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By R. Le

"The principles of noise control aredescribed with particular emphasis on personalactive units as opposed to passive ear muffspresently in general use. A discussion followsfor their potential use in a mining environment.RÉSUMÉNous décrivons brièvement quelquesprincipes de contrôle de bruit à l’usage person-nel, puis nous passons en revue quelquescasques commerciaux dotés de ces circuits àprincipe actif. Enfn nous discutons de leurusage potentiel dans le contexte minier.IntroductionLe casque à principe actif est un produitqui existe commercialement, mais encore peurépandu en usage, sûrement à cause du prix,mais aussi de sa méconnaissance par le grand public. Il arrive parfois qu’un journaliste trouvele produit fantastique et le médiatise commeune réalisation de son pays (ou de sa province),mais peu savent qu’il s’agit là d’un principe quia commencé dans les années 30. Par delà lesensationnel, il reste que si l’on veut mettre lamain sur un de ces casques pour l’essayer, on nesait où l’obtenir. De plus, les casques n’utilisentpas tous le même principe actif. C’est la raisonpour laquelle nous faisons cette brève compara-ison. Nous le faisons en mettant l’accent pourune possible utilisation dans le domaine minier,car c’est dans ce milieu que les usagers sontconfrontés aux bruits les plus intenses qui peu-vent endommager leur système auditif, ce quin’exclut pas les autres situations (travaux publics, foresterie, écoute hi-f, etc.)."

Jan 1, 1997

By Shila Jafari, Mari Lundström, Aleksei Kritskii, Pia Sinisalo

A typical process adopted at nickel plant is the processing of nickel-copper mattes and converter mattes using the following technology: pressure oxidative leaching (POX), solvent extraction (SX), electrowinning (EW), cobalt recovery, and solutions purification. As a result of multi-stage atmospheric and autoclave process leaching, copper-nickel separation is achieved. Cobalt and nickel are further separated by SX. Copper in the process can be removed as copper cake (Cu-cake), which is a by-product with high content of valuable metals. In the current paper, a method combining atmospheric and pressure leaching of Cu-cake in sulfuric-acid media is discussed. Suggested method allows to obtain high copper extraction (>98%), with leach residue containing precious metals and PGMs. Sulfuric acid media was chosen to make the suggested technology adaptable for the primary POX-SX-EW circuit. The initial Cu-cake was analysed and a range of process parameters (t = 25–190°C; PO2 = 0–7 bar) investigated to achieve the optimal conditions for leaching process at the ambient as well as at increased pressure. As a result, an initial process block diagram for the treatment of Cu-cake with high copper leaching efficiency and low metal losses is provided. INTRODUCTION The conventional technology for nickel sulphide ore processing includes the following main stages: froth flotation, matte smelting and converting. The subsequent processing of nickel converter matte is possible using fundamentally different approaches - hydrometallurgical (Llanos, Queneau & Rickard, 1974; Rademan, Lorenzen & Van Deventer, 1999; Kshumaneva, Kasikov, Neradovskii & Belyaevskii, 2009; Dutrizac & Chen, 2013) and pyrometallurgical (Tsymbulov, Knyazev, Tsemekman & Golov, 2007). Hydrometallurgical approach in comparison with pyro-process has several advantages, such as reduced environmental load, reduced PGM losses, increased copper and nickel extraction. Typically, hydrometallurgical technologies include leaching, solvent extraction as well as nickel and cobalt recovery in metallic form by electrowinning or hydrogen reduction or as valuable metal salts via crystallization process (Crundwell, Moats, Ramachandran, Robinson & Davenport, 2011).

Jan 1, 2019

By E. G. Baltuch

Natural Ventilation in mining and metallurgical processing applications is key to proper operation function. There are number of ventilator designs available to a project team or design engineers, the selection of which will affect both the type of building structure required, project costs and design performance which is difficult to rectify or re-engineer once implemented. Research and applied results, such as that performed by Air-Therm Inc., demonstrates that computational fluid dynamic simulation allows for 5 dimensional observation, analysis and optimization at significantly lowered cost than previously possible. These results have been fully implemented on a number of mining and metallurgical applications and the company continues to study, optimize and innovate as new tools become available to provide the best possible engineered solutions for particular applications.

Aug 1, 2013

By F. Chevarin

The reaction of O2 with the carbon anode is considered as the main parasitic chemical reaction affecting Hall-Heroult process anodes. The current study aims at investigating the influence of the microstructure of baked anode on its overconsumption. Samples were removed from different positions of an industrial anode. Density, porosity, Lc and BET specific surface area were measured. The anode reactivity was evaluated based on the weight losses for the samples resulting from the reaction of anode with air at 550°C after 7h. The essential parameters determined to control the air reactivity are closed porosity, Lc and pores with a pore entrance radius of 1.5, 8.5 and 12 p.m. The knowledge of effects of these parameters allows better understanding of the reactivity of anodes and consequently reduction of their overconsumption in electrolysis bath.

Jan 1, 2011

By Robert B. Parsons

"While it might seem like heresy to suggest that ""taxation"" can be a source of financing, never the less some generous tax rules can considerably enhance the tax savings pertaining to a particular expenditure or project. A basic tax knowledge, and careful tax planning, can optimize government participation in a project. INTRODUCTIONIn trying to identify sources of financing for a project, ""government"" as a source of funding is normally thought of in terms of government grants, loan guarantees, interest rate buy downs, property tax waivers, hydro subsidies, and so on. Generally, such concessions are somewhat difficult to obtain, especially in the current period of apparent fiscal restraint. One source of government funding which should not be overlooked is the income tax regime, and, at the provincial level, the various provincial mining tax regimes.While the taxpayer would not normally view a tax system as a potential source of government financing, nevertheless various federal and provincial rules applicable to the mining industry can offer attractive tax deductions - and tax savings - with respect to particular expenditures. In fact, it is not unusual for a civil servant to refer to a tax deduction as a tax ""subsidy"". For example, in the right circumstances, the cost of a smelter expansion in New Brunswick would cost the operator only 31 cents on the dollar, with the federal and provincial governments paying for the other 69 cents by foregoing tax revenues (Table I). In a sense, such tax savings could be compared to a government grant equal to 69% of project costs. Of course, not every project expenditure will generate that degree of government funding. The fact of the matter is that the percentages of tax savings attached to different expenditures cover a wide range, depending on a complex mix of factors. The point to understand is that the tax rules can offer some valuable savings, even after tax reform, and that a basic knowledge of the tax rules can yield some fruitful rewards."

Jan 1, 1989

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

By D. A. Bordin, C. J. Newman, R. J. St. Eloi

"The requirements for a metallurgical acid plant treating smelter gases are both unique and demanding in terms of sulphur dioxide treatment and emission control. Since start up in 1981, the copper smelter at the Kidd Creek Division of Falconbridge Limited has undergone several major expansions. The expansion and modification of the acid plant has been an integral part of this process. Both production demands and government regulations dictate that this metallurgical acid plant be unique in terms of operating flexibility. The variable capacity to treat a wide range of sulphur dioxide concentrations, and the operating flexibility to control emissions are the topics of this paper.INTRODUCTIONThe Kidd Creek Division of Falconbridge Limitied is a base metal mining and metallurgical complex located in Timmins, Ontario. The discovery of the original copper-zinc-silver orebody was announced in April, 1964. Mining operations began in 1966 with a 9000 tonne per day concentrator coming on stream in November of that year. In April 1972, a 108 000 tonne per year zinc plant was commissioned. Over the years the facilities have been expanded, such that the concentrator now has the capacity to process 13 000 tonnes of ore per day . To expand zinc production, the world's second installation of the Cominco/Sherritt pressure leaching facility was completed in 1983 to bring total zinc production capacity to 125 000 tonnes per year. In 1973, serious planning for a smelter operation began. In early 1975, after studying both continuous smelting and flash smelting processes, a decision was made to proceed with the technology offered by Mitsubishi Metal Corporation of Japan. The Mitsubishi Continuous Smelting Process was to be used for the smelter and the Onahama No.3 tankhouse technology for the copper refinery.The smelter, which uses the Mitsubishi Continuous Smelting Process for the continuous production of blister copper from concentrate, went on line in June 1981. It has been expanded from its original capacity of 60 000 tonnes to 100 000 tonnes per year of copper.From the very early design stages for the metallurgical complex, the company had adopted a policy of constructing and operating modern plants which would meet existing and anticipated environmental standards. With this in mind, the decision was made to utilize the proven technology of fixing sulphur dioxide emissions, in the form of sulphuric acid. A 636 tonne per day single absorption contact acid plant was built to serve the zinc plant in 1972. In 1981, an 883 tonne per day double absorption contact plant was built to serve the needs of the copper smelter. The copper smelter acid plant has since been expanded to a design capacity of 1692 tonnes per day and it is the main focus of this paper."

Jan 1, 1989

By D. S. Flett, A. V. Tolstov, M. A. Mulagaleeva, N. V. Gudkova, A. M. Zhizhaev, V. I. Kuzmin, Institute of Chemistry and Chemical Technology SB RAS, O. A. Logutenko, V. N. Kuzmina

The complex niobium-rare earth pyrochlore-monazite-crandallite ores of the Tomtor deposit, located in the Siberian Arctic, should be considered as a new type of rare metal materials. The major valuable components of the ore are niobium, rare earth elements, yttrium, and scandium; associated components are titanium, vanadium, aluminum, and phosphorus. Because of the irregular distribution of the rare earth metals and niobium according to grain-size, the extremely finely dispersed nature of the minerals and their close interpenetration to each other, ore processing by gravitation and flotation is not successful. The processes studied for the treatment of the Tomtor ores use direct alkaline-acid leaching to open the ore. A problem in the first stage of alkaline leaching is the high aluminum content, which decreases the activity of sodium hydroxide and alkaline-earth metals, which are bound to phosphorus. Ore processing using alkaline-nitrate and alkaline-chloride leaching was proposed and investigated. The first variant was used to obtain rare earth and scandium materials and a niobium-titanium concentrate, which can be a stock material for processors who use chlorination for the processing of ores and concentrates. The second variant is a complex advanced ore processing scheme with electrochemical regeneration of the waste chloride solutions obtaining sodium hydroxide, hydrochloric acid, and chloridizing agents. Moreover trisodium phosphate is used for purification of the waste mother liquors from metal cations. The complex salt, NaAlCl4, is proposed as the chloridizing agent for the decomposition of the niobium-titanium concentrate.

Jan 1, 2016

By W. R. Richmond, T. S. Li, D. Ilievski

The reactive precipitation of ferrihydrite was studied in a laboratory semi-batch precipitator, where a highly concentrated sodium hydroxide solution was fed into an iron nitrate solution. Instantaneous hydrolysis of iron[III] takes place when the two reagents are mixed generating supersaturation, and leading to immediate precipitation of ferrihydrite via a primary nucleation mechanism then followed by limited crystallite growth to 3 to 7nm. A mathematical model of the semi-batch laboratory precipitator was used to simulate the pH responses during the precipitation of ferrihydrite at different reagent feed rates. The model comprised of interconnected compartments of averaged hydrodynamic conditions, incorporating physically meaningful turbulent mixing time constants. The precipitation process is described by the solute concentration conservation equation incorporating a postulated ferrihydrite primary nucleation model. It was found that the semi-batch precipitator model predicted the experimental pH response reasonably well. The experimental results demonstrated that the reagent feed rate has a critical effect on the course of the precipitation of ferrihydrite, i.e. it is a rate determining step given the fast hydrolysis and precipitation kinetics.

Jan 1, 2005

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By B. C. Legg, G. L. Tiley

"Many of the ore bodies presently being developed are in remote locations and are, or will be, served by electrical power supply systems of limited capacity.The largest single components of the electrical systems of an underground mine are usually the production hoist drives; the power demands of these drives vary continuously throughout each hoisting cycle.Before 1970mine hoists were driven by either wound rotor induction motors or DC motors in conjunction with motor generator sets.Static Power conversion equipment now costs less to purchase and install and is claimed to be more efficient than motor generator sets. On the debit side, however, it can adversely affect the hoist motors, it operates at relatively low power factors, and it produces harmonic currents.This pa per discusses the effects of static equipment on both DC motors and AC power systems, and evaluates the relative consumption of the three classes of drives."

Jan 1, 1993

By L. Jiang

This report investigated the dynamic recrystallization (DRX) phenomenon in magnesium alloy AZ31 billets to understand the deformation mechanisms and microstructure evolution during extrusion and other metal forming processes, Compression tests of coarse-grained as-cast magnesium alloy billets containing lamellar Mg17Al12 eutectic phase and (Al, Mn) particles suggest that temperatures higher than 300°C, strains greater than 0,25 and strain rates above 0,l/s lead to the formation of fine DRX grains in the deformed samples. Microstructural observations also indicate particle-stimulated DRX nucleation (PSN) during hot deformation of the AZ31 alloy, facilitated by the presence of Mg17Al12 and (Al, Mn) particles, While the Mg17Al12 is dissolved into the matrix at about 350°C, (Al, Mn) particles may remain effective for PSN at temperatures up to at least 400°C, This study suggests that alloy design with a proper distribution of second-phase particles can provide the desired microstructure for improved properties and formability in wrought magnesium alloys.

Jan 1, 2004

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai."

Jan 1, 2017

By François Baillargeon

Two types of ore deposit provide the bulk of the world nickel production. They are the hypogene magmatic massive sulfide deposits and the supergene lateritic deposits. Platinum group elements (PGE) are also extracted from magmatic sulfide deposits. Recent sky-rocketing price of palladium has prompted the mineral industry to seek alternative resources. In such a manner has emerged the Lac-des-Iles type of target, a very low sulfide-bearing bulk tonnage type of deposit. Furthermore, unconventional (e.g. non-magmatic) types of deposit are now sought more intensively (Wilde et al., 2003). Considering both this trend of the PGE Industry, and that only a few magmatic deposits account significantly for the world nickel production, someone may wonder if a diversification of the hypogene nickel resources base would not be needed in the near future. Laterites are residual deposits developed on ultramafic rock under wet tropical climate. Are all ultramafic protoliths equal to generate high-grade lateritic deposit? Are some preweathering processes important to generate favourable ultramafic protoliths? The mineralogical heterogeneity of some ?dry? lateritic nickel deposits renders their ore beneficiation difficult. Is the type of nickel-bearing mineral found in the protolith a significant factor influencing the laterite heterogeneity? To contribute to answer all these questions, we have undertaken a research project on the nickel occurrences of the southern Quebec serpentinite belts. Why choosing this specific region for such a project? First because, due to continuous mining of asbestos ore since 1870, the serpentinite belts of this region are among the best exposed and studied in the world. Secondly, this region host a complete spectrum of nickel deposits that have been described before in the scientific literature. Furthermore, this region is slightly to moderately metamorphosed which make it perfectly suited to study the departure from magmatic nickeliferous paragenesis through various metamorphic conditions. As a matter of fact two orogenic events affected this region, the Taconian, in Ordovician time, and the Acadian during the Devonian. The magnitude and the timing of these dynamo-metamorphic events vary considerably through the region (Gauthier et al., 1994). These variations are now well constrained due to precise age dating.

May 1, 2003

By C. H. Stockwell

RICE LAKE-BERESFORD LAKE area, situated 100 miles northeast of Winnipeg (Figure 1), is Manitoba's foremost gold mining district, although it is exceeded in gold production in the Province by the Flin Flon base-metal mining district. At present, the area is producing at the rate of about one and three-quarter million dollars annually, almost entirely from the San Antonio and Gunnar mines. The total production to date is about $14,000,000. Of this total, over $7,000,000 has come from the San Antonio mine, over $2,000,000 from the Gunnar mine, about $4,000,000 from the Central Manitoba mine, and the balance from several smaller properties. The writer has led Geological Survey parties in the area for the past four summers. The present paper gives a summary of the results of this work and also includes the findings of C. S. Lord, who was in charge of a party for one year. Much valuable information was obtained from earlier published reports on the area and from officials of mining companies, to whom the writer is indebted for their kindly co-operation. It is impossible in this short paper to give proper credit to the earlier workers or to discuss certain points o disagreement between their conclusions and those presented here. For further information the following references may be consulted.

Jan 1, 1940

By H. Sano

Most of the dust generated from the copper smelting process in Chile has been stored after the stabilization by hydrometallurgical process because it contains high concentrations of arsenic. However, in recent years, the dust generation has increased because of degrading the quality of concentrate. In addition, the environmental regulations become stricter. On the other hand, valuable metals such as copper and zinc are contained in the dust at high concentrations and it is desirable to recover them. In this study, the effect of dust recirculation to the smelting process was examined in order not only to decrease the amount of dust but also to recover copper. Dust generation and the distribution of arsenic, lead, zinc etc. among the matte, slag and gas phases were evaluated as a function of the amount of recirculated dust, partial pressure of oxygen and temperature. It was found that the direct dust return to the smelting process was quite effective for the recovery of copper and the reduction of dust generation, but the acceptable dust amount was limited by the produced matte quality.

Jan 1, 2007

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By I. Yutronic

Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved. Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals. On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs. Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others.

Jan 1, 2012

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004