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By H. Hu

Observations were made on the recrystallization of a 70 pct cdd-rolled silicon-iron crystal with an initial orientation of (113) [332]. Its polygonization and recrystallization characteristics were studied. Results indicated that re crystallization tendency of the deformed crystal is much weakened by the polygonization of the matrix. Complete recrystallization in such specimens is achieved by the growth of recrystallized grains of sufficient size and of the right orientations in relation to the matrix. Evidence was also furnished which suggests that the difference in the re-crystallization tendency is a result of the difference in the severity of lattice bending rather than the difference in orientation of the deformation texture. DUNN and Koh1,2 have made an extensive study on the rolling and annealing textures in silicon-iron crystals. Their results indicated that the recrystallization tendency can be widely different in crystals with different orientations. A particularly interesting example of their results was a crystal with an initial orientation of (113) [332], which developed a deformation texture of (001) [110] after 70 pct cold-rolling. Recrystallization in this crystal took long time anneals at high temperatures. Other crystals having different orientations recrystallized very rapidly. Wiener and corcoran3 have observed the retention of the (100) [011] deformation texture in a low-temperature annealed specimen of a commercial silicon-iron alloy, corresponding to areas of light-etching low-angle boundaries in the annealed struc-

Jan 1, 1960

By A. W. Farenwald

Fine grinding cannot be accomplished in machines in which the component parts move in definite and restricted paths with respect to each other. Such machines are crushers. A "grinding mill" may be defined as any machine in which the crushing elements are free to make direct contact with each other but are kept from doing so by the sand to be crushed. Such a machine must possess the ability to give numerous contacts per unit of time. Upon consideration, one will see that this definition nearly includes the old Chilean and Huntington mills, the "rolls" and the stamp mill. It definitely includes all forms of ball, pebble and rod mills. The ideal (perfeet) grinding mill may be defined as one in which the crushing elements are identical in shape and substance and possess perfect freedom of motion with respect to one another. Of the mills mentioned, only the ball and pebble mills come under this definition of the ideal mill. Even the rod mill fails to get a place under this definition of the perfect mill. Modern Fine-grinding Mill In current practice fine grinding is performed in rotating cylinders1 partially loaded with hard objects, the agitation of which accomplishes the crushing or grinding of the rock or ore. The hard objects called "grinding media" nearly always are steel or some other alloy of iron. Hard rock (flint pebbles) have been and still are used to a limited extent. When steel is used as the grinding substance, the form is the sphere or "ball." The combination of rotating cylinder and steel-ball grinding media is termed "ball mill." Shapes other than the sphere have been tried. Cylindrical grinding media also have been and are now used in grinding mills. When cylindrical media are used the mill is termed "rod mill." Mechanical Elements of Grinding Mills The mechanical elements of a grinding mill arc: (1) the rotating element, (2) the grinding media, (3) the rotating means.

Jan 1, 1935

The classification here used is one of convenience only; it is not intended to include all known types of ore deposits. The characteristic features of the several well-marked types of primary mineralizations are described without reference to the ultimate source of their metals. The minerals of many deposits of obscure origin were probably introduced through fissures that are now healed, or are due to the migration of metals from such deposits. [ ] It is not within the scope of this book to enter into a general discussion of the genesis of ore deposits but, in view of the progress being made in our comprehension of the conditions under which ore deposits were formed, mention should be made of recent work. J. E. Spurr's two volumes, "The Ore Magmas," are recommended as crystallizing the views of those who are inclined to ascribe the origin of most ore deposits to a differential precipitation from magmatic rock masses and to the migration and precipitation of the viscous, liquid or gaseous exhalations from those masses. He has especially emphasized the role

Jan 1, 1932

Jan 1, 1917

By B. F. Koch

COPPER reverberatories develop large amounts of exit gases of a temperature in the neighborhood of 2000°F. The gases are not only of a noxious nature but must usually be disposed of at considerable heights above the yard level by a stack. Handling these gases at the temperature mentioned would require rather expensive construction of conveying flues and stack. Moreover, wasting such amounts of heat is certainly most uneconomical. Numerous investigations have indicated that waste heat boilers of the water-tube type are the most practical and economical means for utilizing that heat although the gases are heavily laden with rock dust and copper-bearing slag, which upon cooling form hard deposits on the surfaces of dampers or heat absorbing elements placed in the gas stream. Avoiding Slag and Dust Deposits Based largely on the experience of the paper industry in burning black liquor, a waste heat boiler design was developed a few years ago, providing not only extensive water-wall surfaces for cooling the gases below the fusing point of the slag but also settling out, as far as possible, the solidified particles of slag by creating low gas velocity. Matter carried in a stream of gases or air has a tendency to maintain its original direction upon a change in the direction of the flow of the conveying medium. Reverberatory waste heat boilers installed at Hurley and Morenci endeavored to utilize that tendency for the elimination of slagging particles at predetermined places and before they would strike the tube banks of the boilers. Both installations were successful in minimizing the slagging of boiler tubes and thereby minimizing the need for hand lancing. However, the low draft carried at the up-take of the reverberatory furnaces resulted in a positive pressure in the upper part of the furnace of the waste heat boilers, causing the emission of gases from lancing doors and making more difficult the already unwelcome work of cleaning the boilers by handlancing. Attempting to correct this nuisance as much as possible, the overall height of the Chuquicamata waste heat boilers has been reduced to the minimum considered necessary to obtain proper water circulation in furnace walls. Moreover, it is attempted to solidify slag and dust particles by providing large amounts of water-cooled surfaces before the gas stream reaches super-heater and convection banks of the boilers. The furnaces have been made as deep as an economical and practical arrangement of headers for water

Jan 1, 1952

By R. L. Sandefur

Professor Kim's excellent review article1 on ultimate pit planning contains a statement of the apparently widely held but incorrect belief that "kriging provides information on the confidence limits around the estimate which no other extension technique is capable of supplying." If a geostatistical approach is valid, there are several good reasons for using kriging but uniquely provided confidence limits is not among them. If kriging is possible, then confidence limits can be calculated for any other linear estimate. Kriging is the procedure which finds the weighing coefficients which minimize the estimation variance [ ] is the variance of blocks like the one being estimated. wi is the covariance of the estimated block and the i-th sample. oij is the covariance of the i-th sample and the j-th sample. Ai is the weighing coefficient for the i-th sample. N is the number of samples. The formula for estimation variance can also be used to calculate confidence limits on blocks estimated by any linear combination of sample grades including: 1) Polygons a. Hole nearest block centroid is assigned weight 1. All other holes are assigned weight 0. b. Polygonal area weighing. The samples are assigned weights directly proportional to their polygonal areas of influence within the block. The weights sum to 1. 2) Inverse distance weighing. The samples are assigned weights directly proportional to the reciprocal of their distance to some power from the block centriod. The weights sum to 1. Often only holes nearer than a certain distance and/or the nearest hole in each octant is considered. If there is an antisotropy to the ore body, an elliptical transformation often gives more accurate results. The most popular inverse distance weighing function is inverse squared distances (IDS). 3) Simple average. All samples within a certain distance are assigned the same weights which sum to 1. As an example of the applicability of the above formula to any linear estimate an internal verification on copper grade of 665 blast holes on the 1040 bench at Utah's Island Copper mine is presented. Internal verification is simple and applicable to non-linear estimates as well. Any sample (drill hole, bulk, trench, or chip) is dropped out, the value of the dropped sample estimated and compared with the actual value. If this is done for all samples, a measure of confidence limits is obtained. Internal verification is used in Cominco's MEPS system4 and in the BLUEPACK system.5 Comparison of block values against estimates697 is not dissimilar to internal verification. Results of the internal verification are presented below:

Jan 1, 1980

By Pope Yeatman

In my experience, perhaps the most interesting problems came up during the testing, prospecting, developing and equipping of the Chuquicamata and Braden Copper Mines in Chile, and it is proposed in this article to give as briefly as possible what some of those problems were, their solutions, and the decisions made as to the different methods to be employed. The romance of mining is still a great lure to the young man who is making a choice of a profession to follow. The thought of travel to strange and out-of-the-way places, the glamor of pioneer life, the excitement of discovery, the constructive work of building something, entirely "from the grass roots up," or of reconstructing a played-out property and making a success of it-all of these phases have a strong appeal and often influence the young man in the choice of mining as a profession. That great engineer, Col. Seeley Wintersmith Mudd, whom we are endeavoring to honor, while having too much common sense to have been materially influenced by the romance of mining, certainly experienced all of the

Jan 1, 1932

By Joseph G. Debanné

Foreword The three case histories and the liquid fuels planning scenario presented in this paper span a twenty year period, from the pioneering days of computers in the petroleum producing industry during the mid-fifties, to the energy crisis era of the seventies. Inasmuch as two of the main actors, Ian McKinnon and I, are featured in all three case histories, while I am currently involved in the fossil fuels scenario, this paper provides four related and personal spot readings along an evolutionary path: from the one dimensional technical domain to the multi-dimensional techno-socio-economic domain of computer applications in the petroleum industry. Coincident with this evolution in the direction of increasingly comprehensive and powerful computer applications, the evolution in hardware/software capability and in analytical power are also kept in perspective. The three case histories are: 1. The Bonnie Glen-Wizard Lake Case (Calgary, Alberta, 1955-1957); 2. The TransCanada-Great Lakes Gas Transmission Case (Ottawa-Washington, 1966); 3. The Westcoast Transmission - El Paso Pipelines Gas Export/ Import Case (Ottawa-Vancouver-Washington, 1966-1967). The liquid fuels planning scenario is a demonstration exercise rather than a case history; however, it represents an important point on the evolutionary curve and, provides a concrete example of tech-

Jan 1, 1977

By Nicholas J. Grant, Noboru Komatsu

Electron-micrographic studies and hardness tests were made of an internally oxidized dispersion-strengthened Cu-12 vol pct SiO2 alloy follozuing longtime annealing at elevated temperatures. The rate of coarsening of SiO2 particles and the relationship between hardness and interpavticle spacing were Dispersion -strengthened alloys exhibit a remarkable stability of structure and properties at elevated temperatures compared with conventional alloys; nevertheless, when they are exposed to high measured. The rate of coarsening of SiO2 particles is controlled by the decomposition of SiO, rather than by the diffusion rates of silicon or oxygen through the copper matrix. The mechanism of coarsening was also studied by using a diffusion-couple technique. temperatures, weakening takes place as a result of coarsening of the dispersed phase. The theoretical treatment of the coarsening of dispersed phases has been treated by Greenwood,1 wagner,, and others3 by considering the interfacial energy of dispersions and the diffusion of solute atoms. Recently, experimental work on the coarsening of relatively insoluble, finely dispersed cobalt particles in copper was reported by Livingston,4 and on aluminum oxide in nickel by Dromsky, Lenel, and Ansell;5 according to these investigations, the rate

Jan 1, 1964

By T. M. Morris, F. M. Lewis, W. C. Lay, Gordon M. Bell

Part I of this chapter is concerned with the description of and metallurgical data pertaining to the flotation circuits used in the London mill of the Tennessee Copper Co., at Copperhill, Tenn. The ores treated at the London mill are massive complex sulfides, in which pyrrhotite and pyrite are the predominant minerals. Other sulfides are chalcopyrite and sphalerite; magnetite is also of economic value. The approximate mineralogical analysis of the ore is shown in Table 1. [ ] The chalcopyrite and sphalerite are closely associated with pyrrhotite as shown by the tracings of micrographs (Fig. I), which are representative of the mill feed. Fig. la illustrates the type of locking between pyrrhotite and chalcopyrite; Fig. lb illustrates the way in which sphalerite is attached. Thesephotographs indicate that it is not practical to break all of these attachments. Hence, in order to produce concentrates with satisfactory grades and recoveries, most of the locked chalcopyrite particles must be recovered into the copper concentrate, and the locked sphalerite-pyrrhotite particles must be separated from the iron concentrate. A copper concentrate, a zinc concentrate, and an iron concentrate are made. Typical metallurgical results are tabulated in Table 2. HISTORICAL In 1922 the London mill started as a copper concentrator, with a capacity of 300 tpd, and in 1926 an additional flotation circuit was added to recover the iron sulfide remaining in the copper tailing. In 1927 a zinc flotation circuit was installed between the copper and the iron flotation circuits. This procedure was not satisfactory because the iron recovery was low, due to the

Jan 1, 1962

By G. C. Gould

The nature of freckle segregation is determined by chemical analyses, microradiograplzy, and electron microprobe. In addition, the influence of chemistry variation on freckle formation is studied in laboratory experiments. It is demonstrated that controlled laboratory solidification can produce freckle segregation. "FRECKLE" segregation is a discontinuous, rod-like segregation observed in vacuum consumable -electrode ingots. Figs. 1 and 2 show this segregation as pencil-like, dark etching areas of segregation found in longitudinally and transversely sectioned consumable-electrode ingots. In most cases the segregation is perpendicular with respect to gravity and parallel to the longitudinal axis of the ingot. The segregation is most often encountered at or around midradius in large vacuum consumable-electrode ingots. The austenitic alloys, A-286* and 718, † have shown particular susceptibility to this mode of segregation. The origin of these rodlike pockets of segregation is not well-understood. It has been suggested that the segregation is a result of a portion of the electrode dropping off and passing through the arc un-melted. On the other hand, smeltzer1 has demonstrated the freckle segregation in A-286 to be comprised of low-melting constituents relative to the matrix melting point. The discontinuous nature of the segregation is the most perplexing facet of the freckle-segregation problem. It was to gain some insight into this part of the problem that this work was undertaken. I) PROCEDURE At the outset of the work identification of the phases present and the elements concentrated in the freckle areas was undertaken. The electron micro-probe was used to determine general enrichment as well as -specific phase chemistry. Microradiography using cobalt and chromium radiation was also used on the freckle areas again to determine the elements involved in the segregation. X-ray diffraction patterns were made from portions of these same foil specimens. Optical microscopy and Knoop hardness measurements were also used

Jan 1, 1965

By Hjalmar Sjögren

Introduction.............767 Group I. The Ores of the Archean Crystalline Schists.... 770 Distribution............. 770 The Rocks.............770 Structures............772 The Rocks of Norrbotten..774 The Ores.............775 Type A. Apatite.Ores..........776 Type B. Mixed Hematite and Magnetite..777 Type C. Quartz-Banded Ores....777 Type D. The "Skarn" .Ores l..778 Type E. Limestone-Ores,..779 The Origin. of the Ore-Deposits......... 779 Arguments against the Sedimentation Theory,... 780 Concentration and Transformation within the Deep-Seated (Ana-morphic) Zone........783 The Chemical Changes.......784 Transformations in the Surface.Zone....789 The Graingesberg and Norrbotten Deposits,.....791 Analogous Deposits........794 Group II. The Ores of the Porphyries (Keratophyres) ... 796 Kiirunavaara. Luossavaara and TuoIlavaara....797 The Syenite.........799 The Porphyry of the, Foot. Wal1 .....799 The Porphyry of the Hanging-Wal1 ....799 The Ores.........800 The Forms and Dimensions of the Ore-Bodies ..802 Contact-Zones........803 The Genesis of the Deposits .......804 Mertainen and Painirova.......806 Ekatrömsberg..........808 Analogous Deposits,........808 Group 111. Magmatic Seregations in Basic Eruptives,... 809 Taberg in Smaland,.........811 Segregations in Diabase Younger than the Dala Sandstone, . 814 Iron-Ore in Nepheline. Syenite.......815 Ekersund and Soggendal in Norway......816

Jan 1, 1908

By Lawrence Wright

THE occurrence of gold, gold-silver, silver-lead-zinc ores in the post-Cambrian sediments in the Black Hills of South Dakota, and their genetic relationship to the Tertiary intrusives, is well known and accepted, but the occurrence of gold in the pre-Cambrian rocks at the Homestake mine, which underlie this Tertiary gold mineralization, has given rise to differ-ences of opinion as to the period of major gold introduction into the older rocks. Fig. 1 illustrates. the distribution of mineralization along the axis of the Tertiary uplift in both pre-Cambrian and post-Cambrian rocks. The following possibilities have been presented: 1. The Homestake gold deposit was formed in pre-Cambrian time and the deposits in the overlying Cambrian sediments formed during Ter-tiary time. 2. The Homestake lode existed at the beginning of Cambrian time, but was enriched by the passage of Tertiary auriferous solutions. 3. The Homestake lode was represented by pre-Cambrian quartz-chlorite sulfide mineralization, very low in gold content and the gold superimposed on the older nearly barren mineralization during the Ter-tiary metallogenic epoch. 4. The sulfides and sulfarsenides as well as gold were deposited in both pre-Cambrian and post-Cambrian rocks during the Tertiary period. Those favoring the first proposition feel that the question is pretty well settled, while the proponents of the second theory are more flexible in their view, feeling that the amount of gold introduced in either period is still an open question. The third and fourth theories, with some modifi-cations, are supported by the proponents of the Tertiary theory, who feel that the evidence strongly favors that period. The following pages are intended to present the evidence and to give the reaction of various observers with my own comments and conclu-sions; also, the accumulated facts of observation gathered over a period of close association with the area under discussion, beginning in 1919.

Jan 1, 1936

By C. H. Li, R. J. Stokes, T. L. Johnston

A portion of the Ni3Cr-Ni3Al phase dzagram has been investigated, including the precipitation of 1 (Ni3Al) as well as the existence of ordered Y (Ni matrix), Extensive metallographic studies by electron microscopy have been carried out and X-ray diffraction diagrams have been taken at both elevated and ambient temperatures, No long-range ordering of the phase was found above 893°C (1639°F) in the compositional range investigated. The high rate of formation of the ordered ?1 phase upon quenching has been confirmed, a phenomenon which up to the present Lime has retarded the understanding of this phase diagram, Specimens with controlled amounts of ?1 exhibited up to a six-fold improvement in yield and creep strength compared with single-phase Ni-Cv-A1 alloys. MOST of the important high nickel heat-resistant alloys are related to the nickel-chromium-aluminum system. One of the important functions of the aluminum, often accompanied by titanium, is to produce a precipitate of the very fine ?1 phase (Ni3A1, X) where X may be Ti, Cr, or other elements. A number of investigators1-" have demonstrate the presence of y' in these alloys but most of their materials contained large amounts of other elements resulting in appreciable amounts of con- fusing phases such as carbides. Further clouding of the precise role of y' has been the suspected existence of an ordering reaction in the y matrix itself, ro-3,12-17 It appeared from these investigations that aluminum in Ni-Cr alloys would raise the ordering temperature of the matrix from 540°C at NisCr to 1300°C at Ni,Al. In support of this possibility, the matrix phase in the parallel Ni-Fe-A1 system is ordered to very high temperatures.1 OBJECTIVES OF THIS RESEARCH From this survey of the literature it appeared desirable to conduct an investigation of the simple Ni-Cr-A1 system using the alloys of the highest available purity to avoid the complication of foreign phases and thereby isolate the structures in the Ni-Cr-A1 system. Procedures were developed to study ? - ?o and ? - ?1 equilibria. Preliminary mechanical tests at elevated temperatures were also conducted.

Jan 1, 1962

By C. E. Siebenthal

produce attractive and consequently more salable products. It would seem, however, that if solder and babbitt were cast in closed molds, just as good practical results would be obtained by the user, without his being able to give preference to solders of unnecessarily higher grade on account of their appearance. It would be hopeless for any one. manufacturer of solder to undertake a change of this kind, but if all manufacturers of solder agreed upon it, they would be able, in my opinion, to get the users of solder to take, and to approve by their practical tests, metals containing less tin than they have been accustomed to. The same is true with regard to babbitt metals. An illustration of how, in the use of an alloy, appearance sometimes is deceptive, is to be found in the case of what may be called intermediate grades of babbitt. I am thoroughly convinced that high-tin or high-lead babbitts are better than those containing both lead and tin with relatively high percentages of each. A high-tin babbitt should not contain more than about 10 per cent. of lead, and a high-lead babbitt should not contain more than 10 per cent. of tin, unless the percentage of antimony can be correspondingly increased. The intermediate babbitts, such as those that contain from 30 to 70 per cent. of lead or tin, may give nice appearing castings that flow easily, but they have not the serviceability of the high-lead or high-tin babbitts. Their hardness diminishes very rapidly as the temperature rises, and they have a relatively low softening point due to the eutectic components present. The Cadmium Supply of the united States* C. E. Siebenthal, † Washington., D. C.—From being one of the most maligned of metals—a veritable bugaboo—cadmium has almost overnight become respectable, though its slender claim to respectability rests almost wholly on the possibility of its substitution for tin. Preliminary to any campaign for such substitution, particularly for enforced substitution, the possible supply of cadmium should be determined as closely as possible; for that reason the statistical inquiry of which this paper embodies the results was undertaken. Production Cadmium is marketed in two forms, as metallic cadmium, in sticks or bars, and as cadmium sulfide, the pigment. The metal has found its greatest field of use in this country as a component of an easily fusible alloy that is used in automatic fire extinguishers. The sulfide is used to some extent in paints but chiefly to give color and luster to glass and porcelain. The metal was first made in this country by the Grasselli Chemical

Jan 1, 1919

By John Vasey

A shaft of 1690 m depth is currently being sunk to exploit a large copper sulphide orebody. The primary crusher chamber, main pump chamber and the other excavations on the crusher level were developed from the shaft during the sinking operation. The maximum principal stress is horizontal and has a magnitude twice that of the vertical stress. It increased linearly with depth and on the elevation of the crusher level, 1613 m below surface, the stresses induced by mining can exceed the strength of the rock. The development of a workable crusher level layout, and a crusher chamber design and support system are described. Excavation and support of the workings are detailed and a comparison of expected and actual results is made.

Jan 1, 1983

By Earl C. Smith

Jan 1, 1935

By Earl C. Smith

Jan 1, 1935

[ ]

Jan 1, 1938

By W. A. Hockings, G. W. Lower, K. A. Smith

The kinetics of dissolution of metallic copper in aqueous cupric ammonium carbonate solutions were investigated. The major variables studied were temperature, agitation, and the cupric, cuprous, ammonia and carbonate concentrations. The rates of copper dissolution from rotating discs were determined by measuring the weight loss. The dissolution rate increased with the square root of the disc rpm and doubled when the temperature was increased from 20°c to 40°C.

Jan 1, 1973