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By Richard S. Ghent, Daniel G. Warnock

JOHN HAMRIC: Our next speakers are Richard Ghent, manager of environmental health and safety for CF Industries, Hardee Phosphate Complex, in Wauchula, Florida. Richard has 20 years' experience with environmental health and safety affairs. He has a bachelor of science degree from the University of South Carolina. With him is Daniel Warnock, who is supervisor of safety and training also at the Hardee Phosphate Complex. Daniel's experience is in safety programs and electrical training. Their presentation is "Regulations Versus Management Practice." RICHARD GHENT: Written procedures give structure to safety programs. At their best, they are brief and understandable to facility personnel and clearly identify roles and responsibilities. At worst, they attempt to recite the entire regulation they are intended to address. Some regulations, such as OHSA's Hazard Communication Standard, require employers to develop, implement, and maintain a written program. As written programs and procedures are developed, some basic questions arise: Is the program designed to achieve compliance with regulatory requirements or does management expect the program to go beyond compliance to some higher level of performance? Management may have difficulty in measuring and communicating performance expectations in safety. A facility with 4 million safe work hours does not suddenly become unsafe the day their safety record is broken. Generally, management expects safety programs to meet regulatory requirements and to protect the employer from enforcement actions and fines from regulatory agencies. Management also expects that safety programs will result in a safer work environment with fewer incidents, accidents, and near misses. But it is difficult to know when a safety program has succeeded. If the program is expected to go beyond compliance, what other standards should be included (e.g., ANSI standards, company management practices, lessons learned from inspections and audits, recommendations from safety committees, etc.) in the

Jan 1, 1998

By Douglas W. Fuerstenau

This paper concern the specific adsorption of sulfate anions on nonmetallic minerals and its role in flotation. The specific surface affinity of sulfate ions in various systems has been observed in the results of electrokinetic measurements that show conditions under which sodium sulfate can reverse the sign of the zeta potential. The electrical double layer model provides a means for interpreting the results and for estimating the free energy of adsorption of sulfate ions. Because of their surface activity, sulfate ions not only can function as a depressant in the flotation of oxide minerals with physisorbed anionic collectors but also can function as an activator for flotation with physisorbed cationic collectors. Their role in depressing or enhancing the flotation of the sparingly-soluble mineral barite is also explained in terms of the double layer model.

Jan 1, 2005

By J. E. Hoffman, Corby G. Anderson, T. J. Keefe, O&apos, Suzzann M. Nordwick

Antimony removal has become necessary as it is commonly found in precious metal refractory ore bodies. The Sunshine Mine in Kellogg, Idaho has recovered metallic electrowon antimony from its argentiferous tetrahedrite (Cu2S'Sb2S3) deposits for over fifty years. Recently, Sunshine conducted an intense research effort to improve and modernize its antimony facility. This paper presents information which was learned about the antimony electrowinning processes and the development of a single¬-electrolyte antimony electrowinning technology. The relevant effects of process variables were investigated. The research results and the relevant chemistries involved in metallic antimony electrowinning will be discussed.

Jan 1, 1993

By H. Burger

For mine planning in the hardcoal industry the reliable prediciton of the properties of a deposit-both ahead of the zone to be worked as well as of zones at depths not yet developed - may help improve the production results of workings. With the wide spacing of exploration drillings usual in the coal industry, it is hardly possible to establish adequately reliable plans just by simple kriging methods. During the exploration phase a decision has to be made whether the zone ahead of a face area is economically profitable and, in addition, accessible and safe in order to be included in the production planning. It is, first of all, important to gather global information on certain parts of the planning area it the form of local estimates. Moreover, cut-off problems play a critical role, e.g. if there are set cut-off thicknesses as a criterion for minability or if safety aspects have to be considered. Conditional simulation appears to be a useful geostatistic method in order to localize or predict areas of potential rock burst hazard - based on geological criteria in conjunction with the guidelines by mining authorities - in the zones ahead of a working. It is a means of providing an objective basis for the evaluation and planning of mining activities.

Jan 1, 1986

By Al. Valero

This paper quantifies in universal units (energy units), the annual decrease in the mineral endowment of the planet. This is done for some important extracted non-fuel minerals, namely aluminium, cobalt, chromium, copper, gold, lead, uranium and zinc and is compared with the depletion figures of conventional fossil fuels. The results of this study reveal that each year, the decrease of the global non-fuel mineral bonus provided by Nature is 2 to 3 orders of magnitude greater than the loss associated to the burning of fossil fuels. Particularly for 2008, the depletion in mineral wealth of the studied commodities was about 20 times greater than that of fossil fuels. The assessment methodology is based on the Second Law of Thermodynamics. It quantifies the useful energy (exergy) required to concentrate a mineral from a completely dispersed state in the crust, to the conditions of composition and concentration found in the mines. Exergy can be a useful measure for quantifying the mineral depletion caused by man, as it takes into account the main physical features that make minerals valuable: composition and concentration. This analysis enhances and puts numbers to the importance and necessity of material reuse and recycling.

Jan 1, 2011

By Adrian Smith, Debra W. Struhsacker

13.1 INTRODUCTION Cyanide is, a generic term indicating the presence of the cyanide ion (CN-). Cyanide is a very common, naturally occurring compound produced by many biochemical reactions. Many plant species synthesize organic compounds which contain cyanide in the form of cyanogenic glycosides (Knowles, 1976). For example, trace amounts of cyanide are present in the seeds and leaves of many members of the Rosaceae (rose) family (Kingsbury, 1964). Many common items such as lettuce, maize, sweet potatoes, kidney beans, (Oke, 1969) almonds, and cigarette smoke contain cyanide. As examples, a recent chemical analysis of chocolate-covered almonds measured a total cyanide content of about two ppm (Steffen Robertson and Kirsten, 1987); and the U.S. Surgeon General (U.S. Department of Health, 1964) has shown that cigarette smoke contains up to 1,600 ppm total cyanide. The chemistry of cyanide solutions is complicated because the cyanide ion forms compounds and complexes with many elements. Some cyanide species are highly toxic whereas others are relatively inert and harmless. Molecular hydrogen cyanide (HCN) is the most toxic form of cyanide. Under most conditions, HCN exists as a gas which readily dissipates or reacts with the environment to form less toxic or nontoxic forms of cyanide. Thus HCN is an ephemeral toxin, and many naturally occurring geochemical processes reduce the HCN concentration of a heap system with time. As discussed below, free cyanide includes the two species, ionic cyanide (CN-) and molecular hydrogen cyanide. Free-cyanide toxicity in man, mammal s, and aquatic species is we1 1 documented (Doudoroff, 1976; Ecological Analysts, 1979; Towill et al., 1978). The lethal doses reported for human adults vary with the type of exposure as follows: • One to three mg/kg body weight if ingested; • One hundred to 300 ppm if inhaled; and • One hundred mg/kg of body weight if absorbed. Acute toxicity of free cyanide to freshwater invertebrates ranges from 0.028 to 2.295 mg/l, depending on species and test conditions. Generally, free-cyanide concentrations greater than 0.1 mg/l are expected to kill sensitive species in freshwater or marine environments (Doudoroff, 1976;

Jan 1, 1988

By K. S. E. Forssberg, M. I. Hallin

In many cases, the reuse of process water in flotation plants is desirable both for plant operating reasons and for environmental protection. The main advantages are better housekeeping of fresh water and process chemicals together with the reduction of polluting species to the environment. There are however a number of problems involved in the use of recycled process water. The main problem is that recycling sometimes has a deterious effect on the process and can occur months after the start of water recycling. The Division of Mineral Processing of Luleå University of Technology has been conducting experiments on recycling of process water at various sulphide plants in Sweden for over ten years. The experiments have been carried out in pilot- and full industial scale, in collaboration with the mining companies operating the plants. Until 1988 investigations were carried out in four different sulphide plants. The objectives of the experiments were: first to document differences in the composition of the process water during recycling; secondly to investigate any changes in the pulp chemistry of the flotation circuits wich may be due to the influence of recycled water; and lastly to establish critical levels, if any. of the parameters measured. While conducting experiments of this kind several things have to be kept in mind. Normally, recycling is done by using tailings pond water as process water. This means that time effects are important, because of the time lag between water input in the tailings pond and the reclaim of that water back to the plant. As will be shown, the

Jan 1, 1989

By Mark D. Cocker

Georgia?s Coastal Plain contains important sediment-hosted deposits of kaolin, bauxite, heavy minerals, sand and gravel, silica sand, carbonate rocks, and fuller's earth. Genesis, location, size, and quality of these deposits are related to terrestrial, marginal-marine, and shallow-marine depositional environments that evolved during development of the southeastern North American continental margin. From the Cretaceous to Eocene, kaolin and aluminous sediments, which contained mica and feldspar, were deposited in marshes, ponds, and bays located in deltas or behind barrier islands or spits. In the Cretaceous sediments, subsequent, intensive, in situ chemical weathering converted mica and feldspar to kaolin. Kaolin eroded from deeply weathered granitic rocks in the Georgia Piedmont was deposited in Paleocene to Eocene sediments. Subaerial exposure during the Paleocene and Eocene desilicated kaolin sediments to form bauxite. Sand and gravel, silica sand, and heavy-mineral deposits are found in Cretaceous to Eocene fluvial and shoreline sediments, some of which are associated with the kaolin and bauxite deposits. Source areas, intensive chemical weathering in the source areas, transportation by the major river systems, and deposition of these clastic sediments in similar or nearby depositional environments are common elements in the genesis of these resources. Eocene fuller's-earth deposits are opaline claystones in near-shore to shelf-marine sediments, which overlie the kaolin-bearing strata. These claystones consist of montmorillonite and opal/ cristobalite derived from alteration of diatom frustules. Favorable ocean currents provided nutrients for extensive planktonic growth. Oligocene and Miocene carbonate rocks were deposited principally in shallow-marine embayments. Miocene fuller's- earth deposits in south-central Georgia and adjacent parts of Florida contain palygorskite that formed through alteration of montmorillonite/bentonite clays. Deposition and subsequent alteration occurred in shallow, brackish-water lagoons under relatively high temperature and subtropical conditions. Middle and late Miocene phosphorites were deposited on a shallow carbonate-shelf platform and were concentrated proximal to anticlinal highs. Numerous marine transgressions and regressions since the beginning of the Pleistocene resulted in shoreline detrital deposits containing aggregate sand, silica sand, and heavy minerals on the Coastal Plain and on the Continental Shelf. Major river systems transported sand and heavy minerals from source areas in the Piedmont and Upper Coastal Plain. Deltaic deposits of heavy minerals were redistributed and concentrated by longshore currents, shoreline processes, and aeolian processes. River-terrace sediments, correlative with the Pleistocene shoreline deposits, contain sand-and-gravel and silica-sand deposits. Aeolian dune sands are associated with both Pleistocene fluvial and shoreline detrital deposits.

Jan 1, 1999

By B. J. Scheiner

The Bureau of Mines, U.S. Department of the Interior, has investigated the use of rheology to provide insight into the mechanism of flocculation. A technique developed by Tattersall has been modified and used to explain the flocculation of calcium montmorillonite with polyethylene oxide. The results indicated that there are two types of bond systems operating during the flocculation sequence. Also, flocculation results are highly dependent on the shear rate and the amount of polymer added.

Jan 1, 1989

By Husheng Li, Zhongli Wu

This paper discusses the fundamental strategies adopted in the simulation package FIRES developed for ventilation simulation under mine fires. These fundamental strategies include (1) fire characteristic curves specifying the development of a mine fire with time, (2) simulation of fume spread in a ventilation system, (3) determination of the aerodynamic effects of mine fires on flows; and (4) dynamic simulation of flow state under mine fires. The major functions of the simulation package are also addressed. The package has been used to simulate an experiment of mine fire. A comparison is made between the simulation results and the measured data.

Jan 1, 1993

By H. J. Zhang, W. Wui

With the adoption of market-oriented economic policies, Chinese non-ferrous metals industry has gained remarkable progress. The continuously increasing domestic demand for non-ferrous metals, however, calls for more import of raw materials in short supply, such as copper concentrate and bauxite. As an alternative for balancing the shortage and assurance of more stable mineral supply, direct investment in oversea mining project has come to the agenda. This paper discusses the computer-assisted method used for evaluation and comparison of potential mining projects.

Jan 1, 1996

By Mayank Srivastava, Satya Harpalani

Production of methane is an inevitable consequence of mining coal. Although the number of mines practicing recovery of methane prior to, or during, coal mining is increasing, ventilation air methane (VAM) is still a significant source of methane addition in to atmosphere. Recent studies have shown that there are ways to recover the VAM energy, while simultaneously reducing the methane emission in to atmosphere. This paper discusses a case study, currently underway, to develop a technique to quantify the VAM emission from a mine. It also presents the different VAM utilization techniques and the suitability of one for the mine being studied. Finally, the paper summarizes the research issues that require further investigation.

Jan 1, 2005

By Nolan B. Aughenbaugh

Zoning and environmental restrictions on land usage now make open- pit quarrying more and more difficult, especially near urban areas. One option for quarry operators is to go underground for mineral production. While underground-mining costs are higher than those for open-cut work, there are several compensating advantages. In many cases it is possible to produce the same material underground without affecting land values, and the surface is preserved for industrial, residential, or agricultural purposes. Proper planning can yield underground sites which have great potential value for industrial plants, warehouses, or other business uses. It is essential to plan underground mineral extraction using a three-dimensional modular-room architectural concept to fully exploit secondary space utilization. Prior to the start of underground mining an operator must make a careful geological engineering study to deter- mine the suitability of the deposit and must prepare a plan for safe and economical mining for the purpose of converting to secondary usage.

Jan 1, 1974

By P. Bevilacqua, G. Vallebuona

Empirical models are now used for predicting the performance of hydrocyclones in terms of capacity. cut size (d50.c), water split and partition curve. These models (such as the model by Lynch and Rao and the model he Plitt) were developed and checked for hydrocylones with diameters larger than 4 in. However, for smaller-diameter hydrocyclones, little empirical modeling has been done. This paper reports on an extended experimental research program on small hydrocyclones. For these cyclones, the suitability of existing empirical models was investigated and their accuracy was compared. To improve the predictive capability of these models to small cyclones modifications to the equations are proposed.

Jan 1, 1996

By David R. Shaddrick

Ore reserves are based on sampling developed by drilling programs. Correct choices concerning the type of drill to be used, depth of drilling, hole orientation and sample spacing are not only critical to the accuracy of the ore reserve but to the cost in time and money of the project. Appropriate interpretation and use of geologic information can significantly enhance the ability to make these decisions effectively. Geologic characteristics of mineralized rock that affect drilling and sample quality include: rock quality, openness, water content, mode of gold occurrence, internal gold distribution and grain of mineralization. Each of these characteristics and sources of data about them are revuewed, then related to the various drill program options. Finally, some procedures for checking the validity and appropriateness of the selected options are reviewed.

Jan 1, 1987

By E. D. Goddard, D. S. Murphy

Acid resistance, zeta potential and ESCA (electron spectroscopy. for chemical analysis) experiments were performed on emperador marble and four calcium carbonate samples (onyx calcite, travertine calcite, Iceland spar calcite and aragonite). Six fluorine-containing reagents were used to treat the surfaces of these materials: magnesium hexafluorosilicate, zinc hexafluorosilicate, sodium fluoride, zinc fluoride, strontium fluoride and stannous fluoride. The acid resistance of treated samples proved to be much higher than that of their untreated equivalents. The isoelectric point of treated samples approaches the isoelectric point of fluorite. Also, the fluorine content, as measured by ESCA, of a marble surface treated with magnesium hexafluorosilicate is much higher than that of an untreated sample. The binding energy off of fluorine and calcium the treated marble is consistent with the formation of calcium fluoride.

Jan 1, 1994

By H. Cho, P. T. Luckie

A study was undertaken to investigate the liberation behavior of coal macerals through size reduction and density separation. It was seen that the liberation of coal macerals could be achieved by size reduction, allowing selective separation of coal organic components. However, the degree of liberation was dependent upon the comminution history. Even for the same fineness, the extent of liberation might not be the same depending on how the material was generated. The liberation of coal macerals was analyzed by examining the liberation index. It was seen that, although comminution produced fine particles enriched in inertinite (primarily fusinite and semifusinite), these particles were less liberated than coarser particles. However, the liberation of macerals increased when all the feed was ground to a finer size.

Jan 1, 1999

By K. A. Natarajan

This paper deals with the various electro- and biochemical mechanisms involved in the bioleaching of multisulfide minerals such as those containing copper-lead-zinc and copper-nickel-iron. Galvanic series for sulfide minerals consisting of pyrite, chalcopyrite, galena, sphalerite, pentlundite, and pyrrhotite in an acid bacterial leaching system is illustrated, and the role of relative electrochemical activity on selective dissolution is discussed. Typical leaching results are shown to illustrate the practical applicability of galvanic effects in bioleaching of multisulfides. Attachment of Thiobacillus fewooxidans onto chalcopyrite and sphalerite mineral substrates is illustrated through scanning electron micrographs. The role of high-metal-tolerant, specially adapted strains in the leaching of multimetal concentrates is also outlined.

Jan 1, 1987

By Alva L. Kuestemeyer, Randall J. Scott

INTRODUCTION Pincock, Allen & Bolt, Inc. (PAH) has developed a series of cost models for Western U.S. Gold Mines. The models indicate the economic potential of developing gold properties at various production rates and ore grades. Various combinations of mining and processing methods are also analyzed. The conclusions shown in this paper are taken from PAH's 600 page study titled, "Capital and Operating Cost Models for Western U.S. Gold Mines." PAH decided to develop the cost manual as a result of our perception of the industry's need for such a document. It was our impression that exploration development decisions were being made on the basis of limited economic information. PAH has compiled a substantial database on unit cost information. That database and the engineering capabilities of the firm allowed us to develop a reasonably detailed analysis of capital and operating costs and overall development economics. The study has developed a series of algorithms for underground and open pit mining, processing, G&A, and infrastructure costs. The capital and operating cost data served as a basis for performing after tax discounted cash flow analysis for the various development alternatives. For the base case scenarios, a 15% DCFROR was assumed and the required ore grade was back calculated using the computer. The ore grade versus production rate graphs summarize the economics of developing gold projects in the Western U.S.

Jan 1, 1987

By R. E. Wardwell, J. D. Nelson

The design of cover systems for reclamation schemes in tailings requires estimation or determination of tailings materials properties such as compressibility, shear strength, and consolidation characteristics. It is very difficult and expensive to obtain truly undisturbed tailings samples for laboratory testing. In situ testing methods have been developed for economically obtaining large amounts of information. Two of these methods are described, the piezocone and the flat plate dilatometer. Both of these methods provide a rapid means of detailed material identification in a nearly continuous fashion for the entire depth investigated. The equipment is described and typical data from a uranium tailings impoundment is presented. The results are compared and the advantages and disadvantages of these methods are discussed.

Jan 1, 1987