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By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008

By H. Skretting, J. Gundeesen

The paper compares operational parameters for the electric reduction smelting of pig iron and ferroalloys in pilot and industrial furnaces. Data from two pilot furnaces of approximately 200 and 500 kW operating-load capacity, as well as from several production furnaces, are included. Examples are given for the smelting of pig iron, ferronickel, ferromanganese, ferrochromium, and ferrosilicon. In most instances, the results from the pilot furnaces, such as the values for consumption and product analyses, corresponded fairly well with comparable data from the industrial furnaces. For ferrosilicon, the power consumption in the pilot furnace was higher than that in the industrial furnace.

Jan 1, 1979

By L. Woollacott, R. P. King

Although several models for the carbon-in-pulp (CIP) or carbon-in-leach (CIL) processes have been published, most of these models do not consider in detail the way in which the carbon phase flows on large-scale plants. This paper illustrates the importance of these details if the CIP or CIL process is to be modeled correctly. An appropriate model, based on population-balance techniques, is then derived. Suitable mathematical techniques for the solution of the model equations are also described. Finally, a method for estimating the model parameters for a full-scale plant is described.

Jan 1, 1990

By F. F. Roxborough, P. King, E. J. Pedroncelli

This paper describes tests on the performance of a continuous miner in cutting South African coal. Although coal cutting has been investigated extensively overseas, the results have not led to significant changes in machine design because these machines find little difficulty in cutting the softer overseas coals at a fast rate. In general, the results of the tests show that cutting efficiency improves markedly as the depth of cut per revolution of the drum increases, and that the best spacing of picks on the drum is twice the depth of cut. Pick shape is of secon¬dary importance in terms of cutting efficiency, only small differences having been found between the performances of conical- and chisel-shaped tools.

Jan 1, 1981

By N. Boegman

The meteorological conditions in South Africa are not conducive to the effective dispersion of air pollutants. In the light of this, and because of the magnitude, concentration, and future growth potential of the metallurgical industry, control of air pollution is essential. Methods of abatement are discussed for each branch of the metallurgical Industry, as well as for open-cast mining and bulk ore storage. Some recommendations are made regarding potentially rewarding research and development.

Jan 1, 1978

By R. Rubin, P. A. Laxen, G. S. M. Becker

An account is given of developments in the use of activated carbon for the recovery of gold from cyanide solutions. The carbon-In-pulp process employed at the Homestake Mine is described, and its various applications in South Africa and their effectiveness are discussed. Probable future work on the carbon-in-pulp process and other possible applications of carbon for the recovery of gold are outlined.

Jan 1, 1979

By M. C. van Blerck

This paper outlines the tax provisions that became defective in January 1992, which allow a working mine to make tax-deductible contributions to a dedicated environmental body that is itself not subject to tax. Such a body will then provide a source of funding for the mine's future environmental expenditures. It is concluded that the establishment of such environmental bodies is a financially sound, tax-effective route, allowing mines, prospectors, and quarry operators to provide for future environmental rehabilitation.

Jan 1, 1994

'We are going to be short of engineers for the foreseeable future, and particularly short of civil and heavy-current electrical engineers'. This is the basic message that emerges from the report 'The supply of and demand for engineers, 1984,t, prepared by Dr Philip Lloyd and Professor Bob Plewman for the Federation of Societies of Professional Engineers (FSPE).

Jan 1, 1985

By H. Sasao, Y. Obara, A. Hirata

In the upper part of the planned location of the portal of a highway tunnel, there was a steep rock cliff with several unstable rock blocks. It seemed that the risk of those rock blocks to fall was very high. The cut-out to stabilize the rock cliff was monitored with various measuring instruments to prevent the sudden fall of the rock blocks. This paper discusses the measurement of acoustic emission and interpretation of its result during excavation of the rock cliff. We calculated displacements by integrating the accelerogram twice in terms of time, and demonstrated that slight displacements can be calculated from the measured AEs. Dans la partie supérieure de l’emplacement prévu pour le portail d’un tunnel autoroutier, il y avait un escarpement rocheux raide avec plusieurs blocs rocheux instables. Le risque de chute de ces blocs semblait très élevé. Lors de la coupe pour stabiliser l’escarpement rocheux, le suivi a été effectué avec différents instruments de mesure pour éviter la chute brutale des blocs rocheux. Cette thèse présente les mesures d’émission acoustique (EA) et l’interprétation de leurs résultats pendant l’excavation de l’escarpement rocheux. Nous avons calculé des déplacements en intégrant l’accélérogramme deux fois par rapport au temps, et montré que de petits déplacements sont calculables à partir des EA mesurées. Im oberen Teil des geplanten Ortes des Stollenmundes eines Autobahntunnels gab es einen steilen Felsen mit mehreren instabilen Felsenblöcken. Die Gefahr schien sehr groß zu sein, dass diese Felsenblöcke einstürzen können. Beim Abbau um die Stabilisierung des Felsens wurde das Monitoring mit verschiedenen Messinstrumenten zusammengestellt, um den plötzlichen Verfall der Felsenblöcke zu verhindern. Das vorliegende Papier diskutiert die Akustische Emission und die Auslegung deren Ergebnisse während des Abbaus des Felsens. Wir berechneten die Verschiebungen durch zweimalige Integrierung der Accelerogrammen in Bezug auf die Zeit. Die dargestellten kleinen Verschiebungen können aus den gemessten akustischen Emissionen berechnet werden.

Jan 1, 2003

By W. Bleloch

In the process described, hydrogen is used to generate high-temperature steam and oxygen in the molten bath. Steel is decarburized to low levels to produce a pearlite-free steel suitable for deep drawing. The process makes use of the favourable thermodynamics in the reactions between steam, carbon, and iron, as well as providing high-temperature oxygen for the decarburizing reaction. The process can easily be incorporated in existing BOF (basic oxygen furnace) plant but can also be contemplated as a greenfield process.

Jan 1, 1987

By A. B. Cook

The South African socio-economic history started with pastoral and agrarian communities which had low levels of industrialization and small needs for energy. The discovery of diamonds (in the Northern Cape in 1867) and of gold (in the Transvaal in 1886) heralded economic and industrial development, with a concomitant demand for energy. The energy needs of the fledgling mines, and mining towns, were met by the combustion of wood, cut locally, or by coal, hauled laboriously from the primitive collieries, and sold to the mining companies and townships at high prices.

Jan 1, 1994

The First International Symposium on Seismicity in Mines, organized by the South African National Group on Rock Mechanics in collaboration with the South African Institute of Mining and Metallurgy, was held in Randburg (near Johannesburg) from 13th to 17th September, 1982. It was the first attempt to provide an international forum for the consideration of seismic problems specifically affecting mines or associated with mining. Numerical mathematics The South African Society for Numerical Mathematics and the Computer Science Department of the University of Natal are organizing the Ninth Symposium on Numerical Mathematics to be held in Durban from 18th to 20th July, 1983.

Jan 1, 1983

By P. J. D. Lloyd

The Federation of Societies of Professional Engineers (FSPE) recently conducted a survey of professional engineering manpower in South Africa. This article presents the data relevant to mining and metallurgical engineering. FSPE in their survey attempted to determine the supply of engineers in South Africa both from local universities and by immigration. The immigrants gave some problems in that it is difficult to know whether a man who claims to be professionally qualified really is. However, it was estimated that the ratio of immigrants who claimed to be qualified to those who really are the equivalent of our local graduates was between 1,0 and 1,9 for mining engineers, and between 2,0 and 4,1 for metallurgical engineers.

Jan 1, 1980

By H. Von Michaelis

The world is rapidly becoming more ?green? i.e. energy conscious. Since mining and mineral processing are massive energy users, the mining industry is seeking ways to reduce its energy footprint. In mining and mineral processing operations, energy is often the most expensive cost item. Comminution, i.e. grinding, is frequently the most energy-intensive step between mine and metal. High pressure grinding rolls (HPGR) are being installed in a rapidly growing number of ?hard rock? mineral processing operations. In the energy conscious cement industry, HPGR grinding has been standard practice for decades. HPGR is known to be energy-efficient; the question is how energy efficient? How can the energy efficiency of HPGR be enhanced? This paper reviews recent HPGR applications for the processing particularly of copper, gold, platinum, PGM-Ni-Cu and iron ores. HPGR technology is discussed with respect to energy efficiency. The harder the ore the greater the energy savings are likely to be. Typical energy savings of 10?20% can be expected when installing HPGR vs. a SAG mill. Wipf(2005) showed why conventional Bond Work index tests on HPGR product is likely to under-estimate the energy savings that can be achieved by installing HPGR. Energy efficiency of HPGR is, however, ore-specific. The biggest energy savings of HPGR tested thus far is 9.5 kWh/tonne claimed for Vista Gold?s Mt. Todd gold ore from Western Australia, a savings of over one-third of conventional SABC comminution energy. Several commercial scale iron-ore pellet feed plants install HPGR for fine-grinding of concentrate to increase the surface area of pellet feed in a manner that reduces overall energy consumption. Energy-consumption in comminution is, however, only part of the energy savings benefit story. HPGR typically also reduces the amount of steel lost through wear of mill liners and media. Marsden(2008) showed that when the energy that would have been consumed to produce the steel that is saved by applying HPGR is factored in, then the overall energy savings of HPGR is considerably greater. Johnson et al.(1988, 2005) tested HPGR in a flowsheet in which energy savings of around 50% can be expected if HPGR product screen oversize is recirculated to the HPGR. Innovative flowsheets have been proposed by Rule et al.(2008) and by Morley (2008) which are expected to result in significantly increased energy savings. HPGR applied in flowsheets in conjunction with coarse ore separation devices, e.g. ore sorting or DMS to remove barren waste from HPGR feed promises significantly greater energy efficiencies. Fine-grinding and ultra-fine grinding of ore or concentrates in conventional ball mills results in energy consumptions that increase exponentially with product fineness. Wipf (2009) presented a flowsheet in which he proposed the installation of HPGR ahead of the Aerosion ?Disintegrator? for ultra-fine grinding of ores and/or concentrates. This dry grinding arrangement is expected to achieve ap80 = 7 µm using up to 100 kWh/t less energy than could be achieved by wet ball milling. Using conventional comminution, an ore might require grinding to p80 = 45µm (? 325 mesh), for example, to liberate the valuable components, e.g. magnetite, from gangue, e.g. silica. Inter-particle comminution in HPGR may break some ores along grain boundaries thereby liberating valuable minerals from gangue at a much coarser particle sizes. Early magnetic separation rejection of silica gangue liberated from magnetite by HPGR at coarser grain sizes could further reduce downstream comminution energy consumption.

Jan 1, 2009

By Northrop. I. N.

Hardmetals possess extremely high hardness and wear resistance, which render them ideal for applications such as metal-cutting tools, rock-drilling tools, and industrial wear-resistant parts like dies, punches, and seals. However, hardmetals are britle, and show poor resistance to impact and shock. They can therefore rarely be used unsupported, and it is common practice to attach hard metal working parts to a more resilient tool holder or support, which is normally made of steel. . . . Owing to the widely differing physical and mechanical properties of steels and hard metals, the Joining of one to the other is problematic, and the method used must be chosen with care. This paper reviews several methods available for the joining of hardmetal to steel, and discusses the advantages and disadvantages of each.

Jan 1, 1987

By P. Stevenson

Correlations for the critical velocity needed to hydraulically convey particles in horizontal, or near-horizontal, pipes are either explicitly dependent upon the shear stress imparted by the fluid upon the surface of the particle bed, or require a velocity and hydraulic diameter. Often such approaches are modified to account for pipe inclination by the introduction of simple factors. However, we assert that the physics that underpins the hydraulic conveying of particles in steep pipes (such as a directionally drilled oil well) is dissimilar to that which governs particle behaviour in horizontal pipes. In steeply inclined systems, a sliding sediment induces an upward counter flow and hence an autogenous contribution to the shear rate. The physics underpinning particle hydraulic conveying in steep systems is explored using the separation results of Laskovski et al.10

Jan 1, 2007

By D. D. Howat, J. van der Colf

Selected members of the slag system were reduced in graphite crucibles in an argon atmosphere, and the physicochemical properties of the reduced derivatives of the slags were determined in inert crucibles. It was found that slags having magnesium aluminium titanate as the primary phase before reduction underwent an increase in liquidus temperature, accompanied by a change in the primary phase. No analogous behaviour could be detected for the slags having perovskite as the initial primary crystallization product. In most instances, the viscosity of the melt passed through an initial minimum, followed by an increase as the reduction time was extended. Increased MgO/CaO ratio. basicity, titania content, and reduction temperature all served to accelerate thickening. During reduction, the electrical conductivity of the slags tended to rise relative to the value for the unreduced melt.

Jan 1, 1979

Contribution by J.S. Kuijpers* Kirsten's paper discusses the potential for seismic activity on faults in relation to depth, span, stope support, and discontinuity strength, and puts forward some explicit conclusions. Quoting from the author, the main conclusions are as follows, together with my comments. Author's reply The author gratefully acknowledges the contribution to his paper. It provides further elucidation to the very complex problem of quantifying the effects of mining-induced seismicity. The mechanical behaviour of rock under seismic excitation has been sadly neglected over the past twenty years, during which attention was almost exclusively focused on the study of the spatial location of seismic events. It is to be lamented that, on the eve of South Africa's movement to significantly greater depths of mining, so little quantities information is known about the mechanical effects of seismicity. It is a challenge at this stage to make up for this lapse in knowledge in the shortest possible time.

Jan 1, 1994

By H. E. Parkinson, Y. P. Chugh

About 90 percent of the coal mined underground in the U.S.A. today is mined by the room-and-pillar system. The productivity of the system dropped from about 14,1t per man-day in 1969 to about 7,3 t per man-day in 1978. Since 1974, the U.S. Department of Energy (formerly the U.S. Bureau of Mines) has been engaged in research to improve the production and productivity of the room-and-pillar system. The effort involves the development of integrated, automated, and remote-controlled equipment and systems including remote-controlled continuous miners, automated miner-bolters, automated extraction systems, continuous haulage systems for use behind miners, and remote-controlled equipment for miners, bolters, and shuttle cars. These systems are discussed briefly, the discussion being related primarily to coal winning, although the concepts could be utilized in room-and-pillar systems in mines other than coal mines.

Jan 1, 1981

By M. W. Grodner, J. Maaren, G. Guler, J. K. Schweitzer

The selection of the most suitable mechanized mining strategy has to consider the geotechnical environment in which it will be operating. A mechanized mining method or machine is designed to a given set of specifications to work within an environment. The geological conditions that define this environment are fixed—detailed information of these conditions for design specifications is thus critical. Two major classes of geotechnical parameters are defined—critical and design. The critical controlling factors are a result of mineral composition, size, shape, abundance, assemblage and associated texture, as well as discontinuity type and orientation. Design parameters are specific to each deposit, and their nature cannot be broadly described, as with the critical factors. It is shown that for major deposits in South Africa, namely the Witwatersrand Basin (gold), the Bushveld Igneous Complex (PGEs) and the Karoo Coalfields that by incorporating geological and geotechnical information that appropriate mechanized mining methods can be deduced, and that the performance and design parameters of specific technologies can be determined

Sep 1, 2001