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By D. L. Paulson

The Bureau of Mines used 50-and 800-kva electric-arc furnaces to confirm the feasibility of producing ferronickel in electric-arc furnaces from pre-reduced concentrate from the Yugoslavian FENI project. The relationships were established among metallic iron concentrations (degrees of prereduction), ferronickel grades, and nickel recoveries. Smelting the concentrate containing 1.27 wt-pct nickel and metallic iron levels between 2 and 3 wt-pct, produced 15 to 20 pct ferronickel. Higher or lower metallic iron concentrations were compensated by adding oxide pellets or carbon to the electric-arc furnace charge. Over 90 pct of the contained nickel was recovered when up to 20 pct ferronickel was being produced. Data obtained while smelting 16 tons of prereduced concentrate in the 800-kva electric-arc furnace indicated ferronickel can be recovered at an energy consumption of 530 kwhr/ton of prereduced material.

Jan 1, 1977

By Charles E. Munroe

At the outset of the war the uncontrolled production and possession of explosives obviously became a serious menace to the safety of persons and property and the successful conduct of military opera- tions. Even in the years immediately preceding the entrance of the United States into the Great War explosives were employed in attempts to wreck munitions plants as at Eddystone, Pa., or to inter- rupt transportation and conveyance by demolition of munition-laden cars as at Black Tom Island, N. Y., or by attacks on ships, bridges, and viaducts. Outrages with explosives, such as that which Holt inflicted on the Senate reception room, United States Capitol, were not infrequent, and often caused serious loss of life and injury to persons as well as destruction of property. The regular manufacturers of explosives were keenly alive to this menace and early took such steps as lay within their power to meet it as is shown by the following letter:

Jan 1, 1921

By John W. Moore

The discovery of porphyries in petroleum by Treibs (17-19) is one of the most significant achievements relating to the origin of petroleum. The presence of these remnants of chlorophyll and hematin in petroleum has immediate practical interest in several aspects of the petroleum industry. Because of their interfacial activities and film-forming tendencies, the metal-porphyrin complexes may be expected to affect the wettability of petroleum-reservoir rock surfaces and influence the flow of fluids in these reservoirs. Also, studies of the relationship of trace elements and porphyrins in petroleum may be expected to yield valuable information on source beds and petroleum migration. Finally, the extreme stability of several metal-porphyrin complexes complicates removal of these metals from some petroleum stocks where they exert deleterious effects on processing and utilization. Metal-porphyrin complexes are commonly associated with the asphaltic residues of crude oils in which they occur (8, 9, 15). However, investigations in this and another laboratory (15) show that small amounts of these complexes often remain in partly refined petroleum products, such as thermally cracked distillates and deasphalted stocks.

Jan 1, 1957

By G. W. Birge

Carbonizing properties of the principal coalbeds of Elk, Clarion, Jefferson, Clearfield, and Centre Counties, Pa,, are described in this Bureau of Mines report, Twenty-six samples, representing the Upper Freeport, Lower Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, and Brookville beds, were carbonized by the Bureau of Mines--American Gas Association (BM-AM) method, and yields of products and physical properties of cokes were determined. Expansion or contraction of the majority of the samples was measured in the Bureau of Mines sole-heated oven. Chemical analyses, agglutinating values, and free-swelling indexes are given for all samples. In this area the coals generally are characterized by high sulfur and moderately high ash content, and their suitability for metallurgical use would depend largely upon satisfactory cleaning. The samples from Elk, Clarion, and Jefferson Counties were high-volatile A bituminous In rank, whereas, most samples from Clearfield County and all those from Centre County were of medium-volatile rank. Coals from Clarion County had dry, mineral- matter-free fixed-carbon contents ranging from 56.5 to 60.3 percent and were weakly coking. With the exception of two samples which contained excessive ash, the medium-volatile coals of Clearfield and Centre Counties were strongly coking and, as indicated by sole-oven expansion results, would require blending with lower rank coal to avoid oven damage.

Jan 1, 1963

By Jeffrey H. Welsh

This report presents a study on the use of computerized, continuous remote monitoring systems for fire and explosive atmosphere safety in underground coal mines. The effects of these systems on the safety level in mines are investigated, and the relationship between mine safety regulations and computerized, continuous, remote monitoring is analyzed.

Jan 1, 1982

By J. H. McClain

In the last 3 years' operation of the zirconium-production plant, zirconium metal has been employed to good advantage in many applications. The most frequent use has been in situations requiring resistance to attack by hydrochloric acid. In this service, it has been shown to be a serious competitor to Hastelloy. Zirconium also has excellent resistance to most other corrosives end could be considered for use as an all purpose metal. For example, this report cites 18 applications in hydrochloric acid, 4 applications in sulfuric acid, 5 applications in phthalic-hydrochloric acid, 3 applications in wet hydrogen chloride-chlorine atmospheres, and 2 applications in fused caustic.

Jan 1, 1954

By S. C. Termes

The Bureau of Mines conducted research on the flocculation of various minerals with insoluble cross-linked starch xanthate (ISX) to determine its potential as a beneficiation technique for low-grade, highly dissem-inated ores and for selective desliming. Covellite, chalcocite, pyrite, pyrrhotite, chalcopyrite, bornite, sphalerite, galena, and molybdenite fines flocculate with ISX. Floc formation, floc size, and settling rate are dependent on pH, with the pH dependence differing for each mineral. Quartz is not flocculated by ISX. Experiments to obtain selective flocculation of sulfides from quartz were attempted. Good selectivity was only obtained for the bornite-quartz system. postflocculation separations resulted in flocculated bornite in grades as high as 92 pet. Evidence is presented that the flocculation of many of the sulfide minerals with ISX may involve covalent bonding of the xanthate group to lattice metal site(s).

Jan 1, 1983

By M. S. Seehra, R. S. Pandurangi

"INTRODUCTION Silica and kaolin (a layer aluminosilicate) are among the major constituents of most coal mine dusts.' Whereas kaolin is cytotoxic in vitro but nonfibrogenic in vivo in humans and experimental animals,2-4 the cytotoxic and fibrogenic potential of silica is rather well established.5 Wallace and co-workers 6-8 have studied the cytotoxic potentials of both native and surface-modified silica and kaolin and inferred that retoxification is slow in the case of occluded silica vis-à-vis native silica. Recent epide¬miological studies indicate that silica concentration alone in a mine dust, as determined by transmission IR spec¬troscopy (TIRS), does not correlate well with the pro¬gression of coal workers' pneumoconiosis. 9 This obser¬vation has led to the suggestions that silica particles occluded by clays such as kaolin may not be fibrogenic. This proposal requires accurate estimations of kaolin, silica, and occluded silica. The current method of silica analysis in a mine dust sample employs TIRS of the 797- cm -1 band of silica, although its accuracy, as well as that of x-ray diffraction studies, is no better than 25 % , even in a laboratory-generated dust.° In this paper we have employed the techniques of diffuse reflectance spectros¬copy (DRS) and photoacoustic spectroscopy (PAS), in conjunction with an FT-IR spectrometer, for the quan¬titative determination of silica in laboratory-generated silica-kaolin mixtures.One of the main advantages of DRS and PAS is that, in these techniques, problems arising from sample prep¬aration of the KBr-based disks used in TIRS are avoided. There are, however, several other considerations (e.g., particle size effects and saturation phenomenon) which complicate the use of DRS and PAS for quantitative work. 10-25 In this paper, we have carried out a systematic comparison of the quantitative abilities of the two tech¬niques, as applied to the silica-kaolin mixtures, with par¬ticular attention to the saturation behavior of several bands with different absorption coefficients. In particular, we show that a weaker band for silica at 1875 cm-1 is suitable for quantitative purposes, and that quantitative accuracy is higher in DRS than in PAS. Details of this work are given below."

Mar 1, 1992

By R. W. Geehan

The Yellow Pine zinc-lead mine, situated about 3-1/2 miles northwest of Goodsprings, Clark County, Nev., was explored by core drilling during the fall of 1942 and the summer and fall of 1944 by the Bureau of Mines in cooperation with the Federal Geological Survey. The Yellow Pine district was located in 1855. The original claims covering the Yellow Pine mine were located in the following years: Rover, 1892; Hilo, 1897; Bybee, 1900; Radio and Como, 1906. The mine was operated by the Yellow Pine Mining Co. from 1906 to 1929. This company was dissolved in 1935. At a later date, S. E. Yount and the Security First National Bank of Los Angeles, Calif., acquired ownership of the mine. Since 1939, the mine has been operated in a small way by leasers. Production has been at least 175,000 tons averaging about 10 percent lead and 25 percent zinc, with a gross yield of $5,785,174. Virtually all ore produced by this mine consisted chiefly of oxidized zinc and lead minerals and came from long, pipelike shoots in the 100-foot thick Yellow Pine limestone. Ore shoots are sharply defined; elsewhere, the limestone is nearly barren. Numerous faults cut the mine into blocks. Ore is now mined in an open stope, but in the past, large tonnages wore mined in stopes by square-set methods. Ore produced recently was shipped direct to smelters unprocessed; in the past, it was milled by gravity and produced separate lead and zinc concentrates.

Jan 1, 1949

By H. B. Humphrey, F. E. Cash

From 1900 to 1929 , 1,005 or approximately 30 per cent of all fatalities in the coal mines of Alabama were caused by fires or explosions of gas and dust . In the 3 -year period from 1927 to 1929 only 15 men were killed by these causes , a reduction from 30 to 9 per cent of the total . Notwithstanding this marked improvement , which is due largely to the efforts made by the State inspection department , the operators , and the Bureau of Mines to stamp out this type of disaster , Alabama still has more than its share of such fatalities which can and should be prevented. A list of explosions from 1894 to 1929 compiled from information obtained through the records of the State Inspector's office , the reports of Engineers of the Bureau of Mines , and the operators , is given in Table

Oct 1, 1930

By Willard L. Hunter

The smelting of tin slags was undertaken at the Bureau of Mines Albany Metallurgy Research Center (AMRC) to produce crude columbium-tantalum ferro-alloy as a unit operation in the production of pure columbium and tantalum oxides or chlorides. Columbium and tantalum-rich alloy was prepared during short unrelated campaigns over a total period of 12 years. Tin slags from Malaya and the Congo (Geomines) were smelted. These slags were reduced by carbon in a small, single-phase, steel-making furnace} a larger three-phase, steelmaking furnace, and a three-phase, submerged-arc furnace, In all cases depleted slags were fluid and easily tapped from the furnace. However, unless diluted by iron additions, the metal product was a viscous, high-melting, heterogeneous mixture that could be removed from the furnace only by hand rabbling.

Jan 1, 1966

By E. G. Davis

Under a memorandum of agreement with Reynolds Metals Co., Richmond, VA, the Bureau of Mines studied the problem of corundum formation on refractory linings in aluminum recycling furnaces. A laboratory test was developed for evaluating refractories in contact with molten recycled aluminum and identifying the mechanism of corundum formation. A test apparatus was designed and constructed to evaluate the performance of refractory samples. Corundum mechanism formation studies indicated that corundum formed on refractories when there is metal penetration. Once corundum forms, it acts as a wick allowing the molten aluminum to move to the surface where it is oxidized, thus causing further growth of the corundum. Phosphoric acid treatment or a spinel mortar coating prevented corundum formation on the 70-and 90-pct-A1203 refractories.

Jan 1, 1988

By T. J. Williams

Researchers at the U.S. Bureau of Mines monitored rock mass response to mining of an experimental underhand longwall stope in Hecla Mining Co.'s LUCKY Friday Mine, Mullan, ID. This stope design, the Lucky Friday underhand longwall (LFUL), was proposed as a means of controlling rock bursting while also allowing increased mechanization of mining operations. Instruments were specifically manufactured to monitor three geomechanical factors (backfill performance, ramp stability, and rock mass response) that directly affect the success of stope design. Despite considerable difficulties with instrument installation and survival in the harsh mine environment, especially within the stope fill, sufficient information was collected to suggest that the LFUL method was successful in achieving project goals. This conclusion, in addition to favorable economic and operational evidence, led the mine to adopt the method throughout the mine. Indeed, this study and mining experience suggest that underhand longwall mining could be considered a feasible mining method for rock-burst-prone ground throughout the Coeur d'Alene District. Further Reports of Investigations (RI) in this series present in-depth analyses of the effects of backfill on rock bursting and calibration of a stope numerical model.

Jan 1, 2010

By Robert H. Townsend

The following paper discusses the mining, transportation, and crushing methods, with costs, at the San Andreas plant of the Calaveras Cement Co. It is one of a series, prepared for and published by the U. S. Bureau of Mine describing methods used in cement-rock quarries throughout the country. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total cost. It is recognized that publication of total costs mightin some instances cause embarrassment to individual producers as well as to the industry as a hole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost-tabulations shall ensue.

Jan 1, 1933

By H. D. Kline

Manganese ores have been mined in the Batesville district since 1849. Although not continuous over the intervening years, production had totaled approximately 432,000 tons of manganese ore and ferruginous manganese ore to the end of 1953. The ores occur in deposits, essentially low in manganese content, distributed over an east-west belt 24 miles long and 4 to 8 miles wide, the core of which is about 6 miles north of Batesville, Independence County. Although the reserves of high-grade ores in the district are comparatively small, the large deposits of subgrade ores and low-grade manganiferous material comprise potential sources of supply of manganese that may have increasing future importance. The manganese occurs as primary oxide and carbonate minerals in relatively flat-lying limestone and shale formations in which they were originally deposited and as oxides in residual clays resulting from decomposition of the shale and lime-stone. Most of the deposits underlie from a few to over a hundred feet of sedimentary chert, but many occur in the residual clays on exposed slopes of chert-covered hills.

Jan 1, 1956

By R. O. Dannenberg

A metallic displacement process, utilizing easily available steel wool or steel window screen, was devised and successfully used for the recovery of silver from waste photographic fixing solutions. Laboratory and prolonged commercial-scale testing established that the iron filament type unit will efficiently precipitate silver, as a high-grade sludge, from acidic waste photographic fixing solutions ranging in grade from less than 1 to over 10 grams of silver per liter. Data and design information are presented to facilitate the construction and operation of a practical unit of any desired size. A smelting process for recovering pure silver from precipitated sludge containing 27 to 80 percent silver was devised.

Jan 1, 1968

Develop geophysical techniques suitable for enhancing miner safety. Specifically, to use geophysical methods to detect hazardous conditions in a rock mass in deep underground mines as well as to assess the mechanical integrity and monitor changes of the rock.

Jan 1, 1997

By H. P. LeVan

Research was conducted to examine the feasibility of extracting manganese from Georgia umber ore by a three-stage continuous sulfuric acid-ferrous sulfate pickle liquor leaching process. A continuous cyclic process for treating the umber was operated successfully, using a synthetic solution simulating a ferrous sulfate fortified anolyte solution discharged from a manganese electrolytic cell as the leaching medium. Leaching efficiency based on removal of the manganese from the ore ranged from 83 to 89 percent for all systems tested.

Jan 1, 1965

By J. A. Cavallaro

To determine whether magnetite consumption could be reduced and salable coal production increased by using froth flotation units in series with magnetic separators, the Bureau of Mines conducted laboratory froth flotation tests on primary magnetic separator effluents obtained from three coal preparation plants. Tests were performed in a standard 500-gram-capacity laboratory batch flotation cell. Oleic acid and methylisobutyl carbinol were used as the collector and frother, respectively. Magnetite recovery was comparable to that expected from secondary magnetic separation, and salable float coal recoveries of 0,8 to 7.6 tons per hour were obtainable. The economics of the proposed technique appear to be sound.

Jan 1, 1966

By A. W. Ambrose

A few years ago, (March 3, 1915) Congress passed a law providing for the establishments of ten mining experiment stations under the supervision of the Bureau of Mines. In 1917 the Secretary of the Interior decided that one of these stations should be devoted to Petroleum, and in the early part of 1918, approved the establishment of the Petroleum Experiment Station at Bartlesville, Oklahoma, upon the condition that the city furnish the site for the buildings and guarantee $50,000. for the erection of the buildings. A building site of 5 acres and the necessary building fund was furnished by the Bartlesville Chamber of Commerce.The buildings consist of an administration and laboratory building, both of brick construction. The former is a two-story structure of eight rooms. A large room occupying over half of the main floor is devoted to the library, reception room, and clerical force. The remaining rooms comprise a drafting room and six offices occupied by the staff assigned to this station. The laboratory is a one-story brick building and contains a well-equipped chemical and physical laboratory, also a machine shop and mechanical laboratory. In addition to the main buildings there now are on the property an experimental refinery, a blue-print house, and a store house. These latter buildings are all of sheet-iron construction.

Oct 1, 1920