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By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020

By R. Castro, R. Gómez, F. Betancourt, M. Moncada

In block cave mining, rock fragmentation is a key parameter that influences the production level design and mine planning. Fragmentation occurs mainly by natural breakage during the caving process and in the draw column. The breakage that occurs within the column is known as secondary fragmentation. Secondary fragmentation has been successfully described using the block caving comminution model, which replicates the fragmentation mechanics between particles under drawn and vertical loads in a draw column. This model is based on a kinetic and population balance approach, in which non-normalized and normalized assumptions can be used depending on material and comminution system behaviour. In this paper, the non-normalized and normalized approaches are applied and compared to laboratory data to determine which assumption should be used for secondary breakage in block caving. Approaches are compared graphically, with the mean square error and the Fisher test with a false-rejection probability of 0.05. Based on a statistical analysis, the results show that the normalized model can be applied to all the rock types tested.

Nov 1, 2021

By N. Naudé, J. de Villiers, C. P. Bergmann

It is proposed that the physical and chemical composition of individual mineral particles are an appropriate basis from which to model the performance of minerals processing equipment. Such a particle-based approach enables modelling across disciplines such as comminution, classification and flotation and automatically generates the traditional mass and chemistry balances. The general approach followed is to generate full grade-recovery curves for a separator by sampling product and tailings at varying mass yields. AutoSEM characterisation of each sample provides particle data that is used to reconcile mineral deportment and liberation to the measured size and assay data. In this way, partition surfaces can be generated and modelled. In this paper, an empirical model for the performance of a gravity spiral concentrator treating fine chromite ore is proposed. The model is based on the combination of two partition surfaces and is able to accommodate both forward and reverse gravity concentration effects per size fraction. The results show that this approach is well suited to represent spiral performance for the cases evaluated. The effect of two feed particle size distributions on the performance of the Multotec SC21 and SC25 spirals is demonstrated. Simulations are run in an Excel environment, linked to Python-enabled routines for enhanced data management and calculation speed. Keywords: Spiral concentrator, gravity separation, particle-based modelling

Jan 1, 2020

By H. J. Le Roux, W. B. Drummond

1. INTRODUCTION We have a moral responsibility towards the world to reduce the harmful deposits we emit into the environment arising from beneficiation technologies. Industry has not willingly spent money to limit these emissions because it affected their profit margin with the end result of emitting harmful elements into the environment. Governments have thus rightly stepped in and enforced systematic reduction of these emissions through legislation. In the past beneficiation of sulphur bearing ores was typically done through hydro-metallurgical concentration, smelting, followed by Sulphur removal by converting processes like the Pierce Smith converter. The latter two processes emitted substantial quantities of Sulphur into the atmosphere. Spiralling costs and legislation have resulted in the quest to develop more efficient and environmentally friendly processes to achieve the same end results. New hydro-metallurgical processes like the ActiVox process has completely eliminated the pyro-metallurgical processes. Kansanshi are also operating a similar process. It however elicits other ground water and spillage pollution hazards and problems of it?s own. Various improvements has also been made to the pyro-metallurgical stages, examples being combined smelting and converting with the Noranda reactor, the Codelco CMT furnace, one step flash smelting/converting or the Mitsubishi continuous smelting, converting and slag cleaning process. The new converting processes are also normally enhanced using oxygen leading to higher SO2 gas strength with only a marginal increase in off-gas volume. These processes have led to better efficiencies and a more controlled environment that reduces pollution, but does not eliminate it completely. The fact that there are still more than 70 existing Pierce Smith converter plants throughout the world that needs to be replaced or upgraded at tremendous capital cost, means that we will have the environmental problems for some time to come. The need thus exists to cost effectively get these existing plants into a state where they meet the new environmental regulations, community and safety requirements. This paper will concentrate on just one aspect of this quest, i.e. reduction/removal of off-gasses emanating from the converting of non ferrous sulphur mattes to achieve higher or specialised grades of refined metals.

Jan 1, 2005

By F. P. Greyling

The aspect of sustainability of ferroalloy processes has long been a serious matter for consideration in many of the world?s industrialized countries. A number of countries can be named where ferroalloy plants that were once flourishing, have all but disappeared. One of the most important factors playing a role in this type of occurrence is the cost and availability of quality raw materials. Given that all natural resources will be depleted with time, users are compelled to develop new processes that are sustainable in the changing environment. The DC arc smelting furnace is one such process that has proved itself, and has gained increasing popularity over the past two decades. This process, amongst other benefits, directly addresses the use of more readily available and more affordable raw materials in ferroalloy production. Since early in the new millennium, GLPS has been involved in various studies for different clients of furnaces for the production of ferroalloys. Two of these recent studies have culminated in the design, construction and commissioning of DC arc furnaces for the production of ferrochrome. One of these furnaces is a 10 MW unit at Mogale Alloys, and the other a 60 MW unit at the Middelburg plant of Samancor Chrome. This paper discusses the approach taken in the design and construction of these two furnaces, which, although varying significantly in size and capacity, are very similar in many other aspects of their design. Keywords Furnace, DC arc, and ferrochrome.

Jan 1, 2010

By H. M. Stewart, N. F. Dawson, J. P. Beukes, P. G. van Zyl, Q. P. Campbell, A. Jordaan, R. I. Glastonbury, L. N. Sadiki

"SynopsisThe physical properties of oxidative sintered pellets produced from typical South African UG2 ore are compared with the physical properties of pellets produced with conventional South African metallurgical-grade chromite ore (from the Lower Group 6 or the Middle Group 1 and 2 seams). A statistical evaluation of the cured (sintered) compressive strengths proved that pellets prepared from UG2 ore are likely to have the same, or better, compressive strength than pellets prepared from metallurgical-grade chromite ore. The cured abrasion strength of the UG2 pellets was also superior to that of the metallurgical-grade pellets. Scanning electron microscopy (SEM) backscatter, secondary electron, and elemental X-ray mapping were used to determine the reasons for the general superior strength of the UG2 pellets. The case study UG2 ore also required 13 kWh/t less energy for milling to attain the required particle size distribution prior to pelletization, which can lead to substantial cost savings. Results presented in this paper can be utilized by ferrochromium (FeCr) producers to better quantify the advantages and disadvantages associated with the use of UG2 ore for FeCr production.IntroductionChromite, a mineral of the spinel group, is the only commercially viable source of virgin chromium units. Geologically, commercial chromite deposits in the world are found in three forms, i.e. alluvial-, podiform-, and stratiform-type deposits (Murthy et al., 2011; Cramer et al., 2004). Alluvial deposits were formed by weathering of chromite-bearing rock with the subsequent release of chromite and gravity concentration by flowing water. However, these deposits are relatively small and of comparatively minor commercial interest. Podiform-type chromite deposits usually occur as irregularly shaped pods or lenses, and their distribution within a mineralized zone is usually relatively erratic and unpredictable, making the exploration of these deposits difficult and costly (Cramer et al., 2004). Stratiform-type chromite deposits occur as parallel seams in large, layered igneous rock complexes with more regular layering and lateral continuity (Cramer et al., 2004). The largest example of a stratiformtype chromite deposit is the Bushveld Complex (BC) in South Africa, which holds an estimated three-quarters of the world’s viable chromite ore resources (Cramer et al., 2004).Several chromite seams exist in the BC. The seams of economic interest are the Lower Group 6 (LG6), the Middle Group 1 and 2 (MG1 and 2), and the Upper Group 2 (UG2) seams (Cramer et al., 2004). The LG and MG seams are specifically exploited for their chromium content, while the UG2 seam is mined primarily as a source of platinum group minerals (PGMs) (Xiao and Laplante 2004). Extraction of the PGMs from the UG2 ore usually involves the liberation of the sulphide by milling and subsequent recovery of the PGM concentrate through flotation (Xiao and Laplante, 2004). Chromite in the PGM concentrate is undesirable; therefore, PGM recovery circuits are specifically designed to ensure maximum rejection of the chromite to the tailings stream. However, the chromite in the PGM tailings can potentially serve as feedstock for ferrochrome (FeCr) production, after beneficiation to increase the chromium content."

Jan 1, 2015

By C. Steyn, J. D. le Roux

A dynamic model is used to represent the single-stage closed grinding mill circuit at Mogalakwena North Concentrator. The circuit consists of a ball mill closed by a hydrocyclone. The circuit is modelled according to a semi-mechanistic non-linear dynamic model available in literature. An algebraic routine is used to fit model parameters to steady-state process data. Preliminary validation results against dynamic data indicate that the model is capable of capturing the main dynamic trends of the plant. Since classical system identification techniques proved insufficient to produce accurate models; the non-linear model can be used as a reliable source for model-predictive controller design. Keywords: Grinding, modelling, process control, parameter estimation

Jan 1, 2020

[The following notations will be used: O an ore body. W a sample of size w located in O; the size of this sample. W a block or a sample, of size W, located in O; the size of this block or sample. z' a point in W. W' a block or a sample, of size W' greater than or equal to W, located in O; the size of this block or sample. z" a point in W'. y (h) point semivariogram in O. s (h) point covariogram in O. In the previous chapter, we saw that the point semivariogram y (h) usually cannot be estimated directly from the data available. Rather, the values of samples of size w are available in O, and from these a regularized semivariogram y w (h) can be estimated. The following relationship has been proved (5.8): Y w(h) = Y (w;w+h) - Y (w;w). y (w;w+h) is the average value of y (z' z") when z' takes all possible positions in a sample w and z" all possible positions in a sample w+h of the same size, h being the distance between w and w+h. y (w;w) is the value of y (w;w+h) for h = 0, i.e. the average value of y (z' z") when z' and z" take all possible positions in w. We also saw that the regularized covariogram aw(h) is related to the point covariogram a (h) as follows (5.9): w(h) Gr In the following chapters, it will be shown that calculation of the average value y of y, or -a of a, in the general case relating to samples or blocks W and W' which need not be of the same size, plays a very important part in all the practical applications of geostatistical theory. The purpose of this chapter is to introduce various methods of calculating y and a-. Furthermore, mathematical equations and graphs are provided which can be used when the point semivariogram can be represented by one of the more common equations, and when the blocks W and W' are of simple shape. By definition (Fig. 6.1): [ ] Y (W;W) = WW f dz' f y (z' z") dz" (6.1) in W z" in W']

Jan 1, 1978

By O. Barron, C. Felix

In 2023, polymer electrolyte membrane fuel cell membrane electrode assemblies accounted for about 62% of the global fuel cell market share and this demand is expected to grow. Commercialisation requires technologies capable of cost-effective, high-volume manufacturing. The membrane electrode assembly is crucial and represents a significant cost to polymer electrolyte membrane fuel cell manufacturing. Manufacturing the electrode components for membrane electrode assemblies at high volumes can reduce production costs while delivering on the forecasted industry demands. Roll-to-roll is a mature coating technology applied in various manufacturing industries such as batteries, printed electronics, microelectronics, photovoltaics, printing, paper consumables, etc., with significant potential for polymer electrolyte membrane fuel cell manufacturing. While the high-volume production process for membrane electrode assembly manufacturing differs from laboratory-scale, the membrane electrode assembly structure remains unchanged. Roll-to-roll is a continuous coating process with speeds of 10 m/min being achieved. In this work, MicrogravureTM and slot-die coating methods have been adopted and have shown promising outcomes for producing gas diffusion electrodes for membrane electrode assemblies. An overview of the MicrogravureTM and slotdie coating methodologies is provided, and a discussion on preliminary results and challenges are presented. Work on MicrogravureTM gas diffusion electrode manufacturing has already achieved comparable performance with spray-coated gas diffusion electrodes. The influence of coating parameters and drying on the coated catalyst layer quality is discussed.

May 27, 2025

By G. Popplewel

Commencing with the Pre-Feasibility Study (PFS) conclusions, the Orapa 3 process design evolved through a phase of value-engineering studies. An overall re-evaluation of the originally proposed process design was necessary both in order to address the interim increase in target throughput from 9.8 Mtpa to 12 Mtpa as well as to increase capital efficiency. In the interests of clarity, the PFS process design for Orapa 3 has been omitted from this paper, as it is no longer relevant. Recognition is however due to those engaged in earlier phases of the Orapa 3 project with respect to fundamental mass-balancing modelling; and ore and diamond characterization, which fanned the basis for the process design that has evolved from feasibility study activities.

Jan 1, 2010

MEMBERSHIP In terms of By-laws7.7.1 members are hereby notified that the membership of the following has been cancelled and their names removed from the Membership Register: H. Digby Roberts, R. J. P. van Tonder, S. D. Williams (Members), A. I. de Klerk, M. F. Ford, A. W. Hine, H. A. Johnston, R. T. Joyner, H. D. Small, P. White (Associate Members), J. de F. Agrella, A. Leibowitz (Affiliates), J. P. M. Maidment, C. P. J. M. Steyn (Graduates), H. C. M. Fourie, B. C. P. Job, J. P. Kruger, E. C. Nicolas, A. P. Prinsloo, B. Schuitema (Students). INSTITUTE PUBLICATION Transactions of the Seventh Commonwealth Mining and Metallurgical Congress Requests are still being received by the Institute for sets of the above transactions. Members who wish to dispose of sets in good condition are requested to contact the Secretary, P.O. Box 1183, Johannesburg or 304 Kelvin House, Johannesburg. As these are for resale a price of not more than R10.00 can be offered per set of three volumes. INTERNATIONAL SOLVENT EXTRACTION CONFERENCE, 1971 The Society of Chemical Industry has agreed to sponsor an International Conference devoted to the science and technology of solvent extraction. This will be held in The Hague in the Netherlands during the week commencing 19th April, 1971. The organisation of the Conference will be in the hands of a Conference Committee under the chairmanship of Mr B. F. Warner. The emphasis of the Conference will be on technical solvent extraction of both inorganic and organic substances, including basic principles and practical applications. Sessions are envisaged covering the chemistry of solvent extraction, industrial processes and economics, the performance of contacting equipment and the underlying phenomena involved, and the response characteristics and control of such units. The Conference Committee will welcome offers of papers for presentation at the Conference. In the firts instance, intending authors should submit a preliminary title and an indication of the scope of their contribution to the Conference Secretary: Dr. C. Hanson, University of Bradford 7, U.K. It is hoped to have available in September a first circular giving further details of the Conference. Copies may be obtained from: International Solvent Extraction Conference, 1971, 14, Belgrave Square, London, S.W.1. SOUTH AFRICAN TUNNELLING CONFERENCE TO BE HELD IN 1970 A South African Tunnelling Conference, to be known as TUNCON 70, is to be held in Johannesburg during the latter half of July, 1970. South Africa, in common with other countries, has a vital and growing interest in tunnelling. Apart from the 800 kilometres of tunnel excavated annually in the gold mines, the 82 kilometre-long Orange-Fish Tunnel is being driven to carry water from the Orange River to the drier areas of the Eastern Cape Province. This and the realization that services such as water and transport are increasingly being carried underground in various parts of the world have emphasized the need for a forum at which the technology and potential of tunnelling can be discussed. TUNCON 70 is being supported by three professional engineering societies representing some 6,000 engineers, namely, the South African Institute of Mining and Metallurgy, the South African Institute of Civil Engineers and the South African Institution of Mechanical Engineers, as well as by the Geological Society of South Africa. The conference has three main purposes. Firstly, to pool and exchange expertise by authorities on tunnelling; secondly, to discuss future developments in tunnelling technology with the aim of making those concerned with long-term planning aware of the potentialities of tunnelling; thirdly, to propose standards for tunnel shapes and sizes. Adoption of standards for tunnelling equipment and accessories would be a major step forward in improving tunnelling efficiency. The five themes of the conference will be: tunnel utilisation, exploration, design, construction and standards. The conference will be held at the University of the Witwatersrand, Johannesburg, from 21st to 24th July, 1970. Arrangements will be made for visits to be paid to mines and tunnelling projects before the start of the conference. Further information is obtainable from the Organising Committee, TUNCON 70, P.O. Box 1183, Johannesburg, South Africa.

By G. Akdogan, M. Tadie, A. Tapfuma

The Southern African region contains abundant gold tailing heaps that are an environmental concern due to dust pollution and chemical contamination of nearby water bodies. Nevertheless, these heaps contain gold with potential to be extracted for financial gain. In this study, the feasibility of extraction of gold from a Witwatersrand gold tailings using glycine was investigated using a two-level full factorial design. Effects of variables such as glycine concentration at levels of 0.5–1.5 M with a solid–liquid ratio of 50–200 g/L were investigated. Although the solid–liquid ratio used in this study was below the industrial norm, it provides a starting point for investigating the applicability of this technology. To enhance the gold extraction, potassium permanganate pretreatment and copper ion addition were adopted. The results revealed that 91.4% gold extraction was achieved after 24 h pre-treatment of the tailings using 2 g/L potassium permanganate followed by subsequent leaching using 1.5 M glycine at pH 12, with 50 g/L solid–liquid ratio and 2 g/L copper ions. Statistically, the solid–liquid ratio and potassium permanganate pre-treatment of the tailings were found to be significant at 95% confidence interval, whilst interactions of copper ions and glycine concentration were significant factors. The work demonstrates that potassium permanganate pre-treatment prior to glycine leaching of low-grade secondary gold resources, such as tailings, can be beneficial. Furthermore, the methodology developed in this work provides an opportunity for further investigation of the recovery of gold hosted in complex mineralogical matrices.

Apr 14, 2024

By J. Fu

"Since it was first identified in 1817, selenium has received considerable interest. Native selenium and a few selenium minerals were discovered several decades later. With the increasing number of selenium minerals, the occurrence of selenium minerals became the focus of much research. A great number of selenium deposits were reported all over the world, although few independent selenium deposits were discovered. Selenium is obtained mainly as a byproduct of other metals, and is produced primarily from the anode mud of copper refineries. This paper presents a comprehensive review of selenium minerals, as well as the treatment of copper refinery anode slimes for the recovery of selenium. Our focus is on the selenium minerals, including their discovery and occurrence, and the distribution of selenium resources. In addition, the main methods of recovering selenium from copper anode slimes are summarized. IntroductionSelenium (Se) was first observed in 1817 in a laboratory (Greenwood et al., 1984). The discovery of selenium was made by the Swedish chemist J.J. Berzelius and J.G. Gahn, who isolated selenium from a red residue in sulphuric acid from pyrite mined at Fahlun, Sweden. Selenium was named from the Greek word selene (moon), since it resembled tellurium, which had been discovered a few years earlier and named from the Latin word tellus (Earth).After the first observation of selenium in the laboratory, selenium received considerable interest. In 1954, E.P. Kaiser pointed out that Se is enriched in sulphide ores and often associated with Bi, Co, Sn etc. (Kaiser 1954). In 1959, Hawley and Nichol investigated selenium in Canadian sulphide minerals, and presented the content of selenium in sulphide from several deposits of different types. They also proposed that Se is enriched in lowtemperature hydrothermal pyrite (Hawley and Nichol, 1959). The thermodynamic conditions for forming native selenium and selenium minerals in sedimentary rocks were discussed, as well as geochemical behaviour of selenium near the oxidation zones of sulphides in the 1970s (Howard III, 1977; Zhu et al., 2003). Zhu et al. examined the morphology, features, and genesis of native selenium from Yutangba, Enshi City, Hubei Province, China in 2004, and pointed out, from the different forms of native Se, that selenium can be activated,transformed, remobilized, and enriched at sites such as in the unsaturated subsurface zone or in the saturated zone (Zhu et al., 2005). The transport and deposition of selenium in felsic volcanic-hosted massive sulphide deposits of the Yukon Territory, Canada was studied and reported by Layton- Matthews et al. (2005)."

Jan 1, 2016

By Roger A. Blais, Michel David

"Matheron's geoslalislical method for the estimation of ore reserves has been developed to the point at which real-life problem may be handled effectively. The steps involved in the method are:(i) obtalning the variogram,(ii) fitting a model, and(iii) producing block estimates.All three steps may cause difficulty, and would-be users need a deep understanding of the theory if failure is to be avoided.To illustrate these points, specific cause are considered:(i) two almost equidimensional porpbyry deposits, one drilled randomly and the other regularly; and(ii) two iron formation, one drilled extensively and being mined, while the other is still at the stage of early estimation."

Jan 1, 2014

By Richard F. Link, Jr. Koch

"A mathematical simulation model has been devised to guide the layout of surface or underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. The ore bodies may be contained within veins, sedimentary beds (including reefs), or other tabular structures.Programmed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations and values. Deterministic or controllable variables include (i) locations and costs of workings (for underground exploration); (ii) drill station locations and costs; and (iii) drill hole azimuths, inclinations, lengths and deflections (if any).For various assumptions about the natural variables, the model is run while the controllable variables arc changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated."

Jan 1, 2014

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By L. B. McRae

The following papers were presented at a seminar that was organized by the SAIMM and held at Mintek during 1991. The occasion was a visit by 12 members of the Committee for Metallurgical Fundamentals of the Verein Deutscher Eisenhitenleute.

Jan 1, 1991

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By G. A. Bezuidenhout, S. Bradshaw, W. Malan

"Currently, the matted-based collection process is most widely used for platinum group metal (PGM) recovery. However, because PGM-containing concentrates are becoming more enriched with UG2 (Upper Group 2) low-grade concentrates, this is expected to be integrated or replaced with an alloy collection process.The reduction LG (low-grade) concentrates with silicon carbide (SiC) was investigated. The purpose of the study was to ascertain the feasibility of using SiC as reductant with regard to metal fall, PGM grade in the alloy, slag composition, and overall PGM recovery, and if possible, the integration of such a process in the current matte-based collection process. Rowland and Easterns LG concentrate samples from Lonmin were analysed by Xray diffraction (XRD), X-ray fluorescence (XRF), and inductively coupled plasma mass spectrometry (ICP-MS). It was found that SiO2 and MgO are the most abundant oxides and Pd is the most abundant of the PGMs. Sulphide-bearing minerals such as chalcopyrite were detected in low concentrations (below 1%), and Cr2O3 concentrations are between 2-4%. SiC reduction of Rowland and Easterns concentrate were conducted at 1600°C with reductant to concentrate ratios ranging from 2.5 to 3.5 kg SiC per 100 kg concentrate.The reduction experiments revealed that PGM recoveries from Rowland concentrate were poor. SEM images showed entrained metal prills in the slag phase. The slag viscosity at the end of the melt was calculated by using FactSage, and the results indicated that the viscosity was higher than 4 poise, which is above that of Easterns slag. PGM recoveries for Easterns concentrate were significantly better. More than 85% of the Ir and Pd and almost 60% of the Pt were recovered in a test with a reductant to concentrate ratio of 3.5 kg SiC per 100 kg Easterns concentrate. At this reductant to concentrate ratio, Fe recovery was also the highest, at 66%. SEM imaging of a slag sample revealed few or no metal prills entrained. The FeO content in the initial concentrate charge was then increased by adding Peirce-Smith converter slag in order to decrease the slag viscosity and further increase PGM recovery. A test was conducted with the addition of 10 kg converter slag per 100 kg Easterns concentrate. The reductant to concentrate ratio was kept at 3.5 kg SiC per 100 kg Easterns concentrate. The Ir and Pd recoveries were more than 95%, while Pt recovery was almost 70%. Fe recovery increased to 76%. On the basis of these results an optimum feed ratio between Easterns and Rowland concentrates and Peirce-Smith converter slag were calculated. FactSage predicted that the concentrate charge should consist of 70-80% Easterns concentrate with 20-30 kg converter slag per 100 kg LG concentrate. SiC reduction of this optimum LG concentrate charge is expected to recover more than 90% of all PGMs. Cr and Si concentrations in the alloy will be below 1% in total.The effectiveness of SiC as reductant was also compared to carbon reduction. Carbon reduction of an optimum concentrate charge at the same reductant to concentrate ratio resulted in a marginally higher metal fall than SiC reduction. However, gas emissions and energy requirements are higher for carbon reduction.The study has shown that base metals and PGMs can be recovered in an iron alloy by SiC reduction of LG concentrate with converter slag additions. Integration of such a process into the matte-based collection process could be considered as a future alternative for smelting UG2 LG concentrates."

Jan 1, 2014

Alexander Sutulov. Mineria Ghilena 1545-1975 (Mining in Chile 1545-1975). Santiago, Centre of Investigation of Mining and Metallurgy, 260 pp. (In Spanish). G. B. Rothenburg. Speciality steels. D.S.A., Noyes Data Corp., 1977. 270 pp. Witbank Middelburg Branch A General Meeting was held at the Wit bank Golf Club on 20th April, 1977, at 17h30. Treatment of waste water An International Research Symposium on New Processes of Waste Water Treatment and Recovery is to be held in London from 6th to 8th September, 1977. It NIM reports Report no. 1708 An examination of the suitability of various reducing agents for the production of ferrochromium. (27th Feb., 1975; re-issued May 1977). Report no. 1724 The preparation and reduction of chrornite pellets containing a reducing agent. (14th Apr., 1975; re-issued Mar. 1977). Report no. 1854 The interaction of pyrite, oxygen, and xanthate. (8th Mar., 1977). Report no. 1876 The ultrasonic determination of the mud level in a thickener and the resin level in an ion-exchange column. (6th May, 1977). Report no. 1878 The electrochemical dissolution of galena in aqueous solutions. (5th May, 1977). Report no. 1881 n-Octylaniline, a new extractant for noble metals.(28th Mar., 1977). Report no. 1883 The determination of iron, chromium, titanium, and tungsten by X-ray-fluorescence spectrometry. (31st Mar., 1977). Report no. 1889 Entropy relations in the formation of complexes of silver (1), mercury (II), and cadmium (II) with llwnodentate liyaruls. (5th May, 1977). Mechanics of granular materials A conference on the above subject is to be held in London on 8th and 9th September, 1977, under the auspices of the Institute of Mathematics and Its Applications.

Jan 1, 1977