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By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

By S Choy

Aquatic macroinvertebrates have been used as a monitoring tool for many years. They are ubiquitous and occupy a central role in the ecology of rivers. They are a key link in the aquatic food chain, forming a pathway between primary producers (such as algae and macrophytes) and predators (such as fish, platypus and birds), and some are sensitive to flow conditions, water quality and habitat condition. They are not very mobile and are good indicators of local impacts. As most aquatic macroinvertebrates are benthic, they are better able to integrate effects of changes in water quality, and habitat condition and structure. Their diversity is crucial to the maintenance of a balanced, functioning and healthy river ecosystem. Thus, data on benthic macroinvertebrate community structures can be used for predicting potential impact, assessing the extent of damage and for gauging recovery from damage. Over the past eight years, State agencies throughout Australia, through the National River Health Program have developed models (AusRivAS) to assess river health using macroinvertebrate communities. The Queensland Department of Natural Resources and Mines has sampled both macroinvertebrates and water quality throughout Queensland, including areas affected by mine discharges. This paper will assess results obtained from sampling in the Mt Morgan area to illustrate the usefulness of this method of river health assessment.

Jan 1, 2003

By J Plinke

The imperative to operate sustainably requires all equipment and processes to operate at their maximum possible efficiency. Achieving this ideal state requires a thorough understanding, not only of the process itself, but also of the tools available to design and assess potential improvements. This paper presents a case where the widely employed Discrete Element Method (DEM) toolset proved insufficient to model problematic material flow during the process of optimising wet screening performance. A Smoothed Particle Hydrodynamics (SPH) model was found to more accurately replicate the flow characteristics of the physical system. Site observations identified biased loading of the screen decks to cause inefficiencies in the wet screening of an iron ore processing circuit. Two numerical modelling approaches were pursued with the aim to select the most suitable one and continue the optimisation process based on that selected model. Selection criteria were established, based on the minimum requirements of being able to replicate the problem, including the main flow dynamics deemed to cause the issue. The DEM model was found to over-simplify the slurry flow dynamics within the scrubber and no laterally biased flow was introduced by the scrubber’s rotation to the otherwise symmetric system. Since DEM was not able to accurately replicate the existing problem, it was deemed an unsuitable method to assess the effect of any changes to the system. The second approach consisted of a SPH model. This model was deemed to map the flow within the scrubber with sufficient accuracy to address the problem, as it produced biased screen loading comparable to that reported from site. Changes to the wet chute, delivering material from the scrubber to the screen, aimed to neutralise the non-centrality introduced via the scrubber, were then successfully designed and assessed using the SPH model.

Nov 8, 2021

Traditional methods for monitoring, and hence controlling, pyrometallurgical processes rely heavily upon the skill and experience of operators. A skilled operator will usually achieve consistent, though often conservative, results, whilst an un-skilled operator will require considerable time and training to achieve the same results. Semtech Metallurgy AB have demonstrated that continuous and precise control of pyrometallurgical processes can be achieved through on-line analysis of pyrometallurgical flame off-gas using optical spectroscopy. The feasibility of the technology has been demonstrated on a large number of full-scale tests at production plants and by several commercial installations. Evidence suggests that installation of this technology, called Semtech Optical Production Control (OPC), has resulted in considerable economic benefits to the plant efficiency and asset life. These economic benefits are believed to be a direct result of improved objective on-line control. Technically the following benefits have been demonstrated: improved metal grade control, reduced metal losses, reduced processing time, and improved personnel safety. SemtechÆs OPC is a non-intrusive technology which relies on the fact that the composition of the vapour phase above a high temperature melt is closely related to the instantaneous status of the melt. This enables on-line real-time analysis of the furnace melt to accurately determine melt status and in particular reaction endpoints. Originally developed for on-line monitoring of copper converting in a Pierce-Smith vessel the field of applications for the technology is steadily growing. This paper introduces the Semtech OPC technology; discusses various applications and outlines the demonstrated benefits.

Jan 1, 2002

Titanium tetrachloride may be reduced to trichloride with hydrogen on a hot tungsten filament and other hot: surfaces. The effect of temperature, time and size of t.he filament on the rate of reaction has been studied. A laboratory unit for preparing a few pounds of trichloride at a time is described. The yield of trichloride is 2·2 - 2·4 gm/sq. cm. of hot surface/hour at 1,000°C. and the energy requirement 3'5-4 kWh/pound of trichloride produced.'INTRODUCTIONThe lower chlorides of titanium (titanium tri- and dichlorides) are amenable to electrolysis, being electrovalent in nature. Furthermore, relative to other oxygen-free titanium salts, they are easy to prepare in a pure state and their use has been investigated to prepare titanium. The experimentaJ work described in this paper deals with the preparation of titanium trichloride by reduction of titanium tetrachloride with hydrogen on hot surfaces.REDUCING AGENTS FOR TITANIUM TETRACHLORIDEThe free energy diagram (Fig. 1) for the formation of chlorides suggests that titanium' tetrachloride may be reduced to trichloride by various reducing agents such as aluminium, zinc, arsenic, antimony, tin, mercury, silver, hydrogen, sodium, potassium and magnesium. Ruff and Neumann (1923), Thorpe (1885) , Billy and Brasseur (1935) and Seurbert and Schmidt (1892) used various metals to reduce tetrachloride to trichloride and found that the yields were invariably low and the products difficult to separate.Besides the metallic reducing agents, hydrogen may also be used to reduce titanium tetrachloride to trichloride.Goerges and Stahler (1909) obtained a deposit of violet...

Jan 1, 1956

Industrial minerals and rocks (alternat ively called non-metallic minerals) are those- which are economically important because of their desirable physical or chemical properties rather than their metal or energy content. They are divided into nine classes: structural, pig- ments, process aids, ceramics and refractories, chemical source minerals, abrasives, foundry minerals, gem stones, electrical minerals. Development of deposits is influenced by the dominance of marketing,by the required range of products, the-need for specialized process- ing, place value, and the transportation and distribution of high-bulk, low-cost commodities. Evaluation is different from that of base metals because of differences in geological occurrence, sampling methods, testing, treatment, placing a money-value on the material and the importance of export markets.

Jan 1, 1973

By A D. Ferreira, A E. C, A D. Padovezi

The increasing market requirements regarding the quality of products, the enhanced predictability from detailed mine planning, the need for process consolidation and upgrading require continuous investigation on the characteristics of different ore types to be concentrated. This paper addresses the mineralogical and technological characterisation of several itabirite iron ore types and the influence of the composition and mineralogical associations on desliming and flotation. Pellet feed quality and the influence on the major performance indicators, such as weight recovery of slimes, selectivity index, metallurgical recovery, flotation kinetics of iron minerals and gangue is also emphasised. The investigation resulted in a classification of iron ores according to their mineralogical composition, morphology of the crystals, and/or texture and microstructure of mineral particles with respect to desliming and flotation performances.

Jan 1, 2005

Proper technical appraisal of a coal deposit and the determination of optimum open- pit mine design can only be made after detailed examination of a number of interrelated geographical and geological factors. Initial evaluation of the geography and the overall attitude of the coal measures can often determine the most likely coal mining technique. Conclusions reached in the early stage of the investigations frequently dictate the quality and quantity of particular types of data required from further drilling of the deposit. In many cases, insufficient information relating to the overall engineering aspects of a coal deposit is derived from drilling. Little or no attention is paid in the exploratory phase to such things as the specific gravity of selected overburden samples, floor conditions, clay content of the overburden and selected strength tests on cores. This is a direct result of geologists treating coal deposits purely in geological terms without sufficient consideration being given to the engineering parameters required for a proper evaluation of the deposit.

Jan 1, 1977

Polyacrylamide flocculating agent has been used in the Leaching Division of the Risdon Works of the Electrolytic Zinc Co. of Australasia Ltd since October, 1960. Since the introduction, the.: number of thickeners in use in the continu-ous thickening stage has been reduced from eight to three; there has been an increase of 25% in throughput and a reduc-tion of solids in.:thickener overflow from 3-4 gòpòl . solids to 0.5 g.p.l. solids. Reagent addition has been at the rate of 0.25. lb SEPARAN, NP10 per ton solids.Additionally there has been a gain of 3% in current efficiency as the direct result of the addition of SEPARAN NP10 to purified cadmium sulphate solution prior to electrolysis for cadmium metal. A smoother deposit has resulted and it has been possible to increase deposition time between strip-pings from 47 to 71 hours. However, there has been a slight increase the lead content of the cadmium-metal produced.

Jan 1, 1963

By N Slade, D Kennedy

Optimal throughput is a key objective for the successful operation of any manufacturing or processing business. In the mining industry in particular, in order to obtain maximum return on the significant capital investment in the physical assets involved, ensuring continuous throughput is a major focus for the complete leadership team. Failure to meet throughput objectives becomes a major source of distraction for management which too often attempts to solve shortfalls by æforcingÆ and æenforcingÆ production targets. This focus on the short term and the lack of attention to addressing root causes frustrates operators who attempt to satisfy unattainable short-term targets and lose sight of the long-term goal. Mount Isa Copper Operations, Xstrata Copper, North Queensland, had ambitious plans to increase throughput volume by ten per cent within a four month period to allow budgets to be achieved within the financial year. To achieve this, the process had to overcome the interplay of a multi-node (æsiloedÆ) production system and its associated inventories, each node, of which on the face of it at least, had more than enough ænameplateÆ capacity to meet these plans. However, the actual volume achieved at the end point of the system was well below this nameplate capacity and the system operated with an extraordinarily high standard deviation. The key issues in terms of making or exceeding plan were: how to substantially reduce the variability of the system and managing the inventories between nodes, how to synchronise throughput between the production nodes, and how to improve the decision-making ability within the process. In this paper, the implementation team has shown that a revolutionary process view of the operation together with appropriate planning decisions allowed increased throughput to be achieved without further capital investment.

Jan 1, 2006

This paper discusses a number of examples of how environmental factors have been incorporated into the water management aspects of mining projects. One example is the Kingston Lignite Project in the South-East of South Australia where the most significant environmental issue was considered to be the effect of drawdown from mine dewatering and depressurization upon the use of groundwater. By proposing an alternative mining method - the use of floating dredges rather than a two-pass dragline method - drawdown effects would no longer be a concern. A second example is the Pine Creek Gold Mine in the Northern Territory. In this case the principal area of interest from an environmental viewpoint was water management - in particular effluent disposal, contaminated seepage from overburden and tailings, and project water supply. Through an integrated approach to the management of wastes and water the potential for water quality impairment was significantly reduced and external water supply requirements were also significantly reduced.

Jan 1, 1987

By S E. Box, J L. Mauk

The Middle Proterozoic metasedimentary rocks of the Belt Supergroup contain important metallic mineral deposits like the diagenetic sediment-hosted stratiform copper mineralization, including the Troy (Spar Lake) deposit and the epigenetic hydrothermal veins in the lower Belt and Ravalli Group in the Coeur d'Alene district. Magnetite (Fe3O4) is a common and widespread accessory mineral in these rocks and can have multiple origins including ore stage in deposits, mobilization stage in source rocks, metamorphism of red beds and alteration mineral in thin halos enveloping Ag-rich veins in the Coeur dÆAlene district. As shown in several classic studies, the composition of magnetite from igneous rocks varies significantly in response to controlling factors such as melt composition, temperature, silica activity, and oxygen and sulphur fugacity. Therefore, the distinctively different geologic settings within the Belt Supergroup strongly suggest that there may be differences in the magnetite compositions. However, initial microprobe analyses detected no variation in magnetite composition.   Three possibilities may give an adequate explanation for these initial results: 1.      the magnetite formed primarily as pure Fe3O4, 2.      one or more tectonothermal events led to regional scale re-equilibration that affected all rocks in the field area, and 3.      the variations in the composition are below the detection limit of the microprobe.

Jan 1, 2007

The task of designing stable high walls and spoil piles in strip coal mines, and stable openings with controlled roofs and floors in underground collieries - within the constraints normally imposed by economics - depends upon a reliable assessment of rock mass strengths and rock mass reactions under a variety of stress conditions. Of the geological factors influencing internal friction and cohesion within rock masses, many may be determined qualitatively or empirically from bore-hole evidence. Rock types, descriptions and properties of intact rocks, location of boundaries, limits and degrees of weathering, potential for slaking or decomposition of rocks when exposed, bedding characteristics, the nature of rock anisotropy and the likely effects of water on rock mass properties can be assessed from bore- hole data. Discontinuities, whether they be major such as faults and dykes, or minor such as joints and fractures, present a greater problem, and in most instances the mine geologist must resort to additional techniques to describe or predict their occurrence, nature, frequency, intensity or physical properties. Information on ground water and seam gas is available from bore-holes within certain levels of reliability.

Jan 1, 1977

At moderate depths this question is of relatively small importance, but at depths over 2,000 feet it becomes a matter of some consequence. The rate of increase of temperature with the depth varies in different localities, but as a rough average we may take it to be about 1° Fahr. for every 50 feet of depth. The variation of temperature of the earth's surface from summer to winter penetrates to a comparatively shallow depth. At 50 feet the variation becomes practically insensible, and the temperature of the strata will be about the mean temperature at the given locality, from 60° to 75° F. in this country or the comfort of men working in the mines it is desirable to maintain a temperature of about 70° F. in the workings, or approximately the temperature of the strata near the surface.In order to obtain some idea of the magnitude of the undertaking involved in cooling a mine, I have examined the effect of placing in a long drive an apparatus by means of which we can abstract heat at a uniform rate from the drive, keeping, thetemperature nearly the same at all points of the drive at any given time.The lowering of temperature 70 F. at any distance feet from the centre of the drive (treated as a cylinder of the same sectional area as the actual drive), after an interval of time days from the commencement of the operation is given by the formula...

Jan 1, 1907

Mining of the silver-lead-zinc orebodies at the George Fisher Mine officially started in 2000. A review of mining performance to date shows that many of the extracted primary stopes have experienced some degree of hangingwall dilution. The degree of hangingwall failure in the stopes became progressively more extensive throughout mining of the orebodies in 2001 and 2002, culminating in the unplanned catastrophic failure of the 744D stope in which the ore between 13C (2683RL) and 12L (2714RL) sublevels caved into the previously mined cavity between 13L (2654RL) and 13C sublevels. This was followed several months later by another unplanned caving event in a nearby stope, 740D. As a direct result of these unplanned failures it was decided to mine the stopes with a smaller span than had been previously planned and in a primary-secondary pyramidal stoping sequence. To limit the exposure of the stope hangingwall, a hangingwall drive is no longer developed and therefore geologists no longer have access to the detailed geological information that this provided. Geologists at George Fisher Mine have had to be adaptable and flexible in response to these proposed changes and rely more on data from drilling than mapping for their geological interpretation. The result is that the drilling cycle has become much more critical in the planning process.

Jan 1, 2003

By Sneddon J

This Is not a highly technical paper, but rather an attempt to give a general outline of coal mining for the benefit of those present who may have little or no experience in the industry, and is intended to give some general knowledge which may help to a better understanding of the problems of the industry. A knowledge of the disposition of workable material is necessary to give a comparison with other mining practices. Coal Is usually found in comparatively fiat seams of varying thickness, whereas other minerals are generally found in highly inclined lodes of variable width. However, even in comparatively flat seams unaffected by faulting, grades can, and do, vary greatly over short distances.This variation causes many local problems in working the small area affected. Even very steep seams, and some are much steeper than 1 in 1, vary considerably not only in grade, but also in direction of grade and level course. This is probably caused by folding during alteration of the shape and form of the basins after deposition.These swellies are common to most coal seams and vary only in extent. This type of variation in grade and direction of grade, while common to most ore bodies, is a matter of great importance in coal mining when it is considered that roadways are driven in the seam itself and have to be graded and made suitable for haulage purposes.The area of ground involved in an individual coal mining operation is often very large; many times larger than most metal mining propositions, and often comprises many thousands of acres.When it is considered that the specific gravity of coal may be only one-fifth of that of some ores mined, and the coal seam may be five or six feet in thickness, the vastness of the area necessary for continuous mining operations over many years will be realised.To achieve comparable outputs, with about five times the bulk of material to handle, much more ground and working places must...

Jan 1, 1947

The medical evaluation of the health effects of dust exposure in the mining industry should be based on the premise that the results of the medical examinations will be considered in relation to the previous history of exposure to dust.(l) To this end the Mines Regulation Act and the Regulations under that Act in West- ern Australia provide for: the prime responsibility for dust sampling to rest with the mining companies; the appointment of a Ventilation officer by each mine and the sampling and record- ing by him of dust and toxic gases in work places at three monthly intervals, or more frequently as required; the appointment of a Mines Medical Officer who shall make provision for the medical examination of persons and the prevention of occupational diseases; the appointment of a Ventilation Board, consisting of the State Mining Engineer, the Senior Inspector of Mines for the State, an Inspector of Mines having specialised training in ventilation tech- nology, a medical practitioner having specialised experience in occupational health problems relevant to the mining industry, and a Scientific Officer having duties under the provisions of the Clean Air Act, 1964;

Jan 1, 1979

IT is intended herein: to make some brief comments on geophysical 'work in general and on the various methods, and then to refer to that branch which, perhaps, is of the greatest importance and interest to the metalliferous mining engineer, i.e., the variousmethods of electrical prospecting.The term geophysics was originally applied to those larger physical and geodetic studies and methods concerned with such purely scientific subjects as the investigation of the true figure of the earth and the determination of the stability relations resultingtherefrom. Applied geophysics and geophysical methods of prospecting are concerned primarily with the search for, and investigation of, useful mineral deposits concealed within the earth's crust and not readily detectable by the normal methods employed bythe mining geologist and prospector. The methods employed have been devised as a result of co-operation between mining men, geologists, and physicists, and, although steady progress has been made during the past 20 years or so, it is within the last four orfive years that the importance of these methods has been acknowledged by the mining world in general. Although many of these methods are still in, or have barely emerged from, the experimental stages, a steadily increasing list of important discoveries is attributable to their employment-more particularly in Europe and America than elsewhere. The various methods have each their own limitations regarding the class of work they can undertake, and no one method is capable of general application. The greatest care should be exercised in selecting the method, or methods, to be employed in any particular area, the...

Jan 1, 1928

By J du Plessis, W Marx

The FutureMine Collaborative Research Initiative has been successfully completed after three years of activity. The main objective of this initiative was to provide applications of research previously undertaken in the DeepMine initiative in terms of realistic solutions to problems facing gold mining operations as they reach for depths beyond 3500 m below surface. The FutureMine initiative was subdivided into four broad streams of technological expertise: rock engineering and seismicity; mining engineering and orebody management; software and communications and ventilation, cooling and refrigeration. This paper presents a summary of research output in this last area of expertise. Broadly, research in mine ventilation, cooling and refrigeration was directed in areas related to the recirculation of air, cyclical use of ventilation and cooling systems, air scrubbing technology, optimisation of chilled water reticulation, obtaining direct cooling at the workface, improving underground refrigeration systems through dry air-cooling and water heat rejection systems and a number of software simulation programs to be used in specific applications and as a tool assisting real-time monitoring of underground environmental conditions.This paper describes in broad terms the outcomes from this section of the research program and proposes ways in which some of these technologies may be combined synergistically in novel systems aimed at maintaining acceptable environmental conditions while reducing the impact on the profitability of operations.

Jan 1, 2005

The development of reliable and accurate solution sampling systems plus on-line atomic absorption spectrophotometers and voltammetric analysers at Pasminco Metals - EZ's (PMEZ) zinc refinery at Hobart, Tasmania, has led to extensive implementation of On-Stream Analysis (OSA) throughout the hydrometallurgical circuit. These systems complement industrial autotitrator and colorimetric analysers and with the comprehensive use of a powerful integrated Distributed Control System (DCS), provide extensive monitoring and control of all the important in solution' parameters for the plant. Samples can be left unaltered, or filtered or settled, to remove solids. They are then precision diluted and pneumatically transported to analyser shelters, where they are analysed for zinc, acid, copper, cadmium, lead, antimony, cobalt, nickel, mercury and ferrous, ferric and/or total iron. The range of analyses depends on the sample itself. The results are used for feed forward and/or feedback control of reagents where possible, or simple trend monitoring and out-of-specification alarming when closed loop control is not practical. The overall system reliability and accuracy is such that many daily composite plant samples are no longer analysed off-line. Operator sampling has also been reduced, and in two places, autotitrators with automatic sample pre-treatment have been installed for preparing and analysing samples collected by operators.

Jan 1, 1993