Search Documents

By R. C. Dorward

DIFFUSION considerations are necessary to describe many technologically important metallurgical and physical processes. Since most commercially important alloys are comprised of more than two components, diffusion calculations applicable to binary systems are often unjustified. However, in many instances the more general equations valid for three-component systems may be employed. The phenom-enological description of ternary diffusion is now well-established,1-4 and the theory has been applied with some success to a few practical situations.5"7 The flux equations for the solutes (components 1 and 2) of a ternary solution may be expressed by:

Jan 1, 1969

By Edward C. Roper

Pegasus' Gold Ltd. operates two gold/silver heap leaching operations in the Little Rockies area of Montana. The Little Rockies has produced gold from underground operations on an intermittent basis from the 1880's to the early 1950's and from the open-pits on a continuous basis since 1979. Run-of-the-mine ore is drilled, blasted, sorted, loaded and hauled. The waste is dumped and compacted into 30 meter (100 foot) fills to be used for future leach pads. The leach pads have a central drain system and the impermeable membrane is constructed of bentonite and 30 mil PVC. The plants which have beenexpanded to 4900 Ipm (1300 gpm) capacity use the Merrill-Crowe process for gold and silver recovery. 4600 liters (1200 gpm) of the 9500 Ipm (2500 gpm) spray capacity is recycled through the old leach pads for upgrading before being processed. The gold/silver precipitate is smelted and the resultant dore' is shipped to a buyerhefiner. 1983 projected production is 2,177 kg (70,000 02s) of gold at a cost of less than $10/gm.

Jan 1, 1984

By E. J. Haug, M. M. Fine

For several years work has been carried on by the U.S. Bureau of Mines at Rolla, Mo., to develop improved methods of concentrating the oxidized ores of lead and zinc. Various samples have been investigated, and results on some have been published. Details of the progress to date are given in a mineral dressing study now being conducted for an extensive oxidized lead-bearing tract in southeast Missouri, property of St. Joseph Lead Co. These oxidized ores present problems typical of many encountered in modern mineral dressing research in that recovery of very fine particles is of

Jan 4, 1955

By John Harmon

THIS paper was written-with two objects in view: (1) To describe in detail what has been done toward the ventilation of the main unit of the Portovelo mines and the results; (2) to give information that may be useful to anyone who may have to make a preliminary mine ventilation survey, with recommendations for the improvement of the existing system and finally the maintenance of the improved system.

Jan 1, 1931

By W. W. Anderson

A formula for quantitative efficiency is proposed, in which the efficiency value is a function of the improperly distributed material at the gravity of separation effected by the cleaning equipment. The misplaced material is expressed as a percentage of the total material discharged from the equipment. Numerous examples are given, demonstrating application of the formula to various types of separation, including multiple-product separations.

Jan 2, 1950

By R. V. Mrazek, F. E. Block, S. B. Knapp

The mixed homogeneous and heterogeneous kinetics of the thermal decomposition of tungsten hexacarbonyl were studied by employing a batch reactor. The system was such that a sample of tungsten hexacarbonyl could be injected into the preheated reactor, and the progress of the reaction followed by a simple pressure measurement. Both the homogeneous and heterogeneous reactions were found to be first order, and approximate activation energies were determined for each reaction. It is shown that the dis-proportionation of carbon monoxide to give carbon and carbon dioxide cannot be the source of carbon in tungsten deposits prepared by this reaction. The kinetics of the thermal decomposition of tungsten hexacarbonyl have been investigated as part of a continuing study by the U.S. Bureau of Mines on the decomposition of organometallic compounds. Reactions involving the thermal decomposition of metal carbonyls have a potential application in the preparation of pure metals and fine metal powders. Indeed, it was these applications which provided the impetus for much of the early work involving the carbonyls of nickel1 and iron.' The relative lack of study of other metal carbonyls can be traced to the comparative difficulty in synthesizing these compounds. The most common use for tungsten hexacarbonyl has been as an intermediate in vapor-phase plating.7'8 However, attempts to obtain a carbon-free deposit of tungsten by this method have not been successful, and some investigators have taken advantage of the carbon contamination and used this process to form tungsten carbide deposits.lo Other investigators have studied the thermodynamic properties11"14 and molecular structure of tungsten hexacarbonyl. However, very little is known about the kinetics of this thermal decomposition, the mechanisms involved," or the source of carbon in the resulting plate. In contrast, studies have been made of the kinetics of the thermal decomposition of nickel tetracarbonyl, iron pentacarbonyl, and molybdenum hexacarbonyl.'l It has been found that these thermal decompositions occur by a mechanism which is partially heterogeneous in nature. Information available on the equilibrium constants for the decomposition of tungsten hexacarbonyl was used to determine a temperature range, 500" to 560°K, in which the reaction could be expected to be essentially complete. APPARATUS The apparatus used allowed the injection of a sample of tungsten hexacarbonyl into a preheated batch reactor and the use of a simple pressure measurement to follow the progress of the reaction in the sealed reactor. The pressure was sensed by means of a pressure transducer (Consolidated Electrodynamics Corp., 0.3 pct)* capable of operating at the *Reference to specific products is made to facilitate understanding and does not imply endorsement of such brands by the Bureau of Mines._______ reaction temperature. This type of sensing element was chosen to avoid the problem of condensation of the sublimed carbonyl in the capillary tubing leading to any type of remote pressure-sensing device. stirring was provided by rotating the entire apparatus. Glass beads placed in the reactor provided a pulsating agitation. To minimize thermal gradients in the reactor walls, the reactor was constructed of aluminum. The support tube which held the reactor in the furnace was thin-walled stainless steel to minimize heat conduction out of the reactor. As a result of these measures, a nearly uniform temperature (°C) was maintained throughout the reactor. Fig. 1 is a schematic diagram of the apparatus. The small gear motor rotated the entire apparatus at about 200 rpm. The bearings shown at the ends of the air cylinder were perforated to allow air to be fed to the charging piston and to allow inert gas to be fed to the reactor during the preheating period. The sample was simultaneously injected and sealed inside the reactor by operation of the air piston. Fig. 2 shows a cross section of the air cylinder and the adjoining portion of the support tube leading to the reactor. The sample carrier is shown in place at the right-hand end of the injection rod extending from the air piston. The piston is shown in the retracted position, as it would be prior to the start of an experiment. The small Teflon gasket which encircled the sample carrier at the end of the injection rod sealed the reactor when the sample was injected. This seal was maintained throughout the test by maintaining air pressure on the piston. The sample carrier was a 2-in. section of thin-walled, -in.-diam nickel tubing with an internal blank about 1 in. from the base and with the base end sealed.

Jan 1, 1969

By C. W. A. Muir

Laboratory and plant-scale testwork on the extraction of gold from highly refractory antimonial and arsenical concentrates using both direct low-alkalinity pressure cyanidation, and acidic pressure pre-leaching followed by ambient low-alkalinity cyanidation, is described. A novel method for treating effluent solutions containing extremely high concentrations of base metal cyanides, as well as arsenic and antimony compounds, was developed in order to make the process ecologically acceptable.

Jan 1, 1984

By A. K. Gangopadhyay, J. J. Moore

The effect of grinding media composition, mineral type, and slurry environment on the wear rate of various grinding media (balls) are discussed. Sufficient wear data have been obtained and correlated. Modes of wear were determined from examination of the ball surfaces using scanning electron microscopy. Five modes of wear have been identified to be operative under certain slurry conditions for the various ball compositions studied.

Jan 1, 1986

By O. B. Harden Harden

IN working out the geological structure of a complicated district, where the problems are difficult to solve by the ordinary methods in use, a model, upon which all the geological and topographical data may be put, will be found of great value, bringing, as it does, all the facts in their proper relationship at once under the eye. In the teaching of structural geology, also, a model is of great value, since the student can thus have before him, in miniature, a representation of the rocks, as he would see them in place. Topographical models-may often be useful in suits at law for damages in rail-road accidents, or for trespass against mining companies, etc., in order

Jan 1, 1882

By John A. Church

The Lake Superior blast-furnaces probably represent the maximum economy of fuel possible in this country. They smelt an ore which is very rich and easily reducible, and as the small amount of gangue present is not all silica, but in part a silicate, the amount of limestone required is a minimum. The average yield of the ore treated at six furnaces was 63 per cent., and the average quantity of limestone 179 pounds per ton of pig. The fuel used is charcoal, so burned as to retain most of the combustible volatile part, which, before the utilization of furnace-gas, was burned away. With these conditions it is not surprising that the Lake Superior charcoal practice is extraordinary in almost every respect. In any scientific discussion of American furnace work, the establishments there will be found at the head of the list, and they work under conditions which are extremely favorable for careful study. The Bay Furnace, near Marquette, has the honor of carrying "the broom" for the largest daily make. With a capacity of 1908 cubic feet it has, for months together, produced 29 tons of pig, graded at

By W. Laird

For years, the coal industry has been confronted with face ventilation problems, ignitions, dust, and their effect on productivity. To improve face ventilation, minimize face ignitions, and control dust in the face areas, studies have been conducted over the past 30 odd years by coal companies, federal government research programs and others. These studies included brattice curtains, water spray nozzles, water pressures, highly efficient water filtration systems, auxiliary fans, differ fans, various dust collection systems and the recently developed "Spray Fan" ventilation system. This system consists of spray banks strategically placed on continuous miners to ventilate immediate face area.

Jan 1, 1984

By Eugene Guccione

For at least 10 years, various industry people had warned about the alarming decline in the nation's oil and gas reserves. Then, in October 1973, the Organization of Petroleum Exporting Countries launched an oil embargo and sharply increased crude oil prices. Suddenly, everybody discovered the "energy crisis." In November 1973, former President Nixon advocated a Project Independence program so that ". . . by 1980 we shall be able to meet America's energy needs from America's own energy resources."

Jan 5, 1975

By John G. Reid

Subsequent to extensive laboratory testing, a pilot plant was constructed to further evaluate the process for high temperature copper cementation on iron in continuous operation. The plant was designed to produce 1 to 10 tons of copper a day depending on the copper concentration of the pregnant solution. The energy required to operate the plant was very low as virtually all the solution heating requirements were supplied by the exothermic cementation reaction. The results demonstrated that this, process has potential for commercial application with respect to operating considerations, and yields a copper product in excess of 95% copper at high reaction rates, low iron consumption, and at least 98% copper recovery from solution.

Jan 1, 1976

By G. G. Griswold, B. S. Morrow

The copper-bearing ores concentrated at the Anaconda plant of the Anaconda Copper Mining Go. are principally a mixture of copper and iron sulfides associated in a gangue consisting of quartz, lightly altered granite and feldspars, with sphalerite and galena and more rarely barite and hubnerite as accessory minerals. The predominant sulfide is pyrite. The copper minerals present are: chalcocite, bornite (erubescite), enargite, chalcopyrite, covellite, tetrahedrite and some tennantite. Normal concentrator practice removes a slime prior to ball-mill grinding. The deslimed ore is ground to approximately 10 per cent plus 65 mesh for flotation. Two selective flotation circuits are used, one for deslimed ore and one for slime. Microscopic studies of concentrator products disclose such an interlocking of copper minerals with pyrite that any material increase in concentrate grade entails additional grinding unless recovery is sacrificed to a considerable extent. During the latter part of 1931 and the early part of 1932 the problem of producing a high-grade concentrate (40 per cent Cu) with at least no

Jan 1, 1935

By S. C. Lee

An uncoupled thermoviscoelastic finite element formulation with an application to Underground Coal Conversion (UCC) is presented. An incremental solution procedure with an implicit time stepping scheme is used under the thermorheologically simple material (TSM) postulate. The presented formulation, for a homogeneous and isotropic medium, is employed in the simulation of the UCC post-burn phase. Temperature, displacement, stress, and failure responses under thermomechanical loading are predicted. The solutions for the selected field problem indicate potential roof collapse, stress relaxation, and modest surface subsidence with a progressive thermal and failure front. The corresponding thermoelastic responses with temperature- dependent elastic properties are also presented and compared with the thermoviscoelastic results.

Jan 1, 1984

By Hans Rausch, Kurt J. E. Meyer

A PELLETIZING plant in Germany must be able to process ores of different origins, having quite different characteristics. This requirement was of great importance for the development of the Lurgi process. For the production of green pellets a ma- chine would, therefore, have to be capable of dealing with all kinds of raw materials, and hardening must be done in a furnace, the temperature of which is adjustable to the different temperatures of the ores. Making Green Pellets To produce green pellets, experiments were made on a number of machines, such as drums, vacuum extrusion presses, and compacting machines. In 1949, Lurgi was the first to use pelletizing discs to produce iron ore pellets; until then this type of machine had been used exclusively in the cement industry.

Jan 3, 1958

By R. E. Hanneman, A. N. Mariano

In conjunction with the need for accurate volumetric data in the Fe-V system for subsequent use in calculating the high-pressure diagrams, room- and high-temperature X-ray diffraction measurements have been carried out. No previous measurements have been published on lattice parameters or volume changes associated with the a transformation for Fe-V alloys. The existing literature on lattice-parameter data for the a and s phases has been reviewed by pearson1 with considerable uncertainty indicated in the data. In order to obtain a good estimate of ?Va-? for thermodynamic calculations of the a D ?(bee D fee) phase stability, high-temperature vacuum X-ray diffraction measurements were made on an Fe-V alloy of 0.92 wt pet V. The term ?Va-? is the difference of molar volumes of the limiting solubilities of the a and y phases at any given temperature; these values can be calculated readily from the appropriate lattice-parameter data. The equipment used was a commercially available MRC (Materials Research Corp.) high-temperature X-ray camera which was fitted to a Norelco diffractometer

Jan 1, 1964

By A. B. Bowman

Banner Mining Co. became interested in this Tucson area early in 1950, and after several months of reconnaissance work, a lease-option purchase agreement was concluded on the Mineral Hill property which allowed time for considerable exploration and development work. Unwatering of the mine began in August 1951 after electric power lines were extended from nearby Tucson. The unwatering and rehabilitation work was done under a Defense Minerals Exploration Administration project and was completed in December 1952 after about 15 months of tedious work. The mine had been under water for more than 30 years with resulting cave-ins and timber deterioration. In some badly caved areas spiling was necessary to reopen the old drifts and crosscuts.

Nov 1, 1955

By L. C. Brown, E. B. Hawbolt

If a single-phase alloy is rapidly cooled such that insufficient time is available for an equilibrium transformation to occur, the high-temperature phase may be retained to room temperature or may undergo a massive or martensitic reaction. The massive or martensitic product develops without a composition change and usually has a crystal structure approximating an adjacent equilibrium phase. The characteristics of a massive transformation are intermediate between the equilibrium reaction in which long-

Jan 1, 1969

By Byron S. Gottfried

This paper describes a comprehensive computer program, developed under the joint sponsorship of the U.S. Environmental Protection Agency and the U.S. Bureau of Mines, that simulates the performance of coal preparation plants. A typical plant configuration may include several different washers, crushers, and screens as well as stream blenders and stream splitters, interconnected in whatever manner the user may specify. The program will predict the mass and energy yields of each unit and the properties of each flowstream (weight, ash, pyritic sulfur, total sulfur, and energy distributions), provided the feed properties and appropriate values for various control parameters are given. The program is used to assess washability characteristics of different coals, to determine the effectiveness of different plant operating conditions, and to compare the performance of various plant configurations. A brief description is given of the methods used to carry out the calculations for each type of unit. Results of some calculations are also presented. These results illustrate the versatility of the program for analyzing both simple and complex plant configurations. The paper concludes with a description of other accomplishments and future plans.

Jan 1, 1977