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By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC' s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By O. Moselhi

Material can be seen as the fuel needed to execute the project from inception to completion. Material installed provides good indicators of progress achieved onsite vis-a-vis project schedule performance. It correlates well with the role of the schedule performance index (SPI) of the earned value method (EVM). Material is recognized to have a significant impact on achieved progress for physical completion of project activities. This paper presents a study on the development of material status index (MSI) in support of the EVM. Unlike the SPI, the newly developed index account for the criticality of project activities. This is carried out considering the total float of each activity, percent float (i.e. the ratio of float to activity duration) and the total float of the path on which the activity is located. MSI, can independently and jointly with SPI provide root causes behind problems encountered during project execution. In turn MSI can reveal material related factors behind the performance detected by joint interpretation of the two indices. MSI serves to provide added value in alerting management to take corrective actions. While SPI and MSI may have different values, they can jointly augment and enrich the captured project status based on EVM. To demonstrate the capabilities of the developed MSI method, it is implemented on a case study. The case encompasses the construction schedule of a hydro power station constructed in northern Quebec. Different scenarios are adapted from the real case to demonstrate a set of practical aspects of the developed index. The results generated from the analysis of the case study illustrate the useful features of MSI beyond those of the traditional SPI on two fronts; causation and the considerations of criticalities of actives.

Aug 1, 2013

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By F. Habashi

Lead is an ancient metal. The alchemists related it to the planet Saturn. It was largely obtained by smelting galena which generally contains small quantities of silver. That is why the metallurgy of lead was closely related to that of silver and in some cases the ore was treated only for its silver content. It was also known during the Roman time that lead vapors were toxic. Lead has been produced exclusively by pryrometallurgical methods. Lead refining is a complex process because of the presence of deleterious impurities such as arsenic, antimony, and bismuth. In the nineteenth century lead played an important role as a material of construction in the manufacture of sulfuric acid. In the twentieth century tetraethyl lead was used exclusively as an anti-knock reagent. In recent years lead is mainly used for making batteries.

Jan 1, 2008

By M. Rafieazad, P. Fathi, X. Duan, M. Mohammadi, A. M. Nasiri

"Direct metal laser sintering (DMLS) is a metal additive manufacturing technology that creates highly complex components by fusing metal powder into a solid part. In this study, the impact of surface roughness on corrosion resistivity of AlSi10Mg_200C alloy manufactured through DMLS was investigated. The as-printed DMLS-AlSi10Mg _200C alloy was subjected to various surface finishing processes including grinding and sandblasting. The corrosion performance of the surfaces was then evaluated using potentiodynamic polarization testing and electrochemical impedance spectroscopy (EIS) in a 3.5 wt.% NaCl solution to mimic seawater environment. Surface characterization and corrosion morphology of the samples were assessed by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) spectroscopy. The results of this study show that the surface finishing process and the resultant surface roughness has a significant impact on the corrosion resistivity of the DMLS-AlSi10Mg_200C alloy in the seawater environment.INTRODUCTION Direct Metal Laser Sintering (DMLS), also known as Selective Laser Melting (SLM) (Sames, List, Pannala, Dehoff, & Babu, 2016), Laser Beam Melting (LBM), or Laser Metal Fusion (LMF) (Herzog, Seyda, Wycisk, & Emmelmann, 2016), is an additive manufacturing process that utilizes a precise, high-power laser to micro-join powdered metals and alloys layer by layer to form almost fully dense and functional components in three dimensions from the 3D computer-aided design (CAD) data. Complex geometries not possible with conventional manufacturing processes can be readily manufactured with high accuracy using the DMLS process with no need to time-consuming tooling."

Jan 1, 2018

By K. Hawboldt, J. E. Halfyard, C. Bottaro

The removal of sulfur from leach residues has been practised in the zinc industry using a combination of flotation and hot melt filtration. The process is highly dependent on the nature of the concentrate and the subsequent residue. When the mineral constituency of the residue alters, the process can encounter significant operational challenges. An alternate method of converting elemental sulfur to water-soluble polysulfides was applied to leach residue from Vale's nickel demonstration plant in Argentia, Newfoundland. Reaction parameters, sulfur purity and other key indicators are discussed as is the potential commercial application.

Jan 1, 2011

By Kwang-Hyun Jeon

Recently, 3D printing technology in the manufacturing field is in the spotlight. In the construction industry, similar rapid prototyping technology that does not use conventional form can be applied to meet the demand on free formed structure that can provide aesthetic value and functionality. Conventional formwork can increase construction cost and period for various structure with complex shapes while it has numerous advantages such as high strength, convenience, accuracy and good quality of surface roughness. To meet the demand on free formed structure, automated freeform construction systems such as Contour Crafting and Concrete Printing have been developed with active collaboration between university and industry in USA and England. However, details on the system have not been fully released in public, so the possibility of its fusion and spin-off technology cannot be expected. In this paper, cost-effective solution for mechanical and control system for constructing a free curved structure without mold are described. As an appropriate material for the system, fiber reinforced mortar was selected by experiments on compressive strength, setting time and fluidity. After performing G-code simulation, transfer and extrusion experiments with the selected mortar mix were performed and the possibility of the development of automated freeform construction system was demonstrated. Based on this research results, it is required to keep the automated freeform construction system improve and extend it into the new application area in construction industry.

Aug 1, 2013

By Ralph J. Holmes

"An accurate knowledge of the chemical, mineralogical and physical characteristics of ores and mineral products that are mined, processed and sold commercially is crucial to resource definition, effective resource utilisation, plant design, process control, metallurgical accounting and finally quality control to ensure that contract specifications are met and equitable payment is received for product sales. However, the responsibility for sampling is often entrusted to personnel who do not fully appreciate the significance and importance of collecting fully representative samples for analysis, and they seem satisfied as long as some material is collected and returned to the laboratory for analysis. Furthermore, sample stations incorporated into the design of new plants are often the first casualties when cost cutting exercises commence. There is really little point in accurately analysing samples if they are not representative in the first place, because the resultant analyses can be seriously biased and the effort taken to carefully analyse such samples is largely a waste of time and resources.Ultimately, a poor knowledge of the characteristics of ores and mineral products limits the ability of mining companies to optimise the life of ore resources and plant performance, and failure to meet final product specifications can have disastrous consequences, including price penalties and more seriously loss of sales contracts and significant revenue losses due to poor sampling practices at the point of sale. Consequently, it is critical that sampling is given the attention it deserves as the first important step in the quality measurement chain. The golden rule for correct sampling is that all parts of the ore, concentrate, slurry or other material being sampled must have an equal opportunity of being collected and becoming part of the final sample for analysis."

Jan 1, 2016

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By K. G. Wheeland, K. G. Byberg

The occurrence of a secondary, dust-fuelled explosion following blasting of sulphide ores has been reported in mines in many countries, including canada, the USA, Australia and South Africa. However there has been little effort to document the events and develop effective control technology. Following a detailed investigation of an incident at the Geco Di vision of Noranda Minerals Inc. , the company held a conference of interested parties in October 1986 to review the state-of-the-art and to agree on action. '!his paper outlines the causes and effects of such explosions, the key conference points and conclusions, and subsequent information-exchange and teclmology-developrnent activities.

May 11, 1988

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By M. M. Papic

"This paper describes the Sasol coal liquefaction process, as used in South Africa. It covers coal supply, coal gasification, gas purification, Fischer-Tropsch synthesis, the major utility systems involved and the economics of the process.IntroductionThe Sasol coal liquefaction process is based on Fischer-Tropsch synthesis of liquid fuels from carbon monoxide and hydrogen, which are in turn obtained by gasification of coal with steam and oxygen. The process is shown schematically in Figure I.The first step in the process is coal preparation, in which the coal is crushed and screened to a 3-50 mm size for gasification on one side and to -3 mm size for steam and power production on the other. Oxygen needed for coal gasificatoin is produced in the air separation plant.Coal is gasified under pressure by steam and oxygen in the Lurgi gasification plant, where raw, impure gas is produced . The raw gas is first washed in a scrubber with a circulating gas liquor, heat is then recovered from it in a waste heat recovery boiler and the gas is further cooled for purification. Water-insoluble materials (tar oils) in the gas liquor are separated from aqueous solution and sent to tar refining for the recovery of tar products. The aqueous portion of the gas liquor goes to a Phenosolvan solvent extraction process, where phenols and ammonia are recovered. Water then proceeds to the effluent treatment plant.The scrubbed and cooled raw gas goes to a Rectisol gas purification plant, where all components other than hydrogen, carbon monoxide and methane are removed as completely as possible by absorption in refrigerated methanol. The acid gases (CO2, H2S) stripped from the methanol in the Rectisol unit are processed in a Stretford plant for recovery of sulphur. Regenerated methanol is returned to the process. The purified synthesis gas is passed to the fluidized-bed Synthol reactors, where Fischer-Tropsch synthesis reactions take place.The synthesis products are recovered in a product recovery unit as separate streams of decant oil containing higher-molecular- weight hydrocarbons, light oil comprised of lower-molecular- weight species, the aqueous stream containing water solubles, a C3/C4 stream, a C2 stream , a methane stream and a hydrogen-rich stream. Most of the hydrogen is recycled to the Synthol reactors; a major portion of the methane is reformed to hydrogen and carbon monoxide for recycle; the C2 fraction goes to an ethylene plant; and liquid streams proceed to the product refinery.The product refinery is used to upgrade and purify the Synthol products to specification fuels and chemicals.Sasol l, the first coal liquefaction plant in South Africa , was built in 1955. It is still operating and has a product output of about half a million tonnes per year. The Sasol II plant is in a commissioning stage and will be in full operation in 1981. It is about five times the size of Sasoll. It uses over 12 million tonnes of coal and produces more than 2 million tonnes of saleable products annually (1,2,3). The Sasol llI plant, which is a mirror image of Sasol II, is under construction and scheduled for completion in 1983."

Jan 1, 1981

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

Most of automotive magnesium applications are presently produced by high-pressure die casting processes, For further expansion of the alloy usage in automobiles, novel-manufacturing processes needs to be developed, In this study, squeeze casting of AM50 alloy was carried out using a hydraulic press with an applied pressure of 70 MPa, Tensile properties and fracture behavior of the squeeze-cast AM50 were characterized in comparison with the die cast counterpart, The squeeze-cast AM50 alloy exhibits virtually no porosity in the microstructure evaluated by optical microscopy, The results of tensile testing indicate that the improved tensile properties for the squeeze-cast samples over the conventional high-pressure die-cast parts, The analysis of tensile behavior shows that the strain-hardening rate during the plastic deformation of the squeeze-cast specimens is constantly higher than that of the die-cast specimens. The SEM fractography evidently reveals the ductile fracture features of the squeeze-cast alloy AM50.

Jan 1, 2005

By The Staff

"A general description of the equipment, personnel and work sequence •being used in the sinking of a circular, concrete lined, 14 foot diameter shaft which at present is at a depth of 2,484 feet. Equipping, lining and sinking of the shaft is being carried out concurrently and waste is re-moved using a mechanical mucker.INTRODUCTIONTHE BUCHANS UNIT of the American Smelting and Refining Company operates a group of mines at Buchans, Newfoundland. Buchans is in the centre of the Province (Lat. 48°47'N.; Long. 56°50'W.), five miles north of Red Indian lake at an elevation of 900 feet and is accessible by 37 miles <Jf private railway which connects with the Canadian National railway at Millertown Junction, and by 47 miles of gravel highway, which connects with the Trans-'Canada Highway at Badger."

Jan 1, 1959

By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008