Search Documents

By F. C. Araújo, T. Tavares, J. Leite

"This work presents the small-scale mining cluster of kaolin in Rio Grande do Norte (RN) and Paraiba (PB), both Brazilian states, including the following information: number of companies, process flowcharts, production numbers, mineralogical (XRD) and chemical (XRF) composition, granulometric distribution (screen and laser granulometer) and image analysis (SEM). Some social indicators in the region of the RN and PB States are presented in association with these data. The number of companies and their flowsheet were obtained through in situ visits and sample collection for technological characterization. The comparative study of the different flowsheets for kaolin production in the world was done using the databases and presenting the state of the art of kaolin processing. The results indicated that the mean feed typically contains 35-39% kaolin with quartz, muscovite and kaolinite as main mineralogical components and SiO2 (65.83%), Al2O3 (21.19%), K2O (3.9%), and Fe2O3 (0,63%) as main chemical constituents. The products of mineral processing are twofold, one between 74 µm and 37 µm, and the other smaller than 37 µm. The wastes of operation had major quantities of kaolin. The average Human Development Index (HDI) of the cluster region is approximately of 0.61, which shows an association between mineral processing plant and social indicators. The kaolin recovery, however, is between 30-55% for the three most common types of flowsheets that are currently used in the small kaolin mining cluster, indicating a need for technological improvement to achieve regional development. These data could be used incrementally to adapt the process plant currently used in the small-scale mining cluster of kaolin."

Jan 1, 2014

The ultimate goal of a mineral processing plant is to recover as much of the target mineral(s) as possible from the ore being treated to achieve the best economics. Selection of the mineral processing techniques is the most important step in achieving this goal. However, due to the complexity of the ore, the recoveries of valuable minerals may be not satisfactory even when the mineral processing technique(s) are well chosen. In other words, minerals of interest can be lost to the tailings for mineralogical reasons. For example, gold is mainly extracted from the ore by gravity, flotation, cyanidation, or a combination of these processes, and high recovery (>90%) can be achieved when gold occurs as coarse grains. However, when a refractory ore is being processed, gold extraction will be challenged by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery mainly include grain size, shape, surface coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking in sulphide, silicate and other minerals as fine-grained gold inclusions and/or as invisible submicroscopic gold is by far the most common factor leading to poor gold recovery encountered in gold ore processing. Processing of PGE ores faces the same challenges as gold. Small grain size and locking of PGM in sulphide and non-sulphide minerals often cause PGM losses. When silver ore contains significant amounts of pyrargyrite, proustite and stephanite, silver recovery by cyanidation can be very low because of the slow dissolving kinetics of these minerals. In the processing of base metal ores, high content of pyrite, intergrowth of chalcopyrite with sphalerite and presence of clay miner-als may cause problems in recovering Cu-, Pb- and Zn- bearing minerals. Process mineralogy helps address all issues and problems related to mineral processing with predicting and trouble-shooting being two major objectives. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. The information acquired from a process mineralogical study can be used as a guide for a metallurgical testwork program for process design or optimization.

Jan 1, 2014

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By Caibin Wu, Ali Lei, Ningning Liao, Jingsheng Ye

"The particle size distribution characteristics of ground product can influence the quality of the classification overflow and the next beneficiation indexes in an ore concentrator. Usually, the size distribution of ground product is considered to be determined by that of new ball mill feed. However, based on large amounts of data from industrial grinding circuit surveys, this paper has clearly shown that the size distribution of ground product should be determined by the size characteristics from classification underflow unless the circulating load was small, because the new feed is an important component and occupy a dominant position of mixed ore from belt feed and classification underflow. On the other hand, the correlation coefficient of the size distribution between ground product and classification underflow can be more than 0.99 when the relevance principle and its method are used. Meanwhile, their P80 value also keeps a synchronous correlation. The greater the capacity of classification underflow is, the higher the correlation of size distribution between the ground product and the mixed feed is. Furthermore, the correlation coefficient of the size distribution between ground product and classification overflow which is from primary or secondary can be 0.96. It is another discovery that the correlation coefficient is related to the type of classifier. The coefficient of size distribution of overflow and underflow from hydrocyclone is superior to that of spiral classifier, which can explain the reason why the hydrocyclone is widely used to replace the spiral classifier in concentrator.INTRODUCTION It is well knows that ball mill circuits closed with cyclones or spiral classifier such as a primary grinding circuit, a secondary grinding circuit and SAB mill have become an industry standard. Which grinding process employed will be determined by the P80 value of ground products. When the primary closed circuit ball mill or SAB that it is different throughout between the two processes was employed, a grinding fineness with -200mesh under 68% will be available. However, the secondary grinding circuit with the fineness of -200mesh above 80% can be conducted. Of course, the grinding fineness is determined by the grain size characteristics of the mineral."

Jan 1, 2018

By R. S. C. Smart

Surface chemical factors, including the balance of hydrophobic (e.g. collectors) and hydrophilic (e.g. oxidation products, precipitates) species, are major control determinants in flotation rates of specific minerals and therefore grade and recovery. There are a number of challenges involved with the surface analysis of different mineral phases from process streams in a flotation facility. The first is to collect samples that are representative of the process and retain their surface chemistry prior to introduction into the instrument. The second challenge in studying the surface chemistry of specific minerals is to find reliable methods of mineral phase recognition. In surface analysis of mineral particles, confident mineral selection can be difficult with many multi-metal minerals and with precipitated, adsorbed, reacted and contaminant species in the outermost molecular layers. The third challenge is to provide a statistical surface analysis of multiple grains of the same mineral. Methods to achieve these aims are described. Principal component analysis (PCA) of ToF-SIMS data provides improvement in phase recognition, particle selection and associated variations in surface species. Specific examples from both lab and plant operations, demonstrate that this technique can be utilized to differentiate surface chemical factors promoting (hydrophobic species) or inhibiting (hydrophilic species) flotation. A study of copper ion transfer (inadvertent activation) from chalcopyrite to pyrite and sphalerite clearly identified a statistical difference in copper intensities between the sphalerite and pyrite phases corresponding to their flotation response. The PCA analysis applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrated extensive CuOH and NiOH transfer between chalcocite and heazlewoodite minerals. The statistical analysis has been able to identify mechanisms controlling recovery and selectivity. High intensity conditioning (HIC) tests in which sphalerite was separated from a complex sulfide ore gave a 5% increase in the overall Zn recovery. The PCA/ToF-SIMS statistical analysis revealed the discriminating depressant action of adherent aluminosilicate (gangue) fine particles and adsorbed ions on the surface of sphalerite grains. HIC conditioning resulted in the removal of these gangue fines improving surface collector attachment efficiency.

Jan 1, 2014

By F. N. Shi

Ore breakage characterization plays an essential role in the design and optimization of comminution circuits. Recently, the JKMRC comminution research team has developed a Rotary Breakage Tester (JKRBT). The JKRBT uses a rotor-stator impacting system, in which particles gain a con-trolled kinetic energy and are impacted against the stator, causing particle breakage. The first unit of industrialised JKRBT was installed at the Anglo Research in South Africa in March 2007, and five more JKRBTs are currently being fabricated for some of the world?s major mining companies. In addition to the JKRBT, an improved breakage model has been developed at the JKMRC, which more accurately describes the effect of specific energy, particle size and incremental breakage caused by repetitive impacts. The validation outcomes show that the JKRBT, together with the new breakage model, generate statistically similar breakage parameters to the traditional drop weight tester (DWT), but with significant advantages over its predecessor. The limitations of the DWT, specifically its lack of precision of the energy input, the lengthy time required to run individual tests and the challenges en-countered in testing small particles, have all been overcome by the JKRBT. The recent developments in the JKRBT and the new breakage model offer several prospective applications. These developments have the potential to revolutionize the ore breakage characterization in the years to come.

Jan 1, 2014

By Imre Gombköto, Zoltán Pap, Ákos Debreczeni, Sándor Nagy

Eddy current separators have become generally used in waste recycling industry during the last decade. There are many papers dealing with separation processes on eddy current separators, and also many article describes particle trajectory and different particle features affecting particle trajectory. These data are used in modeling as well. Within the frame of R&D project called ‚Fundamental research into the exploitation of the economic development potentials of critical raw materials in international co-operation - CriticEl?, authors are aimed for using Eddy Current Separator (ECS) as a mechanical separation step of high value critical elements recovery of selected WEEE’s like display panels, PCB’s. ECS, equipped with 305 mm wide belt, and a concentric magnetic rotor is used for experiments targeted development of methodology for determining separability of different particles on ECS. The subject of our work was to investigate the behavior of model particles with different shape, conductivity (aluminum and copper), orientation and size in order to separate Al and Cu according to the results of many experiments were carried out in this field. However it looks like that throwing distance of one particle is only possible to describe by a certain distribution for even the same particle within the frame of the same conditions. Sample mean and standard deviation are depending on some of the particle feature and acting forces. The paper is going to draft the first results on the relationship between distribution of throwing distance and particle properties.

Jan 1, 2014

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By H. R. Manouchehri

"In mining and minerals industry, except profitability, there are some crucial factors that represent components in economic machinery of a mine and related activities. These are sustainability and minimizing environmental impact factor. Environmental concerns combined with the water and energy availability and related costs, as well as public license to operate all contrive to demand for more efforts targeting sustainability. Mining industry is highly energy-intensive (estimated to consume 6-7% of total world’s energy), with varying the energy efficiency across the industry resulting in significant costs. Size reduction is the main energy consumer contributing to almost 50% of the total energy used in mining. That means efforts must be made to introduce energy efficient comminution flow-sheets and machineries for sustainable development. Since the crushers are more energy efficient than mills, it is logic to push down-sizing in crushing stage(s) as far as technically possible. That has been strategy for Sandvik Mining and Rock Technology in supplying advanced and effective crushers to provide fine crushed product for subsequent milling stage. Lowering the energy consumption and related costs as well as increasing throughput have been the main objectives in design and development of comminution circuits and related machineries. Inefficiency in comminution technology, particularly in grinding, has long been regarded as a major area for investigation and development, especially when production of fines and ultra-fines are considered. In an attempt to explore the potential of fine crushing and its effects on subsequent milling process the fine crushing performance of Sandvik’s conventional cone crusher and Vertical Shaft Impactor (VSI) in pilot scale to define the energy consumption and circulating load in fine crushing. Tests were conducted to obtain fine crushed products at P = 2 mm in a close circuit. Furthermore, the crushed products were characterized and compared by grind-ability, morphology, and surface area measurement tests. Finally, the energy consumption to grind the crushed products to specific grind size was calculated."

Jan 1, 2018

By Matthew Thurley

Optimisation and control of comminution, pelletization, and agglomeration processes is a complex task with large potential for gains in productivity, energy efficiency, and particle size distribution quality. One factor in realising these gains is the requirement for fully-automated online particle size distribution measurement. Moreover, online particle size distribution measurement that is based on the particles on the visible surface and can avoid or mitigate substantial errors that result from under-sizing overlapped particles and over-sizing areas of fines particles. Literature review indicates a body of substantially 2D photographic based particle size measurement systems that suffer from a large number of significant errors except in the simplest case of a monolayer of particles under good illumination with limited color variation in the material. In order to measure the visible particles on a pile there are a number of requirements including; avoiding particle delineation errors due to variation in material color and shadows, detect overlapping versus non-overlapping particles, and identify areas of fine particles as fines and not large rocks. Results are presented using a fully-automated online measurement system of crushed rock on conveyor belt using a 3D surface laser profile. The system provides continuous online measurement and results are shown on over four hours of production after the primary crusher. Size distribution results are calculated using volumetric estimation of the particles on the surface of the pile. The results show a strong capability to discriminate size variation especially in the 10% and 20% passing values. Furthermore results show that if areas of fines are misclassified as large rocks, and overlapped particles misclassified as small rocks, then a near complete loss of discrimination occurs for the P10 and P20 values which become largely constant values.

Jan 1, 2014

By S. K. Kawatra, T. C. Eisele

"Coal-fired electrical power generation plants produce 56% of all the electricity in the U.S., burning approximately 860 million tons of coal annually. This results in the production of 58 million tons of fly-ash; 19 million tons of bottom ash and boiler slag, and 23 million tons of desulfurization sludge.s annually. These are a considerable disposal problem, and it would therefore be very valuable to be able to sell these residues and by-products as useful materials, rather than paying to dispose of them in landfills. However, utilization rates are currently very low, below 32% even for the most thoroughly commercialized combustion byproduct (fly-ash). This poor utilization rate is a result of the high impurity content of combustion byproducts, which makes them unsuitable for existing markets.Mineral processing techniques are useful for upgrading and utilizing combustion by-products. Fly-ash can be processed to remove unburned carbon, or utilized as a binder component in ore pelletization and agglomeration processes; bottom ash can be processed to produce certain aggregate grades; CO2 emissions can be sequestered using modified leaching techniques; and many scrubber sludge’s require processing before they can be used for producing gypsum products.The experiments described in this paper were carried out to study the application of mineral processing techniques to upgrading combustion by-products, particularly flue-gas scrubber sludge. A process was developed for upgrading unoxidized Flue-Gas Desulfurization (FGD) sludge’s by removing the primary impurity (unreacted limestone). A combination of hydrocycloning followed by froth flotation reduced the limestone concentration to as little as 1.7%, while recovering 66% of the sludge weight as a clean product. The recovered limestone was sufficiently concentrated that it could be recycled to the scrubber for more complete utilization."

Jan 1, 2003

By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By Xiong Dahe

In recent years many creative technologies are applied to SLon vertical ring and pulsating high gradient magnetic separators. SLon-2500 and SLon-3000 vertical ring and pulsating high gradient magnetic separators are created towards larger scale. Through optimizing the magnetic system and lowering the electric current density, their energy consumption is obviously dropped. New magnetic matrixes are developed to raise the beneficial efficiency of valuable minerals. Special SLon vertical ring and pulsating high gradient magnetic separators are developed which can treat coarser particles of 0-5 mm. Through these technology creations, the mineral processing efficiency of SLon magnetic separators is further raised and their processing cost dropped. Therefore, they have been found wider applications. SLon-2500 applied in Essar Steel of India. In 2007, Essar Steel did a test on its Kirandul hematite ore with SLon magnetic separator and got very good results. The feed grade is 59.77%Fe, after SLon one roughing and one scavenging, the total iron concentrate grade is 65.00%Fe and iron recovery 93.86%. In 2008-2010, the company bought 10 SLon-2500 magnetic separators to treat such iron ores. In 2010 the first SLon-3000 was applied to processing ilmenite. The magnetite-ilmenite deposit is located in Pan Zhi Hua, Si Chuan Province of China. The ore processing flow sheet is: Drum low intensity magnetic separator is used to take out magnetite, and then the SLon-3000 is used to recover ilmenite for roughing. The mags of the SLon-3000 are further cleaned by flotation. The SLon-3000 average operational results are: feed grade 9.52%TiO2, mags grade 17.43%TiO2, mags mass ratio 41.01%, TiO2 recovery 75.09%, non-mags grade 4.02% TiO2, non-mags mass ratio 58.99%. SLon magnetic separators Applied to treat 0-5mm limonite: The feed of SLon magnetic separator is usually 0-2 mm which needs to be ground by ball mill. As many Chinese iron ores are poor grades, if we can throw part of tails before grinding, the grinding cost will be greatly reduced. In 2010, a SLon-1500 and a SLon-2000 were specially built to treat 0-5 mm limonite. The feed grade is 26.51%Fe, mags grade 53.20%Fe, iron recovery 64.26, and tails grade 13.66% Fe. SLon-2500 applied to purify quartz. In 2009, a SLon-2500 magnetic separator was applied to purify quartz in Shan Xi province. Its feed is 0-1mm quartz which contains 0.15%-0.25%Fe2O3, the designed non-mags grade need to be less 0.08% Fe2O3. The production results of SLon-2500 non-mags are 0.05-0.06% Fe2O3, much better than the designed data. SLon applied in Si Jia Ying Iron Mine to recover hematite. Si Jia Ying is a big oxidized iron mine located in He Bei Province of China. In 2005-2010, a plant annually treating 10 million tons of oxidized iron ore was built in which 39 SLon magnetic separators are applied. The total flow sheet results are: Feed grade 30.44%Fe, iron concentrate grade 66%Fe, iron recovery 80%Fe, tails grade 9.65Fe%. SLon applied to recover specularite. Li Lou Iron Mine in An Hui Province of China built a plant annually processing 5 million tons of iron ore in 2010-2011. 25 SLon-2000 magnetic separators are applied to recover specularite. The total flow sheet results are: Feed grade 31.65%Fe, iron concentrate grade 65%Fe, iron recovery 80%Fe, tails grade 10.37%Fe. SLon applied in Da Hong Shan Iron Mine. Da Hong Shan Iron Mine is located in Yun Nan province of China. It treats 4.5 million tons of oxidized iron ore annually. 15 SLon-2000 magnetic separators are applied to recover hematite. The total flow sheet results are: Feed grade 35.61%Fe, iron concentrate grade 64.95%Fe, iron recovery 74.08%Fe, tails grade 15.55%. Keywords: SLon magnetic separator, iron ore, ilmenite, quartz, beneficiation

Sep 1, 2012

"The JKMRC researchers have been redeveloping the suite of breakage testing techniques to more realistically align with the breakage environment in comminution equipment. Computational modelling, especially with the DEM, has highlighted the modes of impact and contact, along with the energies of these interactions in a wide range of equipment. This has driven the need to match these modes in laboratory ore characterisation tests. The objective has been to build a continuum of breakage tests and associated models that span the required range of breakage forces and environments. The ore sample is subjected to a sequence of tests covering: abrasion (surface breakage) of angular through to smoothed particles; single particle impact from high energy single impact breakage down to low energy; incremental breakage covering 60 mm down to 50 µm particles; particle strength distribution; and bed breakage over a range of compression and energy input. These tests are suited to multi-component ores with a distribution of strengths. A modelling technique is also being developed to utilise primary breakage for modelling breakage under different types of confinement. This paper draws together these techniques, previously published by the authors, into a coherent whole. The suite of tests is approaching the point where a fixed set of tests can be used to model the performance of a full range of equipment, removing the need to conduct repeat ore characterisation tests for each different piece of equipment incorporated in a circuit design. This path should open up the application of different circuit configurations and novel equipment in comminution circuit design.1 INTRODUCTION Comminution modelling utilizes a wide range of ore characterisation techniques and methods to deal with the range of comminution equipment available for production use. In general, the tests have been designed to correlate with specific pieces of equipment, using calibration factors to provide the link between the small-scale test and industrial-scale performance. The majority of tests focus on estimating the power requirement of process equipment to achieve a desired throughput and grind size. Overall, this approach has achieved acceptable outcomes in the past, but the reality is that equipment sizing suffers from considerable uncertainty, in excess of ±20% is not uncommon. This uncertainty is covered by safety margins and automatic scaling factors in equipment selection. In striving to improve reliability, the industry tends to add more adjustment factors to the tests, and design margin rather than question the basic validity of the testing process. As the tests are often correlated to production equipment via carefully guarded databases, they are also locked into historic operating inefficiency, not providing direction or revealing opportunities to improve production efficiency in comminution equipment or circuits. Safe in the knowledge that they are achieving the expected production based on test work predictions, a site is unlikely to set their sights on reducing specific energy consumption by 10%."

Jan 1, 2018

By B. P. Baruah

A good deposit of high sulphur coals of tertiary origin is existent in North eastern region of India. These coals are known to have indifferent characteristics in comparison to other Indian coals. The general Physico-chemical characteristics are low ash and high volatile matter, calorific value and sulphur content. Sulphur in these coals (70-95% of organic) is mostly affixed to the structure of the coal. Owing to the stringent environmental regulations, the utilization of these coals has severe limitations due to high sulphur content. In the present investigation, sulphur incorporation in to these coals has been discussed along with possible organic sulphur functionalities. The various desulphurization techniques carried out for removing sulphur from these coals have been discussed. Two step oxidative desulphurization processes has been found to be most efficient for organic sulphur removal along with mineral matter and potential toxic elements. Keywords: oxidative desulfurization, potential toxic elements, sulfur incorporation

Sep 1, 2012

By John Starkey

"The development of the Minnovex SAG Power Index (SPI) Test in Canada has created a new and accurate way to measure ore hardness in a SAG environment. Coupled with the standard Bond Ball Mill Work Index Test it is now possible to determine from these two relatively inexpensive laboratory tests, the amount of energy required to grind an ore from the primary crushed size to the desired liberation size. By testing multiple samples to discover where the hard and soft ore zones are located, the representative hardness distribution for the ore body can be determined and grinding equipment selected that is capable to meet production targets for all mining areas of the deposit.In the last century, it was deemed prudent to select up to 50-tonne samples of ore for Semi Autogenous Grinding (SAG) pilot plant tests and a second 5-tonne sample for metallurgical pilot plant work. The methods outlined in this paper show how the 50-tonne sample is no longer required for SAG design because it is better to measure the representative hardness distribution of the ore body than the hardness of a “chosen” representative sample. This is demonstrated to be true by the fact that the lower horizons of an ore zone cannot initially be accessed to recover 150mm pieces, and the bulk samples taken, rarely represent the desired design hardness of the ore. Median hardness will not yield a good result in most cases and a clear understanding of the location and extent of the hardest zones is imperative to achieve a truly successful grinding circuit design.This paper discusses two plants (Kubaka and Agnico Eagle) that have been designed using SPI and Bond with no pilot plant test backup. Both have been very successful in that they can grind design tonnage on the hardest ores in the mine. This guarantees that the mine’s profitability is protected in any mining sequence. It also allows the extra power to be converted to higher throughput on softer ores if additional cash flow is needed. The advantages from the owner’s point of view are dramatic. This procedure will be attractive as well when considering the costs for test work, and the samples for testing. Existing diamond drill core is normally used and this allows the inclusion of data from the deepest regions of the mine. In addition, it is also clear that the decision to use a crusher can now be made at the design stage of a project based on measured parameters and the estimated capital costs of alternative designs."

Jan 1, 2003

By Junwei Han, Wenhua Li, Wenqing Qin, Fen Jiao, Wei Liu, Jiaqi Xu

"A novel technology was developed to study the process of recycling copper from waste printed circuit boards (WPCBs), which are the main source of metal production in the next decades. The chemical compositions of the WPCBs were investigated. The results indicated that the PCB powder was mainly composed of copper (38.5 wt.%), iron, aluminum, and non-metallic materials. Copper is mainly in the form of Cu and is the most valuable metal for the recycle of WPCBs. The concentrated WPCBs powder, obtained by the mechanical process, were pressed as the anode, which was directly electrolyzed to produce copper. The effects of H2SO4 concentration, Cu2+ concentration, current density, pole pitch, and liquid-to-solid ratio on the voltage, current efficiency, and copper extraction were investigated. The results indicated that the optimum conditions were liquid-to-solid ratio of 30 mL/g, current density of 571 A/m2, sulfuric acid concentration of 180 g/L, 50 g/L of copper ion, polar distance of 3 cm. Under the conditions, a desired current efficiency could be achieved. Meanwhile, about 95.62% Cu was recovered from the WPCBs. The experimental studies also revealed that the purity of copper obtained at the highest current efficiency was higher to 99.98%. Produced copper sheet were characterized by X-ray diffraction (XRD). XRD analysis indicated that the copper was the main phase. INTRODUCTION With the rapid development of electronic industry, more and more waste electronic and electrical equipments (WEEE) are generated every year (Fogarasi et al., 2012; Liang et al., 2013). The production of printed circuit boards (PCBs) is the base of electronic industry, because it is the essential part of all electrical and electronic equipments (Schlummer et al., 2007). As a result, a considerable amount of waste PCBs containing plenty of heavy metals have to be treated. In general, PCBs contain about 28% metals that are abundant non-ferrous metals such as Cu, Pb, and Sn. Printed circuit boards can be considered as a secondary resource for recycling rather than wasting. The contents of gold and silver respectively reach 80 g/t and 3300 g/t, which are much higher than that of primary ores. Copper is the main metal of PCB and its content is as high as 26.8% ( Zhang et al., 2009)."

Jan 1, 2018

By Cuim R., M. L. Li

Fankou Lead-Zinc Mine produced pyrite concentrate (P.C.) from the zinc tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34% ( to the feed of S circuit). On the one hand, the economic value of P.C. increases with its purity, on the other hand, when the S grade of P.C. feed to sulfuric acid manufacturer is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the P.C. with S grade of 47% as target. The direct way to reach that goal was to clean the rougher P.C.. Lots of cleaning flotation tests were conducted and the compromised strategy was to produce two ranks P.C. with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of P.C., gravity separation was introduced into the flowsheet. The numerical simulation and separation tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rougher P.C.. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to P.C. with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough P.C., single P.C. with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality P.C. at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry.

Jan 1, 2018

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS) excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a of which are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 20 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction.Pure mineral phases and mineral mixtures were used for the flotation tests. As opposed to current knowledge, the results were reproducible with technical flotation machines."

Jan 1, 2003