating disc in a bromide-containing aqueous solution. In the present work, preliminary tests with four selected ore samples were tested to evaluate the dissolution of gold with the same system already tested with the rotating disc (Br-/Fe3+/H2o2/NaCIO). Compared to the conventional cyanidation, results were superior in one instance only. The major obstacle seems to be the maintenance of a suitable potential to allow the complex formation. However, the studied system may be interesting, is in some situations it may yield better results than conventional cyanidation; therefore, further investigation seems to be worth doing.

Jan 1, 1995

By S. S. SHINDE, P. C. JIKAR, N. B. DHOKEY

Mill scale is an oxide waste product of steel mills, containing around 70 percent iron and other allied impurities. In the present context, a dynamic prototype counter-current reactor (CCR) was used for the experimentation and simulation of a particle bed using the discrete element method (DEM). Mill scale was pulverized to ASTM mesh range 140 (106 μm)/+ 270 (53 μm) and oxidized in a CCR to make a single oxide Fe2O3 phase by maintaining the required thermodynamic conditions, such as pure oxygen at 1,100 °C. This oxidized powder was then subjected to a reduction reaction in the CCR, with gas mixture (H2:N2) ratio of 1:4 at 875±5 °C for filling degree, fd , and reactor revolution, ω, ranging from 5.38 to 16.14 percent and 2 to 5 rpm, respectively. A creeping fluid flow condition (Re < 1) and natural heat convection (Gr/Re2 >> 1) were maintained during the solid–gas reaction, and the particle-bed behavior was quantified by Froude number for the optimum operating window. The simulation was validated with the experimental results of reactor reaction product by X-ray diffraction (XRD) and scanning electron microscope (SEM) images.

By Yi-Hsuan Chen, Jürgen Brune, Candace S. J. Tsai, Alejandro Munoz, Connor Krause

This study highlights the significant presence of submicrometer- sized airborne particles in underground coal mines, especially around the belt conveyor drift areas. Using realtime instruments and gravimetric samplers, the assessment revealed that particle concentrations were notably higher in the belt entry compared to other locations, with a strong presence of submicrometer- and nanoparticle-sized dust. The study’s findings emphasize the importance of addressing small particle exposure, as these particles, composed of harmful substances like calcium, copper and iron, can pose serious health risks to miners. This research emphasizes the importance of improving air exposure estimation through more effective monitoring and characterization techniques to better understand and reduce workers’ exposure to hazardous airborne particles in the mining environments.

Apr 1, 2025

By Alexander May

In its role of providing technology to promote the efficient use of minerals and mineral process waste, the U.S. Bureau of Mines has conducted research at: its Tuscaloosa Research Center to identify and develop high volume uses for phosphogypsum. Mixtures containing a maximum of 50 percent phosphogypsum, 6 to 10 percent lime, and the remainder fly ash had compressive strengths as high as 4,800 psi. The effects of the mounts of phosphogypsum, lime, and fly ash were investigated. Also, the effects of fly ash to lime ratios were studied.

Jan 1, 1983

By Ashma Singh, Nichole Maistry

Due to declining iron ore grades, low-grade ores with complex mineralogy — namely, banded iron formation (BIF) — are being explored to maximize iron ore resources and increase the life of mine. Flotation is the standard global process used for the beneficiation of BIF ores, as it is a complex ore reserve, and liberation is typically achieved below 1 mm. This study focuses on the flotation of a South African BIF, evaluating its response to different collectors, as well as effect of grind. As flotation is an expensive process and South Africa ranks high on the production cost curve, preconcentration by gravity or magnetic separation is performed prior to flotation. Thus, flotation was also performed on a gravity concentrate to determine if a grade suitable for steelmaking (approximately 63 percent) is achievable. The results indicate that the use of an alkyl ether amine-based collector partially neutralized with acetic acid is suitable for separation of hematite from illite and quartz at high pH values. Further optimization tests are being pursued to improve overall recovery and grade.

May 1, 2025

By Duane B. Jorgensen

The two calcium sulfate minerals, gypsum and anhydrite, occur in many parts of the world, and gypsum has long been of economic importance in the family of industrial minerals. Gypsum, the dihydrate form of calcium sulfate (CaSO, . 2H20) and anhydrite, the anhydrous form (CaSO,) are frequently found in close association, and it is seldom that a calcium sulfate deposit will consist exclusively of one mineral or the other. Although known gypsum deposits are extensive, anhydrite makes up the larger part of total calcium sulfate resources. Although it has very minor economic use, it is important to the understanding of gypsum deposits and is referred to frequently in the following discussion. Calcium sulfate is one of the principal constituents of evaporite deposits, and when pure, has the following composition: [ ] Deposits of pure gypsum or of pure anhydrite which are large enough to be considered commercial have not yet been found because of both the metastable relationship between the two minerals, and the presence of impurities such as calcium or magnesium carbonates, chlorides, other sulfate minerals, clay minerals, or silica. Most gypsum produced ranges from 80 to 95% pure and beneficiation is normally limited to selective mining or quarrying or upgrading by crushing and screening during mill processing. END USES The largest use for gypsum is based upon the unique property which calcium sulfate has of readily giving up, or taking on, water of crystallization. With the application of a moderate amount of heat in a process known as calcining, gypsum is converted to plaster of paris, the hemihydrate of calcium sulfate (CaSO4 ½ H2O), which when mixed with water will set or harden as the calcium sulfate returns to the stable dihydrate form. This semifinished product, usually called stucco, is then manufactured into a large variety of plasters, wallboard, and block for construction use, or into plasters for industrial applications. About 75% of the gypsum used in the United States is calcined for these purposes. Uses of uncalcined gypsum are principally as a retarder for portland cement, as a soil conditioner, as a mineral filler, and other minor industrial applications. About 25% of the gypsum mined in the United States goes into these markets; however, in other countries with building practices different from those in the United States and Canada, relative usage varies widely. Calcium sulfate deposits are the world&apos;s largest sulfur resources; minor quantities of gypsum and anhydrite have been used to produce sulfur or sulfur compounds. This use is accompanied by a unique site-specific set of economics because sulfur is generally available from non-gypsum sources at lower cost.

Jan 1, 1994

By Campbell J. McKenzie

Following on from the successful completion of three exploration programs and the discovery of two new inactive Seafloor Massive Sulphide (SMS) deposits within New Zealand?s Exclusive Economic Zone (EEZ), Neptune is now poised to take the next step from explorer to developer. Neptune considers that commercialization of SMS deposits represents the future of the mining industry, providing a new source of metals to the world economy, and enabling host countries to benefit from this new industry. Neptune recognizes that marine biodiversity is among the greatest treasures of New Zealand. The geological isolation, range and complexity of habitats, and a number of major ocean currents that influence New Zealand have created diverse marine communities. Neptune, recognizing both the environmental importance of marine biodiversity and the value it provides to all New Zealanders has made commitments to ensure sustainable development. There are many unanswered questions regarding how the marine environment may be affected by SMS development, however best practice environmental management is a key aspect of the Company?s approach to our activities and the code for ?Environmental Management of Marine Mining? prepared by the IMMS has played a part in this approach. Neptune has close relationships with the scientific community to ensure that appropriate environmental strategies and plans are developed in order to minimize the effects of our activities on the environment.

Jan 1, 2008

By James C. Irvine

Pea Ridge Iron Ore Co., previously Meramec Mining Co., a joint venture by Bethlehem Steel Corp. and St. Joe Minerals Corp., mines and pelletizes iron ore at the Pea Ridge mine. The Pea Ridge property, now wholly owned by St. Joe, is located near Sullivan, MO, about 112 km (70 miles) southwest of St. Louis. The ore body was delineated in the mid-1950s by St. Joe during a lead exploration program. The first test holes drilled on the Pea Ridge magnetic anomaly revealed the presence of a large magnetite deposit; further drill¬ing in 1956 and 1957 confirmed that the ore body was minable. Meramec Mining Co. was incorporated in 1957 and shaft sinking began late in the year. Pro¬duction commenced in April 1964. The ore body is overlain by about 396 m (1300 ft) of flat-bedded sediments. It is tabular, about 792 m (2600 ft) long, and up to 182 m (600 ft) thick. It dips about 1.39 rad (80°) and is of unknown depth. The ore is mainly high grade magnetite with small zones of specular hematite. The wall rock is a Precambrian rhyolite porphyry. The mine was initially started with five major levels on 45-m (150-ft) intervals. Crosscuts were driven across the ore body on 58-m (190-ft) centers. Banks of stopes were mined between the crosscuts by a modi¬fied shrinkage stoping method (Fig. 1). This was done by undercutting a 12 m (40 ft) wide by 45-m (150-ft) long block and blasting horizontal "lifts" drilled on 1.5-m (5-ft) intervals. A 20-m (65-ft) sill was left between levels which contained the slushing drift, fin¬gers, crown pillar, and adequate thickness for support. By 1971 a "lattice" of pillars had been left and mining had progressed to the point that an orderly pillar re¬covery program was necessary (Fig. 2). INITIAL PILLAR RECOVERY PROGRAM The program was started in the upper western por¬tion of the ore body, furthest from the shafts. Due to the fact that the ore body narrows in the western extremity, the stope orientation was changed to mini¬mize required development. This left pillars 18 to 24 m (60 to 80 ft) wide and up to 79 m (260 ft) in length. The area selected for the start of the program had been developed between the uppermost level at 419 m (1375 ft) below surface and the 510-m (1675-ft) level. Due to the 91-m (300-ft) difference in depth, sublevels were driven on 15-m (50-ft) intervals and the ore was taken by rather classical sublevel stoping methods (Fig. 3). This left a structure with accesses compatible with drilling with 114-mm (41/2-in.) bore drifters mounted on columns. Most holes were drilled 63.5 mm (21h in.) diam and reamed to 100 or 127 mm (4 or 5 in.). Practical depth capability was about 21 m (70 ft) for holes above horizontal and 13 to 15 m (45 to 50 ft) for holes below horizontal. The interdependence of these long pillars necessitated that several of them be blasted simultaneously, making large blasts the only practical approach. Due to the required length of such loading cam¬paigns, it was necessary to select an explosive which could stand in the hole in an underground mine for a 4 to 6 week period. After some consideration a pump¬ able water gel was selected for both uphole and down¬hole loading. This afforded a high velocity, high density explosive which could be handled in large quantities. Loading the downholes was a fairly straightforward process. The holes were lined with an 8 mil polybutylene plastic sleeve and water gel was pumped into them with a double diaphragm pump mounted on the bottom of a stainless steel tub with a 81-kg (180-1b) capacity. Potential leakage into cracked areas of the pillar was

Jan 1, 1982

By Ralph P. Hackl

Biooxidation processes for treating arsenical and other types of refractory gold ores are touted by many as being simple, inexpensive and environmentally friendly. One of the advantages claimed by proponents of biooxidation is that arsenic is disposed of as insoluble ferric arsenate which is suitable for long term disposal in tailings ponds. However, there is considerable controversy as to the stability of ferric arsenate with respect to re-dissolution of arsenic. In particular, there is concern that the amorphous ferric arsenate produced at low temperature is not stable, especially at the alkaline pH's required for cyanidation. There is a general lack of published information on the stability of arsenical bioleach tailings. Past work on ferric arsenate stability has usually involved purely chemical systems and the use of synthetically prepared precipitates. Upon completing the Salmita bioleach pilot plant campaign (Hackl and Wright, 1989) the author had the opportunity to test the stability of the arsenical bioleach/cyanide tailings which were produced. This paper summarizes the results of that work.

Jan 1, 1990

By Yuting Xue, Danqing Gao, Brijes Mishra

Heterogeneity and discontinuity significantly affect rock strength. For accurate stability prediction, intact rock behavior is imperatively included in rock mass behavior. However, past research largely used arbitrary scaling approaches to produce rock strength. This paper considers a stochastic approach in order to determine the strength of a rock. Based on the laboratory data, a MATLAB® with extreme value stochastic model generates a database for each physico-mechanical property. Then FLAC® simulates laboratory-sized rock specimens. The grids developed in the numerical model can in turn develop random material properties in MATLAB®, which researchers then applied to the final FLAC® model. Model runs simulate the approach performed in the laboratory. The results from the model indicate that a stochastic approach produces strengths that are lower than a deterministic approach. Failure modes for each specimen are different, similar to observations in the laboratory. In addition, random density also influences the failure mode, highlighting the importance of stochastic analysis in rocks.

By S. L. Zhu, Brij M. Moudgil, J. L. Pinault

Prompt neutron activation probe (PNAP) was evaluated to determine chemical composition of phosphate rock slurry in-situ. The technique was able to precisely analyze Ca, Si and H using a 252Cf source. Direct measurement of P and Mg was not accurate due to interference by the rare earth elements associated with the Florida Phosphate Rock. The solids loading, particle size distribution and flotation reagents present in the slurry had no significant effect on the accuracy of the measurements. The technique was found to be reliable also under industrial conditions.

Jan 1, 1993

By G. X. Wang, J. O. Marsden, M. C. Fuerstenau

Zinc cementation of high-temperature carbon eluates is now used extensively in gold processing to replace electrowinning. Under these conditions, zinc consumption is high. In this paper, zinc solubility is press rated us functions of temperature, cyanide concentration and pH in the presence of gold, silver and mercury cyanides (both individually and in combined solutions). Based on the experimental results, cementation of these metals is characterized and discussed. The importance of cyanide concentration in cementation efficiency and the effect of mercury and its co-precipitation onto zinc are also discussed.

Jan 1, 1997

By R. Sharma, S. Svoronos, S. Gupta, N. A. Abdel-Khalek

This paper presents the results of a column flotation study on a fine feed sample of Florida phosphate. A central composite design was used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to produce a high-grade concentrate with a high recovery. A 15ppm concentration of nonionic frother was found sufficient to maximize the recovery at pH of 9.5.

Jan 1, 2002

By T. H. Parker

The Guasare Coal Project is located a short distance from Lake Maracaibo, in the Northwestern region of Venezuela. In 1987, Carbones del Guasare, a joint venture comprised of Carbozulia, ACC Venezuela, a subsidiary of ARCO, and AGIPCoal of ENI Group, Italy, was formed to develop the Guasare coal reserves for world markets. Drilling with the Venezuelan state of Zulia has indicated a coal resource of over 6 billion metric tons. Further exploration has delineated the Guasare deposit as an area particularly suited for cost-effective surface mining. The calculated mineable reserves of this area (300 million metric tons) and the coal quality characteristics are based on extensive core drilling programs.

Jan 1, 1989

By F. E. Kottlowski

Widespread high-calcium limestones in New Mexico region are low -in magnesium, but some units include shale interbeds deleterious for sulfur removal usage. Thick limestones in Mississippian Escabrosa, Lake Valley, and Leadville, Pennsylvanian Madera and Hermosa, Pennsylvanian-Permian Horquilla, Permian Hueco and Capitan, Cretaceous U-Bar, and some Cenozoic travertines are high-calcium units. Significant outcrops are in mountains of southwestern, south-central, central, southeastern and north-central New Mexico, southeastern Arizona, southwestern Colorado, and northwestern Chihuahua. Coal-fired powerplants are mainly in northwestern New Mexico and eastern Arizona, thus transport is mainly by railroad.

Jan 1, 1994

By P. R. Sheorey, D. Barat, B. Singh

Presented is a stability analysis for a trial stope in a lead-zinc mine. The trial scope would have an excavation width of 20 m with an initial height of 3 m. Filling would commence when the scope was heightened to 6 m. A two-pronged approach to predict the stability of such an opening was used viz. the finite element method and the rock mass classification method. Corroboration is shown to exist between the two methods. Deep borehole extensometer observations during stope extraction have been compared with predicted displacements.

Jan 1, 1981