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By Arun Verma

Thermal energy storage offers a means of effecting significant costs savings and conservation of premium fuels. Na2SO4 has been found to be a good material for storing thermal energy in the medium-temperature range, mainly because of its dimorphic nature and high heat of transition. Basic data and development of the salt to a practically usable block are discussed.

Jan 1, 1978

By A. M. Salomon de Friedberg

"With respect to impurities, HBM&S' copper smelter, located in Flin Ron, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Ron is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S' metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.IntroductionHudson Bay Mining & Smelting Co. Ltd. (HBM&s), has been operating its metallurgical complex located in Flin Flon, Manitoba, since 1930. The smelter and zinc plant were originally separate entities with respect to production. The smelting operation consisted of traditional multiple-hearth roasters, a reverberatory furnace and Peirce-Smith converters. The zinc plant also utilized multiple hearth roasters and then followed with sulphuric acid leaching, purification and electrowinning. The zinc plant also recovered cadmium from a separate purification/electrowinning circuit.The two plants operated essentially independently of each other until rising zinc levels in the copper concentrate and large stockpiles of zinc-rich leach residues prompted the construction of the fuming plant in 1949. The smelter used pulverized coal to reduce zinc oxide present in the reverb slag and then captured the resulting zinc bearing fume in the fuming plant baghouse. The fume was sent to a separate ""oxide roaster"" in the zinc plant where it was first roasted to remove halogens and then leached to recover the contained zinc. This oxide fume became a major source of feed to the zinc plant accounting for roughly one quarter of the total zinc production. Furthermore, through the smelter's treatment of sulphide leach residue, both copper and zinc recoveries were improved for the over-all complex."

Jan 1, 1993

By S. Gaulocher

Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO). A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components: 1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user. 2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer. 3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD. In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples.

Jan 1, 2012

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

By Balmer Neilly

We are regularly told that before making a new investment one should seek the advice of his banker. If we were to place the subject matter of this paper before bankers. other than those who have experience in our mining camps, their reply would probably be evasive. However, if for example: a mining company asks them for a loan and offers as security certain mining investments, they are, in most cases, explosively candid. The idea is preposterous, unless, under Section 88 of the Bank Act, the mining company is able to deposit with the bank, gold or silver bullion, to an amount sufficiently in excess of the loan, to provide for what the banker describes as a reasonable margin of safety in case of contingencies. In addition the directors of the mine personally must jointly and severally guarantee payment of the loan. With any of these conditions missing the banking atmosphere becomes chilly. The local manager explains that the general situation, and particularly European conditions, are so unsettled that head office has warned him that his discretionary powers must not be exceeded under any circumstances.

Jan 1, 1924

By John Galbraith, Dwayne D. Tannant, Chris C. Langille

"Development of underground openings in a deep mining environment requires a support system that is able to absorb energy as a result of dynamic loading due to rockbursting and blasting and static loading due to convergence as the development face advances. The support system must be resistant to corrosion and be effective over the life of the excavation, upward of ten years, yet simple and cost effective to install. Over the past two years, research has been conducted at INCO’s Creighton Mine to try and identify a one-pass grouted support system that will meet these needs.The main problem faced, with simply using grouted rebar at depth, is the effect of tunnel convergence on the stiff grouted bolts. Typically, if fully grouted, stiff rebar are installed to the face of an advancing development heading, the amount of convergence that occurs can result in failure of the bolts at the face plates used to attach the mine screen to the back. An initial support is required to enable crews to continue the bolting cycle in the immediate term, yet allow for this convergence over the longer term as the drift advances. The ideal support system will allow both to occur, giving effective immediate support while providing long-term effectiveness in allowing convergence to occur while maintaining the capacity of the bolt.This paper will investigate the expected convergence in deep development headings at +2200 m (+7200 ft) through the use of direct measurements using both flex rod extensometers grouted into the back of a development heading and five-point tape extensometer stations. Measured results will be compared with simple2-D numerical analysis to evaluate the anticipated convergence expected to be absorbed by the bolting system. The required convergence will then be compared with load deformation response of several support configurations."

Jan 1, 1996

By C. W. Reno

"THE LORNEX MINING PROJECT is one of several large-tonnage, low-grade operations recently placed in operation in British Columbia. It is located in the Highland Valley in the south central portion of the province. This area is described as a divide valley at an elevation range of 4,000 to 6,000 feet and is situated on the divide between two drainage systems. The major drainage to the west flows into the Thompson River and to the east and south the drainage enters the Nicola River system. This open-ended valley lies between low, rounded mountains in fairly heavily-wooded country. Prior to the commencement of copper mining activities, the first by Bethlehem Copper Corporation Ltd. over ten years ago, the valley was only sparsely settled. A few small ranches were in existence on the several Indian Reserves located along the valley bottomland. There has also been a small amount of logging activity in the valley, although much of the area is covered by dense lodgepole pine which has little or no value to the loggers. As the mining interest mounted with further discoveries of the disseminated copper ore typical of the district, much of the valley was covered with mineral claims and exploration drilling was carried on by several companies at various times. At the time Lornex was preparing to commence major construction work in early 1970, there was very little activity of any kind in the Highland Valley outside of the Bethlehem operation and a small amount of ranching."

Jan 1, 1973

By M. Massinaei

Recently constructed circuits have included multiple stages of columns in a variety of applications, from roughing to cleaning. The Miduk copper concentrator (in south-eastern Iran) is one of the unique mineral processing plants which use column flotation cells as rougher. As the bulk of final concentrate is produced by rougher columns, optimized metallurgical performance of these cells is crucial. This paper will present the study and optimization of, a froth washing system of columns. For this purpose, the cross-sectional area of orifices was increased and their orientation altered. Concentrate assay for copper and silica, in addition to bias rate were found to be the assessment criteria. Modification of the wash water system resulted in increasing the purity of rougher and final concentrate. Negative bias and short-circuiting of wash water into the concentrate launder were the main causes of improper froth zone washing in the former system.

Jan 1, 2007

By A. M. Salomon de Friedberg

With respect to impurities, HBM&amp;S&apos; copper smelter, located in Flin Flon, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Flon is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&amp;S&apos; metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.

Jun 1, 1993

By S. Setayeshgar

The identification of potential accidents on construction sites has been a major concern in the construction industry and it needs a proactive safety plan to reduce the risk of accidents. There are no efficient methods for checking if safety measures are taken properly on construction sites. Consequently, workers on site are not given enough awareness about dangerous areas. In addition, construction sites are dynamic and on-site situations are changing in terms of permanent and temporary structures and facilities. This information can be represented using Building Information Modeling (BIM). This paper proposes the integration of BIM and safety risk analysis by considering the risk levels associated with the work spaces of different construction tasks. Work spaces are generated in a BIM model according to the Work Breakdown Structure (WBS) of the project, reference objects in the BIM, and the schedule and resources of the task. Each work space is assigned to one or more tasks or functions, e.g., work spaces for specific tasks, shared spaces (paths), storage spaces, or spaces prohibited to workers. The assignment of work spaces is based on the workers, equipment and materials involved in the task. All the work spaces are associated with a specific duration according to the schedule of the project. Then risk evaluation of the construction site is applied in order to evaluate safety risks based on their severity and the degree of exposure of workers. For example, work spaces for storing hazard materials and for heavy construction equipment have higher risks than other work spaces. The results of the risk evaluation can be visualized in a 4D BIM model.

Aug 1, 2013

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By Z. D. Hora

The major fluorite producer in British Columbia was the Rock Candy Mine, inactive since 1942. Other deposits of economic interest include the Rexspar deposit, in which fluorite is associated with uranium and rare earth mineralization, and the Eaglet and Liard River occurrences. THE former Rock Candy fluorite mine, located 26 km north of Grand Forks, is the only major past producer of fluorite in British Columbia. The deposit was in production from 1918 to 1929 and again in 1942; total output was about 36,000 tonnes with average grade between 22 and 32 per cent CaF2. The fluorite body occupies a steeply-dipping vein structure, approximately 175 m long and up to 12 m wide, in porphyritic syenite. The chief vein-filling minerals are quartz and fluorite with local small len ses of barite. Fluorite content decreases with depth and the deposit becomes silicified. The Rexspar (or Birch Island) fluorite deposit is located 130 km north of Kamloops. The deposit is complex with rare earth elements and high uranium values, but !1uorite mineralization forms an independent zone adjacent to the uranium orebodies. Fluorite is present as fine-grained impregnations and as breccia cement in strongly schistose or brecciated alkali feld spar porphyry. Reported reserves are 1,088,000 tonnes of 22 per cent CaF2 or 450,000 tonnes of 29 per cent CaF2. 268 Another potential deposit of fluorite is Eaglet, situated on the north side of Quesnel Lake. Fluorite occurs as a stock work with scattered veins and irregular lenses up to 20 centimetres wide and as impregnations in altered Proterozoic Kaza Group feld spathic gneiss over an area of 1,500 metres by 500 metres. To date (1983) approximately $2 million have been spent on the exploration of this property and reserves of 18.8 mimon tonnes grading 11.59 per cent CaF2 have been outlined . A group of significant occurrences is known from north of Liard River Hot Springs Park , where fluorite occurs in small zones up to 17 m thick along the interface between Middle Devonian Dunedin Formation limestone and Middle Devonian to Mississippian Besa River Formation argillite. Fluorite, associated with witherite, barytocalcite and barite, is present as replacement bodies, breccia fillings and minor veins.

Jan 1, 1984

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By G. Deschênes

Located in North West Tanzania, Buzwagi is an underground narrow-vein gold mine owned by Barrick Gold. The plant was commissioned in 2000. The reserves are estimated to be more than 25 years. The ore, containing gold, silver and copper mineralization in sulphides, is processed at 3,300 tpd. This paper presents the results of an investigation to determine the performance of an ammonia-cyanide leaching approach to recover gold from two samples. Coarse gold was recovered by gravity prior to leaching. The gravity tailings had the following composition; 1.97 g/t Au and 0.31% copper for the medium cyanide soluble copper (MCSC) sample and 2.80 g/t Au and 0.53% Cu for the high cyanide soluble copper (HCSC) sample. Experiments were conducted for 72 hours in stirred tank reactors with monitoring and control of parameters. The straight cyanidation produced gold extractions of 76.1% for the MCSC sample and 84.6% for the HCSC sample. Associated cyanide additions were 6.1 kg/t and 11.5 kg/t respectively. The gold extraction of the MCSC sample was improved to 88.8% using 350 ppm NaCN and 700 ppm ammonia. The associated cyanide and ammonia additions were 2.5 kg/t and 1.7 kg/t respectively. For the HCSC sample, 82.5% gold extraction was obtained using 500 ppm NaCN and 600 ppm ammonia. The cyanide addition and ammonia additions were reduced to 3.8 kg/t and 1.0 kg/t respectively. No significant decrease in gold extraction was noticed when the cyanide and ammonia were reduced to 150 ppm and 500 ppm respectively. In the presence of ammonia, a significant amount of cyanide was oxidized to cyanate by the cupric ion. In the absence of ammonia, the formation of copper cyanide was the predominant reaction responsible for consumption of cyanide.

Jan 1, 2012

By T. Orser

In 2010 Newmont made the decision to purchase a 42 foot (ft) Semi-Autogenous Grinding (SAG) mill from Metso and a 28 Mega-Watt (MW) Gearless Mill Drive (GMD) from ABB for the Conga Project in Peru. The test and study work showed that a single line 42 ft SAG mill circuit gave the most favorable project economics in comparison to an equivalently powered single line 40 ft SAG mill circuit. This paper does not address the process design or the project economics, but instead focuses on the key aspects of the SAG mill design, GMD design and the associated component manufacturing. This paper also addresses, where applicable, the potential reliability differences between the initially proposed 40 ft SAG mill and the finally accepted 42 ft SAG mill.

Jan 1, 2012

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to maximise health and safety performance in the mining industry through implementing continual improvement in management of major unwanted events. A comprehensive knowledge base has been captured for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This will be extended to outburst, coal burst and bumps, interface displays and controls, tailings dams and inrush in 2013. RISKGATE presents substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry. All major Australian mining companies are contributing topic experts to this broad industry initiative. In the first 24 months, nine coal mining companies nominated over 80 different experts who contributed over 400 days of individual time to the knowledge capture workshops. RISKGATE is the largest single Australian Coal Association Research Program (ACARP) occupational health and safety (OHS) initiative to date.

Aug 1, 2013

By Long Han, A. V. Kalinin, Xiujian Luo, Xiaobo Wang, Xiaoou Xia

"Inertia vibration crusher is a kind of vibration equipment which crushes ore by vibration. When the inertia vibration crusher works, ore between the two moving jaws is subjected to the high frequency contact force, which is produced by the two moving jaws with high frequency synchronous reciprocating motion. The synchronous motion of the two moving jaws depends on the self-synchronous feature of the inertia vibration crusher. To study the self-synchronous feature of the equipment, the dynamic model was established, in which relative parameters were taken into consideration. The kinematic coupling relations of the assemblies are discussed, and appropriate calculation method is chosen to solve the vibrating differential equation. Whether the two vibration exciter can realize synchronous operation depends on the ability of the vibration system's capture moment. Results show that though the two rotors’ motors and damping coefficients are different, and two jaws’ damping and stiffness coefficients are also different, as angular velocities of the two unbalanced rotors reach a certain value, the vibrating system can be stable. Their angular velocities tend to be equal, and the swings of the two moving jaws can be the same. The horizontal vibration and swing of the frame are large in a few seconds after starting the machine. When the system runs stably, the horizontal vibration and swing vanish, and the vertical vibration is stable. The study and its results can provide reference for the optimization design and parameter setting of inertia vibration crusher and related vibratory equipments.INTRODUCTIONMaterials can be easily broken by using the inertia force of the vibration exciter, which can effectively realize the selective crushing, reducing excessive combinations and the energy consumption, as introduced by Zhang in 2005. The initial micro crack between crystals in the material increases and new cracks can be manufactured because of the high frequency impact and the extrusion of the vibration crusher, so vibration crushing equipment can make it possible for any high strength brittle material to be broken theoretically. Inertia cone crusher and inertia vibration crusher have been successfully used in the treatment of metallurgical slag and construction waste, and it verifies the efficiency of vibration crushing."

Jan 1, 2016

By D. Pacey

"This paper reviews the installation, start-up, and operation of a comprehensive monitoring and targeting management technique in which all plant utilities (i.e., electricity, natural gas, compressed air, and water) are managed as controllable resources in the same way that raw materials, mined ore, personnel and capital are managed.The essential elements of monitoring and targeting (M&T) include:•gathering in a systematic, disciplined way the utility information by energy account centres;•closely monitoring the utilities used in each centre and comparing them with production on a common time base (e.g., kWh/ton per day);•bench marking and target setting to pro-vide attainable energy reduction goals which can be further refined as they are achieved; and•establishing an implementation plant that may provide efficiency enhancing benefits to various operating areas within the plant.The M&T system will reduce utility consumption per unit of production on a continuing basis.This would translate into sustained operating cost and waste. M&T will also provide better information for assessing the plant operation and progressively implementing further enhancements."

Jan 1, 1997

By A. L. Nunes, J. R. E. Garcia, G. Silva, U. Prasad, C. Rabe

"Drilling through the Guayabal shales, a gray calcareous shale, and the C1 to C100 formations, a well-cemented calcareous-sandstone in Corralillo field, Mexico, is a challenge due to severe wellbore instability problems. Additionally, there has been a history of ineffective reservoir stimulations by hydraulic fracturing. To predict and mitigate these subsurface issues, it is essential to characterize the mechanical properties and rocks strength for a better prediction of borehole stresses and collapse pressure during drilling. Various correlations can be used to estimate and/or determine the unconfined compressive strength but most of them are based on transit time and porosity.In this study, grain size distribution was combined with acoustic travel time, porosity and static Young’s modulus to develop a rock strength prediction model for the turbiditic sandstones of the Chicontepec basin. The main reason this combination of parameters was employed was because of the wide variations in rock strength estimated using traditional porosity-based correlations such as the McNally’s (1987), GMI-Jizba-E’s and Bradford’s (Bradford et al., 1987).To develop a new correlation, a geomechanical and microstructural campaign was initiated. Mineralogy by X-ray diffraction, pore and grain sizes by petrography, clay distribution by SEM and porosity by mercury intrusion porosimetry were measured. Static and dynamic Young’s moduli and Poisson’s ratios were acquired by triaxial and ultrasonic measurements on undisturbed sandstone samples from the Chicontepec basin. More than ten offset wells with wireline data, including transit time, porosity, density, resistivity and gamma ray, were used for reservoir and geomechanical characterizations.Our analyses lead us to propose a new correlation for predicting the uniaxial compressive strength (UCS) of sandstones of the Chicontepec Basin as a function of transit time and grain diameter, both of which can be derived independently from destructive laboratory tests. Our results also highlight the importance and value adding of a combined approach incorporating grain size analysis in the rock strength prediction. The UCS predicted using the transit-time and grain-size-based model presents a median value (P50) of 76 MPa, P10 of 55 MPa and P90 of 89 MPa."

Jan 1, 2015

By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017