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By W. A. Calhoun

This investigation of low-grade bauxites as potential sources of aluminum by caustic desilication and alumina extraction was undertaken by the Bureau of Mines to develop extractive methods for winning alumina from domestic deposits of low-grade bauxites. This report is the second of a series covering the work by the Bureau of Mines' Rolla, Mo., and Bauxite, Ark., laboratories. The first report published in the Journal of Metals, December 1951,3/ and dealt with kaolin and halloysite. The present investigation is concerned with low-grade bauxites only. The purpose of these investigations is to increase the domestic supply of aluminum ores. With eventual depletion of high-grade deposits, aluminous materials, such as low-grade bauxite, clays, shales, and high-iron laterites, will become our principal domestic sources of aluminum. The development of extractive processes for winning alumina from these low-grade materials is one of the many national security measures undertaken by the Bureau of Mines. A method has-been developed in the laboratory for successfully treating high-silica bauxites from domestic deposits. In this process the bauxite was calcined at 980° C. to form amorphous silica and alumina. The calcine was then leached by percolation with 15-percent sodium hydroxide solution at 940 to 96° C., removing 67 to 77 percent of the silica with a loss of 4.1 to 5.0 percent of the alumina. The sodium hydroxide in the spent liquor used in desilication was 95 percent recoverable, and comparable desilication results were obtained with 100-percent reclaimed liquor, The indicated cost of reagents, for sodium hydroxide and lime used in the desilication and regenera¬tion of spent liquor, was about $4.00 per ton of calcine treated.

Jan 1, 1954

By W. W. Adams

[The quantity of explosives sold in the United States in January, 1931, for domestic consumption, amounted to 368,100 kegs (9,202,510 pounds) of black blasting powder, 4,810;000 pounds of permissible explosives, and 16,533,000 pounds of high explosives other than permissible. These figures are based on reports received by the United States Bureau of Mines, Department of Commerce, from nearly all manufacturing companies, and include an estimate of sues by several companies that do not furnish monthly reports. Reports actually received from manufacturers shored sales of 365,977 kegs of black blasting powder (consisting of 220,892 kegs of granular powder and 145,085 kegs of pellet powder), 4,687,900 pounds of permissible explosives, and 15,498,152 pounds of high explosives other than permissible. Sales in January, 1931, were smaller than in January last year, the decreases being 14 per cent for black blasting powder, 19 per cent for permissible, and 17 per cent for high explosives other than permissible. Sales in January 1931 when compared with soles in December 1930, show increases for all three classes of explosives as follows: 2 per cent for block blasting powder, 16 per cent for permissible explosives, and 7 per cent for other high explosives. PERMISSIBLE EXPLOSIVES: Of the 4,687,900 hounds of permissible reported sold during January, 97 per cent was used for coal-mining operations, Including 32 per cent for anthracite mines and 65 per cent for bituminous mines. The following Staten were the largest users of permissible explosives daring January: Pennsylvania, West Virginia, Illinois, Alabama, Kentucky, Indiana, and Utah. Their combined sales represented 89 per cent of the entire sales reported for this class of explosives.]

Jan 1, 1931

By W. W. Adams

The quantity of explosives sold in the United States in January, 1931, for domestic consumption, amounted to 368,100 kegs (9,202,500 pounds) of black blasting powder, 4,610;000 pounds of permissible explosives, and 16,533,000 pounds of high explosives 'other than permissible. These figures are based on reports received by the United States Bureau of Mines, Department of Commerce, from nearly all manufacturing companies, and include an estimate of sales by several companies that do not furnish monthly reports. Reports actually received from manufacturers showed soles of 365,977 kegs of black blasting powder (consisting of 220,892 kegs of granular powder and 145,085 kegs of pellet powder), 4,687,900 pounds of permissible explosives, and 15,496,152 pounds of high explosives other than permissible. Sales in January, 1931, were smaller than in January, last year, the decreases being 14 per cent for black blasting powder, 19 per cent for permissibles, and 17 percent for high explosives other than permissible. Sales in January 1931 when compared with soles in December 1930, show increases for all three classes of explosives as follows: 2 per cent for black blasting powder, 16 per cent for permissible explosives, and 7 per cent for other high explosives.

Jan 1, 1931

By L. Garner McDonald

The U.S. Bureau of Mines, under contract to the U.S. Department of Energy, investigated the erosive-wear properties of seven commercial alloys with potential applications as valves for coal-conversion plants. A dry particle, jet-erosion apparatus was used to determine the wear of seven materials: 316 and 440-C stainless steels, K-68, K-701, and K-801 cemented tungsten carbides, HC-250 white cast iron, and Haynes 6B. The alumina abrasive entrained in the nitrogen gas jet had particle sizes of 27 or 50 µm, the abrasive velocities were 55 to 170 m/s, and the particle impingement angles were 15° to 90°. The maximum specific wear for ductile materials was found to occur at impingement angles of 15° to 30°, and the minimum specific wear occurred at 60° to 90°. For the brittle materials, maximum specific wear occurred at impingement angles of 50° to 85° and minimum specific wear was at the lowest angles. As the velocity and erosive particle size increased, the specific wear increased. The specific wear was related to the velocity by the power function WocAVn, where n was 1.8 to 3.9 for ductile materials and 1.8 to 3.6 for brittle materials.

Jan 1, 2010

By D. C. Dahlin

The U.S. Bureau of Mines investigated the magnetic susceptibility of minerals as a function of mag-netic field strength to determine how it might affect the potential for high-field magnetic separation as an alternative to other separation technologies. Single-mineral concentrates were prepared from specimens from the same deposit to compare magnetic susceptibilities of minerals that occur together and from specimens from different deposits to compare magnetic susceptibilities of like minerals. A vibrating-sample magnetometer with a superconducting magnet capable of producing a magnetic field of 7.16 x 106 Aim (90 kOe) was used to measure the magnetic moment of the samples. The data were then converted to specific magnetic susceptibility data and plotted as a function of magnetic field strength. Cursory studies were also completed on the effects of iron content and oxidation roasts on magnetic susceptibility in high fields. The results showed that magnetic susceptibility is essentially constant in magnetic fields above those needed to saturate ferromagnetic constituents. Although magnetic susceptibility is influenced by iron content and by thermal treatment, the changes are not large enough to influence separations in fields above 1.59 x 106 Aim (20 kOe).

Jan 1, 2010

By D. P. Lindroth

The Bureau of Mines is engaged in research on ground probing radars for detection of geologic hazards in advance of mining. Penetration distances and interpretation models depend on the dielectric properties and wave propagation characteristics for coal measure stratified media. Relative dielectric constants and dissipation factors were measured under ambient conditions for Pittsburgh Seam coal measure rock over the frequency range of 20 to 100 MHz by the susceptance-variation method. The rock types measured were representative sedimentary rock located above the Pittsburgh Coal Seam. Extreme values for the computed attenu-ation distance ranged from 1.7 m at 100 MHz for siltstone to 230 m at 20 MHz for a particular limestone.

Jan 1, 1984

The Bureau of Mines has conducted considerable research to improve life support technology for underground mining applications. This proceedings volume presents several new developments that may help increase the chances of mine workers in surviving underground disasters. Several papers address the performance of present self-contained self-rescuers (SCSR's) and provide proposed guidelines for the design and testing of a second-generation SCSR. Improvements In the safety and effectiveness of mine rescue and recovery operations are described, including the design of a low-profile rescue breathing apparatus and a rescue team helmet.

Jan 1, 1987

By E. J. Kloos

One phase of the work of the Bureau of Mines in health and safety is promoting the use of safe, satisfactory, and reliable respiratory-protective devices. To insure that such devices will be available, the Bureau has established schedules of minimum-performance requirements for the approval of self-contained breathing apparatus (1),4/ gas masks (2), supplied-air respirators (hose masks, air-line respirators, and abrasive-blasting helmets, hoods, or masks) (3), dispersoid (dust, fume, and mist) respirators (4), and nonemergency gas respirators (chemical-cartridge respirators) (5). Approval tests of self-contained breathing apparatus are conducted by Health and Safety District B; approval tests of other types of respiratory-protective devices are conducted by the Branch of Health Research. Manufacturers of respiratory-protective devices may submit their equipment to the Bureau of Mines for approval under the requirements of these schedules. If the device, when tested by the Bureau, meets the schedule requirements, a certificate of approval will be granted, which not only states that the equipment has passed the schedule requirements but also gives information about the limitations of the device. If it is found at any time that approved devices do not meet the requirements of the pertinent schedule, the Bureau may rescind approval.

Jan 1, 1959

By E. L. Singleton

The electrochemical reduction of aluminum chloride to aluminum was investigated in a closed, two-compartment cell utilizing a molten chloride electrolyte. The externally heated cell was divided into a reduction compartment and a combination AICl3 feed and metal removal compartment. Aluminum was deposited at 700° C on a molten aluminum catbode from a KCI-NaCI-AICI3 electrolyte. The AICl3 content of the electrolyte was replenished by either vapor or solid additions. The chlorine evolved was collected and measured to give a quantitative evaluation of AICl3 reduction. The effects of anode and cathode current densities and AIC13 concentration on anode current efficiencies were studiedo A range of 64 to 84 percent anode current efficiency was obtained with the 25-pound electrolyte capacity cell and related auxiliary equipment.

Jan 1, 1968

By Martin H. Stanczyk

The Bureau of Mines studied continuous closed-circuit attrition grinding of a coarse commercial filler-grade kaolin to produce paper-coating-grade clay having a particle size analysis of at least 70 percent minus 2-micron equivalent spherical diameter (esd). The coarse clay, containing about 12 percent minus 2-micron-esd material, was ground in a Bureau-developed 10-inch-diameter attrition grinder in closed circuit with a 5-foot-diameter bowl classifier. In the best test, a finished product containing 82.7 percent minus 2-micron-esd material was obtained when grinding 20 pounds of raw clay per hour at percent solids with a 100-percent circulating load. Energy consumption was about 341 kilowatt-hours per ton of clay feed, or 487 kilowatt-hours per ton of minus 2-micron-esd material produced. Closed-circuit grinding gave some-what greater particle size reduction and lower energy consumption than either batch or continuous open-circuit grinding.

Jan 1, 1965

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010

By B. D. Nash

The Bureau of Mines continued its research into the recovery of fluorine by the phosphoric acid acidulation defluorination of phosphate rock concentrates. A small process development unit with a capacity of about 10 kilo-grams of charge per hour was operated, and concentrates from both Idaho and Florida were processed. Over 80 percent of the fluorine was evolved and recovered as a dilute fluosilicic acid solution. Phosphate extraction from the concentrates always exceeded 98 percent. The fluorine was converted to a synthetic fluorspar product (3CaFa?SiOa) suitable for use as a slag conditioner in electric furnace steelmaking operations.

Jan 1, 1977

By R. A. Beall

This paper summarizes the development of a furnace for producing titanium castings. The general problem is outlined and chronological details are given on the construction and operation of four different casting furnaces, all utilizing consumable-electrode arc heating and water-cooled copper crucibles. Of the two methods of pouring, the tilt-pour technique has been more satisfactory than bottom tapping. Mold design, electrode fabrication, and deep-pool production are discussed. INTRODUCTION In the early summer of 1953 the Bureau of Mines was contacted by the Department of the Army through Watertown Arsenal to explore the possibility of conducting research on casting titanium metal. The objective of the program was "to develop a technique for producing formed castings of titanium metal not less than 40 pounds in weight and without introduction of deleterious contamination."

Jan 1, 1956

By Arthur B. Johnson

The Bureau of Mines investigated the concentration characteristics of high-clay sylvinite ores from four potash companies operating in the Permian Basin near Carlsbad, N. Mex. These ores, containing 13 to 22 percent K20 and 3 to 7 percent clay slimes, cannot be effectively processed by current commercial flotation methods because of their high slime content. A solution to this problem was shown to be the use of two-stage moderate scrubbing conditions and washing of the ore as opposed to strenuous attritioning. Bench-scale physical beneficiation techniques for recovering potash minerals and the development of ore-dressing systems by flotation resulted in obtaining acceptable product grades and recoveries. By using a coarse grind, emphasis was placed on production of premium granular and coarse products. Flotation results showed that concentrates of 58.7 to 60.4 percent K20 with recoveries of 71.0 to 83.4 percent 0f the K20 values can be obtained.

Jan 1, 1971

By Robert S. Warfield

The Federal Bureau of mines and U.S. Geological Survey conducted exploratory investigations and geologic mapping in the Wishbone Hill district of the Matanuska coalfield almost continuously from 1942 through 1958. These investigations delineated reserves of high-volatile bituminous coal necessary to supply the rapidly expanding military and civilian requirements in the Anchorage area. This report describes the program conducted by the Bureau of Mines from 1949 through 1958, and briefly summarizes previous investigations, the results of which have already been published. The coal-bearing structure on both the north and south limbs of the prominent Wishbone Hill syncline was explored by 8,719 feet of churn drilling and 25,460 feet of diamond-core drilling. A total of 33 holes were drilled ranging in depth from 60 to 2,114 feet. To supplement the drilling operations, bulldozer and dragline trenching were undertaken at key locations; about 25,000 cubic yards of dragline trench were excavated in the vicinity of the old Premier mine.

Jan 1, 1962

By Richard D. Miller

The helium resources base of the United States was estimated by the U.S. Bureau of Mines (Bureau) to be 894.6 Bcf as of January 1, 1989. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 282.4 Bcf, (2) helium in probable natural gas resources, estimated at 237.7 Bcf, (3) helium in possible natural gas resources, estimated at 263.1 Bcf and (4) helium in speculative natural gas resources, estimated at 111.4 Bef. These helium resources are further divided into depleting and nondepleting, with the helium in storage being in a classification. The depleting resources are those associated with natural gasfields that are, or will be produced for the natural gas they contain. Almost all of the helium in potential (probable, possible and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 775 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, i.e., those in shut-in, abandoned, or otherwise nonproducing natural gas fields, are estimated to total 84 Bcf There is 35 Bcf of helium in storage in the Federal Government-owned Cliffside Gasfield near Amarillo, TX.

Jan 1, 1990

By Scott A. Stebbins

This Bureau of Mines publication presents a method for estimating capital and operating costs associated with the exploration, mining, and processing of placer deposits. To ensure representative cost estimates, operational parameters for placering equipment and basic principles of placer mining techniques are detailed.

Jan 1, 1987

By Robert L. Rough

This report presents the results of an investigation by Federal Bureau of Mines engineers of water-injection projects in the northwestern Pennsylvania and southwestern New York area, where oil-producing wells have been converted from pumping to flowing. Data from 24 leases converted to flowing were collected and examined. Only 10 leases had information of significant scope for inclusion in the final analysis. The projects were classified in one of two categories. Group I consisted of leases operated to permit an evaluation of operational changes in terms of existing pressure differentials between injection and producing wells. Group II included remaining properties, for which enough information was available to justify an economic analysis but which did not have sufficient production data to support an engineering study because of radical changes in operational techniques. Variations in production and costs resulting from conversion to flowing were examined for production methods, well-spacing and completion techniques, and reservoir characteristics. Where water-injection rates were constant, oil production usually decreased rapidly at the time of conversion; production then increased slightly for 6 to 8 months before resuming a normal decline rate considerably below the estimated pumping rate. The abrupt decrease in production after conversion is indicative of lower pressure differentials between injection and producing wells, caused by the increased hydrostatic head in the producing wells.

Jan 1, 1960

By W. W. Adams

Because of insufficient funds for printing, the Bureau of Mines was unable to publish its annual bulletin covering accidents at metal mines in the United States for the year 1933. A brief mimeographed summary of the principal statistical data for that year was released to the public late in 1934. Since then reports for 1934 have been received from the mining companies, and in order to avoid further delay in releasing this information to the mining industry and others interested in the prevention of accidents in mining, statistics for both years are presented in this publication with a minimum of interpretation and comment. The fatal-accident rate for the metal and nonmetallic mines (excluding coal mines) of the United States was more favorable in 1933 than in any previous year since 1911, the first year for which the Bureau of Mines obtained reports from the operators. Further progress was made in 1934, when the fatality rate was even lower than that of 1933. On the other hand, the nonfatal-accident rate, which had reached its lowest level in 1932, increased in 1933 and increased further in 1934, although not to such an extent as to prevent the rate for either of those 2 years from being better than that for any year previous to r1931.

Jan 1, 1936

In this U.S. Bureau of Mines report, in situ vat leach mineral recovery system concepts are described and cost compared with conventional mining and pad and autoclave leach processing systems. In the proposed systems, leachable ores are enclosed in place in reagent-impermeable in situ vat constructions. The ores are then rubbled and flood leached or flood oxidized and leached. The in situ vats are called stope leach or stope autoclave vessels. The report also proposes ore body-adjacent in situ vat constructions containing rechargeable processing stopes. A series of ore body-specific, innovative, and conventional mineral recovery systems case study designs are described and prefeasibility level costed. Based on a comparison of these prefeasibility level cost estimates, the proposed systems are determined to be economically competitive with conventional min¬eral recovery systems. The in situ vat leach mineral recovery systems concepts for leachable and refractory ores are developed around the drill-split narrow-vein and longwall mining methods described in part 1 of this Information Circular series.

Jan 1, 1995