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By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By R. L. Bruening, L. Navarro, Izatt. S. R., R. Adiga, R. M. Izatt, N. E. Izatt, A. Sharma, N. R. Patel, B. V. Rao

Bismuth is a notorious contaminant in the electrolytic refining of Cu that can cause cathodes to fail to meet ASTM International standards and not be suitable for use in Cu rod and other downstream products. Bismuth can significantly decrease electrical conductivity, decrease the mechanical strength of the annealed wire, retard recrystallization, and sometimes induce hot shortness during the hot rolling process in the production of rod. As a result, the control of Bi in the refinery tankhouse must be carefully managed. This paper describes how SuperLig® Molecular Recognition Technology (MRT) is being used for Bi removal at the Birla Copper Dahej Copper refinery. The operation of the SuperLig® MRT Bi removal plant is described and data on Bi removal efficiency are presented. INTRODUCTION Hindalco’s Cu division, Birla Copper, operates one of the largest Cu refineries in the world at Dahej, Gujarat; India. The main feed for this refinery is produced at the company’s smelter. Due to its massive production capacity, this operation mainly relies on imported Cu concentrates resulting in a variety of metals being carried out as impurities in the Cu anodes because pyrometallurgical technologies alone are not enough to remove them to the extent required. Metal impurities found in Cu ores include Fe, Zn, As, Pb, Bi, and Sb. During electrorefining, less noble metals dissolve in the electrolyte gradually increasing their concentrations creating the need for electrolyte control mechanisms that remove these impurities with varying degrees of success (Wang, 2004; Navarro et al., 2013.) Bismuth is one of the most significant impurities in a Cu refinery because it has the lowest ASTM product specification. This situation is critical because the Bi potential is very close to that of Cu making it possible to plate in the Cu cathode directly. Also, Bi can precipitate at high concentrations causing floating slimes and reduction of current efficiency (Ballinas, San Miguel, Munoz, & Gyves, 2003). Production of high purity cathodes from feed stock containing a diverse range of metal impurities becomes a major challenge in the refining of Cu (Izatt et al., 2015). In this work, the purification strategy followed by Birla Copper for the removal of Bi using a separation process based on MRT is presented, outlining the loading and stripping performance of SuperLig®83 and the benefits of using MRT over other lower selectivity methods where hazardous materials are produced instead of high purity products.

Jan 1, 2019

By Shuan-cheng Gu

Roof bed separation often occurred due to the deformation incoordination of surrounding rock following the excavation of mine roadway. Bed separation has effect on the bolts, and the estimation of the influence will directly affect the safety of support systems. In this paper, the hyperbolic function model to analyze the load transfer mechanism on the bolts was simplified as the exponential function form for easy calculation. An elastic-plastic analysis model of the bolt loading occurred by the bed separation was established. And the development low that the bed separation affected to the bolt loading was discussed. According to the parameters analysis of different separation values and locations, the influence law of the bolt loading caused by roof bed separation was summarized. Finally, the effects of bed separation were considered for the bolting design, it was able to provide a reference to the anchorage design of stratified rock.

Aug 1, 2013

There are many inherent risks in creating a mine plan for a new ore zone in an underground mine; one of such risks is the redistribution of stresses that could be a cause of instability. Using numerical modelling tools, it is possible to model the planned stope extraction sequence and evaluate the influence of mining induced stresses on the stability of remnant pillars, and use this information to remedy potential setbacks. This paper demonstrates this approach through a case study of the short-term mine plan of the Lapa mine of Agnico Eagle Mines Ltd., an underground gold mining operation near Val d?Or. Three-dimensional boundary element modelling is used to compute the stresses induced by the stope extraction sequence as planned with a longitudinal retreat mining method. The proposed methodology can be generalized to other mines that require an understanding of the stress concentrations at the pre-feasibility stage of mine design.

May 1, 2009

"Here, we statistically proved that giant earthquakes occur at lunar phases specific to each subduction zone. Enough attention during the lunar period, especially when seismicity is occurring, will significantly reduce damage from giant earthquakes. Two case studies in which giant earthquakes occurred after seismicity in dangerous lunar phases were discussed, and the mechanisms underlying why giant earthquakes occur around neap tide at some subduction zones were explained by prohibition of giant earthquake occurrences due to high strain rates at spring tides at N–S subduction zones. The prohibition was statistically proven for uniaxial creep tests on Inada granite with slight stress disturbances. INTRODUCTIONIn previous studies, we showed that from 1900 to present, giant earthquakes (MW ??8) have occurred at lunar phases specific to each subduction zone (Fujii & Ozaki, 2012; Ozaki & Fujii, 2012). Although we later proposed a possible reason for these occurrences, the study lacked statistical analyses (Fujii et al., 2013). Therefore, this paper shows the results of such statistical testing and presents case studies for the Tohoku 2011 and Chile 2014 events, thereby providing updated data on giant earthquakes through July 2014."

Jan 1, 2015

By Ahmad Ghahremaninezhad, Denver H. Cowan

Much of today’s gold is locked within sulphide minerals. These sulphide minerals, including pyrite, need to be subjected to oxidative pre-treatment in order to leach the refractory-gold using traditional methods. Typically autoclaves employing high temperatures between 180?225 ºC, and extremely high pressures between 1,500?3,200 kPa, are used for the oxidative pre-treatment. However, the autoclaves themselves are very expensive, costly to operate and maintain, and produce excess sulphuric acid. This paper studies the atmospheric oxidation of pyrite in ferric sulphate solutions. In general, pyrite oxidation under atmospheric pressure can result in high elemental sulphur production, i.e. less acid generation. Activated carbon has displayed an ability to catalyze the process, achieving reasonable kinetics. The reaction kinetics were investigated by altering acidity of the leaching solution, temperature, catalyst ratio, sparged oxygen and agitation. A combination of X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray fluorescence, inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS) were used to monitor the kinetics of the process and elemental sulphur yield. The purpose of this investigation was to determine optimal operating conditions that maximized kinetics of the atmospheric oxidation while maximizing elemental sulphur yield.

Jan 1, 2015

By Ellie Condolios

Hydraulic hoisting offers a number ~f attractive features over conventional hoisting methods: small shaft space requirements; great flexibility of layout, including pick-up or delivery of the material at points distant from the mine shaft; low investment and operating costs. However, limited practical experience with this type of hoisting dictates that careful design and, frequently, extensive testing be done by competent engineers before large-scale installations are built. This paper covers the following: basic laws and design criteria for hydraulic hoisting installations; a description of a coal hoisting installation which has been in industrial operation since 1960, with a vertical lift of 600 feet and an annual capacity of 500,000 tons of -3 ~-in. coal; and a tentative appraisal of the process, including cost estimates. THE transportation of solids in water flowing through a pipe-line has, for a number of years, been common practice in dredging, public

Jan 1, 1963

By Anthony T. Eyton

Intelligent Systems: Advantages for Mining ? Increased safety (reduced risk to workers) ? Increased productivity (reduced downtime) ? Reduced maintenance costs ? Customized solutions for different mines ? Growing acceptance among mine managers A Typical Precarn Project ? Meets definition of intelligent systems ? Involves at least two Precarn members ? a technology developer partner and a user partner ? in a true collaboration ? Involves at least one university and may have various other players ? Leads to a demonstrated prototype ? Costs $2-4 million, and lasts 12-30 months ? Gets up to 40% of its funding from Precarn (max. $1 m) ? Produces new intellectual property -- owned by the project team

May 1, 2002

By G. Chi

Outline 1.Regional geologic setting 2.Host rocks and structures 3.Mineralization, alteration and paragenesis 4.Geochronology 5.Major and trace elements 6.Fluid inclusions 7.Carbon and oxygen isotopes 8.Conclusions

Apr 1, 2005

By D. Q. Li

"This paper briefly introduces problems that can occur in the design of rare earth separation processes and that require close attention during engineering design. Important factors must be considered include the following. 1) The separation process is primarily based on two points. One is the raw material composition and the other is the product purity requirements. 2) Optimization of the rare earth separation process requires optimization of the flowsheet configuration and each process parameter. 3) The separation of heavy rare earths is performed under non-equilibrium conditions. 4) The radioactive elements uranium and thorium must be removed from the feed to separation. 5) Process economy and environmental protection must be considered together in the evaluation of any separation technology options. INTRODUCTIONThe importance of rare earth (RE) is well recognized in high-tech applications and sophisticated national defense technologies. RE is the treasure house of the 21st Century new materials. The RE separation processes developed using HEHEHP (P507), P507-alcohol (ROH) and naphthenic acid (NA) have been widely applied in China. These processes have led to industrial production of all of the individual RE with up to 4N (99.99%) or higher purity (Li, Wan, Lin, Xie, Lin, & Wang, 1980; Li, Wang, & Xie, 1985; Li, 1995; Li, Wang, Meng, & Li, 2005). In order to achieve the best economic and environmental benefits, this paper discusses several problems to which attention must be paid in the design of rare earth separation process."

Jan 1, 2016

By Karl J. C. Harries

"6.1. INTRODUCTIONThis chapter comments on some of the more common types of agreements related to property examination and acquisition, other than the farm-in/joint venture agreement or common undertaking, which is dealt with in the next two chapters. Many of the comments made in Part IV of Chapter 4 apply equally to any such agreement. In addition, many of the comments in Chapter 8 and the examples in Volume II are most certainly relevant to many other types of agreement.6.2. RIGHTS OF FIRST REFUSAL1A right of first refusal is a right that obligates an owner to offer his property, or an interest therein, to the holder of the first right if the owner intends to sell or otherwise dispose of it. It may be triggered either by the owner wishing to offer his property for sale or by receipt of a bona fide offer to purchase his interest from an “outside” third party. The mechanics and procedures to implement a first right should be set out clearly in the agreement, and their basics are the same, whether the first right is a stand-alone document or is part of an acquisition agreement.2Rights of first refusal are common in agreements to permit some control over the disposition of an interest and there they can be a valuable provision. However, some explorationists feel that they are also a good stand-alone agreement to have while a property is being evaluated to decide whether or not it is worth optioning. The reasoning is that such an arrangement will tie up the property to allow a quick look and, if the property looks interesting, the balance of the term of the first right will give an ample exclusive period of time to negotiate with the owner and settle an acquisition agreement. In addition, the explorationist is protected by the first right if the owner decides to negotiate a deal with another party."

Jan 1, 2003

By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By L. Yacher

Most metallurgical plants already have sophisticated control systems as well as a process-historian that manage thousands of real-time and historical variables. There exists a huge potential for operational improvement through the inference of patterns, correlations and cause-effect relationships within these records. The ability to run online and offline advanced multivariate statistical analyses represents a great potential for the mining industry, in various areas such as cathode quality improvement in an SX/EX plant, the analysis of the correlation between the ore characteristics and the mill throughput, the determination of early failure alerts for major equipment, etc. The background theory is described, as well as some practical experiences of operations in Chile and Peru. Cu2007

Jan 1, 2007

By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994

By M. Mirnezami, J. A. Finch, S. Uddin

A fast, reliable and practical way of measuring zeta potential using sedimentation potential method is proposed. A cell was designed along with the instrument control software to determine the required variables simultaneously i.e. sedimentation potential, specific conductivity, volume fraction of solid as well as pH. High purity alumina and silica powders were used as test samples. Measured zeta potential using the proposed technique was comparable with the results by electrophoresis.

Jan 1, 2009

By Alan J. Wianwright

Introduction ??New world-class Upper Devonian porphyry Cu-Au system located in south Mongolia ??6.5 km NNE-trending mineralized corridor ? 4 discrete deposits ??Southern Oyu deposits: Chalcopyrite, deposits: bornite ??Hugo Dummett: Zone: Hypogene chalcocite in addition to chalcopyrite and bornite ??Total resource exceeds ~2 Gt@ >1% Cu, >0.25 g/t Au (0.6% Cu equivalent cut-off) (Ivanhoe Mines press release, 2005)

May 1, 2006

By P. Babak, E. Insalaco, O. Babak, P. Henriquel

"Detection of outliers is an important primary step in geomodelling. Geological datasets often contain errors due to problems such as measurement device limitations and recording glitches. In this paper, a robust Mahalanobis distance–based approach is successfully applied to particle size distributions of the Joslyn lease, an oil sands development site near Fort McMurray, Alberta, Canada. Automatic outlier detection and geological review were combined. Outliers from the Mahalanobis distance approach were compared with their respective core photographs to determine if laboratory measurements and facies classification were correct. A checking procedure for laboratory technicians is proposed.RÉSUMÉ La détection des valeurs aberrantes constitue une étape primaire importante de la modélisation géologique. Les ensembles de données géologiques contiennent souvent des erreurs en raison de problèmes tels que les limitations des instruments de mesure et des pépins d’enregistrement. Dans le présent article, une méthode robuste basée sur la distance de Mahalanobis a été mise en oeuvre avec succès aux granulométries du bail minier Joslyn, un site de sables bitumineux en développement à proximité de Fort McMurray, Alberta, Canada. La détection automatique des valeurs aberrantes a été combinée à une étude géologique. Les valeurs aberrantes de la méthode de la distance de Manalanobis ont été comparées avec leurs photographies respectives de carottes de forage afin de déterminer si les mesures en laboratoire et la classification des faciès étaient correctes. Une procédure de vérification pour les techniciens de laboratoire est proposée."

Jan 1, 2015