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Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By J. W. Merkley, K. B. Hustwick

"The authors describe the use of a computer system for the control oj warehouse inventory at Cominco's Canadian operations. The challenge presented by the company's diverse products and various locations necessitated a practical approach to operational and manpower requirements. The utilization of modern forecasting techniques, manual intervention and exception reporting provides system flexibility. The system also provides both operational and management control to set required service goals at the lowest inventory levels for inventory management.IntroductionCominco Ltd. is a Canadian company, with international operations, the principal business of which is zinc, lead and chemical fertilizer s. Its involvement is fully integrated and range s from mineral exploration through mining, smelting, refining and by-product production to international marketing. It also embraces related services, including trade, wharfarge and power. With head office in Vancouver, it is involved, directly or through subsidiary or associated companies, in Canada and in the United States, Greenland, Europe, Australia, India and Japan.Cominco has over 12,000 employees and 26,000 shareholders, with 91% of all shares held in Canada.Cominco's Inventory Control System is one of the most extensively used computer systems employed by the company. Also, inventory control is regarded as one of the most economically successful computer applications to be undertaken by the Data Processing Services (D.P.S) Group that was responsible for the development of the Inventory Control System.The main use of automatic inventory control has been at operating plants in Western Canada and the Northwest Territories, which are separated by large distances. Each location has equipment-intensive mining and processing operations and it is essential to maintain control of parts and supplies inventories. Some of these locations are remote from urban and industrial centres and it is important to avoid the adverse effects of high personnel costs and re-training due to turnover."

Jan 1, 1982

By T. W. Wlodek

Abstract A simplified method of fatigue testing full-dimension, as-rolled, non-machined, mining drill rods is very desirable to the mining and steel industries in the classification of steels available on the market, through the evaluation of their fatigue limits and endurance strength. In this paper one such simplified method is presented and analysed. The preliminary results show many advantages of this method, such as simplicity and constancy of loading. The type of loading applied more or less simulates the working conditions of the outside fibres of the mining drill rods. Additional advantages of this method are the possibility of testing under dry and wet conditions, its quietness, and its ease of operation. Specially designed adaptors and specially applied techniques of fixing and preparation of samples make possible the breaking of a quarter-octagon hollow drill rod in a free length of uniform section in a rotating beam machine. At first glance this seems to be difficult to achieve. In the first preliminary test three different lots of steel were used. S-N curves under dry conditions were determined. These curves permit of the classification of the drill rods on the basis of the fatigue limit and endurance strength of the outside fibres of the metal, which is dependent to a greater or lesser extent on the effect of surface decarburization, surface imperfections, and special surface treatments. The average slope of the S.N curve in the damaging zone, and the fatigue limit in equal tension-compression rotating bending, were determined for SAE 1080, chromium-molybdenum and nickel-chromium-molybdenum mining drill rods. INTRODUCTION The fatigue limit and the endurance strength of mining drill rod steels are of interest to both the mining and the steel industries. These industries are greatly interested in lowering the cost of mining by reducing the consumption of these steels per ton of ore exploited.

Jan 1, 1951

By James L. Parks, David M. Kjos

"Significant increases in mill liner life and plant availability can be achieved by following guidelines that have evolved from over twenty years of practical experience with autogenous grinding (A0) and semi-autogenous grinding (SA0) mills. A0 and SA0 mill liner functions, performance criteria, designs, wear-resistant materials and maintenance procedures are reviewed. Operating practices that can lead to accelerated wear and breakage are discussed.IntroductionEfforts to improve the performance of liners for autogenous grinding (AG) and semi-autogenous grinding (SAG) mills began as soon as the modern, large-diameter versions of these comminution machines were first intalled in commercial plants twenty years ago . While concentrators with conventional circuits were typically running at 95010 or better mill availability, many of the new autogenous and semi-autogenous circuits were struggling to achieve 80% availability. Liner maintenance, which involves not only material and labour costs but also loss of production, was quickly identified as one of the major reasons for downtime.Today, liner designs and materials have evolved to the point where virtually maintenance-free liner life of two to three years is possible in autogenous mills and one year in the more severe operating conditions encountered in semi-autogenous mills. Of concern, however, is that hard-won lessons from the past sometimes seem to be forgotten or ignored during the design of new mills and the operation of existing mills. As liner suppliers, we are often confronted with performance problems that could have been avoided by applying well-publicized guidelines for liner design and materials selection.This paper provides an overview of AG and SAG mill liner functions, criteria for evaluating performance, designs, wear-resistant materials and maintenance procedures. Also, operating conditions that can lead to accelerated wear and liner breakage are discussed in detail."

Jan 1, 1990

By David Nicholls

?Overview of New Afton ?Reserves and Resources ?Geology and Mineralization ?Exploration ?Capital Project Development to Date ?Mine Development ?Processing ?Construction ?LOM ?Health, Safety, Environment and Social Responsibility Overview of New Afton ?Fully owned by New Gold Inc ?Large gold-copper porphyry deposit, amenable to block cave mining, production commencing in 2012 -1 million ounce gold reserve -1 billion pound copper reserve -Estimated 13 year mine life ?Low operating cost ?Estimated capital expenditure requirements -Spend to date ?US$200million -Remaining to be spent ?US$400milllion ?Robust economics ?Excellent location and infrastructure ?Significant cash flow contributor for the Company

May 1, 2010

By G. Frithum

In the present paper a new and highly economic route for Fe-separation from HCl leaching processes in hydrometallurgical applications is described. In most ore leaching processes, Fe is involved and needs to be separated; HCl has become an interesting leaching agent, because it can be recycled. Usually a mix of Fe2+ and Fe3+ is obtained which can be hydrolyzed directly (in case only Fe3+) or roasted via pyrohydrolysis (in case of Fe2+) to ferric oxide. Economic oxidation of Fe2+ to Fe3+ is described, and potential technologies for regeneration of HCl with separation of Fe are shown and compared.

Jan 1, 2014

By Gérald Riverin, Bernard Boily, Daniel Bernard

"The Donalda gold deposit is located in the southern part of the Noranda camp, approximately 2 /em east of the Horne deposit. Combined past production and current reserves total over 1.5 Mt grading 6.9 grams of gold per tonne.The deposit consists of two main veins which are both narrow but persistent structures. The No 1 Vein, hosting about 80% of the gold ore, consists of an EW-striking banded quartz vein dipping on average 25° to the south. Although variable in thickness, it averages lessthan1 metre. TheNo2 Vein, located 300 m below the No 1 Vein, is similar to it except that it dips 50° south. Gold occurs mostly as fine native gold disseminated in quartz, with 2-3% pyrite and trace amounts of various sulphides and tellurides. The wall rocks are only weakly altered and mineralized with pyrite, hematite and sericite.Structurally, the Donalda deposit is centered on the Horne Creek fault (HCF) where the HCF is intersected by the ENE-trending DonaldaandCentralfaults.NorthoftheHCF,theNo1Veinishosted by the Quemont Rhyolite, whereas south of the HCF the vein is hosted by magnetic basalts and diorites of the Wilco Andesite Formation. The No 1 Vein extends across the HCF with only minor displacement, whereas the No 2 Vein has not yet been traced south of the HCF.A preliminary structural analysis of the mine shows that the HCF, which strikes 275° and dips 70° north in the mine area, has a reverse movement a lid that the flat dipping No 1 Vein is a tension vein. Both probably developed in response to the same stress conditions. Although the absolute age of the Donalda veins is not known, structural relationships indicate that they formed during the latest movements of the HCF, but prior to the intrusion of the Proterozoic D' Eldona Diabase. The occurrence along the HCF of gold-rich synvolcanic massive sulphides and much younger vein-type gold deposits (such as Donalda) indicates that the HCF was a very long-lived, deep-seated (?)structure which has controlled the circulation of gold-rich fluids over a long period of time."

Jan 1, 1990

By A. J. Faulds, K. C. Westaway, Z. Waszczylo

"PAH compounds have been found in the exhaust from all types of engines burning hydrocarbon fuels . They have also been found in the air over cities and in water. The authors report on a study to assess the concentrations of twelve different PAH compounds in several different environments in dieselized underground mines. In addition, the differences in the PAH levels and distributions in different mines will be demonstrated. Finally, the influence of blasting and the type of diesel engine used as well as the effect of catalytic converters in the exhaust system on the PAH concentration in the mine will be discussed.IntroductionMining methods have been altered significantly in the last 25 years; i.e ., the tools and machinery used underground have changed from electrically operated trains and other equipment to diesel-powered equipment. This has been done for several reasons: 1) economics, 2) convenience and 3) safety. Today, most mines are heavily committed to using diesel equipment.Although the introduction of diesel equipment has revolutionized mining methods and has been a tremendous boon to the mining industry, it has also created new problems. These problems arise because the exhaust from diesel engines contains several pollutants which can be hazardous to the health of the miners. These pollutants are CO2, CO, NO., SO2, oxygenated hydrocarbons produced during the buring process and unburned hydrocarbons. There are two classes of hydrocarbons, of which polynuclear aromatic hydrocarbons (PAHs or PNAs) are a part."

Jan 1, 1981

By W. D. Sinclair, R. J. Cathro, E. M. Jensen

"The Cash is one of the largest porphyry copper-molybdenum Deposits found in Yukon to date. It is 80 km northwest of Carmacks, within the unglaciated portion of the Dawson Range, and is associated with the Big Creek fault, an important tectonic feature. Part of the mineralized zone is blanketed by up to 70 m of alluvial drift . The remainder is covered by a relatively thin residual soil layer. The mineralized zone, however, was not detected by conventional stream-sediment sampling because pathfinder elements, such as Cu and Mo, have not been geochemically dispersed into the main drainage system. The deposit was discovered by a combination of soil analysis and inspection of rock fragments from small pits.Twenty widely spaced, shallow drill holes have outlined an areaover 2700 m long and 550 to over 1000m wide that grades more than 0.1% copper equivalent (% CuE = % Cu + (5 x % MoS2)). Two smaller zones grading over 0.4% copper equivalent occur within the larger area. The limits of the widest end of the deposit have not been delineated.The Cash deposit is fairly typical of high-level, calc-alkaline porphyry copper-molydenum occurrrences in the Canadian Cordillera {cf, CIM Special Volume 15) and is representative of most prospects in the Dawson Range. It is associated genetically with a subvolcanic complex of small, irregular stocks and dykes of feldspar porphyry and related breccias of Late Cretaceous age. Copper and molybdenum sulphides occur along fractures, in quartz veinlets and disseminated in feldspar porphyry and in older metasedimentary and intrusive rocks. Higher-grade zones of copper and molybdenum have associated potassic alteration. Phyllic alteration is, in part, superimposed on potassic alteration. Argillic alteration occurs locally.This paper describes the history of the discovery and the geochemical and geophysical characteristics, together .with the regional geology, and the nature and distribution of the host rocks, hypogene mineralization and hydrothermal alteration."

Jan 1, 1981

By Chantale Doucet

L?utilisation du remblai en pâte dans les exploitations en vrac est de plus en plus importante. Puisque la technologie existe pour fabriquer du remblai en pâte sans construire une usine coûteuse, il est maintenant possible d?élargir le domaine d?utilisation du remblai en pâte pour y inclure des gisements filoniens où le besoin annuel de remblai est moindre. Dans certains cas, l?utilisation du remblai en pâte pourrait permettre de réaliser d?importantes économies telles que la réduction de la dilution, la stabilité des ouvertures, la récupération d?une plus grande partie du minerai par la réduction de la taille des piliers et l?entreposage de moins de résidus à la surface. L?ampleur des économies est parfois difficile à chiffrer mais il est tout de même important d?en tenir compte lors de la décision d?utiliser du remblai en pâte puisque ce sont souvent ces économies qui seront déterminantes. Différentes méthodes d?extraction avec remblai en pâte appliquées aux mines filoniennes seront présentées. Des défis et les solutions reliés à l?utilisation du remblai en pâte à la Mine Doyon seront discutés.

Oct 1, 2001

By D. R. Lentz, J. A. Walker

"Abstract -The Flat Landing Brook Zn-Pb-Ag deposit of the Bathurst Mining Camp occurs within a narrow thrust-bound nappe containing felsic volcanic and volcaniclastic rocks of the Tetagouche Group. Within the host nappe, the Tetagouche Group is represented by the Nepisiguit Falls Formation and the overlying Flat Landing Brook Formation. The Nepisiguit Falls Formation is divided into two members: quartz- and quartz-feldspar-phyric volcaniclastic rocks ± minor lavas (Grand Falls member), and aphyric, fine-grained volcaniclastic rocks (Little Falls member). The Flat Landing Brook Formation consists of aphyric rhyolite flows and interbedded pyroclastic rocks. Several gabbroic intrusions occur in both the footwall and hanging-wall sequences. These gabbros locally cut out the mineralized horizon at shallow levels, and are considered to be feeders to tholeiitic basaltic flows (Forty Mile Brook member) of the Flat Landing Brook Formation. The Flat Landing Brook deposit has many of the characteristics typical of volcanogenic massive sulfide deposits occurring within the highly productive Nepisiguit Falls Formation in the eastern part of the Bathurst Mining Camp. Mineralization occurs within or at the top of the Grand Falls member and comprises four or more massive to semi-massive sulfide lenses that vary in thickness between 3 and 5 m. Massive lenses are laterally gradational to, or underlain by, zones of disseminated sulfides up to 38 m thick. The deposit contains an estimated resource of 1.7 Mt grading 4.9% Zn, 0.94% Pb, and 19.54 g/t Ag to a depth of approximately 150 m. From 150 to 300 m below surface, mineralization is low grade and mostly disseminated. However, below 300 m, ore-grade (>10% Pb+Zn) massive sulfide lenses have been intersected over mineable widths. Oxide facies iron formation overlies and (or) grades laterally into the sulfide lenses. The oxide facies has strong positive Eu anomalies and gently sloping rare earth element (REE) profiles suggesting that it was formed from relatively hot acidic fluids that had interacted with felsic volcanic rocks in the footwall. In contrast, the silicate facies iron formation that is more distal to sulfide accumulations has very weak positive Eu anomalies and gently sloping REE profiles, suggesting either cooler hydrothermal fluids or dilution of the hydrothermal component by detrital material. Hydrothermal alteration has affected most footwall rocks. Most notably, albite-destructive alteration has resulted in Na2O depletion, whereas mass addition of K2O is manifested in the formation of sericite (white mica). In more intensely altered quartz- and feldspar-phyric volcaniclastic rocks of the Grand Falls member, feldspar destruction is accompanied by chlorite alteration, producing quartz-phyric rocks similar to those in the footwall of many Bathurst Camp deposits."

Jan 1, 2006

By Engineering Staff

"This paper briefly describes the surface mining operations at Smoky River Coal Limited (formerly McIntyre Mines Limited, Coal Division) near Grande Cache, Alberta. Geology, mining methods, equipment, manpower and reclamation and environment topics are discussed. Introduction Smoky River Coal Limited, a wholly-owned subsidiary of McIntyre Mines Limited of Calgary, Alberta, produces a high quality, low sulphur, low volatile bituminous coking coal from its minesite located at west central Alberta, approximately 20 km from the town of Grande Cache and 360 km west of Edmonton (Fig. I). Most of the coal property is contained within a 30 km long by 20 km wide block lying in a northwest-southeast direction in mountainous terrain. Elevations vary from 920 m above sea level ·at the plant·site on the Smoky River to 1,600 mat the upper levels of current and proposed mining operations. A total of 11 coal seams have been identified. Only two seams, No. 4 Seam and No. 10 Seam are currently considered of major commercial value. These seams are recovered by both surface and underground mining. Approximately 650Jo of the plant feed coal is obtained from a conventional shovel/truck surface mine; the balance is mined underground by room-andpillar methods. Background In 1921, McIntyre Mines Limited acquired some 26,300 hectares of coal leases at Smoky River. Since then the leases were explored intermittently by different companies including McIntyre. In the mid-l 960s exploration activities increased and several feasibility studies were completed. Development of the area was undertaken by McIntyre in 1968 and, in August of the same year, a long-term contract was signed with a consortium of Japanese steel mills for delivery of 2 x 106 t of clean coking coal for 15 years commencing in 1970. Production was focussed on underground mining, using longwall methods."

Jan 1, 1985

By D. S. Hines

The purchase of mechanical equipment for mines is not unlike the purchase of other materials or supplies in general principle, but on account of the major part such equipment plays in the operations, and of the fact that life and valuable property are at stake, the matter demands the most careful attention on the part of the purchaser. The problems and difficulties encountered are dealt with below in their sequence in the purchasing procedure. Requisiting Although it is quite a common practice to submit a tentative specification of requirements to recognized manufacturers of equipment- soliciting alternative propositions or recommendations for study in the selection of certain equipment-as a rule the first step in purchasing procedure is the requisition. Primarily, it is the form that carries to the purchasing department the record of equipment wanted. A full and complete description or specification, and accuracy of record, are the important points to be insisted on in a requisition. Too much attention cannot be given to this detail, as this is one of 'the most important phases of purchasing work. Incomplete information, either in specification or detail, leads to delay in handling the requisition, and, if not detected in the purchasing department, may mean receipt of material which cannot be used for the purpose intended. In addition to description of material or equipment to be ordered, the requisition should also show where or what the equipment is for, whether for operating or new work. If for capital account, the number of the authority for expenditure should be given for record and distribution purposes.

Jan 1, 1930

By I. R. Jonasson, R. W. Boyle

"Current interest in the distribution of mercury in the natural environment comes from quite different, though not unrelated, sources. Mercury has long been an important metal in many industries and has, therefore, been much sought after by mining interests. The presence of mercury traces in the various media of the natural environment, namely soil, rock, air, water and vegetation, is exploited by geochemists not only to find mercury and polymetallic ore deposits, but also to find most other types of economic metal mineralization. More recently, however, mercury has caught the attention of health authorities and environmental scientists who are becoming increasingly concerned over the hazards of mercury wastes and the danger these present to the environment and to man. It is now apparent that the trace quantities of mercury, considered so important and helpful to exploration geologists, can be concentrated in the biosphere to such levels as to present considerable problems for ecologists. This article summarizes most of the available data on mercury contents in materials of geological interest and presents average normal values for rocks, ores, minerals, soils, sediments, waters and plants. The geoch.emical cycle for mercury in nature is presented and the mechanisms of mercury migration around the cycle are discussed."

Jan 1, 1972

By W H. Poole, E. R. W. Neale

A new style of tectonic map based on age of folding has been prepared for the Canadian Appalachian region as part of the Tectonic Map of Canada Project. This style of map pro-vides a clearer picture of the tectonic history of the region than any meth-od hitherto attempted. Precambrian blocks that were relatively unaffected by Palaeozoic de-formation are distinguished on the Great Northern Peninsula and in the Conception Bay region of Newfound-land. K/ A age determinations suggest that these blocks were intruded and metamorphosed during Grenville orogeny. Other Grenville-like rocks, on Cape Breton Island and in New Brunswick, were more actively involved in subsequent Palaeozoic orogeny. Taconic orogeny, the first phase of Palaeozoic deformation, took place in Middle and/or Late Ordovician time and was accompanied by intrusion of ultrabasic rocks. Evidence of the -

Jan 1, 1961

By C. R. Edwards

"Equity Silver Mines Limited, Canada's largest silver mine, has designed, built and operated a leach plant to reduce the levels of antimony and arsenic in its silver-gold-copper flotation concentrate. The orebody contained deleterious antimony and arsenic minerals in such proportions that the economic long-term sales contracts necessary to obtain project financing could not be procured. Construction of the leach plant therefore allowed development of the mine to proceed. Although the plant took some time to reach design throughput and product specifications, due to the complex and unique nature of the operation, these goals were successfully met and surpassed. This paper describes the physical plant and/or process technology modifications made to mold the main processes-concentrate leaching and filtering, autoclaving and filtration of by-products, and crystallization of salt cake-into an effective, economic operation.IntroductionEquity Silver Mines Limited, a member of the Placer Development Group, owns and operates an open-pit silver mine and related facilities located 37 kilometres southeast of Houston in north-central British Columbia. The mine occupies a 44 I-hectare (1089 acre) site at an elevation of 1300 metres (4265 feet) on the Nechako Plateau. Producing a copper concentrate containing high values of silver and gold, it is the largest silver mine in Canada and one of the largest in the western world. Equity stresses open communications, positive motivation, and production with safety, and achieved the best mine safety record in western Canada in 1984."

Jan 1, 1985

By J. R. Morris

"A hoisting plant design should satisfy two basic requirements:1. to provide the necessary materials handling capacity, including ventilation where applicable, while meeting the requirements of good practice and, as a minimum, government regulation; and2. to optimize the economics of the project. Selection of hoisting equipment to meet the first objective is a complex but logical engineering process. The necessary calculations of payloads, accelerations, speeds, rope strength, hoist size, and power requirements are very readily carried out on computers or programmable calculators. A variety of hoist options can be quickly examined to assess the effects of changes in design parameters.Meeting the second requirement involves balancing the costs of various hoist arrangements and shaft designs, together with the time cost effects of differing shaft sinking rates and potential advances to be gained by concurrent level development. The proposed mine layout is significant here, as is the possibility of future shaft deepening and/or production increase. The availability of used equipment may be significant, both as regards first cost and delivery time. The factors are interactive, with their relative effects .varying from project to project. This paper sets out the primary factors to be considered."

Jan 1, 1990

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By Yujing Jiang, Xuezhen Wu, Bo Li, Tomomi Iura, Gang Wang

"Yielding bolt has been widely used for rock reinforcement in mining and civil engineering in high stress conditions. However, the interaction mechanism of yielding bolt and matrix mass is still not clear at present, and no analytical model is available to predict its reinforcement effect quantitatively. In this paper, the mainstream yielding rock bolts were reviewed firstly. After that, a coupling model is proposed to account for the interaction between yielding bolt and matrix mass. Based on the plane strain axial symmetry assumption and the incremental theory of plasticity, equilibrium equations and compatibility equations of matrix mass, and also the response of yielding rock bolt are deduced theoretically. The proposed method was programmed in Visual Basic development environment, and a semi-analytical solution for the coupling model is achieved. The reinforcement mechanism of yielding bolt in conventional tunnelling is clearly demonstrated through an illustrative case study. The reinforcement effect of yielding bolt is estimated quantitatively, and the distribution of axial force along the bolt is presented. In addition, the validity of proposed method is verified by numerical simulations. INTRODUCTIONHigh stress in surrounding rock mass can cause serious stability problems such as massive squeezing in soft rock and rock burst in hard rock. It is observed that many conventional rock bolts failed when experiencing large displacement, which implies that they are too stiff to sustain large deformation and dynamic conditions (Stillborg, 1994; Hoek et al., 1995). Yielding bolt, which can also be called energy-absorbing bolt, has been widely used for rock reinforcement in mining and civil engineering for these conditions (Neugebauer, E., 2008). This paper focuses on the static reinforcement effects of the yielding bolts with analytical method and numerical simulations."

Jan 1, 2015