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By B. Stettner, J. Asante, S. Abraham

The levels of nitrogen in steel produced in various metallurgical vessels vary significantly. For example, the tap nitrogen levels in steel produced in the BOF are around 4Oppm, as compared to 70-100ppm in both DC and AC electric arc furnaces. Given the pressing need to reduce nitrogen levels in steel to satisfy customer demand, IPSCO Inc. has gained considerable experience in controlling nitrogen levels in steel over the course of the last three years. Hence, a cost effective process has been developed through an intensive nitrogen control program from steel melting in the EAF through to the continuous slab casting stage. This paper describes the practices employed at each stage of the steelmaking process that have enabled IPSCO Inc. to reduce and control nitrogen levels in steel.

Jan 1, 2004

By Robert Dickson

Princess colliery is operated by Old Sydney Collieries, Limited, a direct descendant of the General Mining Association of London, England, which, in the first quarter of the nineteenth century, pioneered in coal mining in Nova Scotia. The coal worked is a 5 ft. 6 in. seam known generally through the Sydney coalfield as the Harbour seam but referred to locally as the Sydney Main. Entry is made by shafts, 680 feet deep, sunk in 1871 on a headland forming the northern entrance to Sydney harbour. From them extend the main roadways of the colliery, a distance of 700 feet to the shore line and a further distance of 14,700 feet in submarine areas to a total length of 15,400 feet. It was the first colliery in Nova Scotia designed to work submarine areas. Lateral development extends across a frontage of 16,000 feet and the submarine area from which the coal has been extracted is slightly over 6 square miles. There yet remains sufficient territory ahead of the workings to assure a future life to this colliery estimated at over 80 years at the current rate of production. In this area the seam dips at 6 to 7 per cent and face workings have reached a depth of 1,690 feet below the sea level. Until 1923 extraction of the coal was by room-and-pillar, followed by the drawing of the pillars. At that date the superincumbent strata had reached a thickness of 1,400 feet, resulting in heavy weighting on the roof and severe side pressure on the coal ribs. In combination with a soft, heaving pavement this created a set of conditions involving great difficulties and expense in keeping open places driven in the solid sufficiently long to permit recovery of the coal in the pillars by methods and equipment then available. The operator was forced to resort to extraction by longwall as the only economical method of winning the coal.

Jan 1, 1948

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By D. K. Sarkar, J. Perron, J. D. Brassard

"Nearly perfect spherical shaped water drops rolling-off from the surface of lotus leaf is one of the beauties of nature. This kind of surface is called superhydrophobic, since the water does not like it. Physically, a superhydrophobic surface provides a contact angle (CA) of water over 150°. The combinations of both mico-nanostructure topography as well as low surface energy are essential to have such high CA on a surface. Nano-micro structured superhydrophobic surfaces have been developed in different methods. (i) Monodispersed fluorinated silica nanoparticles have been synthetized via Stöber Sol-Gel process and deposited on various surfaces, such as aluminium or glass, to obtain transparent superhydrophobic thin films. (ii) Similarly, zinc stearate nanocomposite coating has been fabricated by spray process on the same substrates. These thin films are found mechanically robust with drag reduction of coefficient 16% lower than as-received surfaces. (iii) By electrodepositing pure zinc on steel surfaces and further coating it with diluted room-temperature vulcanized silicone rubber, the surface become superhydrophobic. This superhydrophobic surface protects the steel against corrosion by increasing the polarization resistance from 1.5 k? on steel to 44.4 k?. This coating also reduced the ice adhesion on the steel surface 6.3 times as compared to bare steel substrates. Globally, these superhydrophobic surfaces have tremendous applications against corrosion reductions, drag reductions and ice adhesion reductions.INTRODUCTIONSuperhydrophobic coatings are increasingly attractive to the industry and academia due to their unique self-cleaning properties as a result of their water repelling characteristics. Fabrication of superhydrophobic coating is an inspiration from nature as water is seen to repel on many natural surfaces such as those of the lotus leaves, butterfly wings, water striders’ legs, and so on (Gao & Jiang, 2004; J. Huang, Wang & Wang, 2006; Neinhuis & Barthlott, 1997; Zheng, Gao & Jiang, 2007). This non-wetting phenomenon is well understood on lotus leaves, shown on the Figure 1 (a), and it is considered as the basis of the studies of superhydrophobicity. The existence of this binary structure on the surface of the lotus leaves allows a large amount of air entrapment and consequently reduces the contact area of water on it and the presence of low surface energy waxy components with reduced affinity to water together leads to the superhydrophobic properties. The phenomenon is shown on Figure 1 (b). Cassie and Baxter (Cassie & Baxter, 1944) as well as Wenzel (Wenzel, 1936) proposed two mathematical models to explain the wetting phenomena on rough surfaces that leads to superhydrophobic properties. By definition, superhydrophobic surfaces are characterized by a water contact angle value = 150° with the rolling off of water drops from the surfaces (Sarkar & Saleema, 2010). Superhydrophobic surfaces find tremendous importance in the technological world where it can applied in domains such as anti-corrosion, anti-biofouling, electrowetting, icephobic and even in drag reductions (Bushnell & Moore, 1991; Cao, Jones, Sikka, Wu & Gao, 2009; Carlborg & van der Wijngaart, 2010; Carré & Mittal, 2009; Y. Huang, Sarkar & Chen, 2010a; R. Karmouch, Coude, Abel & Ross, 2009). However, the most important challenge faced by industries is their feasibility large scale in an effective an economical manner."

Jan 1, 2016

By Greg Gosson

"Early efforts to develop formal reporting systems to quantify and classify mineral deposits date back over 100 years. (e.g. Hoover 1909: “Proved, Probable, Prospective Ore”). This was at first driven by mine operators’ need for reliable estimates of what their mines could produce. Disruption of transportation routes by world wars prompted western governments to recognize the need for assessments of strategic sources of metals and minerals that could support domestic industry during times of crisis. Categories were created to quantify mineral potential which were additional to those of mine reserves. Terms such as hypothetical and undiscovered resources entered the lexicon. Capital markets serving the mining industry were traumatized during the latter part of the 20th century by undisciplined and fraudulent disclosure by exploration companies of mineral deposit potential. Government securities regulators pressed for the development of credible reporting codes (e.g. SEC Industry Guide 7: 1981; JORC 1989; SAMREC 1994, CIM 2000). Representative organizations from the major western mining countries generally agreed that there should only be three categories of mineral resources (measured, indicated, and inferred) and two categories of mineral reserves (proven and probable). This was formalized in 1997 with the “Denver Accord”. Acceptance of the standard terminology may have been the easy part, because the challenge for the 21st century is to get general industry acceptance and agreement of the principles behind the definitions of each category. There has been noticeable movement towards this objective in the last few years. This is reflected in part in the updated reporting codes by JORC 2004, CIM 2005; SAMREC 2007; SME 2007; and PERC 2008, and the development of the CRIRSCO International Reporting Template 2007."

Jan 1, 2003

By W. A. Jones

"The Ross mine, a subsidiary operation of Hollinger Consolidated Gold Mines, Limited, is near the north end of lot 1, con. II, Hislop tp., Ontario. The property comprises the north half of lot 1, con. II, and the south onethird of lot 1, con. III. It is readily reached by a good motor road from the village of Ramore, 7 1/2 miles to the southeast on the Ontario Northland railway. The mine is being developed to a depth of 1,500 feet, and the current daily production rate is approximately 300 tons. From the inception of operations in March 1935 until December 31, 1945, 692,000 tons of ore, with a total value of $5,762,685, was milled . The silver to gold ratio of 1.48 to 1 is unusually high for Ontario gold mines.TYPE OF 0REBODIES AND MINERALIZATIONThe orebodies consist of lens-shaped and pipe-like stringer lodes and tabular vein zones composed of parallel quartz stringers. The host rocks are steeply inclined eruptive breccias and tuffs, striking N.70°W., intruded by very small stocks of red syenite. The orebodies appear to be spatially related to an intricate system of fault planes. Hydrothermal alteration is widespread and is not zonally related to individual quartz stringers. The wall-rocks contain abundant fine-grained pyrite, but gold is confined to the quartz stringers.RELATIONSHIP TO REGIONAL STRUCTURELack of outcrops has prevented the detailed mapping of the Keewatin complex in the vicinity of the Ross mine with the degree of success that has been achieved in the Porcupine area.A northwesterly trending belt of slates and greywackes, bounded by faults, forms the central part of a broad anticlinal arch about 3 1/2 miles north of the Ross shaft. Lava flows forming the south flank of the structure face south toward the mine. If the sediments are to be tentatively correlated with the large areas of Keewatin slates and greywackes of the Porcupine area, it must be assumed that they are younger than the lava flows and that they have been down-faulted."

Jan 1, 1954

By D. S. Salonine

Aluminum alloys are widely used in modern industry. Tubes and hollow shapes give great opportunities for structural purposes as well as fluid transport due to their stiffness and lightness, Extrusions on a mandrel or through a bridge die, that requires splitting of the billet with re-welding, produce hollow shapes with varied contours, fins and multiple cavities. Moving and stationary mandrels, mandrel lubrication, tooling for ribbed-tube heat exchangers, and for drilling pipes are considered. Bridge dies can be classified by the bridge position relative to the die face, by mandrel support structure, and by assembly type, The main parameters influencing the quality of the die-welded seams are considered, The difficulties of extruding various alloys through bridge dies are discussed in terms of metallurgical factors, Some approaches to the calculation of the stresses in a bridge are presented.

Jan 1, 2005

By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By J. W. McCammon

WHEN times are booming and metal prices are high, most mining men pay little attention to the industrial mineral industry. However, when metal prices drop and mines close down, many mining eyes begin to scan the less glamorous non-metallic field. For some this proves a temporary diversion, but others find this branch of mining, with its generally more stable conditions, to their liking and enter it permanently. The resulting gradual influx of trained mining men into the industrial mineral industry ?has been one of several factors responsible for the rise in production of non-metallic materials in our Province. Another and ?perhaps the most important factor influencing the production of industrial minerals has been the growth in the population of British Columbia. Because most industrial minerals .are low priced and either heavy or bulky commodities they are normally sold on relatively local markets. Thus the extent of the development of the industrial mineral industry of a region is largely governed by the size of the population and the level of industrialization of that region. This point is well shown by com-paring population and industrial mineral production statistics for 1936, 1946, and 1956 (see Figure 1)9. Note that not only has the overall production rate grown with the population increase, but that the per capita production has risen greatly.

Jan 1, 1958

By W. Dziurzynski, St. Wasilewski, T. Palka, A. Krach

"Air parameter monitoring systems, regardless of gasometrical protections, provide a significant number of measurement data. The obtained data broadens the knowledge on processes taking place in underground workings and shows the relationships and influence of machines and technological processes on the variability of ventilation parameters in the areas of longwalls. Nowadays, computer simulation methods are increasingly used to reproduce the flow of air and methane mixture in the area of longwalls equipped with shearers. The paper presents the results of a research experiment covering a long-term observation of a longwall area during mining with a shearer using sensors from the mine's monitoring system. Data from sensors for methane concentration, pressure and velocity were used and additional ventilation measurements were taken to determine the parameters characterising the air flow in the area. The influence of different machine cycles in the longwall on the changes of air parameters in the area of the longwall was shown. A numerical model of the ventilation area was developed and the computer program VentZroby was used for the calculations, which allows for the simulation of the process of ventilating the area of the active longwall during the extraction of coal with the use of a shearer and haulage of the run-of-mine. Computer simulation of the influence of the shearer's operation and the methane inflow associated with the distribution of the mixture of air and methane was carried out. The results of the simulation were compared with the data recorded by the monitoring system’s sensors during the measurement experiment. Comparison of the recorded methane concentration courses with the results of a computer simulation of the air and methane flow conditions in the mining area showed changes in the gassiness. INTRODUCTION Studies carried out in the Polish and global mining industry show that methane is an obvious factor in limiting mining production due to the loss of continuity in the operation of longwall complexes in hard coal mines under methane emission hazard (Schatzel et al., 2008). In addition, methane hazards have a significant impact on the safety of the operators of machinery in the longwall. The requirements of Polish regulations and the practice of safe operation of mining longwalls require correct determination of gas concentration, volume flow, as well as pressure and temperature of the flowing air. As part of the research undertaken in the Budryk (Wasilewski, 2010) and Bielszowice (Dziurzynski et al., 2009) mines to assess the methane hazard in the longwalls and workings in the vicinity of the longwall, research experiments were carried out, during which air parameters were recorded by the mine monitoring system and additional testing equipment in different cycles of shearer operation."

Jan 1, 2019

By Y. Mitsuda, Y. Kayanuma, T. H. Okabe, M. Miyake

A new process to recover platinum group metals (PGMs) from automotive catalyst scrap using metal vapor was developed. To improve the efficiency of the acid dissolution process of PGMs, metal vapor of reactive elements such as magnesium or calcium were contacted with spent automotive catalyst. It was expected that metal vapor would react with metal selectively and form intermetallic compounds. The specimen of the spent catalyst was treated at 1173 K for 3 h, and it was then dissolved in aqua regia for 1 h to recover PGMs. After the reactive metal treatment, 88% of Pt, 81% of Pd, and 72% of Rh in the catalyst scrap was dissolved, while only 77% of Pt, 69% of Pd, and 38% of Rh was dissolved from untreated scraps.

Jan 1, 2004

By Doug Milne

Linking Classification Systems with each other Similar Parameters between systems Different Rock Mass Properties Rock Mass Classification parameters and geology Different sources of data Commonly Used Rock Mass Classification Systems Q? = Q with SRF = 1.0 RMR? = RMR with no joint orientation correction RMR76 = 9lnQ + 44 RMR?76 = 9lnQ? + 44 RMR76 = RMR89-5 RMR?76 = GSI = RMR89-5 MRMR = ??MRMR

May 1, 2013

By A. LA. Salama, D. B. Hyma

"The Western Research Centre (WRC) of CANMET located in Devon, Alberta, is a modern research facility offering services ranging from fundamental research to pilot plant investigations. Recently, a 0. 76 metre diameter by 7.9 metre high Flotaire column flotation cell was installed as a demonstration unit for Canadian coal producers. Because the column cell is intended to be used for research, development and demonstration, WRC recognized that additional sensing equipment and improved process control would be required to generate good data for subsequent column scale-up and engineering design.A low cost, personal computer based control system was, therefore, designed and installed. This paper describes the stepwise procedure in developing the control strategies, selection of system software and hardware, and installation and configuration of the system.Preliminary performance data on a western Canadian coal sample are also presented. Future testwork is planned on additional coal samples to expand upon existing database."

Jan 1, 1993

By A. R. Laplante

Gold recovery early in the flowsheet, typically from the primary grinding circuit, has seen significant advances in the past three years. Some of the advances achieved under the auspices of the AMIRA P420B Gold Processing Technology project are reviewed. The areas covered are gravity-recoverable gold (GRG) characterization, GRG behaviour in classification, gravity recovery simulation and the link between gravity recovery and cyanidation.

Jan 1, 2005

By Paul G. Dunn

The planning of underground mines is a complicated process involving geological, engineering and operational constraints. MIRARCO is in the process of developing a 5D Mining Exploratorium where 3D mining models are combined with time (4th dimension) and costs (5th dimension). The mining exploratorium is a collection of external and inhouse software packages specifically geared to help underground mining companies arrive at better mine plans. This paper discusses the progress made in the development of the 5D Mining Exploratorium and a change in mine planning philosophy by conducting frequent audits in a Virtual Reality Laboratory. The development of genetic algorithms for optimising stope sequences is also presented.

May 1, 2003

By Frank Mucciardi, Louca Gourtsoyannis

"Low and inconsistent recoveries of aluminum in the production of aluminum-killed steels triggered an extensive research program on the aluminum dissolution kinetics at McGill University. This research program led to the understanding of the melting kinetics and the hydrodynamics of making additions to liquid steel. It showed the necessity of gradually releasing liquid aluminum at the bottom of the ladle to increase aluminum recoveries.This knowledge was verified in practice at Sidbec-Dosco, where a prototype aluminum wire injector was developed and installed for the first time in Canada. The industrial application showed the validity of the theoretical and experimental results and provided further data for the mathematical modelling of the process.The development of the theoretical understanding, the industrial results, and the interaction between university and industry are presented.IntroductionAluminum is an extremely effective deoxidizer of molten steel; nevertheless, an efficient method of adding it to steel has eluded steelmakers for many years. It is well known that the recovery of aluminum used in the production of aluminum killed steel is both low and eratic, especially when the aluminum is added in the form of bars or lumps from chutes into filling ladles, a practice still common in many of today's steelmaking operations.As the density of aluminum is only about 40010 that of molten steel, it is conceivable that loose bars of aluminum simply ""thrown"" into a filling ladle will resurface before any appreciable dissolution of the aluminum has occurred, particularly if the depth of penetration of the additions is small. Before one can conclude that this is indeed the case, it is necessary to know the melting kinetics of an aluminum addition. Back in 1972, this information was not available; hence an extensive research program which focused on melting kinetics was initiated at McGill University."

Jan 1, 1982

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

By Jim Robertson

Summary of Presentation ??What is the GARD Guide ??The Need for a GARD Guide ??Mining Industry?s Commitment to Solving ARD Problems ??The Ultimate Solution ?You ??The GARD Guide ?Scope ??The GARD Guide ?Structure ??Wiki Demonstration

May 1, 2009

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016