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By A. L. Holloway, N. M. Soonawala, L. S. Collett

"Since the late 1970s, a major R&D program has been under way in Canada to assess the concept of disposing of nuclear fuel wastes in deep plutonic rock. Atomic Energy of Canada Ltd . (AECL), a federally-owned corporation, has been given the responsibility of directing this research (Rummery et al., 1983).The Underground Research Laboratory (URL), constructed in a granite pluton 15 km east of Lac du Bonnet, Manitoba (Fig. 1) is a major component of the Canadian Nuclear Fuel Waste Management Program. A diverse geotechnical experimental program is being carried out during both the construction and operating phases of the URL. This program involves detailed geological mapping, rock mechanics and hydrogeology studies, and geophysical surveying, to characterize the rock mass surrounding the shaft, and it has been described by Simmons et al. (1983). As part of the construction-phase program, ground-penetrating radar (GPR) surveys are being carried out during excavation, in an attempt to delineate fractures both ahead of the excavation and behind the walls of the excavation. This paper presents the results of surveys performed during shaft excavation and describes a procedure for plotting the data.Ulricksen (1982) cites examples of radar surveys to evaluate surficial deposits, such as peat, sands and gravels, and cavity detection in subsurface hard rock. Fowler (1981) used radar for fracture and clay vein detection in coal seams.In Canada, pioneering work in GPR has been done by Annan and Davis since the mid-seventies (Annan and Davies, 1976). Their work concentrated on problems relating to permafrost in the Arctic ."

Jan 1, 1986

By I. H. Warren

"An analysis of form-coking processes is presented in terms-of their fundamental mode of operation and their relationship to other coking processes. Their possible future role in cokemaking is assessed. IntroductionAny consideration of prospects and possibilities for form coking must commence with the iron and steel industries-their likely future growth pattern on a world and regional basis and the potential direction of future developments in iron and steelmaking technology.From the numerous estimates which have been made of the future consumption of steel, it would appear that a growth rate of 3lllo between now and the year 2000 is likely. Radical changes in steel making technology are unlikely to be commercially adopted on any significant scale during the next twenty years . However, widespread commercialization inter alia of continuous casting and direct reduction, growth of electric furnace steelmaking and a decrease in coke rates will all contribute to a growth rate for metallurgical coke that certainly will be less than that of steel."

Jan 1, 1980

By Frédéric Flament, Mary Goldman, Gille Barbery

"Pilot plant testwork on autogenous and semi-autogenous grinding was conducted at the Centre des Recherches Minérales du Québec (CRM) to investigate the effect of ball addition, solids concentration in the feed, specific energy consumption and feed size distribution.A mathematical model that incorporates breakage and surface mechanisms of loss of mass was developed to predict load size distribution of autogenous and semi-autogeneous mills. An empirical model was used to predict product size distribution of autogenous and semi-autogeneous mills.IntroductionAutogenous (AG) and semi-autogenous (SAG) grinding circuits offer potential capital and operating cost savings when compared with conventional grinding. Empirical relationships have been developed to calculate specific power consumption for SAG mills using pilot plant test results (Mular et al., 1989; Barrett and Allan, 1986). Empirical models can be obtained from plant practice data but are applicable only to the particular ore and set of operating conditions used in the model. Grinding mechanisms have to be taken into account in order to develop a model that can be applied to different ores and mills.In AG and SAG, the ore itself acts as grinding media, with the finer sizes being crushed by the coarser ones. Surface mechanisms of loss of mass, in which the inner core of the particle remains intact, also take place. In SAG milling, the effect of balls also has to be taken into account. The role of each one of these mechanisms changes with particle size and the model has to account for such changes."

Jan 1, 1991

By Francis Breton, Lei Pan, Kun Liu

"Effects of Fe, Cu and Mg minor alloying elements on creep properties of 8xxx aluminum conductor alloys were investigated by conducting compressive creep tests at 100 ºC under a constant load of 69 MPa. The microstructural evolution was studied using an optical microscope and electron backscatter diffraction technique. The creep properties were characterized by the primary creep strain in the first stage and the minimum creep rate in the second stage of creep deformation. Results showed that additions of all three minor alloying elements (Fe, Cu and Mg) demonstrated a beneficial effect on the creep resistance but individual alloying elements exhibited different impacts on creep properties. The additions of Fe and Mg showed a strong impact on both the primary creep strain and minimum creep rate, while the Cu addition displayed a favorable effect on the primary creep strain but no impact on the minimum creep rate. Microstructure observation revealed that with increasing Fe contents, the volume fraction of fine intermetallic dispersoids gradually increased while the subgrain size and misorientation angle became smaller, providing strong barriers to the dislocation and grain boundary movements. The addition of Cu moderately reduced the subgrain size and misorientation angle and in combination of solid solution strengthening it promoted the retardation of the creep deformation during the primary stage.INTRODUCTIONThe 8xxx aluminum conductor alloys offer significant advantages such as low density, high conductivity to weight ratio and low price over copper conductors and become an attractive candidate in electrical engineering and building wiring (McQueen, Chia, & Starke, 1986; Birol, 2009; Engler, Laptyeva, & Wang, 2013). The mass resistivity of aluminum conductors is one-half of copper conductors. Thus, only one-half the weight of aluminum is required for equivalent capacities. Therefore, this unique property coupled with a relatively low price of aluminum offers significant economic advantage to develop aluminum conductor alloys for electrical applications in the electrical wire industry."

Jan 1, 2016

By Lionel C. Kilburn

"This geological engineering method is based on jour main characteristics of mineral properties, viz; location: inclusion of valuable mineralization; inclusion of geophysical and/or geochemical targets; and inclusion of geological targets. These are subdivided into a total of 19 subcategories, which are used to determine the value of the property.The nineteen subcategories are prioritized and assigned relative value factors from 1.3 to 10. Value of each mineral claim unit is determined by applying the appropriate subcategory factors to a base value of $400per 16.2 hectare unit. Property value is calculated by totalling the values of such individual claim-units.The boundary between ore grade and sub-ore grade must be estimated for each property under valuation, thereby making the method sensitive to mineral commodity prices.A clear and disciplined sequence of decisions based on personal experience forms the basis of this method. The method utilizes all factors normally used to value a mineral property.IntroductionIt is generally accepted in the exploration industry that valuation of exploration properties is a subjective rather than objective process (Roscoe, 1986; Lawrence, 1988; Lawrence, 1989; Woodcock, 1985), and that it is greatly influenced by the experience and qualifications of the person who is doing the valuation. However, the significantly low degree of objectivity in mineral property valuation at this point in time invites effort to achieve a more quantitative engineering basis.Value of a mineral property depends basically upon metal prices, recoverable grades, mining and metallurgical practices, commodity supply and demand , and political-economic conditions, all of which vary with time. Therefore, any valuation is valid for only that point in time when it is made. Mineral deposits can decrease as well as increase in technical value with time."

Jan 1, 1990

By Ajit K. Sinha

"Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentaryhosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3070 to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By Michael Bowker

Au/TiO2 catalysts were prepared by incipient wetness impregnation and tested for the room temperature photocatalytic reforming of methanol in aqueous solution. These catalysts proved to be more active, on a molar basis, than Pd/TiO2. The dependence on loading of gold was different from that of palladium, showing a double maximum in yield at 0.1 and 2 wt. % with low rate below 0.01% and above 10%. A model is proposed for the reaction involving band gap excitation of titania electrons which are used to oxidise the methanol via adsorbed CO. With palladium, photoreforming of CO and water can be achieved, but this is much less effective on gold, presumably due to the much weaker bonding of CO on Au.

Oct 1, 2003

By R. Mariano

"The ability to optimise a concentrator from mill feed to final products requires a process simulator that integrates comminution, classification and separation stages. A key part of any such integrated process simulator is the inclusion of a model of mineral liberation in comminution to predict the particle composition distribution of the comminution products. This need was recognised by Gaudin (1939) who proposed a model of liberation based on the cubic fracture of a mineral texture composed of cubic grains of two minerals.This paper describes the development of a texture-based model of mineral liberation that builds on the method proposed by Gaudin. The approach described here, termed the JK-Gaudin Random Liberation model (JK-GRLM) uses as its basis the measured, volumetric mineral texture data that can be quantified for a given ore using X-ray micro-tomography. The textural data required as inputs for the JK-GRLM include the mineral grain size distribution. While the Gaudin model (in common with other existing liberation models) is a two-mineral (or two-phase) system, the JK-GRLM extends the approach to multimineral systems of up to 15 individual minerals, making it more widely applicable.An example of the application of the JK-GRLM to a base metal sulphide ore is provided. In the example the JK-GRLM is used to simulate the breakage of the measured ore texture and the particle composition distributions of the simulated progeny particles are compared to the measured particle composition distributions of ore that has been physically broken.The ability to calibrate this mineral liberation model with measured ore texture will allow it to be applied in greenfield situations where geometallurgical programs measure texture and in brownfield applications as a key part of integrated process simulations. The development of this model enhances our ability to simulate mineral processing operations as an integrated system."

Jan 1, 2016

By Larry T. Yano, Gerald T. Handford

"Tailings Engineering has the responsibility for planning and coordinating tailings disposal and for ensuring the stability of the tailings dyke. The inclusion of both the planning and geotechnical functions in one team has resulted in greater efficiency in the design and planning process. Major challenges in tailings disposal facing Syncrude are in the areas of: (1) sludge disposal; (2) instrumentation and monitoring; and (3) liquefaction. Meeting these challenges will have a significant effect on the cost effectiveness and reliability of the mining operation.IntroductionThe size of the tailings disposal operation has led to the establishment of a large engineering team devoted solely to the disposal of tailings. This paper discusses: the tailings disposal operation, the role of tailings engineering, the organization, inter faces, and the present and future challenges with respect to tailings disposal."

Jan 1, 1990

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By Joseph Licavoli, Paul Sanders, Yang Yang

"Al-Sc-Zr alloys form thermally stable L12 precipitates which provide high temperature strength. Although the overall fraction of L12 Al3Sc and Al3Zr may be increased by increasing scandium (Sc) and zirconium (Zr) content, such additions may increase primary phase fractions and do not produce desirable secondary phase morphologies. Rapid solidification techniques, such as melt spinning, increase solute atom concentration within the matrix. When the supersaturated matrix is aged, higher precipitate volume fractions at low Sc and Zr levels can be achieved improving high temperature strength. Melt spinning was used to rapidly solidify (107 k/s) a thin ribbon of Al-0.5Sc-0.4Zr at. %. The ribbon was compacted and extruded into 99.8% dense rods, and then aged using multi-step isochronal heat treatment up to 600°C. Precipitation strengthening was evaluated by ambient hardness measurement. The ambient hardness of melt-spun ribbon after precipitation hardening increased by 450 MPa (~67% increment) during isochronal heat treatment.INTRODUCTION Small Sc and Zr additions to aluminum improve strength and creep resistance above 300°C due to tri-aluminide precipitation of Al3(Sc,Zr) in L12 structures similar to ??, Ni3(Al,Ti) in nickel superalloy, but the Al3(Sc,Zr) particles have a Sc-rich core surrounded by Zr-rich shell (Figure 1). The Al3Zr shell limits atomic transport between the Al3Sc core and the matrix and reduces coherency strain. These factors reduce precipitate coarsening rate at elevated temperature (Bergner & Van Chi, 1977; Fujikawa, 1997; Knipling et al., 2011; Clouet et al., 2006).Figure 1. Simplified schematic model of precipitate Al(Sc,Zr) in Al-Sc-Zr alloy. Shell is rich of Al(Zr) intermetallic phase, particle core is rich of Al(Sc) intermetallic phase (after Voorhees, 2006). Numerous Al3(Sc,Zr) particles increase alloy strength and creep resistance as the precipitates impede dislocation glide and to a lesser extent climb. Previous work on ternary Al-Sc-Zr alloys show large strength increases versus binary Al-Sc, and Al-Zr alloys in Table 1."

Jan 1, 2018

By L. Jiang

The evolution of twinning in an AM30 Mg alloy was examined by uniaxial tension and compression testing at temperatures from ambient to 250°C and a strain rate of 0.1/s. The samples were cut along the extrusion direction from extruded AM30 Mg alloy tubes. Specimens deformed to various strain levels were examined by optical microscopy and electron backscattered diffraction (EBSD) techniques. The results indicate that the initial extrusion texture plays an important role in the formation of different types of twins and that the twinning behavior also depends on the strain path. Contraction and double twinning are the dominant twinning mechanisms in uniaxial tension, while extension twinning prevails in uniaxial compression. The different twinning behaviors are shown to be responsible for the sharply contrasting strain hardening characteristics of the experimental flow curves.

Jan 1, 2006

By P. R. A. Andrews

"Garnet occurs in schists and gneisses in all provinces of Canada, all mainly in Quebec and Ontario. There is currently a renewed interest in exploration for economic sources of garnet for abrasive applications because of the inherent dangers from exposure to ground silica from sandblasting operations.High-quality garnet is used for lapping and grinding of glass and ceramics; for coated and bonded products such as sandpaper and cloth; and abrasive wheels for grinding and finishing various metals, woods, rubber and plastics. Low-quality garnet is used for cleaning and conditioning aluminum and other soft mewls, particularly by aircraft manufactures. Garnet may be added to grouting cements for oil-well drilling applications, and it has also been used for low- to medium-level radiation shielding. Garnet has been studied extensively by CANMET and its predecessor, Mines Branch, between 1917 and 1990. Twenty-nine studies relating 10 various aspects of beneficiation are presented and a review of the more important studies is presented. The information includes mineralogy, beneficiation methods, product sizes and analyses."

Jan 1, 1995

By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By Garth A. Maki, Douglas M. Smith

"The largest Canadian Lamella thickener installation to date, with 13,600 square feet of effective clarification area, is being successfully operated at the Rocanville Division of the Potash Corporation of Saskatchewan. This paper describes the operational principles and design features of the Lamella thickener, the testwork leading to its specification f or the Rocanville phase two expansion project and a review of the performance of the full- size unit which was ultimately installed.IntroductionThickening equipment operating in the Saskatchewan potash industry is generally situated within the main refinery building or a separate insulated an d he a ted structure due to the harsh winter climate and the need to closely control plant brine temperatures to en sure good flotation circuit performance Because these thickeners process large volumes of slurries, conventional basin-type designs tend to be large, ranging up to 46 metres in diameter or more. As part of the general effort to minimize capital costs, the potash industry has begun investigating the use of alternate high capacity, compact thickener designs. In this regard, PCS Rocanville undertook a program in 1978 to evaluate a LamellaTM thickener and one other type of ‘High Rate' thickener as alternatives to a conventional design for the phase two expansion project.This paper describes the operational principles and design features o f the Lamella thickener (manufactured by Axel Johnson lnc.), the testwork leading to the specification of a Lamella for the Rocanville expansion project and are view of the performance of the full size unit (1486 m2 of the effective settling area) which was ultimately installed and is now successfully operating in the Rocanville plant."

Jan 1, 1983

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019

By R. del Villar, A. R. Laplante

"This article presents four grinding simulation programs, written in Applesoft BASIC. The firs t two calculate residence time distributions (RT Ds) for open and closed loops mills. The third program calculates the select ion functions from the RTD, breakage function and particle size distribution (PSD) o f the feed and discharge. Two linear regression programs are also included to calculate the breakage function. These results are used in the fourth program to simulate continuous or batch grinding kinetics.The modelling approach presented is the size discrete, time continuous matrix formulation presented by Reid (1965) from concepts originally proposed by Epstein (1948). It is at the present time the most widely accepted phenomenological model of grinding kinetics and is standard textbook material (Austin et 01., 1982; Kelly and Spottiswood, 1982, p. 152). The concepts of RTDs and tracer testing originated from chemical engineering theory and practice, and are well presented in Leven spiel (2n d Ed . 1972 , Ch. 9) .Applesoft* was chosen because it is compatible with many micro computers. It is also one of the simplest and least powerful BASIC versions. Thus it can easily be adapted to other more complex BASIC versions.Open Loop Residence Time Distributions (Program RTDOPEN)As mixing, channelling, stagnation and short-circuiting all affect slurry motion in tumbling mills, transport characteristics are very complex an d cannot be derived from fundamental principles. Fortunately , as grinding follows first order kinetics, transport characteristics for the purpose of grinding simulation ca n be represented by the RTD of the slurry phase . It is normally determined using liquid tracers, as it has been demonstrated and is commonly accepted that in industrial ball mill s, the RTD of the so lid phase is particle size independent and equal to that of the liquid phase."

Jan 1, 1985

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996