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By C. H. Bucknam, A. M. Raichur, M. Misra

Simultaneous dissolution of mercury along with gold occurs during cyanidation of gold ores. A method has been found for the efficient removal of mercury from the gold cyanide solution by treating with dithiocarbamates which form stable compounds with mercury. The mercury concentration in the leach solution can be brought down to low levels by adopting this treatment. Furthermore, it is also possible to stabilize the mercury in the ore heap itself by addition of this reagent so that mercury does not dissolve in the cyanide solution during heap leaching. Only trace amounts of mercury were detected in the pregnant solution obtained from a heap treated with dithiocarbamates. In this paper, process parameters are discussed in detail.

Jan 1, 1997

By James H. Lammers

Over the years, the chemical processing industries have con­tinued to move from batch to continuous processing in order to obtain better quality control, simpler designs, and often reduced capital and operating costs. One exception to this trend has been the carbon elution circuits in the gold industry. Although some successes have been achieved on a pilot scale, no continuous elu­tion circuit using Anglo American Research Laboratory (AARL) methods has ever been used on a commercial scale until now. This paper describes the continuous elution circuit which was recently commissioned at a major gold project. The paper also presents the economic justification for the selection of the process over conventional batch technology.

Jan 1, 1998

By Bruce W. Cavender

There is a tendency for managers of mining companies to regard the performance of a process plant as essen­tially fixed, with only incremental improvements to be realized by optimizing individual unit operations. However, a number of op­erations management methods are available that will substantially improve plant performance, through both productivity increases and cost reductions. Known collectively as "world-class manufac­turing" techniques, these include total quality control, just-in-time production and inventory management, the systematic develop­ment of innovative plant practices, and progressive management accounting and business control systems. The implementation of these techniques by plant managers and operators will enable the plant's performance to exceed levels that are currently believed to be maximized.

Jan 1, 1993

By J. H. Heintz

This paper discusses the law as it relates to appraising operational mining properties in the context of a takings claim. Topics include the need for valuation expertise, the differences between de jure and de facto takings, an overview of the law of condemnation, including jurisdictional issues, and defining your strategic options according to the controlling statute. State condemnation law varies by jurisdiction and just compensation can be calculated by comparable sales unit-times-price, before ¬after-valuation, capitalization of income and discounted cash flow methods. Takings under Federal laws are reviewed, as is the necessity of assembling a team including attorneys, valuation experts including a mineral appraiser, a real estate appraiser, economists and geologists.

Jan 1, 2002

By William R. Bond, Jim V. Rouse, Laura L. Damon

As noted by Damon (1990), "The time that a heap (of gold ore) is on the reusable leach pad is of critical economic importance." The Interim Neutralization Study, conducted by Brohm Mining Corporation (Brohm), at the request of the South Dakota Department of Water and Natural Resources and reported by Damon indicated that improvements could be made in leaching and pointed out the need for a better understanding of the gold ore leach procedures. To provide data on an actual heap, personnel from Brohm and GEOCHEM installed a series of pressure/vacuum lysimeters in an active Brohm heap, and conducted subsequent testwork to evaluate the efficiency of leaching. The objectives of the testwork included efforts to:

Jan 1, 1992

By R. L. Grayson

Compliance standards for respirable dust, which are reduced because of high quartz concentrations, have become an industry-wide problem. Research on the physical and chemical character of quartz-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may he coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quartz particles of a mine dust are "pure," then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should he lowered. If, however, the quartz is locked inside another material matrix, or coated, a reduced compliance standard may not he appropriate.

Jan 1, 1991

By John E. Tilton

Looking back on the second half of the 20th century, future historians, I believe, will be fascinated by two major political upheavals. The first is the environmental revolution in the 1960s. It erupted in the United States and parts of Western Europe and then swept across the rest of the globe like a wild fire. The second event is the collapse of the Soviet Union. It was the last of the world's great imperial empires. With its demise went central planning as a viable economic system. History, I suspect, will see this second revolution as an offspring of the first. This is because economic and environmental issues were largely responsible for the unraveling of the Soviet Union.

Jan 1, 1994

By Clifford R. Haryett

The potash industry in Saskatchewan, Canada, has advanced in numerous mining and ore processing areas over the last decade. This article describes these innovations and their effect on the industry in the area. During the 1970s, Canada's Saskatchewan province became a world leader, second only to the USSR, in potash production for crop fertilizer. Despite a serious oversupply in the early part of the decade, and a drop in demand due to the agricultural impact of the oil crisis, the Saskatchewan potash industry continued to make extensive capital expenditures to bring mining and processing innovations onstream. These innovations were directed at reducing production costs, improving work conditions, and overcoming environmental concerns.

Jan 8, 1982

The first of this two part series takes a look at some of the history and types of flotation as well as agents and mechanisms involved in it. Part two, next month, will examine flotation processes as applied to various sulfide and nonsulfide mineral ores. Flotation-"froth" flotation-is a physicochemical method of concentrating finely ground ores. The process involves chemical treatment of an ore pulp to create conditions favorable for the attachment of predetermined mineral particles to air bubbles. The air bubbles carry the selected minerals to the surface of the pulp, there forming a stabilized froth that is skimmed off and from which the predetermined mineral particles are recovered. Other minerals remain submerged in the pulp.

Jan 3, 1982

By A. Iordanidis

Fly ash samples were collected from two large lignite-fired power plants of Ptolemais region, northern Greece. Environmental Scanning Electron Microscopy (ESEM) was applied for the characterisation of the samples. ESEM coupled with Energy Dispersive System (EDS) provided fast and accurate results on the morphology, mineralogy and chemical composition of the fly ash particles. Fly ash consists mainly of aluminosilicate glass, silicates, oxides-hydroxides, sulphates, carbonates and char. Various types of chars, spheres (e.g. ferrospheres, cenosphers, plerospheres etc.), spheroids, agglomerates and mineral crystalls were observed. The size distribution of the fly ash particles was correlated with their mineralogical and chemical composition. Possible environmental impacts and potential utilization is also discussed in this study.

Jan 1, 2005

By Clement K. Chase, Manuel R. Lastra

Introduction The choice of using a dump or heap leaching process or a fine grinding-agitation leaching process is based on the grade and tonnage of the ore body. Low grade ore and small tonnages are best treated by a low-cost method, such as dump or heap leaching. Permeability, however, is the critical factor in a successful leaching operation, regardless of tonnage or grade. Without permeability in the leach bed, no percolation, no dissolution, no extraction, and no success are possible. Solution delivery to the ore is also essential. Solute-to-mineral contact is a requisite. The solute must be effectively strong and not be depleted in active dissolvers, such as acid, ferric iron, cyanide, and oxygen. It must also be moving across the mineral to be dissolved. No pockets of stagnant solution can be allowed. A third factor is recovery of the now-dissolved metal in the pregnant liquor. All such liquor should be gathered at a reasonable metal concentration to make further pumping and processing worthwhile. Control and recovery of pregnant solutions are probably the most ignored factors of solution mining. This stage in recovery is historically where many operations either fail or become viable. Permeability A permeable heap is normally achieved by taking into account heap building/construction and agglomeration/pelletizing. Even though heap building is critical for good permeability, it will not be discussed here. It has been described in detail by others. Instead, this analysis will concentrate on agglomeration and pelletizing. Differences between agglomeration and pelletizing are emphasized. Agglomeration is referred to when small particles are being attached to larger particles -the ore presents a complete size distribution. On the other hand, pelletizing is a process where all particles are fine (less than 850)µm or 20 mesh), as with mill tailings. The difference is important from two points of view: • Mechanical devices used to achieve the desired attaching action; and • Binder dosages. Mechanical Devices Due to the absence of large particles that fines can become attached to, pelletizing should be done in a centrifugal-action-based device, such as an inclined rotating plate, a rotary drum, or a series of belt-transfer points. In agglomeration, large particles play a part as a natural nucleus for the attaching action of fines. Hence, a tumbling action as strong as for pelletizing is not required. Common methods to accomplish agglomeration include: • Cascade belt system with either all belts moving forward or some of them moving forward and at least one moving backward; • Combination of belt plus inclined vibrating chute; • Large concrete mixer drum; and • Belt discharging directly onto stockpiled ore. The proper agglomeration system will depend basically on the size distribution of the ore and the amount and type of clays present. In all of the agglomerating systems described, the tumbling action takes place at the transfer points either from belt to belt, or from belt to inclined chute ore belt to ore pile. Usually, two or three mixing bars at each transfer point are also included to help the mixing action. Plows to move the ore around on a moving belt are also used.

Jan 11, 1984

By Daniel W. Kappes

The 1.8 million tonne Itos tailings deposit is the result of sever­al years of processing by Comibol of the San Jose and ltos Mine ores at Oruro Bolivia. The historic flowsheet consisted of a flotation circuit in which silver-bearing galena and stibnite were concentrated. Approximately half the silver in the ore was not recovered, and the existing tailings contain slightly over 200 grams silver per tonne, in the form of complex sulfides of silver, antimony, lead, and other metals coating grains of pyrite. An extensive laboratory program was conducted to exam­ine conventional processing l)lethods such as cyanide leaching and regrinding followed by flotation. However, the silver-bear­ing sulfides are in intimate contact with the pyrite and the pyrite comprises 30% of the total tailings weight. Cyanide leaching recovers only 40% of the silver and the cyanide consumption is uneconomically high. Flotation produces an upgraded, but still uneconomic, concentrate. For this reason, chloride leaching had been evaluated by Comibol, and in the mid 1980's Comibol undertook an innova­tive test consisting of two 300 tonne field heap leaches using a cold chloride solution. The tests were partially successful, but could not be applied to the bulk of the tailings which are already ground to 50% minus 200 mesh. In 1992, Kappes, Cassiday & Associates undertook to develop a hot agitated chloride leach flowsheet, and is current­ly constructing a treatment plant under a turnkey contract from a Bolivian company, Baremsa, S.A. Using this process, 85% of the remaining silver can be recovered, with significant by-prod­uct credits from antimony and lead. The project features hot, agitated acidic chloride leaching, filtration, crystallization of lead chloride, and precipitation of metals using iron scrap. Arsenic is removed from the precipitate by caustic leaching, and minor metals by furnace refining. Antimony is recovered as the oxide by cupelation, and silver is poured as <lore from the cupel. Production rate will be 600 tonnes per day. Startup is scheduled for late 1995.

Jan 1, 1996

Compared to alternative ways of dealing with coal fines, oil agglomeration has always been a commercial bridesmaid and never yet a bride. Yet interest is high in the process, as shown by a number of pilot plants in operation that are funded by industry as well as government. In the past in the US, alternative ways to handle coal finer than 100 to 200 mesh included flotation, or no treatment except dewatering, or discarding the fines as waste. There are now a number of factors that tilt the economics more toward fine coal recovery. Today, the cost of mining a ton of underground coal runs from $22-30, and discarding even 10% as unrecovered fine coal is a real economic loss. A number of attempts (notably by EPRI) have been made to quantify the effect of coal cleaning on utility boiler operations. Transportation and ash handling costs, frequency of unscheduled outages, fouling and slagging problems, and boiler tube erosion are all lowered by cleaning coal. The advantage of coal cleaning on these parameters has been shown, but the dollar amount varies with many assumptions and is difficult to pin down. The message to a utility, however, has not been lost and the trend toward cleaner steam coal is accelerating. This may lead to fewer installations that only wash the coarse coal, and add back the unwashed fine coal until a maximum contractual ash limit is reached. And, as the proportion of coal fines continues to increase by continuous and longwall mining, it may become impossible to clean the coal sufficiently without cleaning the fines. Flotation and oil agglomeration are the only processes that presently deal directly with cleaning the very finest coal fractions. Flotation has proven its effectiveness in cleaning blackwater and in separating fine coal from mineral matter. It has the achievable potential for far greater pyrite rejection than is now obtained in commercial preparation plants. While flotation will continue to be the predominant method for fine coal cleaning, there are conditions and opportunities where oil agglomeration can be a

Jan 8, 1980

Minter&apos;s excellent recent paper (1990) on the great paleoplacer gold deposits of the Witwatersrand and its subsequent discussion (Cheney, 1991) and reply (Minter, 1991) provide an informative, interesting and up-to-date review of the geology of these unique ores and some long enigmatic questions regarding their origin. Clearly summarized by Minter (1990) are the compelling sedimentologic and stratigraphic relationships indicating that the Central Rand Group conglomerates are ancient placers and documenting the fluvio-deltaic conditions of their transport and deposition. As Minter (1991) indicates, Cheney&apos;s discussion broadens Minter&apos;s 1990 coverage of the subject by considering higher and lower stratigraphic units and by adding detailed comments concerning recently published information about metamorphic and age relationships. Cheney&apos;s discussion and Minter&apos;s reply also readdress the old controversy of epigenetic hydrothermal vs. syndepositional placer origin for these deposits. This controversy has been resurrected by: • recent recognition of hydrothermally-altered granites (HAGS) in the older Archean basement rocks that lie unconformably beneath the Dominion Group rocks north and west of the Witwatersrand depository; • recognition of greenschist metamorphic assemblages in the Witwatersrand strata; and • the presence of interpreted epigenetic mineral assemblages and textures in some of the deposits. These relationships are briefly discussed by Cheney who suggests they may result from later, superimposed metamorphism and deformation and do not prove that the gold was introduced by epigenetic/metamorphogenic processes. In his paper, Minter (1990) cited the 1986 abstract of a subsequently published paper by Hutchinson and Viljoen (1988) who also considered many of these aspects and attempted to integrate them all in a broad genetic hypothesis. In addition, they emphasized the additional important problem of determining the source for the Witwatersrand gold. Although this issue was partially addressed by Reimer (1984), Mossman and Dyer (1985) and Reimer and Mossman (1990), the question has been generally under emphasized in earlier work and was, therefore, not stressed by Minter and Cheney. Reimer (1985) also emphasized the importance of weathering of the basin&apos;s Archean hinterland and its affects on Witwatersrand sedimentation.

Jan 1, 1992

By R. Bhaskar

The results of an experimental and theoretical research study into the spatial and temporal behavior of dust in mine airways is summarized in the paper. Experiments were performed in mine airways under both controlled and normal operating conditions. The controlled experiments included the documentation of the concentration and deposition patterns for two types of dust under three different velocities. Real-time dust concentration data were obtained using Real-time Aerosol Monitors (RAM-I) to determine the dispersion coefficient in a mine airway. On the theoretical front, a convection-diffusion model of the dust flow phenomenon in mine airways was developed considering dominant mechanisms affecting dust transport and deposition in mine airways. Mechanisms modeled include turbulent and gravitational deposition, coagulation, and dispersion.

Jan 1, 1988

By R. J. Sweigard

Differential settlement on reclaimed land presents a particular problem when the land is to be used for row crops. The poorly drained depressions caused by differential settlement restrict crop yield resulting in additional costs to alleviate the problem. Potentially more serious is the threat of failing to meet target yields due to settlement: related reductions. Because the mechanism by which the problem occurs is not well understood, a physical model study was conducted to investigate the importance of several factors. Although the importance of such factors as the relative amounts of rock and unconsolidated overburden in the undisturbed condition and the size distribution of rock fragments were considered, the analysis concentrated on the causes of settlement in the reconstructed soil layer above the rock spoil.

Jan 1, 1989

By P. B. Marchant

Bioleach testing and piloting was conducted on refractory gold sulphide concentrate from Austin Gold Venture in Nevada during 1988. The objective of the test programme was to determine the technical and commercial viability of bioleaching as a concentrate pretreatment step prior to gold extraction by cyanidation as an alternative to shipping concentrate to the smelter. Baseline CIL cyanidation typically resulted in < 20% gold extraction from the Austin concentrate. Bioleaching enhanced gold extraction up to 95% using conventional CIL techniques. This paper summarizes the bioleach test programme and results, including pilot plant studies onsite, and describes aspects of the commercial design for a possible retrofit of the Austin flotation tailings leach circuit to accommodate 20 tpd and 40 tpd capacity concentrate bioleach facilities.

Jan 1, 1989

By William M. Schafer

Mining projects which contain sulfide mineralization face increasing regulatory hurdles due to environmental concerns over acid rock drainage (ARD) and the ability of long-term reclamation to protect water quality. Among regulatory agencies, much of the perception about sulfide projects has been based on conditions at historic mining sites at which little or no effort was made to control ARD. With proper design measures, ARD production can be greatly reduced or eliminated. The science of ARD prediction and control must be expanded to enable mine planners to anticipate the effect of various facility design options on ARD potential. Some common-sense examples of geochemical prediction techniques and mitigation measures for waste rock dumps, spent ore heaps, and mine pits are described.

Jan 1, 1992

By Robert Stauffer, John Frostiak, Rein Raudsepp

Placer Dome's Campbell Red Lake Mine in Balmertown, Ontario produces a refractory gold flotation concentrate containing the sulphide minerals arsenopyrite, pyrite and pyrrhotite. In 1991, the existing concentrate roasters will be replaced with a pressure oxidation plant based on Sherritt Gordon technology to update the facilities and to satisfy environmental requirements. A successful continuous pressure oxidation miniplant program was conducted by Sherrill Gordon in late 1989 which formed the basis for the design of the commercial plant. The paper summarizes the Campbell operation and the environmental aspects of the project, and discusses the results of the miniplant program and the design of the commercial plant. The capital cost of the pressure oxidation plant and the process operating costs are also presented.

Jan 1, 1990

By K. G. Tan

Widely available silver and arsenic bearing concentrates can be smelted to produce a discardable slag, a base metal speiss, and a crude silver button which is easily separated from the other phases after solidification. This paper discusses the development of a novel process as an alternative to existing nitric acid leach methods for the production of high purity silver from the raw silver button. Direct electro-refining of the raw silver anode in a sulphate medium is integrated with downstream purification and recycling modules that are customized to allow efficient recovery of silver and saleable by­products. The test results, flowsheet alternatives and process details are presented and discussed in terms of overall technical feasibility, economical viability and environmental compliance considerations.

Jan 1, 1999