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By S. R. Izatt

The use of MRT, a highly selective separations technology, has long been demonstrated to be a cost effective, efficient, and environmentally sound process for extraction of a wide range of anions and cations that are commonly found in copper electro - refining and electro - winning circuits, as well as in environmental treatment operations. This paper provides an update of commercial MRT applications in the copper industry. Several recent installations and test programs are reviewed including recovery of bismuth from tank house electrolyte, and from chloride matrix selenium reduction solution which is generated in the anode slimes treatment process. Recovery and refining of platinum group metals originating in the anode slimes is also discussed. Various other base metal and other target separations of interest to the copper producer are also reviewed. The recovery products are high purity metal salts which can be marketed directly or readily reduced to metal.

Jan 1, 2007

By T. Hartmann

The presence of crud represents a permanent challenge for solvent extraction in the hydro-metal industry. The crud is a stable emulsion which slowly spreads along the phase boundary between the aqueous and organic phase. The crud can significantly impair the efficiency of hydro-metal extraction because the phase boundary between the aqueous and organic phases assumes substantial proportions, and the settlers cannot react flexibly. In a chain reaction, all settlers connected in series become infected with crud. The transfer of organic phase to the electrowining (EW) cell can cause 'cathode burn'. Continuous treatment of the crud is extremely effective and reliable with a 3-phase separating solid bowl centrifuge. All three phases are separated distinctly from one another. All associated process steps exhibit a steady uniform efficiency. First and foremost, they ensure a reliable, continuous extraction process and, second, they recover valuable re-usable organics from the crud.

Jan 1, 2007

By Jorge Amaya

A critical aspect of long-term open-pit mine planning consists in computing a production schedule based upon a block sequencing strategy. Such a schedule should specify when and if blocks should be extracted in such a way as to maximize NPV, while satisfying wall-slope and production capacity constraints. It is well known that this problem can be modeled with integer programming (IP). However, integer programming is not used in practice because the size of typical block models makes such problems intractable to standard IP solvers. In this article we describe a scalable IP-based methodology for solving very large (millions of blocks) instances of this problem. We show that embedding standard IP technologies in a local-search based algorithm we are able to obtain near-optimal solutions to large problems in reasonable time. This methodology has been tested in several mine wide block models.

Oct 1, 2009

By Jorge Amaya

A critical aspect of long-term open-pit mine planning consists in computing a production schedule based upon a block sequencing strategy. Such a schedule should specify when and if blocks should be extracted in such a way as to maximize NPV, while satisfying wall-slope and production capacity constraints. It is well known that this problem can be modeled with integer programming (IP). However, integer programming is not used in practice because the size of typical block models makes such problems intractable to standard IP solvers. In this article we describe a scalable IP-based methodology for solving very large (millions of blocks) instances of this problem. We show that embedding standard IP technologies in a local-search based algorithm we are able to obtain near-optimal solutions to large problems in reasonable time. This methodology has been tested in several mine wide block models.

Oct 1, 2009

By Sobczyk

The article will present a comparison of classifications of resources according to the JORC Code System with Polish classification, basing on system used in Eastern Europe. The differences between these classifications are significant. The information about mineral resources in Poland is not comparable to the main international system of reporting reserves like JORC, SAMREC, and PERC. Although comparisons between these systems are used, the transfer of particular categories of resources from the Polish system into a JORC category is not simple. Basing on the examples of privatization of Polish coal companies through initial public offering on the Warsaw Stock Exchange, the current practices providing guidelines how to convert resources from the Polish classification to the JORC system are described. Such independent assessment of resources is necessary for development of Mineral Expert?s Report (MER or CPR) which is an integral attachment to the prospectus.

Aug 1, 2013

By C. Bissue, G. M. Castillo

Newmont’s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By Michel Aubertin

Mining activities can produce large volumes of waste rock, which are typically deposited in piles on the soil surface, above the water table. Such piles can cover areas of several tens of hectares and can reach over a hundred meters in height. For hard rock mines, the waste rock grain size can vary from silty particles to metre-scale blocks. The internal structure of a pile constructed on a relatively flat surface typically includes two main zones. The first zone corresponds to the heart of the pile, and is formed by several sub-horizontal stratifications (with dense and loose layers) due to the heavy mine equipment traffic which induces local compaction and degradation of the waste rock. The second zone corresponds to regions where waste rocks are deposited by push-dumping or end-dumping close to the external flank of the pile, inducing grain size segregation along the slope. Depending on the deposition sequence, grain size distribution and bench height, a gradation may then be observed, with coarser particles (with cobbles and blocks) near the base and finer particles near the crest, together with inclined stratifications due to the advance of the deposition face. These internal features affect the distribution and flow of water (and air) in the pile. To assess the internal distribution of material properties within the pile, a combination of several tools is usually required which can provide information on the hydrogeological and geochemical characteristics of the waste rock. In this regard, geophysical tools are very interesting because they can lead to a threedimensional mapping of property variations. The information gathered from a combination of appropriately selected techniques can be used to construct numerical models to further study unsaturated water flow and reactive transport. Such simulations help better understand the pile response in its actual and future states, which in turn provides input to adjust the deposition sequence, to plan for closure, and to select an in situ groundwater monitoring strategy. The presentation will give an overview of techniques that have been developed to characterise material properties in the laboratory and in the field, and to obtain a general picture of a pile?s internal structure. Additional results on unsaturated reactive transport modelling will also be shown to illustrate how the internal pile structure may influence its hydro-geochemical and environmental response.

Nov 1, 2008

By R. C. Urquhart

Since the first use of the electric arc furnace Henri Moissan (1892) and its use by Paul Hérholdt (1902) to melt steel, it has been successfully used as a pyrometallurgical smelting tool in the production of calcium carbide, iron, ferrous and non-ferrous alloys. Commercial forms of the electric arc furnace have evolved from round, single-phase single electrode units to rectangular three electrode three-phase units to round three electrode three phase units and ultimately to rectangular six electrode three-phase units. DC electrical supply has also been used to replace the three phase power supplies in some cases. This paper examines how these electric arc smelting furnaces have evolved in size, efficiency and configuration within the constraints of the smelting process, electrodes and electrical power supply equipment.

Jan 1, 2014

By J. M. Menacho

As usually occurs in technological development, heap leaching knowledge has been built upon two parallel lanes, theory developed on fundamentals but relatively far from industrial applications, and operational know-how generated from empirical trial and error. As a contribution to close the gap between the above-mentioned lanes, the De Re Metallica process consulting group has been developing and applying fundamentalsbased modeling tools for industrial process design and process optimization of existing plants over the last ten years. As result, a library of models is now available with application to the whole production chain from blasting to electro winning. This presentation is centered in heap leaching and several real case studies are developed, showing how paradigms are broken when fundamentals are applied. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By J. M. Shneerson

Gipronickel Institute, Saint-Petersburg will The copper concentrate was extracted from copper and nickel matte after its hydrometallurgical treatment and nickel removal. The concentrate containing 60-74% of copper was represented by two principal copper minerals, digenite and covellite. The oxidising leaching of this kind of concentrate was studied at the Gipronickel Institute. The effect of key parameters, such as temperature, oxygen partial pressure and initial solution compound, on the rate of copper dissolution and transfer of sulphur from sulphide to elemental form was investigated. It was shown that at temperatures about 90DC, the sulphur content of covellite converts to elemental form. Under autoclave conditions at 11ODC, the elemental sulphur dissolves as a sulphate-ion. At the temperature range from 50 to 90DC, the copper dissolution rate is in direct relation with temperature. By increasing the temperature to 130DC, this effect is reversed. Based on the research work, a technological flow sheet for the leaching of the copper concentrate was developed.

Jan 1, 2007

By A. Jain

During sheet forming, metal experiences not only multi-axial load, it also undergoes strain path changes. For example, metal in the flange region may be drawn, may bend and unbend through a bead, before bending around a die radius, etc. Compression data were obtained from AZ31 sheet after pre-straining in compression along an orthogonal direction. The compression directions correspond to the sheet product (rolling-RD, transverse-TD, and normal-ND) directions. Three cases are examined: slip dominated deformation (ND) followed by twin dominated (RD or TD) deformation, twin dominated (RD or TD) followed by de-twinning (ND), and twin dominated (e.g. RD) followed by cross-twinning or secondary twinning (e.g. TD). Slip induced pre-straining simply hardens the material, while twin dominated pre-straining alters the texture allowing the material to either de-twin or re-twin upon changing the strain path. Polycrystal plasticity modeling has been used to predict qualitative features of the flow curves during strain path changes.

Jan 1, 2006

By T. Watanabe, M. Nakagawa, K. Kimapong

Ultrasonic wave was irradiated on metal surface in water to introduce compressive residual stress. The ultrasonic wave that was oscillated with 19.5 kHz ultrasonic transducer and amplified with a step type horn was irradiated. Slight plastic deformation occurred at the surface region of pure metal such as Cu and compressive residual stress was introduced. It seemed that the plastically deformed depth from the metal surface corresponded approximately to the depth of introduced residual stress. The higher compressive residual stress could be introduced into the surface of Cu-Zn brass and SUS304 stainless steel because work-hardening was simultaneously induced to those alloys. Furthermore, since martensitic transformation was induced by the plastic deformation in the case of SUS304, the compressive residual stress could be introduced more deeply into the surface region. The residual stress of SUS304 reached to the maximum value of 574 MPa by irradiating for 5min.

Jan 1, 2004

By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By G. Kordosky

Leaching aids that result in an increase in leaching rates and overall copper recovery have the potential to be beneficial to copper leach/solvent extraction/electrowinning operations. It is generally accepted that effective leaching aids facilitate the penetration of leach solution into ore by lowering the surface tension of the leach solution. Surfactants are designed to do this, and a leaching aid containing the widely used surfactant class, alkyl phenol ethoxylates, has been suggested. Alkyl phenol ethoxylates were tested to determine how they may affect phase separation, entrainment and degradation in a copper solvent extraction plant. The test results suggest the use of leaching aids at a regular rate, or even for a short time period, may have a long term impact on copper solvent extraction. Several scenarios are evaluated regarding existing operations and future solvent extraction projects and cautionary suggestions related to the use of surfactants as leaching aids are given.

Jan 1, 2007

By A. Yousefpour, M. Hojjati, M. Simard, M. Laramée, M-A. Octeau

The need for effective and reliable joining methods grows as the use of advanced thermoplastic composites becomes widespread in aerospace industry. An experimental investigation of resistance welding of APC-2/AS4 thermoplastic composite laminates is presented. In this method, a heating element is placed between the bond-surfaces then the interface is heated by passing electrical current through the heating element. The polymer at the weld interface is melted due to resistance heating, then diffuses and consolidates under applied pressure, resulting in a weld. APC-2/AS4 prepreg, APC-2/AS4 commingled, and different grades of metal mesh heating elements were considered. A custom made resistance welding rig was designed and developed to perform lap-shear welds. The mechanical performance of the welds was quantified using single lap shear tests. The effects of different heating elements on the mechanical performance of the resistance-welded parts were investigated. Also, quality of the welds was examined under optical microscopy.

Jan 1, 2004

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

In addition to the harsh environment, materials for high-temperature applications are often subjected to a significant mechanical loading. Several researchers have noted that the rate of oxidation can be affected by stress in a range of materials. We have recently studied this effect in y-TiAl, based on the preliminary work of Magnan and Weatherly which showed that nitridation rates on the tensile side of a flexural creep specimen could be 10 times higher than on the compressive side. We have since developed a four-point bending creep setup capable of controlled atmosphere testing. We present quantitative data on the effect of creep on scale growth under a range of atmospheric conditions. Finite element analysis will also be used to show how modest applied stresses can have a large effect on scale growth rates through the generation of large stresses due to the mismatch of creep rate between the metallic substrate and the scale.

Jan 1, 2004

By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004

By S. Afshar, C. Allaire

Several studied have recently shown that the use of non-wetting additives is not always a sufficient solution to improve the corrosion resistance of refractories against molten aluminum. Once in contact with liquid aluminum, the coarse aluminosilicate aggregates, which do not benefit from the protective effect of non-wetting additives in the matrix, may be corroded. In some cases, the corrosion of aggregates, especially those containing a significant amount of free silica and/or alkalis, promotes corrosion in the surrounding matrix. The present work explores the possibility to protect the poor corrosion resistant aggregates via a lining procedure. A slip casting method, using either alumina or celsian-like composition based slurries, has been applied for lining of a series of aggregates. The results from this study show that such linings may prevent efficiently the corrosion of aluminosilicate aggregates. This work also analyzes the effects of firing temperature and lining quality on the corrosion behavior of aggregates

Jan 1, 2004

By P. Stantke

Glue, thiourea and chloride are the common reagents which are used in copper electrorefining to achieve fine-grained and smooth copper deposition. While thiourea and chloride are clearly defined chemical substances, glue is a natural product consisting of a mixture of amino acids in different constituent parts. The amino acids are continually degraded in the electrolyte by hydrolysis until they finally become completely inactive. This effect is well-known, largely constant and balanced by the continuous dosing of glue. In contrast, the behaviour of glue in the batch container is not always foreseeable. The glue can become partly or completely inactive by contamination with acid or bacteria, for instance. Usually this is not noticed, and partly or fully inactive glue is added to the electrolyte over a longish period, with the result that the copper growth is significantly impaired. Examples from operational practice show that, with the help of the CollaMat system, partly or fully inactive glue batches can be quickly detected.

Jan 1, 2007