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By Francisco Cubillos, Jorge Menacho, Cesar Gomez, Juan Rodríguez

Mineral flotation is the most used process to selectively separate particles of one or more minerals of interest. The process uses natural or induced hydrophobicity to collect particles on the surface of rising bubbles through collisions and formation of bubble-particle aggregates. Flotation machines must keep particles in suspension and well distributed, while at the same time, disperse a mass of air into a population of small bubbles. The efficiency of the separation depends primarily on the characteristics of the bubble population generated in the machine and its distribution and flow throughout its volume. The formation and separation of bubble-particle aggregates create two zones, with strong interactions between them, and with markedly different hydrodynamics conditions. A model describing two-phase hydrodynamics of the continuous and dispersed phases (frother solutions and bubbles, respectively), moving along the whole unit, is proposed. Bubble populations are characterized at the formation stage including the effect of the presence of frothers. Flow through the aggregates formation zone, where bubbles move freely and are closely spherical, is modeled using drift-flux analysis. In the aggregates separation zone, bubbles initially pack maintaining a water layer thick enough to prevent capillary forces to affect their shape. As water drainage proceeds, bubbles deform, capillary channels form, and a network of channels with a diameter size distribution develops; channels become narrower (permeability is reduced) as the distance from the interface increases. Froth hydrodynamics is characterized using models originally developed to describe unsaturated flow through porous solid particle beds. Effects of hydrostatic pressure are considered.

Jan 1, 2014

By K. D’Elia, L. D. Ogrel, O. A. Malyshev, T. I. Yushina, I. M. Petrov

"The purpose of this research is to develop enhancements in the mineral processing by flotation methods of nonferrous ores. Currently, 180-190 million tons of ore are processed by flotation in Russia. The annual processing volume of copper-nickel and copper-zinc ores exceeds 20 million tons. In the total volume of processed ores by flotation, non-ferrous ores account for roughly 35% and ores of precious metals for another 15%. The total demand of flotation reagents in Russia in 2016 was estimated at 170,000 tons. Sulfur-based collectors used in the flotation of non-ferrous sulfide ores (typically, xanthates) do not always offer sufficiently high recovery of valuable components.It has been found that reagents like DMIPEC and DK-80 improve the recovery of metals into concentrates. To identify the reasons of that higher recovery, quantum chemical calculations of the mechanism and interaction forces of DMIPEC with non-ferrous sulfides were undertaken by determining the stabilization energy of the resulting chemical complexes. It has been shown that, in the interaction of DMIPEC and DK-80 with the surfaces of sulfide minerals, ethylene and acetylene bonds act as the reaction centers, and the formation of molecular p-complexes is the result of metal-cation interactions with the surface and the flotation reagents.In the flotation of non-ferrous ores, DMIPEC and DK-80 act as selective supplementary collectors with foaming properties, and at a flow rate of 3-35 g/ton, they reduce the flotation time, and increase copper recovery by up to 3.5%, zinc recovery by up to 12%, gold recovery by up to 8-10%, allowing to increase the recovery of valuable components by 1.5-12.0%, basically this kind of reagents nearly double the flotation rate, improve the grade of the concentrate, improve the stability of the flotation process parameters, and reduce the environmental impact of flotation plants."

Jan 1, 2018

By Peter Ay, Bodo Müller, Jens Markowski, Manfred Kanthak, Florian Logsch

"Presently the global commodity situation for non ferrous-, precious- and rare metals is characterized by a strong increase in consumption and a simultaneous shortage of materials derived from primary sources. So the use of secondary raw materials gains is important due to economic and ecological reasons. Non Ferrous-, precious- and rare earth metals were detected in household waste (Municipal solid waste, MSW) for years. In MSW-treatments plants NF-metals are actually mostly separated from dried fractions. The separation of these metals is carried out with the aim of removing particles which disrupt further processing. A selective enrichment of individual non-ferrous metals has not been carried out previously. The separated fractions contain mixtures of Al, Cu, Zn, Pb, Sn, alloys, precious metals (e. g. Au, Ag, Pt) and rare metals (Ga, In, Nd etc.) along with considerable amounts of contaminations. The R&D project "NE-Rec" selectively processes the coarsely separated non-ferrous-metal-conglomerates increasing the concentration of targeted metals. Metals and metal mixtures are concentrated by sorting steps and the impurities are discharged from the process. Still contaminated precious metals are then subjected to a wet-chemical treatment. So metals can be specifically brought into solution or can be precipitated to separate unwanted components (inerts, polymers, foreign metals). Further the relevant metals will be concentrated by thermal-metallurgical processes. The technology, developed in the R&D project, enables identification, separation and processing of non-ferrous metals, precious metals and REM in household waste and transfers them into further processable individual fractions."

Jan 1, 2014

In this paper, the recovery of copper minerals and molybdenite in the rougher/scavenger banks of two separate mineral processing plants is compared with recovery in laboratory (batch) cells. A number of metallurgical surveys were conducted in two plants treating porphyry copper and molyb-denum ore. Batch flotation tests were performed on plant conditioned flotation feed slurry, in parallel with the plant metallurgical surveys. The effect of flotation feed density on recovery of copper minerals and molybdenite in the plant and batch laboratory cells was investigated. Changes in flotation pulp density had little effect on copper mineral recovery, in both plant and laboratory cells. The ultimate recovery for molybdenite, on the contrary, increased considerably when the pulp density was reduced, both at plant and laboratory scale. Recovery of copper minerals in the plant and laboratory cells was comparable, while molybdenite recovery in laboratory flotation cells was 3%~13% higher than in plant. It is hypothesised that the flotation rate of molybdenite is sensitive to cell hydrodynamic conditions (i.e. local turbulent energy dissipation) more than the flotation rate of copper. The flotation behaviour of molybdenite particles is likely to be predominantly controlled by bubble-particle collision frequency, which is enhanced in high local turbulent energy dissipation environment. For chalcopyrite, the flotation recovery is mostly determined by attachment and stability efficiencies. An increase in local turbulent energy dissipation, while increasing collision efficiency, may negatively impact on attachment and stability efficiencies. The outcomes may have a considerable impact on increasing molybdenite recovery from porphyry ores.

Jan 1, 2014

By B. K. Gorain

Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine. Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects. The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems Keywords: mineral processing, flotation, flotation problem solving, flotation optimization, plant design, innovation

Sep 1, 2012

By Victor Avdokhin, Ivan Kovlekov

"Studies of the process of concentration of gold-containing sands and technogenic resources show that the main reason of gold losses is misbalance between size of gold particles and degree of roughness of mineral bed. This results in free circulation of small gold particles in pores with following washing off the particles from the bed by turbulent flows.We elaborated design of magnetic sluice, intended for improving efficiency of recovering fine gold by optimizing magnetic field of a magnetic system on the base of forming catching coat from magnetic mineralsThe magnetic sluice includes trough-shaped body from magnetic-conducting material. On the bottom of the trough, magnets are placed, and opposite poles of the magnets are oriented outwards. Thickness of the bottom is determined to be sufficient for locking magnetic lines of force of the magnets on each other. The magnets of rectangular plate shape are placed on the rough bottom, covering the whole surface or with spare areas; the magnets are placed across the trough with alteration of rows with the same pole orientation.Catching coat is formed of natural magnetic and weak-magnetic placer minerals in field of magnetic system of the sluice. Magnetic minerals, placing along magnetic lines of force, form rough coat of fluffy structure. Size of the magnetic particles is chosen taking into account expected size of gold particles, which are to be fixed on the rough coat or between the magnetic particles. Changing coarseness of particles of mineral bed allows to regulate selectivity of recovering heavy minerals.Forming artificial fleece from magnetic minerals of initial sand, increasing capacity of the bed and relative hydraulic proportionality of mineral particles of the bed provide for the most effective recovery of fine gold."

Jan 1, 2003

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By Yuhua Wang, Huilan Yang, Yanqing Jiang, Dongfang Lu

"Generally, the concentration of bauxite flotation tailings is around 10%, a large amount of water in tailings needed to be recycled in the flotation process. Sedimentation and dewatering properties of tailings were investigated under different conditions. Surface high negative charges on mineral particles are the key factor to destroy the settlement of tailings when the pulp pH is around 8.9. Hence, the modification of pulp pH around 7 is necessary to the diminution of the repulsive force between mineral particles and then the acceleration of sedimentation of tailings. Anionic polyacrylamine with molecular weight of 14 million is the best flocculant for the settlement of tailings in all tested polyacrylamines. P-toluene sulfonic acid shows better properties than hydrochloric acid for pulp pH adjustment when anionic polyacrylamine with molecular weight of 14 million is used as flocculant. Although the flotation of diaspore is depressed in the presence of polyacrylamine using sodium oleate as collector, but the recycling water traded by the combination of ployacrylamine and p-touenesulfonic acid does not show the depression effects on the flotation of bauxite ore. The lower residual content of polyacrylamine in recycling water treated by the combination of ployacrylamine and p-touene sulfonic acid plays an important role. INTRODUCTION Generally, the waste water generated from mineral processing plant is usually treated by sedimentation, oxidization, electrodialysis, ions exchange, active carbon adsorption and flotation technology, and the treated water is also used again in the industrial process. Flotation was adopted widely to improve the quality of bauxite from low grade diasporic bauxite in China. For flotation, the grinding fineness of bauxite is over 90% -0.074 mm, sodium carbonate and sodium hexametaphosphate were used as regulators, so the tailings pulp is very difficult to settle and be dewatered (Y. Wang et al., 2004; Y. H. Wang et al., 2007; Wang Yu-hua et al., 2008; Wang Yuhua et al., 2011). The water recycling of bauxite tailings are becoming the highlight for the industrial application of the flotation process for bauxite ore. Researchers in China shift their attentions onto this topic."

Jan 1, 2018

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Automatic identification and characterisation of mineral raw materials and beneficiated products are of major importance in mineral processing. However, minerals show great variety in their composition and physical and chemical properties. Industrial minerals may contain the same elements in about the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. By means of EBSD, diagnostic mineral information can be achieved if indexible patterns are provided.Until now EBSD has not been used frequently on geological samples for mineral and micro structure discrimination.The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques."

Jan 1, 2003

By Ray Everson, Henry Kasaini

"We carried out adsorption experiments in chloride media to study the adsorption characteristics of Pd (II) anions on the surface of activated carbon. Throughout the experiments, we used commercial activated carbon pellets (0.8 Norit). The adsorption process was interpreted by using the ionisation and adsorption model. This implies that palladium anions were adsorbed physically on a protonated surface of activated carbon either as anionic complex species (PdCl4 -2) or aqua chloro-complex species [PdCl3(H2O)-] in acidic media. Furthermore, we established that adsorption of Pd (II) species was reversible at high chloride [Cl-1] concentration. The maximum adsorption capacity (Qsat) of Pd (II) anions averaged 27 mg/g. The Toth adsorption isotherms fairly predicted the equilibrium adsorption of Pd (II) species and the associated surface coverage.The effect of temperature and acid strength of the feed solution on the adsorption of Pd (II) ions were quantified. The adsorption kinetics was limited by external mass transfer since the effect of pore diffusion on the overall rate constant was negligibly small. A pseudo first-order kinetics model was used to describe the adsorption kinetics."

Jan 1, 2003

By E. V. Zelinskaya

"Mineral and industrial raw material mining and preparation make a negative impact on the environment. The main types of impact are the land resources gathering, soil and water balance disturbance, surface-water, underground space and atmospheric air pollution, as well as the vast amount of solid and liquid waste production. Considerable attention in recent decades has been given to waste recycling. The task is to maximize the use of both newly formed and accumulated solid and liquid wastes. The mining and mining and smelting enterprises industrial waters are a very promising source of secondary hydromineralic raw materials. They have high concentrations of not only calcium, sodium, but also, for example, lithium, rubidium, heavy non-ferrous metals. In general, unfortunately, we have to state that today there is no wide practice of extracting valuable components from waste enrichment, as well as processing of man-made waters to extract metals from them. The quantity of extracted components from underground, and furthermore passing waters, is insignificant. At the same time there is a tendency to increased demand for rare metals: Sr, B, Br, I. This is explained by their wide use in many industries. For example, the consumption of lithium products is steadily increasing. The obtained results showed that in the liquid phase in connection with high salt content and a significant difference in the macro- and microcomponents contents, conditions are initially created for the microcomponents selective isolation possibility. The identified conditions realization is most possible in such technological processes as cryotechnology, sorption and ion flotation. There is an urgent need to expand research in this direction and to recognize as a publicly important task the mining and industrial waste processing full-scale introduction into the practice of operating mining and processing enterprises and iron and steel companies.INTRODUCTION Mineral and industrial raw material mining and preparation make a negative impact on the environment. The main types of impact are the land resources gathering, soil and water balance disturbance, surface-water, underground space and atmospheric air pollution, as well as the vast amount of solid and liquid waste production."

Jan 1, 2018

By H. X. Yan, J. X. Zhang, F. S. Niu

"The analysis on influencing factors of hydraulic conditions in fine hematite flocculation, such as stirring speed, stirring time and axial distance of particle size and fractal dimension of floc was investigated. Furthermore, response surface methodology(RSM) has been applied according to the Box-Benhnken center-united experimental design principle to optimize parameters of hydraulic conditions as a response index to indicate the fractal dimension of floc. The results show that when the agitation speed is 900r/min, the axial distance is 2.0cm, and the stirring time is 3.0min, the particle size reaches the maximum value of 35.44µm and the fractal dimension is 1.6594. The interaction between the axial distance and the stirring speed is highly significant, but the interaction with the stirring time is not obvious. The experimental data and model predications match well, which indicates that the established model has high accuracy and practicability. INTRODUCTION With the exhaustion of iron ore resources that are easy to be mined and the vigorous demand for iron and steel, the exploitation and utilization of fine-grained embedded iron ore resources have drawn attention from the industry and the government [1~2]. Flocculation flotation is one of the effective methods for separation and recovery of fine granular minerals. In 1975, the method was first applied and succeeded in Tilden Concentrator, USA. Flocculation and desliming became the key technology of the Tilden to raise its annual treatment capacity from 4 million tons to 8 million tons at that time [3 ~ 4]. In 2008, the selective flocculation and desliming-reverse flotation technology was successfully used to treat 2.8 million tons of Qidong iron ore. Under the conditions of 28.36% raw iron grade and 98% grinding fineness -0.038 mm, the ideal index of 62.5% iron concentrate grade and 68% recovery was obtained [5]. Dr Kitchenner of the Royal College of Mining and the Ore Processing Research Group of Wallenstein Laboratory first proposed the use of flocculation to separate minerals. After that, many scholars conducted a great deal of theoretical and practical researches, but mostly they focused on chemical theories, mathematical models and selectivity differences in the flocculation process, while the research on the influence of the pulp flow state on the separation effect in the flocculation process started later [6~9]. The results show that the motion of the agitated flow field has a significant influence on the formation of flocs. The fluid morphology will change with the change of hydraulic conditions. The change of fluid morphology will not only affect the movement behavior of particles, but also change the action of chemical agents on the surface of mineral particles[10~12]."

Jan 1, 2018

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

By Kumar Ranjan, Kumari A. V. Asha, G. E. Sreedhar, Banerjee R. Raja, M. Narasimha, R. Shivakumar

In this paper, numerical simulation of magnetite, medium segregation and coal partitioning have been made in a 350 mm diameter cyclone. An attempt is made to assess the nature of impairment in efficiency in relation to the increasing amount of near gravity materials in coal. The CFD model approaches the Algebraic Mixture (ASM) model with the granular option and Reynolds stress model (RSM) to resolve the air core and turbulent mixing of the medium and coal particles. The partition characteristics of the DMC were modelled using both Lagrangian & Eulerian particle tracking for particles ranging in size from 0.5 to 8 mm and in density from 1200 to 2000 kg.m-3. Lagrangian frame work based Discrete Phase model used to simulate the coal particle trajectories inside the DMC and attempted to understand the residence time of different size and density coal particles. It was observed that coal particles having density near to separation-density (having fifty percent of probability to under flow and overflow) are exhibiting increased residence time than any density particles. As expected the smaller size coal particles shows higher residence time than the coarse coal particles. CFD simulations on effect of NGM mass fraction are simulated and analyzed using ASM model including for coal and magnetite. Coal particles with high NGM content show significant effect in misplacement of coal particles towards wrong products at all relative densities. The residence time of the particles increases because of its increased interaction with near dense particles. The effect of NGM fraction on overall cyclone performance as well as detailed flow assessment in terms of residence time distribution, NGM particle concentration profiles with respect to LZVV is presented.

Jan 1, 2018

By Venkataramana Runkana, Aditya Pareek, Vishnu Masampally, Nagaravi Kumar Varma Nadimpalli

"Recovery and grade of the ore produced are two important metrics, which define the profitability of a mineral processing plant. Achieving high grade and high recovery at the same time in a mineral processing plant is difficult due to conflicting nature of the two objectives. To explore the operability limits of the plant operations and find the set of operating conditions that can help achieve the best possible recovery and grade, there is a need to solve a multi-objective optimization (MOO) problem. Past research focused on building a plant-wide simulation model or on optimization of individual units or a part of a mineral processing plant like grinding circuit, crushing circuit, etc. However, it is necessary to consider optimization of the complete plant in order to optimize the plant performance. Here, we have formulated the mineral processing plant performance optimization as a MOO problem. We have applied machine-learning algorithms such as random forest to build models to predict the recovery and grade of the ore. A non-dominated sorting-based multi-objective evolutionary algorithm called NSGA-II (Non-dominated Sorting Genetic Algorithm II) was employed to solve the MOO problem. Since the number of parameters that influence recovery and grade are quite large, we have applied machine-learning algorithms for feature selection or identification of key process variables. Pareto optimal conditions were determined for manipulated variables like grinding mill throughput, speed ratio at SAG mill, speed of centrifugal pump, water addition at different locations etc. The results obtained are useful in identifying the operability of a mineral processing plant to achieve the optimum grade and recovery for a given feed grade and the processing circuit. INTRODUCTION Copper is majorly mined or extracted as copper sulfides from large open pit mines in porphyry copper deposits. Among all the available ores, sulfides are the most commercial ores, especially chalcopyrite (Greenwood and Alan, 1997). Copper grade in these ores generally lies between 0.4 to 1.0%. In order to perform smelting operation, the grade of copper has to be improved to around 30% (Biswas et al. 2013). This targeted copper grade is achieved through two stages of mineral processing. Firstly, the copper in the ore has to be liberated by crushing the mineral rock. Secondly, the liberated copper in the crushed ore is then physically separated from other minerals like nickel by froth flotation techniques."

Jan 1, 2018

In looking to the future of mineral processing the focus is typically on improved processing units. Basically it is a search for an elusive wonder machine that could revolutionise the economy of mining: the sorter that strips 50% of the ore with only a few % loss of value; the comminution device that uses 5% of the energy while producing fully liberated particles; or the recovery device capable of producing a 99% recovery at 99% grade. These aspirations are propounded against a reality backdrop of sorters rusting in back yards, mill throughputs below design and varying by 30%, cyclones flaring and cut-sizes fluctuating, mediocre recoveries and soaring processing costs. This disconnect between aspiration and reality appears, to these authors at least, to be a mighty chasm. Moreover, it remains one over which we are expected to magically leap rather than methodically bridge. Indeed one may be forgiven for thinking that should such a wonder machine come along, taking advantage of it would be highly improbable. Questions would inevitably emerge on how to feed the correct material, how to cope with the wide variability of feeds, how to control such advanced equipment and how to handle the new product from such a machine. It is likely these questions might lie unanswered, or more regrettably, unasked. It is generally accepted that as an industry we are exceedingly unlikely to teleport from the current status quo to an entirely new reality in a single flash. It is our thesis that the probability of these magical machines materialising is remote, and even if they miraculously appeared, we simply wouldn?t know what to do with them. Rather, it is our contention, that a step change will only arise through a staircase rather than from a single giant leap. We should focus on building those steps and linking them together into a firm structure ? a workable mineral processing circuit. This paper addresses the alternative of a coherent set of modest but significant improvements, integrated to produce the step change we desire: essentially, a reduction of processing energy to below 40%, which we believe is achievable without recourse to any mystical machines. A key underlying capability to designing these dramatically improved processes, is the weaving of independent process models into a coherent circuit simulation, in order to design the new generation of mineral processing circuits. Keywords: step change, circuit design, circuit simulation, energy reduction

Sep 1, 2012

By N. Acarkan

Beneficiation of the pyrite concentrate of the Kastomonu-Küre (Northern Turkey) copper ore seems to be attractive due to its high Cu, Co, and Zn contents. Pyrite concentrate were used in the experimental studies. Cu, Co, and Zn were recovered from the concentrate by the sulphatizing roasting, leaching and the precipitation using H2S. Sulphatizing roasting experiments were carried out in a rotary furnace and the optimal roasting conditions were found to be at 650°C roasting temperature and 3.0 h roasting period and addition of Na2SO4 of 3 % for the concentrate containing 0.58% Cu, 0.22% Co, and 0.04% Zn. Then, the roasted product was repeatedly leached with 10 g/L H2SO4 solution. Optimal conditions were found to be 60 oC leaching temperature, 2 h leaching period, and 30% pulp density. Leaching efficiencies for Cu and Co were over 99 %. The valuable metals in the pregnant solution were selectively precipitated by H2S as sulfides. Selective precipitation of Cu, Zn, Co was achieved by adjusting the pH and the temperature of the leach solution. Final metal recoveries of 99.20% Cu, 99.40% Co, and 95.60% Zn were attained. The precipitated sulphides are marketable products. Roasting gases with their 15% SO2 content are suitable for the production of H2SO4 and the leach residues can be integrated with the iron ore processing plant as they contain 57.50 % Fe, 17.70% gangue (SiO2, CaO, etc.), 0.04% S, and 0.06% non-ferrous metals.

Jan 1, 2014

By J. Bhattacharya

In many different ways industrial raw materials resources industry as a whole has accepted the principles of sustainable development and has made a commitment to move toward this goal. The critical question now is ?how?? While many companies have adopted policies and are implementing community relations programs, sustainability is not always ?lived? throughout the organization. While traditional programs and commitment from the top are critical, employees within all functional areas can advance sustainability. Individuals can make difference at all organizational levels, and it is this collective action that is so critical for enhanced financial performance as well as the preservation of the industry. Keywords: value chains, sustainability, legislation, auditing process

Sep 1, 2012

By M. Abdollahy

Solvent extraction of gallium from Bayer solution of Jajarm Alumina plant was investigated us-ing Kelex100 as extractant. Taguchi experimental design method was used in order to optimize the separation factor of Ga and Al. Optimum conditions were obtained as follows: Temperatuer: 65°C, volume ratio of aqueous phase to organic phase: 3.0:1.0, process time: 60min and organic phase containing 15vol.% Kelex100, 5vol.% isodecanol in kerosene. In this conditions, 74% gallium and 0.3% aluminum was extracted and separation factor was obtained 828.63.

Jan 1, 2014

By A. N. Zagorodnyaya, T. N. Bukurov, Z. S. Abisheva, A. S. Sharipova

"The paper describes the results of stripping of copper production dusts by leaching with aqueous soda, nitric acid solutions and recovery from solutions resulting in the production of lead sulphate, tribasic lead sulfate (TBLS), ammonium perrhenate, zinc, copper-cadmium cake.The combination of two stripping operations under chosen optimal conditions allows the recovery of 98% rhenium, 82% lead, 92 % copper, and 96% zinc and cadmium each. The major amount of rhenium (~ 80%) is recovered at the carbonization stage, and other metals - at the nitric acid leaching stage.Lead sulfate was precipitated by mixing solutions resulting from carbonization and leaching. Tribasic lead sulfate was produced by dissolving lead sulfate in sodium hydroxide solutions. Rhenium was recovered from mother liquor resulting from lead sulfate precipitation by liquid-liquid extraction and zinc was recovered from raffinates. Trialkylamine (TAA) was used as an extractant for rhenium recovery and di-2- ethylhexylphosphoric acid was used for zinc recovery. Optimal liquid-liquid extraction parameters have been defined allowing the recovery of 96% rhenium in crude ammonium perrhenate and 94% zinc in sulfuric acid solution. Based on the experimental data, the flowchart for dust processing to produce salable products - lead, rhenium, zinc salts has been suggested."

Jan 1, 2003