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By B. Burke

Magnesium and its alloys are attractive materials for use in automotive and aerospace applications because of the low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present paper reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents preliminary results of current work on producing magnesium alloys via powder metallurgy P/M. P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The feasibility of producing magnesium powder metallurgy products utilizing the industrially dominant process of mixed powder blending, uniaxial die compaction and controlled atmosphere sintering was investigated. An alloy composition based on the commercial Mg alloy AZ31 (3% Al, 1% Zn) was used to facilitate comparison to similar wrought products. The optimal processing conditions (compaction pressure, sintering time and temperature, and quenching temperature) were found to maximize sintered density and mechanical properties.

Jan 1, 2007

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By G. H. Hope, D. Green

"Recent process advances at Lac Minerals Est Malartic Division are discussed. The Est Malartic mill treats massive sulphide, copper/gold ore from the Bousquet 2 mine, to produce a gravity gold product, a copper flotation concentrate and a gold precipitate. The mill operation has been improved by the application of Knelson concentrators to replace jigs, the application of Outukumpu high grade tank cells and optimizing the cyanide leach to minimize cyanide consumption.IntroductionThe Est Malartic mill is located near the town of Malartic in the Abitibi Region of north western Quebec. The mill has been in production since the mid- J 930's processing mainly clean, free milling gold ore. Active mining from the Est Malartic mine ceased in 1980 and the mill was switched to custom processing of ore from La Mine Doyon located some 45 km to the west. This custom processing arrangement continued until 1987 when the expanded mill at Doyon became available to process all of the Doyon production. In 1987, Lac Minerals commenced development of a second mine at the Bousquet site located 40 km west of Malartic. This mine, Bousquet 2, is the down dip extension of the La Ronde mine developed by Agnico Eagle. During pre-feasibility evaluations, it was determined that modification of the Est Malartic mill to handle this new ore source was economically more attractive than building a new facility on site. Modifications to the mill to process the high copper/gold ore from the Bousquet 2 mine began in late 1989 and the new circuits were commissioned in mid-1990. Modifications included the addition of both gravity and flotation concentration circuits to recover coarse, free gold and the copper. The existing leach circuit continued operating on the copper flotation tailings with some minor modifications to the solution handling systems. An SO,/air cyanide destruction circuit was also added at this time."

Jan 1, 1993

By Guoxiang Chi

Hydrocarbon fluid inclusions entrapped in diagenetic minerals may be used to constrain hydrocarbon exploration models in two aspects. First, the distribution of different types of hydrocarbon inclusions in different tectonostratigraphic domains, and their relationships with organic matter maturation levels may reflect a regionalscale variation in the thermal regimes of the hydrocarbon systems. Second, the relative timing of hydrocarbon inclusions in the diagenetic history may provide constraints on the evaluation of reservoir potential. This paper summarizes the distribution of hydrocarbon inclusions in four different Paleozoic tectonostratigraphic domains in eastern Canada, discusses its implications on hydrocarbon systems in the different domains, and finally provides two examples to show how the relative timing of hydrocarbon inclusions may be used in the evaluation of reservoir potential. Oil inclusions mainly occur in host rocks that are within the oil zone, although some are found in units in the condensate zone. Light hydrocarbon inclusions occur in the dry gas zone, and methane inclusions were found from dry gas zone to anchimetamorphism zone. This correlation between hydrocarbon inclusions and host rock maturation implies that the hydrocarbons were derived from source rocks having a maturation level broadly similar to the host rocks. Although the Paleozoic rocks are generally relatively poor in reservoir quality, the two examples provided in this paper show that in some stratigraphic units, significant secondary porosities could have existed prior to some hydrocarbon migration events, thus favoring the accumulation of hydrocarbons.

May 1, 2001

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By T. Tsutsumi, S. Kukino

"During the diametrical compression test, the tensile stress generated near the loading plate is influenced by the contact area between the loading plates and specimen. However, very few studies have determined the contact area. Theoretical or analytical models have shown that for an orthotropic material (i.e., with material properties that differ along each of three mutually orthogonal twofold axes), the maximum tensile stress is generated at the center of disk when the angle of the principal material direction to the loading direction is close to ?/4. The maximum value is almost constant, regardless of the contact area. Conversely, the maximum tensile stress is generated near the loading plate when the angle between the principal material direction and loading direction is small. The maximum value decreases as the contact area increases. Therefore, in the latter case, the influence of the contact area on tensile strength measurement of is significant.In previous studies, the distribution of stresses applied on the loading plate is assumed to be a uniform load. In reality, the applied stress is highest at the center of loading plate and seems to decrease with distance from center. The applied load disappears at the edge of loading plates. In this study, in order to satisfy this boundary condition on the loading plate, the cosine curve is adopted as the distribution of load applied on the loading plates in a theoretical model of the diametrical compression test. Furthermore, the elastic solution using boundary conditions shown in this study is used to obtain the tensile stress distributions on the loading axis for an orthotropic circular plane. These distributions are compared with empirical results obtained under uniform loading with a loading plate or concentrated loading in previous studies."

Jan 1, 2015

By S. M. Fatemi-Varzaneh

The AZ31 magnesium alloy is considered as a promising alloy in various applications and industries. Furthermore, to design a proper hot working process (rolling, forging and extrusion), the assessment of hot working behaviour of the alloy is necessitated. Accordingly, the hot deformation behaviour of AZ31 alloy was studied through hot compression testing method. The latter was carried out in a wide range of temperature (523 K to 783 K) and strain rates. The obtained true stress-true strain curves and final microstructures were examined and a partial melting was realized at 740 K. It was concluded that the presence of liquid did change the deformation mechanisms thereby affecting the flow behaviour.

Jan 1, 2005

By Michel Dagbert

"In their paper, Marcotte and Boucher (2001) cast some new light on the old problem of 2D estimation of vein-type deposits with thickness and grade of intercepts. Using a theoretical approach, some extensive simulation experiments and the Walker Lake data, they show that the direct approach (interpolation of grade at points on a regular grid) gives better estimates of the true grade at those points than the indirect approach (interpolation of grade x thickness or accumulation and interpolation of thickness) when there is some positive correlation between grade and thickness and that this better performance increases with the correlation of grade and thickness as well as the variability of both variables.We would like to bring some reservations to that conclusion by showing that even if direct point grade estimates are better than indirect ones, it is not necessarily true for block estimates and in particular for the estimated grade of the whole orebody itself."

Jan 1, 2001

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By Naizhong Xu

During the past 30 years, fully mechanized caving mining has played a positive role in the improvement of the efficiency of coal production, but which has also had a great influence on the mining environment, especially to environment damage of shallow mining areas in the central and western regions of China. The surface subsidence parameters are the basis of the surface environment evaluation and governance. During 1980~1990s of the last century in China, fully mechanized mining subsidence laws were researched more fully, however, since coal caving technology is affected by many factors, and researches on its mining subsidence laws (parameters) were found to be grossly inadequate. Through actually observed in recent years, it is considered that coal caving mining subsidence laws (parameters) can use fully mechanized mining law (parameters) for reference. Based on fully mechanized mining laws (parameters), this paper reveals the similarities and differences of the surface subsidence laws between fully mechanized caving mining and fully mechanized coal mining, which can guide the work of coal mining under buildings, water bodies and railways in new mine area and mine collapse governance.

Aug 1, 2013

By A. Vervoort

The concepts of geostatistics are commonly difficult to understand for students, even for those with a strong mathematical background. A main problem is certainly the link between the variation of the parameter value in space or time, and the calculated experimental semivariogram as a function of the interdistance, but over the entire area. Another problem is to differentiate between directional and omnidirectional semivariograms and the way they have to be interpreted. Furthermore first time users of geostatistics often do not want to struggle through different books with the whole geostatistical background before using it. Too often this leads to using geostatistics as a black box with all the risks linked to it. That is the main reason that we developed some interactive tools based on the free public domain software R. We aim by developing three different modules to assist individual first time users, but also regular students and teachers to get a feeling of the importance of the various aspects in conducting a good geostatistical study. The modules show directly e.g. the impact of deleting, moving or adding data points, of changing parameters of the semivariogram model and of the geometrical parameters during kriging. The first module allows making the link between the variation of the parameter values in one direction and the calculated experimental semivariogram, and this for different given datasets. The second module covers two dimensional datasets and apart from calculating the semivariogram values, models can be fitted to the calculated data. A distinction can be made between omni-directional and directional semivariograms, including the effect of the tolerance on the angle and lag-distance. The third module focuses on ordinary kriging of point values in two dimensions. The aim of the interactive tools developed is limited to educational purposes only, i.e. to visualize some basic concepts for different pre-selected types of spatial variation. They do not intend to do a geostatistical study on a certain dataset (for this purpose there exists already a broad spectrum of good software packages). The original intention of developing the three modules was aimed at users with no or a limited amount of geostatistical experience. However, these modules seem also very useful to remain critical for experienced users. One should never forget that in a real application one does not have a complete view of the phenomenon studied. The geostatistical interactive modules can be accessed through: www.bwk.kuleuven.be/geostatistics . We compiled a manual to facilitate the use of the modules and to guide the user we formulated several questions to be solved for each module.

Aug 1, 2013

By A. -I. Abenhaim, I. Sasu, C. Perron, I. Mantegh, S. Larose

Manufacturing long shafts, such as those used in turbine engines, normally involves with drilling inside them in order to take the excessive mass out. Concentricity between the shaft axis and that of the drilled hole is very crucial as it impacts the mass distribution around the axis of rotation. It is important that the shaft mass be well balanced around the central axis in order to minimise the centrifugal forces on the bearings and supporting structure as well as any unwanted vibrations. The eccentricity problem, mostly in long shafts, comes due to machining limitations. It is difficult in long shafts to maintain the concentricity tolerances while drilling inside the shaft. In this work, we address the problem of correcting this eccentricity problem, i.e., when the axis of the inside hole deviates from the central axis. The presented work is based on a threepoint bending method and investigates its effect on the residual stresses and plasticity regions induced on the shaft. A full finite element model is presented that can used to design the solution parameters (bending load, location, etc.) and predict the effect. Limited experimental results are also presented to validate the finite element modelling.

Jan 1, 2006

By Ed Labelle, Terry Overton, Gary Bell

"LocationThe Miller Minerals lime and limestone production facility is located in the Temiskaming district of Ontario at Hailey bury on the west shore of Lake Temiskaming. Located less than 300 km from Sudbury, Timmins, Rouyn-Noranda and Val d'Or, the plant is very well situated to market products to the mining, pulp and paper, and environmental industries. Being located a few kilometres from the Trans-Canada Highway and the Ontario Northland Railway adds to transportation efficiencies.ProductsAt Miller Minerals, two principal products in various sizes are produced, which are limestone (CaC03) and quicklime (CaO).HistoryProduction of limestone products began in 1979 at this quarry site. During the 1980s, limestone products were marketed to a variety of applications for mining, forestry, environmental and agriculture applications. In 1990, the production of quicklime products began, following the commissioning of an Italian-designed vertical shaft calcining plant. During the 1990s, both quicklime and limestone products were produced to meet the customers' demands.From the quarry's conception until 1992, the operation was owned and operated by Dymond Clay Products. In 1992, it was purchased by Miller Paving Ltd. of Markham, Ontario, and became a key part of the company's industrial minerals sector of business. Other Miller interests include dolomite, cement, paving materials and waste management."

Jan 1, 2000

By I. M. Masters

Iron removal and control in processes employing pressure leaching technologies developed at Dynatec Corporation are reviewed. Discussions are focused on recent developments in the processing of nickel-copper matte and copper concentrates, and on the Ambatovy laterite project in Madagascar. Iron control and its implications on flowsheet design in the pressure acid leaching (PAL) treatment of laterite ores and in the oxidative pressure leaching of mixed nickel-cobalt sulphide intermediates are also discussed.

Jan 1, 2006

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By Jean-Pierre Birat, François Hanrot, Gérard Danloy

Global warming presents an enormous challenge to the steel industry, which is both carbon-intensive and energy efficient. Lean production can provide some short-term emission mitigation, at the level of the Kyoto requirements. In the middle term, more use of scrap will also help alleviate emissions. But to reach much larger reductions in GHG emissions, on a par with the likely targets that will be set after the Kyoto period, the steel industry will have to imagine new production paradigms, which constitutes its most formidable challenge for the years to come. Carbon capture and sequestration, processes leaner in carbon use, electricity and hydrogen from green sources will have to be added together in a patchwork of process routes, which will have to be developed at great risk in the next decade, hopefully through broad international cooperation.

Jan 1, 2004

By M. Amsden

"Since the computer program is far from complete this must be only a brief progress report on the computerization of flotation metallurgy at the Ecstall concentrator at Timmins.Ecstall is currently treating about 10,000 tons per day of two different ore types. One is a low sulphide copper-zinc ore, the other is a high sulphide lead-zinc-silver ore. The concentrator is divided into three individual grinding and flotation circuits. In effect there are three mills under one roof. Normally there are two circuits on copper-zinc ore and oneone lead-zinc-silver ore. At this point in time one of the copper-zinc circuits is under computerized metallurgy control.The first step in this control is the use of an ARL on-stream x-ray analyzer, coupled with a Honeywell 21 computer which types out assays and recoveries for each individual circuit. Our approach to a computer program was to keep it simple. The program was written to coincide as closely as possible to what an operator would do in the performance of his duties based on the in-formation he was getting from the x-ray analyser read-out. Initially, computer control was put on just the copper circuit of the ""A"" Division, controlling the collector addition at three points in the circuit; primary, secondary, and scavengers. The control was based on recoveries and the grade of the copper concentrate. Targets like 95% recovery and 24% copper concentrate grades that it was felt the circuit could achieve were set to start with. It quickly became apparent that this alone was not enough because if on a certain ore the best recovery that could be made was only 94.9% the computer kept calling for more reagents until the circuit was completely out of control. On another ore it might have been quite possible to get 96% recovery but when the set point of 95% was reached the computer stopped trying for any more. To overcome this problem a very simple optimum seeking program was devised by one of the Ecstall staff and it has worked very satisfactorily since being put into use in July 1970.In the copper float only the two collectors R-208 and the xanthate R-317 are under computer control. The addition of frother and depressant is left to the operator. The flotation cells have automatic level controls which can be adjusted by the operator. pH is controlled automatically through a lime loop-sensor arrangement."

Jan 1, 1971

By J. Kang

There is increasing demand to utilize aluminium alloy sheets and their spot welds by the automotive industry. While traditional uniaxial tensile tests only determine mechanical properties to small strain, direct measurement of the constitutive behaviour of aluminium alloy spot welds at large strain remains a challenge. A technique was successfully developed using digital image correlation coupled with shear tests to directly measure the constitutive behaviour of an AA6022-T4 spot weld to large strains. The results show that the spot welding process not only decreases the yield strength but also lowers the work hardening rate of the nugget versus the base material. Details of sample preparation, experimental approach and results will be discussed.

Jan 1, 2011

By J. Arzúa, L. R. Alejano, P. Rodríguez

"After six years of successful excavation with a support pattern, some roof failures have happened in a room-and-pillar underground mine excavated in a stratified rock mass. In this paper the authors give explanation to the failure mechanisms and redesign the support in order to solve the recent problems of roof collapse.The mine magnesite bed is approximately 14 m thick, and runs in the E-W direction with an average dip of 18º. Due to mine constraints and the inexpensiveness of the ore, the excavation is performed in the mineral itself, avoiding the need for mining dumps and waste excavation. Rooms and drifts are oriented in the mineral bed to form an angle of 19º to the direction of the strata, reducing the roadway gradients to less than 10%. Rooms are 11 m wide and pillars are 7 m wide. They are designed to leave a 1 meter thick magnesite bed in the roof of the rooms to act as a supporting beam. More often than not there is a layer of very poor quality marly shale up to 1 m thick resting on this magnesite beam. Overlying the poor quality marly shale there is a better quality, self-supporting sandy shale.First, a characterization of the involved rock masses (magnesite, marly shale and sandy shale) is performed, collecting the geotechnical data from previous studies and performing new in situ geotechnical surveys to check the soundness of the previous data. A distinction is made between different quality zones inside the mine by means of the RMR classification, associated to the occurrence of faults.Back-analysis of some of the failed rooms and data from exploration boreholes were used to determine the failure mechanisms (associated to Voussoir type failure or occurrence of sub-horizontal joints crossing the magnesite beam). Based on an understanding of these mechanisms, the method used to design the support and to analyse the stability of the different possible thicknesses of the magnesite beams of the rooms and drifts of the mine were improved.Numerical models of the most relevant conditions found in the mine were performed in order to better understand the behaviour of the roofs and to simulate the supporting solution obtained in the previous analyses.The most relevant conclusions with regard to the main elements causing the instability of the roof include the appearance of sub-horizontal discontinuities crossing the magnesite bed, which causes total instability of the roof and usually leads to collapse; excessive thinness of the magnesite beam in the problematic rooms; and the relaxation of the deepest (around 270 m in depth) zone of the mine because of existing faults."

Jan 1, 2015

By P. J. Mackey

"The metal producing industries in Canada and in the U.S. in many ways owe their technical beginnings to Welsh technology. The first copper smelter in Canada started in 1849-50 with a Welsh reverberatory furnace and skilled furnacemen brought across from Swansea to operate the equipment1- The Rocky Mountain smelting industry began with the installation of furnaces resembling the Swansea smelters(2). It was only later that the North American industry developed newer and improved methods. This article briefly describes the metallurgical history of the Lower Swansea Valley, being that section of land stretching northward from Swansea along the banks of the River Tawe, and bordered by hillsides east and west of the river. The Valley has had a classic cycle of development and decline common to industrial areas of Britain which grew in the Industrial Revolution. Perhaps more than any other area today, the Swansea Valley represents a complete cycle of use from agricultural to the peak of industrial development through to decline and dereliction. The conditions which made the Tawe Valley attractive to certain industries were laid down nearly 300 million years ago with the Carboniferous swamps and forests which covered the area, later forming the south Wales coalfield. As a result of glacial action and the deposit of glacial outwater and alluvial gravels, the valley adopted the traditional configuration, with its rocky sides occasionally remaining exposed. Up to probably about the 16th century, the Lower Swansea Valley was similar in use and appearance to many other valleys in the region. From the 14th century, the natural oak woodland had provided a continuous source of timber to produce charcoal for iron making as well as for structural purposes. Agriculture was the main activity in the valley in this period, but it was likely that the farmers also mined small amounts of coal by way of ""bell pits"", and adits into the coal seams."

Jan 1, 1999