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By S. M. Runke

[The coarse-grained granitic pegmatities of the United States have long been a source of many important industrial minerals, because of this, they have been studied intensively by geologists, mining engineers, end metallurgists. These studies have amassed a rather astounding array of published and unpublished information. Correlation of geological studies between individual pegmatites, as well as between major districts, has brought fort come semblance of order to the knowledge of the structure and mineralogical composition of those highly complex and irregular deposits, making it possible to classify certain pegmatites and pegmatitic zones into several grouts of associated minerals, based upon the presence or absence of the minor minerals of beryllium and lithium. This classification or trouping of minerals, with the methods that have been developed for recovering certain of these minerals, possible a systematic approach to the winning of many of the industrially important minerals from pegmatite rock by u single integrated process.]

Jan 1, 1952

By William S. Roberts

The Bureau of Mines has initiated a program to determine the availability of land for mineral exploration and development in Alaska. Researchers involved in this pro-gram are comparing land availability, based on ownership and government policies and regulations, to the distribution of known mineral deposits and terranes. This report on southeastern Alaska presents the findings of the first of six regional studies that will cover the State. The study consisted largely of data compilation and analysis using various mapping techniques. Summary land availability data are presented on copies of U.S. Geological Survey (USGS) quadrangles at a scale of 1:500,000. Five categories of land availability were identified: open to mineral exploration and development (approximately 9.4 million acres, or 38% of the 24.8-million-acre study area), open but with possible use restrictions (4.2 million acres, or 17%), selected (0.5 million acres, or 2%), patented (0.74 million acres, or 3%), and formally closed to mineral exploration and development (10 million acres, or 40%). Of the 1,187 known mineral deposits in the study area, approximately 38% are on land in the open category. Mineral terranes comprise approximately 6.7 million acres, or 27% of southeastern Alaska. Approximately 34% of these terranes are on open land.

Jan 1, 1985

Capture airborne coal dust generated by a continuous mining machine to reduce workers? dust exposure and to improve face visibility. Approach Develop a low-profile dust collector system which can be mounted on the boom of a continuous miner. How It Works When coal is mined with a milling head continuous miner, a substantial amount of coal dust (respirable and non-respirable) escapes the dust suppression sprays at the cutter head. This can cause poor visibility around the cutting head and can expose the workers to high levels of respirable dust. A practical means of removing this dust is with a scrubber mounted directly on the mining machine. Under a Bureau of Mines contract, a low-profile, machine-mounted dust collector (MMDC) was developed to avoid adding extra height to the continuous

Jan 1, 1983

By R. W. Van Dolah, N. E. Hanna, F. C. Gibson

Measures that were taken to eliminate noise resulting from explosives work at the Bureau of Mines facility at Bruceton , Pa . , are described . A method for monitoring sound transmission characteristics of the atmosphere and control of the explosives testing is presented as a noise control measure that offered partial relief during the period in which the modifications were made . Design details of the replacement gallery , used for permissibility testing of explosives , and the modifications of four types of bombproofs are given . Operation of the closed facilities are completely satisfactory , and the noise problem has been entirely eliminated .

Jan 1, 1964

By A. Sainato, S. J. Schatzel, D. M. Hyman, J. C. LaScola

The Bureau of Mines determined the gas contents of 135 oil shale samples obtained from approximately 630 ft of core drilling. Drilling was done within a projected mining zone of the Cathedral Sluffs Mine, located in the Piceance Basin of western Colorado. Methane contents were determined by the modified direct method, which can measure the volumes of several gases released from or reacted with mine rock without destructive sample treatment. Over the duration of the test, nitrogen was largely unreactive, CO2 increased slightly, oxygen decreased markedly, and methane increased more than the total increase of all contained gases. The gas volumes were normalized per unit sample mass and are given in cubic centimeters per gram. Common time irzdices for test duration of 3, 40, and 125 days were used to compare methane desorption among samples. The means of the sample populations for these indices were 0.0316, 0.114, and 0.195 cm3/g, respectively. These quantities are lower than those reported in a Bureau emissions study at the Horse Draw Mine in the Piceance Basin. Oil shale samples that were gas enriched beyond the mean methane contents frequently contained bitumens and pyrite.

Jan 1, 1987

By J. W. Miller

Depletion of coals most suitable for metallurgical fuel has nude necessary a general survey of coking-coal reserves in the United States. These investigations were begun in 1948 at the joint request of the Munitions Board, Department of Defense, and a number of coal companies. This report, which is one of a series, by counties, describes the preparation characteristics of the coals of Letcher County, Icy. From these data it is possible to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are suitable under present standards for producing metallurgical coke, (b) which coals require special and more intensive treatment in preparation than is now practiced, and, (c) which coals cannot be upgraded by known commercial preparation methods to metallurgical fuel standards now accepted.

Jan 1, 1955

By A. F. Colombo

The western Mesabi range nonmagnetic taconites containing about 34 percent Fe were evaluated by the Bureau of Mines in a 900-pound-per-hour pilot plant employing a selective flocculation-desliming-cationic flotation technique. The flotation step was a reverse flotation process and involved the flotation of the gangue minerals. The objective of the research was to increase the availability of domestic raw materials for the iron and steel industry. The beneficiated ores yielded concentrates containing 62 to 64 percent Fe and less than 5.5 percent Si02 with accompanying iron recoveries that averaged about 75 percent. Comparable flotation results were obtained with either fresh or 80 to 90 percent reclaimed water. Recycled waters having turbidities as high as 5,000 ppm Si02 did not affect the flotation process. Reclaimed waters containing residual calcium contents of less than 10 ppm gave better flotation concentrates than those containing 15 ppm.

Jan 1, 1976

By K. K. Kelley

Despite the wide interest in titanium and its compounds, no heat and free-energy-of-formation values for titanates (that is, compounds formed from titania and other metal oxides) have been available heretofore except for ilmenite (FeTi03). Such data are needed for understanding and developing processes for producing titania and titanium tetrachloride from ores (and possibly slags) and in connection with ceramic usage of titania. This paper reports experimental measurements of the heats of formation at ordinary temperature of 11 titanates-ilmenite, perovskite, barium metatinate, strontium metatitanate, barium-strontium metatitanate, barium orthotitanate, strontium orthotitanate, barium-strontium othotitanate, geikielite, magnesium-titanium spinel, and magnesium dititanate. The experimental method was solution calorimetry. The solution calorimeter was operated at 73.7°C. and used a strong hydrofluoric-hydrochloric acid mixture as the calorimetric fluid and reaction medium.

Jan 1, 1954

By John C. Holtz

"INTRODUCTION Information on the gaseous products from the detonation of explosives has been obtained in two ways. In the first, the atmosphere in mines is analyzed after blasting, and in the second, the gases found after detonating an explosive in a testing apparatus are analyzed. The Bureau of Mines, in a cooperative research 3/ that compared data obtained in the field with those obtained in the testing station, showed that the results were not in entire agreement. The production of carbon monoxide was found to be governed chiefly by the oxygen balance of the explosive, but the production of oxides of nitrogen did not change in so simple a manner. Because of the increasing interest in correlations between the composition of the explosive and the production of toxic gases, it seemed desirable to continue the investigation.PURPOSE OF INVESTIGATIONAs field tests are both time consuming and expensive and as field results are affected by factors that are not always under control of or clearly evaluated by the operator, the purpose of this investigation is to develop a testing-station procedure that will reproduce the gaseous products quantitatively under known conditions analogous to those that may be expected in the field. In addition, the factors affecting the formation of toxic gases, particularly oxides of nitrogen, will be studied,"

Apr 1, 1940

By G. L. Hundley

The Bureau of Mines has devised a procedure to recover chromium chemicals from concentrates derived from low-grade domestic chromites. These domestic chromites contain silicon and aluminum impurities at levels that are too high to permit processing by present industrial processes. The Bureau procedure consists of reacting chromite with molten NaOH under oxidizing conditions to form sodium chromate (Na2Cr04)' The reaction product is leached with methanol to recover the majority of the unreacted NaOH, then with water to extract the Na2Cr04 and the remainder of the NaOH. The Na2Cr04 product is recovered by evaporative crystallization from the aqueous solution. This report presents laboratory results of studies to determine the optimum leaching conditions for the reaction products of several domestic chromite concentrates. Results of solution purification and crystallization studies are also presented. The concentrates are from a variety of sources including the Stillwater Complex in Montana, Red Bluff Bay and the Kenai Peninsula in Alaska, and a Ni-Co laterite from southern Oregon. Sodium chromate crystals were produced that contained less than 0.01 pct NaOH.

Jan 1, 1988

By R. R. McLellan

The Brown Derby pegmatites are in Gunnison County, Colo., about 18 miles east of Gunnison. Approximately 860 tons of lepidolite concentrates, with smaller amounts of microlite and beryl, was produced from 3 dikes of the Brown Derby group from 1943 through 1947. No mining was done from 1948 until December 1950, when production of lepidolite and beryl was resumed by the Poston Mining & Milling Co. Mining was intermittent during 1951 and 1952. The dikes were mapped and studied by the Federal Geological Survey during the field seasons of 1942 to 1944, and in May 1950 the Bureau of Mines initiated a diamond-drilling project to test the three dikes for lepidolite and beryl. After being recessed twice, the project was terminated indefinitely July 1951. Seven drill holes were completed for a total of 1,841.6 feet of drilling.

Jan 1, 1956

By Roy L. Grant

The Bureau of Mines investigated the up-and-down method with factorial designs to determine if shorter, and therefore less costly, trial sequences could be used. Although sequences of 50 trials are usually recommended, sequences of 20 trials were arbitrarily chosen for the experiments with permissible coal mine explosives described in this report. These explosives were fired from a cannon pointed into a flammable natural gas-air atmosphere at the Bureau of Mines Explosives Research Center gallery to ascertain their safety properties. The investigation demonstrated that the shorter sequences led to useful conclusions with a reduction in cost of the experimental program.

Jan 1, 1967

By Raghoottma S. Pandurangi, Mohindar S. Seehra, Pedro Bolsait, Bronwyn L. Razzaboni

"Surface IR (infrared) modes of crystalline and fumed (amorphous) silica particles, calcined at temperatures up to 1095°C, have been studied by Fourier transform infrared spectroscopy. The ability of these same particles to lyse cells has been measured by a hemolysis protocol. The untreated crystalline and amorphous materials differ by a factor of 40 in specific surface area, and the intensity per unit mass of the sharp surface silanol band near 3745 cm-1 in the amorphous material is an order of magnitude larger than in the crystalline material. A similar difference is observed in the lysing potential of the two materials. The intensity of the silanol band increases after calcination for both materials, reaching peak values near 500°C, followed by a dramatic drop at higher calcination temperatures, and reaching negligible values for materials calcined near 1100°C. The lysing potential data follow essentially the same pattern for both crystalline and fumed silica. These results are consistent with the hypothesis that the surface silanol groups are involved in cell lysis. Further experiments are suggested to evaluate the relationship between the surface structure of ailica particles and their potential cytotoxicity. IntroductionThe characterization of the surface structure of various allotropic forms of silica is of interest because the cytotoxicity of silica particles of respirable size has been commonly related to the chemical interaction of functional groups on the surface of such particles with the lipoproteins contained in cell membranes (1-3). It has been found that the cytotoxic potential of silica particles varies greatly with their crystalline structure (4,5), particle size (6-8), surface composition (9), and molecular surface configuration (1,10). Studies of the infrared (IR) modes of various forms of silica have been reported by a number of researchers (3 ,11-19). Several books and reviews (20-24) have dealt with the identification of functional groups on silica surfaces and the effect of heat treatment on the surface structure. The nature of the surface is said to be critical in determining the biological activity of silica dusts (3).Fourier transform infrared (FTIR) spectroscopy is a highly sensitive ·technique for identifying IR surface modes of tine particulates, and it was deemed of interest to examine the surface structure and its relation to lysing potential of two widely different types of respirable silica dust. The lysing potential of respirable dust particles has been considered a first-level test for potential cytotoxicity."

Jan 1, 1990

By Clayton M. Rumsey

The U.S. Bureau of Mines investigated prospects and mineralized areas in and adjacent to the Indian Pass and Picacho Peak study areas in 1983 and 1984. The Indian Pass study area contains 33,640 acres and the Picacho Peak study area contains 5,450 acres. The study areas are located in the southeast corner of California and are underlain by Precambrian gneiss, Pre-Tertiary metavolcanic and metasedimentary rocks, and Tertiary volcanic and non-marine clastic rocks. Low-grade gold-silver resources may be present in hydrothermally altered gneiss in the upper plate and altered schist in the lower plate of the Chocolate Mountain thrust fault. The thrust fault is exposed in the study areas for about 3.5 miles west and 5 miles east of Indian Pass. Mineralized zones in the thrust plates were not discovered until 1983. Earlier prospecting explored areas containing minor copper carbonate occurrences in schist and sedimentary and volcanic rocks that are younger than the thrust. Twenty-three mines, prospects, and mineral occurrences inside the study areas and fourteen outs; de were examined for this study. These surficial copper occurrences have been prospected extensively in the study areas; large areas have been scraped, pitted, and trenched by bulldozers. However, they appear to be of limited economic significance. Slightly mineralized zones are in the northwest part of the Indian Pass study area where granite contacts sedimentary and volcanic rocks.

Jan 1, 1986

By R. M. Santmeyers

This paper presents one of a series of digests of foreign mining legislation and curt decisions that is being prepared in advance of a. general report relative to the rights of American citizens to explore for minerals and own and operate mines in various foreign countries. This interpretation of the mining legislation of Madagascar was prepared from the best information (in French) available in Washington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers, to whom it dill be referred through the courtesy of the Department of State. INTRODUCTION The basic mining law of Madagascar is the decree of 1923, signed at Rambouillet by the President of France on July 19, and published in the Journal Official de Madagascar et Dependances. It has been modified by a number of subsequent laves and regulations, generally of minor importance.

Jan 1, 1933

By K. S. Gritton

The Bureau of Mines investigated the feasibility of numerlcally modeling the sorption of cobalt, a vulnerable strategic and critical metal, from spent copper leach solutions in a multiple-compartment ion-exchange (MCIX) column. Equilibrium resin loadings, cobalt-sorption kinetics, and resin-fluidization characteristics were determined in simple laboratory tests, and a numerical model was developed to predict cobalt extraction and the MCIX-column resin inventory based upon the test results. The model was implemented on a microcomputer to approximate the solution to the set of differential equations that govern model performance. Results compared very well with data from 12 pilot-scale MCIX-column experiments. The average difference between predicted and actual cobalt extractions was 3.2 pct; the maximum difference was 9.3 pet. The actual and predicted resin inventories differed by an average of 5.8 pet, and the maximum difference was 12.0 pct.

Jan 1, 1987

By Suresh K. Bhatt

Although overall worker productivity for U.S. underground coal mines is available, productivity by mining method and seam thickness is not. Mining technology has gone through dramatic changes in the past decade, and the industry has experienced a lack of accurate productivity Figures addressing these changes. This information is of great interest in planning for future mining systems as thick and shallow coal seams currently being mined are depleted and exploitation of thinner, deeper, and better quality seams is considered to partially meet the requirements of the 1990 Clean Air Act Amendments. In a cooperative program, the U.S. Bureau of Mines obtained raw mine level production and related data from U.S. Energy Information Administration for 1989 and 1990 and performed the needed statistical analysis. Base criteria, parameters, and salient results of the mine productivity analysis are presented in this report.

Jan 1, 1994

By IRENE AITKENS

The emerald is the most costly of all gems , due to the scarcity of flawless stones . This fact gave rise to the ancient axiom , " As rare as an emerald without a flaw . The finer gems not only command the highest prices at all times , but when flawless are considered the most highly prized of all gem stones . George F. Kunz divides emeralds into two distinct classes : " Exceptional specimens , " which bring as much as $ 6,000 a carat ; and " fine- quality specimens , " which bring about $ 1,000 a carat .

Jul 1, 1931

By Edward D. Thimons

This Bureau of Mines report presents expected levels of air pollutants in the face areas of oil shale mines, based upon data collected by the authors and previous investigators. Ventilation requirements to maintain these pollutant levels below their threshold limit values and Federal and local mine air quality standards are discussed. Two practical face ventilation systems are discussed in terms of actual in-mine test experience.

Jan 1, 1986

By Seth C. Schaefer

The Federal Bureau of Mines studied the Gibbs free energies of formation of chromous fluoride (CrF2), chromic fluoride (CrF3), and chromium (II,III) fluorides (CrF2.40 and CrF2.45) with high-temperature galvanic cells employing calcium fluoride doped with 1 mole-pct yttrium fluoride as the electrolyte. Free-energy changes were obtained from open-circuit potential measurements for the following cells: Cr, CrF2 // CaF2 // NiF2, Ni (a) NiO, NiF2 // CaF2 // CrF3 , Cr203 (b) CrF2 , CrF2.40 // CaF2 // NiF2, Ni (c) and CrF2 ?45 , CrF3 // CaF2 // NiF2, Ni (d) with the following overall reactions Cr(s) + NiF2 (s) = Ni(s) + CrF2 (s) (1) 3NiO(s) + 2CrF3 (s) = 3NiF2 (s) + Cr203 (s) (2) 5CrF2 (s) + NiF2 (s) = 5CrF2.4O (s) + Ni(s) (3) and 3.64CrF2.45 + NiF2 (s) = 3.64CrF3 (s) + Ni (s) . (4) These results were combined with the best available literature values of ?Gf° of NiF2, NiO, and Cr203 to deduce Gibbs free energies of formation for the chromium fluorides expressed as follows: ?Gf°(CrF2) = -179.31 + 24.33 X 10-3T ± 0.43 kcal-mole. (5) (858.1 - 964.9 K) ?Gf° (CrF3) _ -226.16 + 1.82 X 10-3T ± 0.79 kcal/mole (6) (880.8 - 957.8 K) ?Gf°(CrF2.40) _ -213.65 + 32.14 X 10-3T ± 0.44 kcal/mole (7) (0053.9 - 936.8 K) and ?Gf°(CrF2.45) _ -176.17 - 12.67 X 10-3T ± 0.80 kcal/mole (8) (875.1 - 937.6 K). Free energies and equilibrium fluorine pressures for three univariant and one bivariant equilibria are illustrated.

Jan 1, 1976