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The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By K. Reipas

"Westmin Resources Ltd. operates the 3300 TPD H-W underground copper/zinc mine on Vancouver Island. Ore storage underground is handled in a 6000 tonne coarse ore bin and a 3000 tonne fine ore bin. Both of these bins have experienced significant wear since excavation and construction in 1985. Wear problems have included both deteriorating rock walls as well as worn out steel liners and concrete at the discharge points from the bins. Extensive rehabilitation work was completed in 1993.The basis o/this paper is the rehabilitation work done on the coarse ore bin. The design and installation of ground control measures are discussed. The bin access methods used to allow the work to proceed quickly and safely are also presented. This involved the use of a Tekfoam safety bulkhead to protect workers.IntroductionMine DescriptionThe H-W mine was commissioned in 1985. Mine access is by vertical shaft with most production areas at a depth of about 500 m. Host rocks are composed of andesite and rhyolite. Mine capacity of 3300 tonnes per day is achieved mainly by longhole open stoping methods, complemented by room and pillar mining. Metals recovered from the massive sulphide ore are copper, zinc, gold, and silver. Mineable reserves at January I, 1994 were 9.7 million tonnes."

Jan 1, 1995

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By Hoeve. J.

"In the unconformity-type uranium deposit at Midwest Lake, mineralization is associated with extensive host rock alteration, which affects the metamorphic basement as well as the overlying Athabasca Group sandstones. Host rock alteration is manifested by (I) transformation of clay minerals [kaolinite into illite and chlorite (sudoile)]; (2) bleaching due to removal of hematite from the lateritic paleoweathering profile and the overlying red bed, Athabasca Group sandstones; (3) loss of coherence of the sandstone resulting from corrosion of quartz cement; and (4) in the immediate vicinity of high-grade ore, development of a clay envelope due to residual enrichment of clay minerals caused by massive dissolution of quartz. Clay mineral transformation and bleaching are the most prominent and the most widespread alteration effects, forming haloes that extend for several kilometres along the strike of the mineralized structure and also constitute distinct alteration pipes that rise f or several hundred metres above the unconformity to be truncated at the present top of the bedrock.Although the two haloes are largely congruent features, cross-culling relationship s indicate that clay mineral alteration represents an earlier phase in the history of the deposit than the large-scale bleaching that gave rise to the superimposed bleaching halo.Because clay mineral alteration and bleaching are intimately tied to the mineralization and extend well beyond the limits of the actual orebodies, host rock alteration may be used as an ore guide in exploration and drill-hole evaluation. In this application a third hydrothermal discharge centre was identified, as yet untested for are, which is located between the hydrothermal centres associated with the two known orebodies of the deposit.It is estimated that host rock alteration may enlarge a potential drill-target by a factor 10 - 20X. Information on the configuration of bleaching haloes can be obtained from systematic core logging, whereas diagnostic clay mineral alteration is readily identified by means of automated, quantitative XRD techniques."

Jan 1, 1984

By B. M. Das, F. Claridge, V. K. Garga

Coal, as well as a large part of other minerals in Canada, is produced by surface mining methods. This has resulted in short and long-term accumulation of waste rock in dumps. Two main problems arise from the flow of water through these dumps: stability of dumps and the impact on stream flows. In recent years, a number of mines have started placing waste rock in valleys for general disposal or far constructing mine access road ways. All these have created challenges in the following areas: effective design of dumps and flow-through dams; stability monitoring of the structures; environmental impacts downstream by way of increased amount of fines in suspension, sedimentation, and toxic substances; and long-term status of flow and flood. Similar situations also exist in many civil engineering structures. This paper discusses the status of rock drains and the immediate and future research needs.

Jan 1, 1990

By Malcolm Scoble

Process Technologies Suitable for Application Underground Design Criteria - coarse particle technologies - compact, robust, flexible - waste products suitable for use as backfill Process technologies identified: - Optical/conductivity sorting - Dense media separation - Coarse-particle flotation Process technologies supported by compact & efficient comminution stages Mineralogical evaluation to select process & estimate Performance Further Work U/G Plant Layout & Excavation Modelling Evaluate scenario at increasing depth Establish properties of waste as backfill Model impact of improved backfill quality Evaluate further case studies Evaluate further Environmental Health and Safety Issues Model impact of system development on inventory of national mineral reserves Conclusions Technologies exist for integrated underground mining and processing systems These technologies to be successfully integrated into underground mining system Positive economic and environmental benefits Technical issues to be resolved at depth System Development path identified

May 1, 2004

By D. B. Haas

THE HYDRAULIC TRANSPORT of solids is becoming increasingly prevalent throughout the world. Major long-distance slurry pipelines currently in operation transport commodities such as coal and various ore concentrates distances of up to hundreds of miles. In the United States, a number of large-diameter, high-tonnage pipelines are under consideration for the transport of Western Plains coal to markets up to 1000 miles away. In these and other applications, the solids are generally quite fine, with 14 mesh being a typical limit of particle size for long-distance (over 100 miles) slurry transport. There are applications where it might be practical to transport solids consisting of larger particles distances of up t o 100 miles. Deposits of high-quality metallurgical coal are found in the inner foothills belt along the eastern edge of the Rocky Mountains on the Alberta-B. C. border. There are few existing railroad s and the possibilities of constructing extensions are limited because of environmental and economic factor s. In these circumstances, the most efficient transportation system might consist of a pipeline to transport the coal from the mine to beneficiation plants located near existing railroads 50 or 100 miles away. Such systems would minimize environmental effects, capital cost s and operating costs. To determine whether such a system would be technically feasible, experimental testing is needed to determine the energy requirements for transporting coarse coal in a pipe line. Currently, run-of-mine metallurgical coal is crushed to less than 1 1/2 inches before going to the beneficiation plant. In the proposed scheme, coal of this size would be transported through a pipeline to the beneficiation plant located at the railroad. The Transportation Development Agency and the Department of Supply and Services have awarded a contract to the Saskatchewan Research Council to study pipelining of coarse coal in pipelines ranging from 4 inches to 12 inches in diameter.

Jan 1, 1977

By J. B. Kwon

For improvement in the productivity of tall building projects, table formwork is one of the main methods that have been adopted for slab formwork. Because the table formwork method is an equipment-oriented construction method, the type of lifting equipment and method of operation considerably affects the productivity and cost of the table formwork. It is also important to make an equipment input plan for completing the table formwork within the time given, according to the structural construction cycle. For performing the table formwork, a tower crane or an independent lifting system, and shifting trolleys, are required. However, if an inefficient equipment input plan is made, exorbitant cost may be incurred. Therefore, the purpose of this study is to analyze the productivity of a table formwork, considering the type and number of lifting equipment and the number of trolleys inputted, and to suggest quantitative data for making a cost-efficient equipment input plan within the construction duration given. It is expected that the results of this research will be utilized as a basis for cost-efficient equipment input planning.

Aug 1, 2013

By V. F. Hollister

Four conditions are commonly accepted as being needed for the development of native sulphur deposits in sedimentary rocks : (1) ample sulphate-bearing evaporite, normally anhydritic; (2) proximity to petroleum deposits; (3) a hydrodynamic system of communication between these two; (4) a stratigraphic or structural trap to prevent escape of the sulphur and sulphur -bearing reaction products. When any of these requisites are absent, apparently no significant residual bio-epigenetic sulphur deposit will form. These requirements are, however, satisfied in some areas, which include both the Triassic and Devonian evaporites of northeastern British Columbia.

Jan 1, 1977

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By H. N. Tran, D. Barham

"A systematic survey of the appropriate literature in terms of phase equilibria and possible reactions involving deposits in Municipal Solid Waste (MSW) incinerators are analyzed particularly with respect to the theoretical first melting points of typical ashes and the possible presence of a liquid phase at the temperature of ash-metal interface. Conclusions are drawn on the basis of the possible presence or absence of various metal chlorides and sulphates in such situations, and their effects on the problems of fouling and metal corrosion. From preliminary results, it would appear that ZnCl2 is unlikely to be present in any molten phase which causes corrosion because it evaporates rapidly from such liquids. It would also appear that PbCl2 and, by inference, ZnCl2 will sulphate at relatively low temperatures if the flue gas contains SO2 and O2.IntroductionMunicipal Solid Waste (MSW) incinerators produce fly ash which deposits on heat transfer surfaces throughout the furnace, leading to corrosion and loss of energy recovery efficiency. Despite a massive amount of research carried out on the subject of corrosion in MSW incinerators, the problem of corrosion of heat transfer metal is still with us, and no definite over-all cause and effect relationship has yet been identified. In order to make a contribution to the eventual solution of this problem, the authors have examined the problem from the beginning, using their knowledge of fouling and corrosion problems in black liquor recovery boilers as a starting point.The incineration of MSW has been used for many years to reduce the volume of material sent to landfill (ash volume compared to raw waste volume), and, in most cases, to recover energy at the same time by raising steam The steam may be ""low- or high pressure/ temperature"" depending on its end use. The higher the steam pressure and temperature, the greater seem to be the problems with corrosion of heat exchanger metal, presumably because the metal must withstand higher surface temperatures.The chemical and physical composition of MSW is extremely variable, not only on a regional basis, seasonal basis, and day-today basis, but also on a minute-by-minute basis, due to the inhomogeneity of MSW. This makes it extremely difficult to define cause and effect relationships, because both cause and effect are transient in nature."

Jan 1, 1991

By Antoine Fournier, Karen St. Seymour

"Responding to market developments, interest in locating deposits of wollastonite has grown significantly. The many occurrences in the Grenville marbles of Quebec can be grouped into disseminated type and discordant vein-type deposits. Disseminated-type wollastonite occurrences have the disadvantages of lower grade, the need for more elaborate mineral separation, and failure to meet ""long grain"" technical specifications. Vein-type deposits have better grades and technical characteristics; exploration should be focussed on these and in the contact-metamorphic aureoles of fluid-rich intrusions. SOMMAIREEn réactions aux nouveaux de bouches, l'interet pour les gîtes de wollastonite a crû de façon marquée. Les nombreux indices sis dans la province de Grenville au Québec peuvent être regroupes en deux catégories soit: les indices dissémines et les indices en veines discordantes. Les indices dissémines ont le désavantage d'être moins enrichis, de requérir une séparation minéralogique plus complexe, et leur wollastonite ne possède pas le degré d'acicularité voulu. Les indices en veines sont plus enrichis en plus de rencontrer les critêres techniques; les efforts d'exploration devraient se porter vers ce type de gites et aussi, sur les auréoles métamorphiques de contact d’intrusions riches en fluides."

Jan 1, 1992

By R. J. Mitchell

"The use of hydraulically delivered classified tailings sands to provide ground support in large mining operations is still widespread despite recent developments of alternate backfilling methods and materials. The major disadvantages of the use of hydraulic fill are the costs and risks associated with slurry delivery. The main risk is that of bulkhead failure resulting from sand liquefaction due to insufficient operational control or due to dynamic loading from earthquake or rockburst. That risk may be eliminated by the pouring of a stiff cemented sand plug in the base of each stope prior to continuous fill pouring in that stope. An additional advantage of cemented plugs is that massive bulkheads are not needed. Instead, a temporary (removable and reusable) bulkhead can be used for plug forming.Physical model studies of fill pressures on a temporary bulkhead were carried out in a 3 m radius centrifuge facility. Fill pouring in-flight was carried out in order to model prototype stress paths. The results indicate that the average bulkhead pressure is likely to be less than 10 kPa under normal operating conditions and less than 20 kPa under the poorest anticipated operating conditions which include smooth walls, high slimes content and high water-content slurries. A portable bulkhead consisting of a central core and a surrounding sealing bladder was modelled and found to be effective. The use of different sizes of cores allowed the stress distribution adjacent to these bulkheads to be evaluated."

Jan 1, 1992

By Arnfinn Prugger

"The construction of the new Scissors Creek shaft at the Rocanville mine, the first potash shaft successfully completed in Saskatchewan Canada since 1979, is summarized here. Located 15km from the existing Rocanville surface plant, this new 6 m inside-diameter, 1121 m deep service shaft was built for fresh-air ventilation and access. Shaft construction in the Saskatchewan sedimentary basin involves sinking through five different rock-types: glacial tills, shales, sandstones, carbonates and salts. The first four rock- types are all water-bearing, and the salts will dissolve in water. This results in five different sinking challenges and requires five different shaft lining designs. The upper 580 m of rock (the till – shale – sands sequence) was frozen before sinking, and grouting methods were used for water control through deeper carbonate levels. Challenges that were faced and overcome during shaft sinking are reviewed, and ideas that future operators working in sedimentary basin environments might consider in order to avoid these difficulties are discussed.INTRODUCTIONThe Nutrien Inc. (formerly Potash Corporation of Saskatchewan Inc. / PotashCorp) Rocanville potash mine in southeast Saskatchewan, Canada has been in continuous production since 1971. Devonian potash, formed approximately 380 Mybp, is mined in a sedimentary basin environment at approximately 1000 m depth below surface in this area of Saskatchewan. The predominant use for finished potash products is fertilizer: potash fertilizer is concentrated and nearly pure KCl (i.e. greater than 95% pure KCl). Currently 10 potash mines are in operation in Canada, all in Saskatchewan. In 2018 Saskatchewan mines produced ˜ 23 million tonnes of finished potash products, which is approximately 35% of World demand of ˜ 66 million tonnes for the year (e.g. Nutrien Inc., 2019).In November, 2007 it was announced that the Rocanville potash mine would be expanded to increase production from 3.0 Million tonnes per year (Mtpy) to approximately 6.0 Mtpy of finished potash products, requiring an increase in hoisting capability from approximately 9.0 Mtpy to over 18.0 Mtpy. The Rocanville potash mine has historically been accessed through two shafts: a production and ventilation exhaust shaft, and a service and ventilation fresh-air shaft located approximately 200 m from each other. All surface offices, processing facilities, etc. are situated near these original shafts.A very important part of the recent Rocanville expansion involved the construction of a new service shaft (6 m diameter, 1121 m deep) for fresh-air ventilation and access, approximately 15km west of the existing surface plant. Once this third shaft was completed in 2015, the historical service shaft was converted to a second exhaust and production shaft. Three shafts are now available for mine access, ventilation and ore hoisting at Rocanville. As of December 31, 2017, annual nameplate capacity for Rocanville was 6.5 million"

Jan 1, 2019

By S. A. Kenzap

Risk & Uncertainty ? Uncertainty about a situation can often indicate risk, which is the possibility of loss, damage, or any other undesirable event. Most people desire low risk, which would translate to a high probability of success, profit, or some form of gain. Risk = Likelihood x Consequence Risk is the possibility of loss, damage, or any other undesirable event.

Oct 1, 2010

By M. Sugamata

Creep tests were carried out for friction welded joints of AZ31 magnesium alloy rods under an ambient atmosphere at temperatures between 423 and 573K. Tensile tests were also performed at temperature from room to 573K. The obtained results were compared with those of the base metal. AZ31 extruded rods of 19 mm in diameter were joined by brake type friction welding machine. Creep and tensile specimens were machined out of the welded rods. The tensile strength of the joints was almost the same as that of the base metal at room temperature. However, joint efficiencies of welded joints were about 92% at above 373K. The elongation of welded joints was lower than those of base metal. The welded joints showed appreciably higher minimum creep rate and shorter rupture time than the base metal at all the tested temperatures and initial creep stresses. Creep and tensile rupture of the joints always occurred at near the weld interface. Thus, friction welded joints of AZ31 alloy showed lower creep and tensile strength than the base metal at elevated temperature.

Jan 1, 2006

By M. Medraj, M. A. Arafin, D. P. Turner, P. Bocher

In this study, the kinetics of isothermal solidification during TLP bonding of Inconel 625 and 718 superalloys with nickel based multi-component filler alloy BNi-2 have been studied through a combination of direct experimentation and mathematical modeling in order to determine the effect of process variables and, thus, to optimize the process. The predicted isothermal solidification completion times from the boron diffusion model and migrating solid/liquid interface model were in good agreement with the experimentally determined values and, they were found to be significantly less than those of other nickel superalloys with different nickel based filler alloys. Further, significant reduction of holding time was observed with increasing bonding temperature and with decreasing joint gap. No significant grain growth in the base metals has been observed in the temperature range being investigated (1325 - 1394K).

Jan 1, 2006

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By D. Milne, P. Germain, G. Sauriol

"The practical determination of optimum stope geometry has, until recently, been an art relying primarily on experience at a given operation. Due to the complex and variable nature of rock masses in situ, stopes are often designed either very conservatively, resulting in excess development, or non-conservative resulting in excessive dilution and, in some cases, in loss of ore reserves.The Geomechanics group of the Mining Technology Division, Centre de Recherche Noranda, uses a combination numerical modelling and empirical design techniques to optimize allowable stope geometries. The above methodology allows the optim ization of stope geometry for varying rockmass classifications within an operation or between different operations. Such techniques require the development of a thorough geotechnical database at each operation and are best used when calibrated to the specific operation through back analysis.This paper discusses the above optimization techniques in light of specific examples from the Noranda Group. The design methods, limitations and results are discussed.INTRODUCTIONMine design has traditionally referred to production planning, general facility layout, (i.e. ore passes, crusher stations, main haulage drifts, etc.) and ventilation design. The dimensioning and sequencing of the stopes and pillars, however, has been almost solely based on trial and error and precedent practice.More recently, numerical stress analysis has received much more attention as part of the design process. It is common now at many operations to look at the effect of proposed stope layouts and sequences on stress redistribution through the surrounding mine workings. Through calibration of actual stope and pillar behaviour in situ, one can then relate the model predictions to support requirements, safety problems, etc."

Jan 1, 1989