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By A. L. Engel

This publication describes further research by the Federal Bureau of Mines in beneficiating domestic manganese ores. The ores selected for treatment were typical of many manganese deposits in California and Nevada in that they have not been economical to mine because they are low grade or contaminated with siliceous minerals and are not amenable to physical concentration.3 4/ It would be desirable to develop a simple treatment method resulting in nearly complete extraction of manganese from these ores and applicable to small-scale operations. Sulfation reduction appeared to be such a method. The studies reported in this publication were directed toward sawdust or lignin-sulfonates as reducing agents. Sawdust, as waste from lumbering, and lignin-sulfonates, byproducts of woodpulp papermaking, are comparatively cheap and may be available in areas where manganese ores are found. Sugar, oils, and coal were also tried as reducing agents.

Jan 1, 1960

By M. Orchin

THIS PAPER is concerned with two aspects of the behavior of coal: (1) Dispersion by solvents atmospheric pressure and high temperature and (2) the destruction and regeneration of the coking properties of coal. Several pure polycyclic compounds and a coal-tar fraction were found to extract 95 percent of the organic material of a bituminous coal. About 20 percent of the extract was soluble in benzene, and this fraction contained the ?coking principle? of the coal. From an extensive chemical spectroscopic, and x-ray study of the benzene-soluble material, some conclusions could be drawn concerning the composition and structure of this fraction of coal. A possible commercial application of the extraction technique is in the preparation of low-ash carbonaceous material for the manufacture of electrode carbon.

Jan 1, 1951

By Andrew B. Cecala

The U.S. Bureau of Mines has designed and evaluated total mill ventilation systems at two different mineral processing operations. Both systems have proven very effective at reducing respirable dust levels throughout the mill in a cost-effective manner. A 25,500-cfm system installed at a clay processing mill provided approximately 10 air changes per hour. This system reduced respirable dust concentrations by approximately 40 pct throughout the mill building. The second evaluation was performed at a silica sand operation. Tests were performed with 50,000 and 100,000 cfm of ventilation to the mill building, corresponding to 17 and 34 air changes per hour. Average mill-wide respirable dust reductions were 36 and 64 pct, respectively. Not only did these systems reduce respirable dust concentrations and increase visibility throughout the mills, they were also easy to install and required minimal maintenance. A total mill ventilation system provides a general purging of the mill air; the system should be viewed as a supplemental technique to assist other dust control systems in operation.

Jan 1, 2010

By D. R. Dolinar, J. Pablic, D. C. Oyler, T. P. Mucho

At a mine in central PA, high horizontal stresses have caused long running roof falls resulting in hazardous conditions for the miners and the premature abandonment of panels. Because of these conditions, the mine requested assistance of the National Institute for Occupational Safety and Health (NIOSH) in utilizing the 'advance and relieve method to mitigate the affects of horizontal stress on the mine roof. "Advance and relieve" mining involves the removal of a pillar or a portion of a pillar during development, thereby creating a cave along one side of the panel. Following cave development, the horizontal stress is relieved over the workings adjacent to the cave in the active panel. The mine has used this system in three panels with a significant reduction in stress damage and no large roof falls.

By Dennis A. Hansen

The solubility of anhydrous aluminum chloride in solutions of titanium tetrachloride and vanadium tetrachloride was determined as part of a re-search project-by the Bureau of Mines to make a homogeneous alloy sponge of titanium, vanadium, and aluminum. Solubility curves were established using an autoclave at 75°, 100°, 125°, and 150° C. The solubility of AJC13 in TiC14 is 0.2 wt pct at 75° C; it increases to 18.3 wt pct at 150° C. The data concur with data from earlier researchers of this bi-nary system for 75° to 125° C. For the VC14-AlC13 binary system the solubility of AlC13 is 0.1 wt pct at 75° C, increasing to 1.6 wt pct at 150° C. For the TiC14-AlClrVC14 ternary system the solubility of AlC13 decreases from the values found with a pure TiC14-AlC13 system to the lower values found with a pure VC14-AlC13 system at the respective temperatures.

Jan 1, 1986

By W. H. Forbes

The prevention of accidents from falls of roof and coal requires a considerable amount of personal judgment , for conditions are different even in adjoining working places in the same mine , and conditions may change from hour to hour even in the same working place as the coal is shot down and loaded . Experience has shown that many men can not or do not exercise enough care to protect themselves from injuries ; moreover , where the foremen have been made directly responsible for the safety of the men under them , accidents from falls of roof and coal have , in many instances , been reduced as much as 50 per cent . There is now no question that careful , constant , and intensive supervision is essential in preventing acci- { dents and more especially accidents of this class . Falls of roof and of coal account for approximately 50 per cent of all coal mine accidents and annually result in the death of approximately 1,000 men and cause lost - time injury to approximately 50,000 men . These and other accidents are recurring with little or no diminution , usually not because of the lack of knowledge of safe and dangerous practices , or of the technique of safety , but largely because of the lukewarm interest of major executives in safety or the failure of mine officials to formulate and to enforce common - sense rules and regulations . When failure is the outcome of a sincere attempt of the managing officials to teach safety to the miner , the fault may usually be attributed to misguided effort . Various solutions for the problem of eliminating accidents from falls of roof or coal have been suggested , some of which are : Standard system of timbering for the specified mining districts ; departure from the room-and - pillar system to a more concentrated system of mining ; more intensive supervision - that is , 1 section foreman for every 25 loaders instead of 1 section foreman for 75 , 80 , or even more loaders the practice in most mining districts . - However , investigations conducted by the writer at numerous mines operated by a number of mining companies in several districts show that employees and officials alike are inclined to work under loose and unsupported roof , relying solely on the " drummy " sound and on their judgment and experience as to whether the roof will stay in place for one hour or for several hours . With but few exceptions , men who had been injured by falls of roof or ccal or were found working under loose and unsupported roof , admitted that they knew of the possibly unsafe condition , but it was their opinion that the roof or coal was not loose enough to fall for some time .

May 1, 1931

By C. W. Davis

Two general schemes have been used for the determination of gold and silver in material containing considerable quantities of copper ; one is known as the " all fire " method , and the other as the , " combination " , or " wet and dry" method . The all fire crucible method , using an excess charge of litharge , has been found satisfactory when the copper content of an ore is under 6 per cent , ( Loevy , J. , Zur Edelmetallbestimmung in hochprozentigen Kupfererzen : Chem. Ztg . Jarhrg . 35 , 1911 , p . 278 ) , or where the precious metal value is so great that a small sample can be used . In the latter case , silica is added until the copper ratio is sufficiently low . If there is more than 6 per cent of copper in an ore , the lead button obtained from a crucible fusion will require repeated scorification before . it can be cupelled successfully . Rescorification is not only tedious , but also causes a slag loss of precious metals . In combination methods , the copper is dissolved , and the gold and silver in the residue . is determined by fire assay Although some combination methods have given satisfactory results for gold and silver , they are not applicable when an estimation of the platinum metals is required . Since substances containing platinum are frequently high in copper , a study of methods which might be used for the estimation of small quantities of gold , silver , and the platinum metals in such material was considered worth while . The estimation of platinum in ores by fire assay methods has been described in Technical Paper 270 of the bureau; ( Davis , C.W. , The detection and estimation of platinum in ores : U. S. Bureau of Mines Tech . Paper 270 , 1921. ) the present paper , which is supplementary to that report , deals chiefly with the application of combination methods , taking them up to the point where the fire assay is to be applied .

Mar 1, 1921

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By Harold E. Marr

The computer program XRF4 was designed by the Bureau of Mines to provide for the calculation of several different interelement correction procedures in X-ray fluorescence analysis, including Lachance-Traill, Rasberry-Heinrich, and Claisse-Quintin procedures. The program was written in the BASIC language for timesharing application, and a conversational interaction with the computer is employed during operation. This report presents test problems using data for iron-nickel-chromium alloys and aluminum alloys and directions for use of the program.

Jan 1, 1976

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989

By E. C. Baker

Costs of disposing of steel slag are estimated based on the present method and a proposed alternate method for a steel mill in the Pittsburgh area. Estimated cost data were calculated by the Bureau of Mines and do not reflect the investment and operating costs and credits of a specific steel mill and processing plant. The alternate method of steel slag disposal would result in an appreciable cost savings to the mill and concurrently supply the industrial and commercial markets with low-cost, high-quality construction materials.

Jan 1, 1970

By Gary W. Krantz

Fibered, portland-cement-based gunite products were applied in the Bureau of Mines Lake Lynn Laboratory Experimental Mine using a variety of pneumatic guns and gunning crews, The demonstrated wet-mix (with silica fume), dry-mix, and surface bonding products were sampled by the Bureau and subjected to a suite of engineering analyses. Gunite flexural and compressive strength, rebound, permeability, porosity, dust loading, shooting rate, crew requirements, and cost factors were evaluated. Steel, fiberglass, or polypropylene fibers were contained in all but two of the gunires tested. Both Bureau and private testing laboratory analyses are provided for some products. Electron probe micro-analysis and X-ray diffraction analysis were performed on the silica fume fraction of the wet-mix gunite to characterize the dust. Aggregate size fraction distribution analyses were performed to provide strength relationships. Results indicate that all of the commercially available fibered-gunite materials tested can provide beneficial sealant, spall prevention, or roof stability control attributes for underground mining environments when applied by an experienced crew using a well-maintained gun, in accordance with product manufacturers' recommendations and when used for the designated purpose.

Jan 1, 1984

By J. W. Horne, W. B. Shirey

"INTRODUCTION The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the noncondensable gases evolved when crude shale oil is distilled under pressure.Hydrogen sulphide is one of the components found in the complex mixture of gases produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills.The study required a complete extraction of all the hydrogen sulphide from the gas stream after it left the water-cooled distillate condensers and before the as stream entered the charcoal absorber for removing the light naphtha. In devising the method it was necessary to take into account a constant variation of velocity, pressure, and percentage of sulphide in the total gas stream coming from the still.Ordinarily, the quantitative determination of hydrogen sulphide in Gas is made by analyzing small samples taken at regular intervals. This estimation can be accomplished by use of the Bunte gas burette as modified by Tutriler,4 or by a similar method. In the industries where the flow of as is constant end of uniform composition, this practice is sufficiently accurate for plant control. For experimental work where many variables have to be taken into consideration, as in the case at hand, these methods are not applicable."

Oct 1, 1931

By R. Hogg

"The problems of sampling particulate materials, and of characterizing the distributions of particle size and composition are reviewed. Requirements for sampling from comminution systems are discussed and a simple formula is presented for estimating the minimum sample size needed. The limitations and errors associated with the techniques available for particle size analysis are evaluated and guidelines are suggested for the selection of appropriate methods. The use of microscopic and macroscopic approaches to the characterization of particle composition are discussed.INTRODUCTIONComminution is a process of particle size reduction in which the goal is to produce a material with a specified particle size distribution from a coarser feed. In mineral processing applications, the product size distribution is often qf secondary importance to the extent to which individual mineral grams can be liberated from one another. However, due to poor understanding of the nature of the liberation process and the lack of reliable procedures for characterizing it, the actual specification is normally in terms of particle size.Particle size distribution can be regarded as the fundamental characteristic of a particulate system. The distributions of particle shape and composition among the various particle sizes present are often sufficient to define the bulk properties and behavior of the system. Description of the distributions of size; shape and composition of the different phases which may exist within individual particles is necessary to complete the picture and is especially important for predicting liberation etc., in comminution processes. It is quite obvious that · the complete characterization of real particulate systems is a formidable, if not .impossible task. Practical characterization procedures should involve ·evaluation of those characteristics which are deemed to be important and which can be measured. In comminution systems, this should ideally include the particle size distribution, the size-by-size distributions of particle composition, and as much information as can be acquired on the internal composition and structure of individual particles. In most cases, of course, we fall far short of even this rather limited goal."

Jan 1, 1988

By D. G. Kesterkel

Low-melting thoriurnrbase binary alloys or metal solutions were prepared by two different techniques involving the electrolysis of ThO2 dissolved in fluoride melts. Experiments were performed at 950° to 1,250° C using electrolytes containing ThF4 and various alkali and alkaline earth fluorides. In the first method, electroreduction of ThO2 and deposition of thorium on a nickel or iron cathode formed a molten alloy that dripped off and collected on the bottom of the cell, or in a tungsten cup. An electrocodeposition technique was used to prepare thorium-base alloys or solutions containing nickel, iron, chromium, or manganese. Electrolytic reduction of the component metal oxides and simultaneous deposition of the two metals on a tungsten cathode yielded a liquid alloy product. Complementary experiments were performed on the fused fluoride electrowinning of dendritic thorium from Th02 at 1,075° to 1,200° C in which thorium crystals were recovered and arc-melted into buttons. Major contaminants were aluminum, carbon, copper, iron, oxygen, and silicon, totaling 0.2 percent.

Jan 1, 1966

By G. L. Oldright

[This paper is the fifth 4/ of a series of publications on smelting in the load blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace by direct experimentation, and to correlate the behavior of the furnace at various tines with the main factors governing the operation of the blast furnace, and metallurgical losses.]

Jan 1, 1929

By A. B. Hooker, J. W. Paul

"There was a time when any suggestion that the Davy flame (safety) lamp be discarded, would have evoked unlimited, criticism. However, that time is past.Investigations both here and abroad have shown conclusively that the Davy lamp does not have the necessary factor of safety against ignitions of mine gas, and England, the lost stronghold of the Davy lamp in Europe, has eliminated this lamp and substituted safer types.In the United States there are companies who still use the Davy lamp in spite of all that has been said and published as to the dangers connected with its use.Recently the purchasing agent of an anthracite coal company requested the Department of the Interior, Bureau of Mines, to pass upon the safety of some braise gauzes for use in a shielded Davy lamp. A shielded Davy lamp is an ordinary Davy safety lamp equipped with a circular brass shield that is attached to the lamp posts. This shield extends about one-half way around the gauze and one-half of the gauze height. The main purpose of the shield is to prevent the lamps being extinguished by a sudden increase in the velocity of the air current past the lamp.The brass gauzes submitted for this test represented two grades of brass - a yellow brass and a red brass. The analysis of these brasses was not determined. Two shielded Davy lamps that were submitted for the tests each had a steel gauze. These steel gauzes were also tested. Tests were made in horizontally moving mixtures of Pittsburgh natural gas and air at velocities of 400 to 1,000 feet per minute. The gas percentages used were 7%, 8.6%, and 11%. Tests were made with the lamp shield in two positions relative to the lamp and direction of flow of the gas-and-air mixture. In one position the shield was between the gauze and flow, as normally used. In the other position the shield was on the downstream side of the lamp. The tests were continued until one or more failures or gas explosions been obtained with each of the six gauzes. The results of these tests summarized as follows:"

Jun 1, 1923

By T. E. Sterner

The Bureau of Mines investigated the use of a chromatographic gas analyzer in determining the concentration of combustion products in gas produced during field and laboratory thermal oil-recovery tests. Several parameters (carrier-gas flow, cell current, sample size, and temperature) known to affect quantitative analyses were studied using a commercially available dual-column, dual-detector chromatographic gas analyzer which had been modified to provide close control of these variables. The apparatus made possible a much closer control of air-and gas-injection rates and provided adequate data for performing material-balance calculations and for determining oxygen utilization during the laboratory and field combustion tests. The chromatographic analysis also aided materially in evaluating and measuring bypassing and gas travel times and in detecting high-permeability zones that were present in the reservoir.

Jan 1, 1965

By J. S. Kennedy, R. G. Omeara

Beryllium is a strategic metal of ever-increasing peacetime importance because of the unusual properties of beryllium-copper alloys. These unusual characteristics are the combination of high strength and hardness, high fatigue resistance, and high wear resistance in alloys that have the corrosion resistance of copper. The principal industrial source of beryllium is the mineral beryl, a beryllium-aluminum silicate that occurs in pegmatites associated with quartz, feldspar, mica, and smaller amounts of various accessory minerals. The beryl is usually recovered in processing the pegmatites for the recovery of some of the other mineral constituents. Pegmatite deposits are found in various parts of the United States, but those in the Black Hills of South Dakota are the source of most of domestic production. The beryl marketed from the South Dakota pegmatite deposits occurs as coarse crystals, which are obtained by hand sorting. These pegmatites also contain other valuable minerals.

Jan 1, 1948

By H. G. Wolfhard

The mode of propagation of explosions through narrow passages is important for understanding flameproofed equipment employed in mines. Narrow channels have been used in this investigation that connected between a small explosion chamber and a large chamber containing fuel-air mixture. The oxygen index of the mixture in the small chamber was determined which caused an explosion in the outer chamber. Preliminary measurements have already been given in Bureau of Mines Report of Investigations 5457 and suggested that) flames do not pass through narrow channels. The hot, burned gases from the explosion in the small chamber, however, are able to ignite the mixture in the large chamber by a process of hot-gas ignition. Systematic measurements are reported in the present paper that cover the influence of channel length and diameter and the properties of the gas mixtures in the large chamber on the transmission of explosions. The influence of such properties as quenching diameter and flame temperature is also discussed. This paper concludes the work on this problem and presents a theory that describes in detail parameters that influence transmission of explosions through narrow channels. INTRODUCTION Flameproofed equipment in mines is usually provided with flanges. A gap between the opposing flanges allows ventilation and release of pressure. The safe gap width has been determined for a number of flange lengths by Smith4/

Jan 1, 1959