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By H. H. Schrenk

[A colorimetric method5/ for the determination of benzene in amounts as low as 0.001 mg has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel fro a the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid - or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations. The development worth included a study of possible interference by chemicals that be present in those situations in which the method. would be employed. In this study it was found that a specimen of hexane prepared by the Gulf Research Laboratory, Pittsburgh, by fractionation of West Virginia natural gas gave positive result for benzene, whereas a specimen of pentane prepared in the same manner showed only a trace, and specimens of n -heptane and octane (2,2,4 trimethylpentane) supplied by Eastman Kodak Co. save a negative result. According to information obtained from the Eastman Kodak Co. the latter two compounds were highly purified, the n-heptene being prepared from line and the octane synthesized in the laboratory. On nitration of a larger amount of tae natural hexane a visible quantity, of needlelike crystals which resembled those of m-dinitrobenzene was obtained. The hexane from this nitration was recovered by distillation and again nitrated, but no crystals or colorimetric indication of benzene was obtained. This imitated that the specimen of natural hexane contained a substance which at least had the chemical behavior of benzene.]

Jan 1, 1935

By Bruce D. Sartwell

The Bureau of Mines is using characteristic X-rays produced by proton bombardment of a solid surface to provide quantitative compositional analyses of surface layers of metals. An integral X-ray yield equation has been developed that quantitatively relates the measured X-ray yield to the thickness of thin films ranging from less than a monolayer to several thousand angstroms. The use of the integral yield equation is demonstrated for the growth of a thin film by vacuum evaporation. Results are presented that show haw proton-induced X-ray emission (PIXE) has been used to determine the oxidation kinetics of iron that had been implanted with several different species of heavy ions. The sensitivity of PIXE for the measurement of very-thin-film growth kinetics is demonstrated from studies of the effect of fractional mono-layer coverages of sulfur on the initial oxidation kinetics of iron. Results are also presented in which PIXE has been used to study the redistribution of alloying elements in components of a gas turbine that had fractured due to corrosion fatigue. By combining PIXE with low-energy ion sputtering, quantitative composition depth profiles of surface layers are obtained. Examples are presented for the profiling of iron samples implanted with 25-kev nickel ions and for a platinum coating on an Fe-5Cr substrate.

Jan 1, 1980

By Fred Garcia, William P. Diamond

As part of its mine safety and health research program, the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, has been investigating the geologic and mining factors influencing methane gas emissions associated with longwall mining. A primary focus of this research has been the consequences of increasing longwall panel dimensions, particularly face width, in gassy coalbeds. Continuous longwall face emission monitoring studies were conducted at two adjacent mines operating in the Pocahontas No. 3 Coalbed, where longwall faces were to be extended from 229 to 305 m (750 to 1,000 ft). Average longwall pass methane emission rates for 229-m (750-ft) wide faces were 61 % (0.072 m31sec (153 cfm)) higher at the VP-3 Mine than at the VP-1 Mine. It was predicted by regression analysis of methane emissions data from 229-m (750-ft) wide faces that extending faces to 305 m (1,000 ft) would increase methane emission rates by only 7%, or 0.009 m3/sec (20 cfm), to 0.144 mysec (304 cfm) at the VP-1 Mine. In contrast, it was predicted that extending faces to 305 m (1,000 ft) at the VP-3 Mine would increase methane emissions by as much as 13%, or 0.029 mysec (65 cfm), to 0.268 dlsec (567 cfm).

Jan 10, 1999

By Lucia Kuizon

The Morongo Wilderness Study Area (WSA) is in south central San Bernardino County, California. U.S. Bureau of Mines examined the area during the fall of 1983. No mines, prospects, leases, or mining claims were found in the WSA. There are no known mineral deposits within the study area boundaries. Sand and gravel in the area is suitable for many types of construction uses, but similar and larger deposits outside the WSA are closer to markets. No energy resources have been identified in the WSA.

Jan 1, 1984

By John Durkin

Information on vertical magnetic noise in the voice frequency band, both within and above coal mines, is needed for the evaluation of through-the-earth baseband electromagnetic communications at mines where horizontal loop antennas are used. This report discusses the theory of the source of electromagnetic noise, the propagation of this noise to an observation point above a mine, and its interaction with the local earth conductivity structure, which gives rise to vertical magnetic noise. The relationship of surface noise to underground noise is also discussed. Bureau of Mines investigators made surface and underground vertical magnetic noise measurements at a number of coal mines located through- out the United States. These data were modeled through regression analysis to characterize expected noise levels. The results are presented, including results in one-third octaves for use in evaluating the expected performance of through-the-earth communication systems by articulation-index studies.

By J. Douglas Causey

In 1985, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied a portion of the 110,000 acre Massacre Rim Wilderness Study Area (CA-020-1013). The area studied, containing 23,260 acres, is located in northwest Washoe County, Nevada, about 25 miles west of Vya adjoining the Charles Sheldon National Wildlife Refuge. Basalt caps older tuffaceous sedimentary rocks in an area that contains no claims or prospects. No mineral resources were identified during this investigation.

Jan 1, 1987

By G. A. Brady

Seven samples of Pennsylvania anthracite from the Bottom Ross bed were analyzed and tested to obtain data on cleaning characteristics, proximate and ultimate analyses, specific gravity, grindability, heating value, and ash softening temperature. Ash content of the samples varied irregularly from 9.0 to 34.4 percent, the range being narrowed to an upper limit of 14.8 percent ash by removing impurities dense enough to sink in a medium with a specific gravity of 1.90. Ash content of the sink material with specific gravity greater than 1.90 ranged from 56.4 to 80.4 percent; corresponding specific gravities were 2.095 to 2.534. Volatile matter contents were indicated to be higher for the ash-forming minerals than for the pure coal substance in the various specific gravity fractions of a given sample. Specific gravities of anthracites with compa¬rable ash contents but from different locations in the bed varied as much as 0.06. The grindability index increased significantly with increasing ash con¬tent of specific gravity fractions from all the samples.

Jan 1, 1968

By James W. Vogh

The report covers initial findings in an experimental program to identify diesel exhaust odorants and determine their contributions to diesel odor. The approach was to isolate selected component groups from exhaust and to evaluate the contribution of each group to exhaust odor. Results were obtained for those carbonyls and phenols that could be isolated from exhaust through inter-mediate conversion to oxime derivatives. Unsaturated aliphatic aldehydes and sterically hindered carbonyls were not included. Hydrocarbons intermediate in the diesel range were "also evaluated and an odor contribution was found from those of the aromatic group. The evaluated carbonyls, phenols, and hydrocarbons were found to account for about 20 pct of the total odor in exhaust from an indirect-injection engine during idle. For exhaust from the indirect-injection engine operating under load and from a direct-injection engine at no load, these compounds were found to have no significant levels of odor.

Jan 1, 1972

By Richard G. Burdick

This Bureau of Hines report describes an interface between a minicomputer and peripheral device, The logic used to develop the device is discussed briefly, after which the device is described in detail; complete construction and operational details are given. The report should aid both in duplicating this device and in designing similar devices for different uses.

Jan 1, 1975

Provide respiratory protection for escape in a toxic or oxygen-deficient atmosphere with a device small and light enough to be belt-worn. Approach Combine a 10-minute, belt-worn respirator with a stored, larger, long-duration (60-minute) attachment that can be plugged into the 10-minute unit without removing the mouthpiece. How It Works The 10-minute device will be carried by the miner at all times, and the 60-minute canister or attachment will be stored near the miner. In the event of a disaster, the 10-minute device would be donned immediately. The miner would then proceed to the stored 60-minute unit and plug it into the 10-minute unit. For the 10-minute unit, a breathing circuit was developed in which air is passed through the KO2 bed twice per respiration. The 60-minute canister differs from the 10-minute unit in that air is drawn only once through the chemical bed per respira-

Jan 1, 1981

By Wing G. Agnew

The drilling and bit-sharpening practice in the southwest Wisconsin zinc district generally conforms to the procedure described herein, except at very small properties, where drill steel is sharpened by hand. Though hot milling of rock-drill bits is practiced in South Africa on some of the large-scale operations, it is seldom seen at American minus in any form. Because of the simplicity and low cost of the equipment, it was thought that a brief description might prove interesting to same of the operators in ether districts who do not have enough steel to sharpen to warrant equipping an elaborate sharpening shop.

Jan 1, 1936

By S. H. Ash

California leads the Nation in the number of operating metal mines and the small number of persons employed at individual mines, which reached a minimum irk 1932 with an average of seven men. The mines are scattered over the entire State, which is the second largest in area (155,562 square miles) in the United States. The mines are situated at various altitudes, with portals ranging from approximately 300 feet below sea level to almost 12,000 feet above. Many of the mines can be reached only during the summer, while at others the heat of the regions adds so the difficulties during the summer months Supplied of explosives the use (or, probably more correctly, the misuse) of which constitutes one of California's gravest mining problems; are handled and stored under condition that contribute many hazards. The problem of providing medical care is serious and complicated, especially at small mines and more particularly in the almost inaccessible mountainous regions; instances in which a knowledge of first aid would have been beneficial but was lacking, or when first aid was instrumental in saving life or limb because it was available are too numerous to be mentioned.

Jan 1, 1936

By C. M. McCulloch

Examination of several coalbeds in Walker County, Ala., Cambria, Greene, and Fayette Counties, Pa., and Raleigh and Wyoming Counties, W. Va., indicates that cleat orientations are similar throughout a vertical sequence of strata. Studies of cleat orientation were carried out in underground mines that are operating in separate coalbeds vertically above one another. The data show that over a vertical separation of 100 to 400 feet, the average difference in coal cleat orientation between mines is 04° for the face and 08° for the butt cleat. Variations of coal cleat direction between coalbeds examined in strip-mined areas show similar values. Cleat orientations measured at outcrops agree well with the directions measured underground, suggesting that the amount of vertical separation between coalbeds has little effect on the resulting differences in cleat directions. The largest variation of cleat directions between adjacent coalbeds occurs where a large horizontal distance separates two sample locations. Cleat orientations for deeper coalbeds are most reliable where the data are taken from directly above.

Jan 1, 1976

By Charles D. Martens

Raw non fuel minerals produced in the United States during 1981 had an estimated value of $25 billion, about the same as that of 1980. In terms of 1980 dollars. the value of minerals produced during 1981 was $23 billion.2 This chapter includes tables for 1980 that were not available for publication in the 1980 Minerals Yearbook, but does not include the corresponding tables for 1981. The underlying causes of the overall decline in U.S. nonfuel mine production during 1981 were varied, but the common factor was the worldwide recession. In some cases the decline was traced to foreign competition. For example, iron ore production was lower in part because of increased imports of steel products such as coiled steel sheet. Another problem experienced by the domestic mining industry was the continuing difficulty in attracting capital. This was due in part to the attractiveness of investments outside the mining industry, such as short-term, high-interest securities. Another reason was the importation of commodities from countries where overall costs were lower because of such factors as high ore grade, lower taxes, lower wages, government subsidies, and less stringent safety and environmental regulations.

Jan 1, 1982

By Oliver Bowles, J. E. Crawshow

A line of cordeau detonating fuse was placed in hole No. 2, no electric detonators being used in the hole. After 12 or 13 cases of 40 per cent nitro starch powder had been poured into the hole in loose form, it was found that a space of only 17 ft. remained for stemming. It was decided that space for an additional case of powder might be obtained by tamping the charge. The tamping was done with a heavy plunger, about 3 or 3 inches in diameter and 10 inches long, made of lead with an iron core with an iron eye in the top to which a 3/4 inch rope was attached, and weighing between 30 and 40 pounds. This weight was intended for use in sinking explosive in wet holes, and not for tamping. It is estimated that the tamping had continued at least 10 The quarry superintendent had gone a considerable distance for a box of powder, returned, and reached a point about 10 feet from the hole, minutes.

May 1, 1920

By C. A. Wilson

The Bureau of Mines started a continuing program to investigate and evaluate analytical techniques to assist governmental agencies to select simple, rapid, reliable methods for crude oil spill identification. Six crude oil samples were analyzed to evaluate gas-liquid chromatography, atomic absorption spectrophotometry, infrared spectoscopy, sulfur and nitrogren determinations, mass spectrometry, nuclear magnetic resonance spectroscopy, and ultraviolet spectrophotometry. Samples were studied from the following selected fields: El Morgan, Egypt; Duri, Indonesia; Minagish, Kuwait; Bachaquero, Venezuela; Gach Saran, Iran; and Prudhoe Bay, Alaska. These samples were chosen to represent high-production fields that are likely to be involved in oceanic transport. Over 50 years of Bureau of Mines analytical research on petroleum served as the basis for evaluation of the experimental results to determine which of the methods are effective techniques to identify crude oil spills. Gas-liquid chromatographic analysis, atomic absorption spectrophotometric analysis, and sulfur-nitrogen determinations are recommended as the most useful of the techniques investigated.

Jan 1, 1975

By Harry Dobroski, Larry G. Stolarczyk

A medium-frequency (MF) communication system has been built and has been tested in underground mines. It provides radio coverage to vehicles and personnel anywhere in the mine via parasitic coupling into existing mine conductors. The system consists of base stations, repeaters, and vehicular and personnel transceivers. Air-core antennas for vehicles and clamp-on antennas for base stations and repeaters were designed for maximum coupling efficiency using existing mine wiring. Personnel transceivers are of a unique vest design that features a low physical profile, good user comfort, and efficient antenna design. In-mine tests show impressive results. Range between rubber-tired vehicles and base stations is often measured in miles. With repeaters, greater range is possible.

To develop a cost-effective tool for improving the performance of rock drilling systems used in detecting and delineating underground mine voids and for coal exploration. Approach To investigate admixtures of polyethylene oxide (PEO) at zero surface charge concentrations as drilling fluid additives to enhance penetration rates and extend bit life in rock drilling systems. Background Bureau researchers have investigated the use of chemical additives to enhance drilling performance and found that the most efficient drilling occurred when the drilling fluid was able to maintain a zero surface charge (ZSC) on the surface of the rock being drilled. Laboratory drilling studies have been performed on rock types such as quart¬zite, granite, taconite, and marble. The lab tests were conducted using 5/8-inch diameter diamond-impregnated coring bits with cationic compounds as the surface charge neutralizing additives. These studies demonstrated enhanced drilling performance, however, only at the singular additive concentration that produced the ZSC condition.

Jan 1, 1991

The Bahamas Oil Refining Co. (BORCO) refinery in Freeport continued to operate at less than half its full 500,000-barrel-per-day capacity. Although owned through subsidiaries by the Carey Energy Corp (65%) and Standard Oil Co. of California (35%), BORCO is ineligible for participation in the Crude Oil Entitlements Program granted to companies operating within the United States proper or its territories. Like some other Caribbean refineries, BORCO has suffered a loss of normal market outlet due to the wt advantage afforded U.S. refineries by the Entitlements Program. Saudi Arabia, Nigeria, and Libya are the major suppliers of crude for the refinery. Its principal products, motor spirits, aviation fuel, distillate fuels, and residual fuel oils, were marketed in the United States and Puerto Rim. The Government-owned Bahamas Development Corp. and Burmah Oil Co. Ltd., held discussions pertaining to a renegotiation of Burmah Oil's management contract for the Grand Bahama Oil Transshipment terminal. The desired contract modifications were not made public but financial problems have plagued the terminal and its operation since construction started in 1972.

Jan 1, 1981

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Jan 1, 2011