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By M. X. Jia

This paper discusses two mineralogy characteristics that may affect the flotation of sulfide ore. The first one, process mineralogy study on a Cu-Ni sulfide ore shows that valleriite and tochilinite are incline to form on chalcopyrite, pyrrhotite and serpentine surface, and the further guess is that the formation of valleriite and tochilinite may also causes the serpentine transform to talc, so the serpentine surface is a phase of talc or a transition phase from serpentine to talc and this enhances the flotability of the gangue minerals. The second discussion on the flotation behavior of the sulfide minerals from the point of view of the mineral semiconductor character.

Jan 1, 2014

By S. Patra, R. Venugopal

"The quality of pellets produced is affected by quality anssastd quantity of green pellets, amount of addition of binders, type of binders added, amount of moisture added along with the other variables like rotation, inclination and fineness of feed. The green pellet quality depends upon chemistry, mineralogy and granulometry of fines used for pellet making, the feed size, its moisture content and porosity. During firing of green pellets ingredients present within reacts to form different phases and microstructure. So in turn physical and metallurgical properties of pellets are influenced by amount and type of binder and flux addition, induration time and temperature. During iron making process, the metallurgical properties of fired pellets are decided by the type and amount of these phases and their chemistry. Green pelletizing and induration studies have been already carried out with hematite ore fines. Indian iron ores of high alumina content showing different pelletizing characters, these studies can’t be directly interpreted. The main objective of proposed research work is to understand the green pelletizing process and determine the water bentonite interaction at different levels. Detailed investigation on swelling behavior of bentonite and microstructure of the green pellets of iron ore fines from SAIL captive iron ore fines from the Barsua in the state of Odisha. To convert these ore fines into pellets, the key raw material, additives and process variables that influence the pellet quality needs to be identified.INTRODUCTION Pelletization is the unit operation of agglomerating iron bearing fines (generally below 150µ with 65-80% passing 40µ) by tumbling in horizontal rotating drums or inclined discs, (Sivrikaya and Arol, 2013; Bhuiyan et al., 2011; Forsmo et al., 2006; Sastry et al., 2003) and the pellets are approximately spherical lumps formed by this process in presence of water and binder, on subsequent induration at 1300°c (Sivrikaya and Arol, 2014; Sivrikaya and Arol, 2013; Sivrikaya and Arol, 2012; Sivrikaya and Arol, 2010; Sastry et al., 2003; Kawatra and Ripke, 2003; Iveson, 2001a; Iveson, 2001b)."

Jan 1, 2018

By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By W. Y. Gao

Diaojuntai Concentrator adopts a process of low intensity and high intensity magnetic separation and anionic reverse flotation, with all the concentrate from magnetic separation being treated by re-verse flotation to obtain a qualified final concentrate. The high reagent cost and energy consumption of the reverse flotation have led to a high concentrate cost. The test research on reducing the feed to the reverse flotation was therefore carried out. Based on the study of the properties of the ore sample, the concentrate of low intensity magnetic separation was screened at 0.076 mm and the undersize fraction was concentrated by concentrator with gravity and magnetic field. The results show that a qualified concentrate can be obtained at various rising current rate, pulsating current and power-on style, with the operation rate over 85%. The extraction of some part of qualified concentrate from the concentrate of low intensity magnetic separation by magnetic separation can reduce the feed to the reverse flotation by about 35% so as to reduce the production cost of concentrate.

Jan 1, 2014

By G. Venkateswara Rao

The multi-gravity separator (MGS) is a novel piece of equipment for the separation of fine and ultra-fine minerals. However, the published literature does not demonstrate its use in the separation of Iron ore fines. Therefore, an attempt was made to study the effects of different process variables on the performance of an MGS for the beneficiation of Iron ore fines. The results obtained from this study revealed that among the parameters studied, drum rotation, amount of wash water and angle of inclination play dominating roles in controlling the yield and grade of the Iron ore. The majority of the newly developed Multi gravity concentrators have tremendous potentials for various applications. Therefore, the performance evaluation of these concentrators treating various minerals, coals, heavy metal recovery from tailing dams, etc., have become an active research topic. Several attempts have also been made to develop appropriate mathematical models of individual concentrators. Despite all these efforts, these concentrators have yet to find the widespread applications they deserve. The ?as received? sample assayed 40.80% Fe, 40.90% SiO2,0.24% Al2O3and 0.20 % LOI and all other trace elements within the specified range. The current paper deals with the Mineralogical studies, characterization and process amenability studies of Sub grade Iron ore from Deposit No. 5, Bacheli complex of Bailadila using Multi Gravity Separator (MGS).

Sep 1, 2012

By Axel Pankewitz, Andrew Smith, Mathias Stender, Christian Behrens

"Particle size measurement is one of the most important factors in obtaining peak performance of the mineral processing plant in order to ensure efficient milling and flotation circuit operation. Off-line particle distribution analysis technologies only allow an infrequent check of the ore slurry size and hence do not allow for timely process monitoring or intervention. Most existing on-line particle size analysers suffer from a variety of disabilities such as poor statistics, non-representative sampling or mechanically complex setup. This paper will describe an Ultrasonic Extinction based method which overcomes many limitations of existing online analysers and has proven its performance for mineral applications over many years. Installation examples will be given. Since new technologies usually raise e questions about comparability and agreement to common particle size analytical methods e.g. sieving or laser diffraction analysis, extensive studies were performed comparing these different technologies to quantify the quality of results as well as its mathematical robustness."

Jan 1, 2014

By Agnieszka Surowiak, Tomasz Niedoba

The paper presents a way of determining relations between ash content in coal, particle size and particle density by means of regression, multidimensional Morgenstern distribution functions and kernel approximation. The three-dimensional random vector (D, ?, ?), where D is a random variable describing particle size, ? - random variable describing particle density and ? - random variable describing ash content, where function ?=?(d, ?) is obtained by means of regressive function. The multidimensional Morgenstern distribution functions and kernel estimators with the use of Gauss function were applied to approximate the functions f(d, ?, ?) and f1(d, ?). This approach is a new way of multidimensional description of grained materials such as coal and it also allows to evaluate material features more properly than the classical statistical approach. The results were verified statistically.

Jan 1, 2014

By G. Demi, G. Belardi, N. Shehu, S. Cico

The physico-chemical interaction between minerals such as olivine, chromite and serpentine and the ions most commonly present in solution, like Ca and Mg and flotation reagents such as EDTA and oleic acid was investigated. The study was conducted via release tests, electrophoretic measurements and microflotation of selected minerals coming from the Kukes deposit (Albania). The results were confirmed by means of beneficiation tests on various types of ores, from the Kukes (Kalimash), from Bulquiza area and from the Rizo deposit (Greece). It has been demonstrated that when Na-K Oleate is used as collector chromite, olivine and serpentine can be separated at pH = 2.5 and/or 5.5 employing EDTA (EthyleneDiamineTetraAcetate) on previously deslimed material. This approach ensures flotation concentrates with a Cr2O3 content about 50%, at a recovery in excess of 65%.

Jan 1, 2003

This article takes the OMRON C200HE PLC for example introducing its application in mica-paper production equipment, including style selection, address assignment of I/O point, and programming for different function. In the transformation process of simulated data and digit data, the corresponding relations between two data and so on are also discussed.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, H. Abedini

Vertical ring and Pulsating Wet High Intensity Magnetic Separator (VP-WHIMS) is widely used for week magnetic mineral beneficiation or ferrous impurity removal from non-metallic minerals. Because of the complexity of this machine, mathematical modelling of its process is complicated and time consuming. In this paper, artificial neural network (ANN) and response surface methodology (RSM) were applied to evaluate the VP-WHIMS performance and optimize its main operating parameters in beneficiating of the Chadormalu hematite sample. The operational parameters of this magnetic separator are considered as: magnetic field intensity (2500-8500 gauss), pulsating frequency (20-100 %max), ring rotation speed (0.6-4.6 r/min) and slurry concentration (15-35 w/w %). Concentrate grade and recoveries (weight and Fe) are monitored as responses. Centre composite design (CCD) was used for experimental study. Four process variables were set using small CCD. Eight star points (a=±1), eight axial points (a=±2) and five replicates at the centre point (a=0) were chosen as experimental points. In ANN system, the best network topology was obtained as (4-5-3). The weights connection and biases were obtained using batch back propagation (BBP) method for 21 experimental data points. The results indicate that ANN

Jan 1, 2014

By Chenyang Zhang, Zhigang Yin, Jianyong He, Yuehua Hu

"A lot of floatation reagents (collectors, inhibitors and regulators) for the beneficiation of copper ores have been well developed in the past century. However, it is still unclear about the micro interaction mechanism of these flotation reagents with copper ores. In this paper, the interaction mechanism of these flotation reagents with the copper atom on chalcopyrite has been systematically investigated by first principle DFT (density functional theory) calculations. Thirty-four specific common functional groups linked with the same hydrocarbon chain (ethyl) are optimized at a B3LYP/def2-TZVP level, the solvation effect was included with the SMD solvation model. The analysis of the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO) and nature bond orbital (NBO) charge of these reagents reveals their potential applications to other types of copper-bearing mineral. Further investigation of the thermodynamics calculations gives more reliable data to screen collectors or inhibitors for copper-bearing mineral. The flotation results from carefully reviewed literatures are in good agreement with the calculation results. This work might also shed new light on the development and discovery of highly efficient and selective flotation reagents with low cost based on the computational methods.INTRODUCTION Froth flotation,(Shean & Cilliers, 2011) a mineral processing approach, is applied to efficiently enrich valuable minerals from the mixture, which is achieved according to the dictinctive surface properties of minerals. In the past century, researchers have develped an aboundant of flotation reagents by extraction or synthetize, and many carefully selected reagents might die in the bench tests or the pilot tests before the pratice.(Bulatovic & SrdjanM, 2007) Generally, it involves a lot of cost and tedious works by conducting flotation tests to screen flotation reagents. Flotation reagents have been boomed robustly with the developing of the organic synthesis.(Liu, Yang, & Zhong, 2017) Reseachers found the specific properties of a reagent are determined by its functional groups and the length of the hydrocarbon, where the functional group is assigned as the adsorption site to adsorb onto mineral surfaces and the hydrocarbon chain is called as a hydrophobic group."

Jan 1, 2018

By E. Hulthén

Crushing plants are widely used around the world as a pre-processing step in the mineral and mining industries and as standalone processing plants in the aggregates industry. Despite automation and different advanced model predictive control, a lot of the process is still managed by operators. The operators affect a lot of the performance. The numbers of the improvement they can achieve are at least as big as the advanced control algorithms?, today. Therefore, it is also important to train the operators so they know how to behave in different situations. Models for crushers and other production units have been developed during the years and the latest add is the different units? dynamic behavior being brought in, which gives the crushing plants dynamic time dependant performance. This can be used as a simulator for operators training. By connecting a Human Machine Interface (HMI) to a dynamic simulator with the models incorporated, a training environment for operators can be achieved. In this paper, a dynamic crushing plant simulator implemented in MATLAB/SIMULINK has been connected to an HMI via a PLC. The HMI is placed in a control room at the university and complemented with monitors showing sequences from the process connected to the simulations, thus creating a realistic control room for training. In the created training environment, the operators can be trained under realistic conditions. Simple training scenarios and how they could be simulated are discussed. Apart from the increased level of knowledge and experience among the operators, the time is an important factor. While a real crushing plant is still being built, the operators to be can already be trained, saving a lot of the commissioning time. Keywords: crushing, cone crusher, simulator, control room, operator, training

Sep 1, 2012

By A. I. A. Salama

In this paper, the problem of sedimentation and consolidation of poly-disperse suspensions is considered. The solid particles are assumed to be of different densities. If the sediment solids stresses are dropped out of the system equations and using the Richardson and Zaki hindered settling model, it has been found that in the limit, i.e., as time approaches infinity, the fluid is completely displaced to the top of the sediment zone. Furthermore, the species segregate completely with the heavier and coarser particles at the bottom of the sediment and the lighter and finer particles at the top of the sediment. Practical observations do not support these behaviors and physical-ly such behaviors do not exist; consequently, results of this kind in the literature are unrealistic. Here, a mathematical structure of the poly-disperse sedimentation and consolidation problem has been proposed. In this case the compaction zone species solids stresses are introduced in the momentum balance equations of the system. The species solid stresses in the sediment are constrained so that the system equations are consistent, i.e., sedimentation and consolidation of two or more identical species should behave as a mono-disperse system. Such a condition has not been recognized and imposed in some of the studies in the literature, which has led to unreliable results. Two practical forms of species stresses that satisfy the system consistency condition are here proposed. It should be noted that the study of sedimentation and consolidation of poly-disperse suspensions could result in more realistic suspension interfaces compared to mono-disperse suspensions, and could lead to more reliable engineering designs of tailings ponds. Predictions of sedimentation and consolidation in models of poly-disperse suspensions are demonstrated using published data.

Jan 1, 2014

By Jonas Addai-Mensah

Despite the fact that nickel (Ni) laterites accounts for about 60 % of the world?s nickel mineralization, commercial processing of complex, low grade Ni laterite ores by conventional beneficiation (e.g. magnetic, electrostatic and flotation separation) still presents intractable challenges, particularly in heap leaching. Invariably, low grade laterite ores require aggressive hydrometallurgical techniques (e.g., highly acidic lixiviant leaching at ambient or elevated temperatures) for Ni and cobalt (Co) extraction. As a precursor to heap leaching, agglomeration of the multi-mineral phase feed particles into robust and porous granules of 4-10 m permeable bed, is essential. In the present work, several basic and applied studies of the agglomeration behavior of real Ni laterite ores and selected oxides and clay minerals (hematite, quartz smectite and kaolinite) which constitute the predominant host gangue phases of typical laterite ores are performed. Isothermal, batch agglomeration tests involving sulphuric acid solution as a binder were carried out to produce coarse, narrow-sized (5 ? 40 mm) granules which were well characterized. The influential role of feed ore characteristics (e.g., mineralogy/chemistry and primary particle size distribution) and binder composition (30 vs. 44% w/w H2SO4) and dosage (15-25 wt.%) in agglomeration behavior and granule properties were examined through several characterization techniques including granule size, compressive strength, bed percolation and re-wetting stability and 3-dimensional micro-structure analyses. Links between feed mineralogy/chemistry and size, binder formulation, agglomeration behavior, curing conditions and final granule properties and structural characteristics are established. The implications of the findings to Ni laterite plant agglomeration for enhanced heap leaching are discussed. Keywords: nickel laterite, complex low-grade ores, agglomeration, heap leaching, micro-structure

Sep 1, 2012

By S. Cagirici, Z. Öztürk, A. Hassanzadeh

Many flotation kinetics models have been studied in the literature. Their applicability was extensively investigated and argued in detail. However, model selection criteria were not adequately discussed from the statistical points of view. In this investigation, the kinetic behavior of a complex copper sulfide ore was studied in a mechanical Denver flotation cell focusing on flotation kinetics of chalcopyrite, pyrite and molybdenite. Different flotation kinetics models including nine common empirical models and four mathematical models namely Hill, Chapman (Sigmodial function), single rectangular (Hyperbola equation) and exponential were applied to the experimental data. In addition to assessment of the goodness of fit criterion for each model, a factor of model complexity was considered using information criteria (IC) (i.e. Bayesian information (BIC), low of iterated logarithm (LILC) and Akaike information (AIC) indices). The obtained results showed that the IC indices could simply manifest the best-fitted model to the experimental data. Whereas, the coefficient of determination values (R2) were relatively same for all models. By taking the R2 and model complexity criteria into account, the exponential model was chosen as the best representative mathematical model to demonstrate chalcopyrite kinetic behavior. However, Chapman model was selected as the best one for the flotation of pyrite and molybdenite. In case of the common first-order flotation kinetics models, fast and slow flotation kinetic model (Kelsall) was reasonably fitted the best to the given data of chalcopyrite. However, the gas/solid kinetics adsorption model was chosen as the best-fitted one for pyrite and molybdenite. Furthermore, it was found that mathematical models represent better results in association with flotation kinetic behavior of chalcopyrite, pyrite and molybdenite due to the consideration of more parameters in modeling. Finally, it was concluded that the IC indices must be applied to the process of model selection due to consideration of goodness of fit, complexity of a model and model consistency.

Jan 1, 2018

By Robin J. Batterham

Alumina demand is steadily climbing around the world and is likely to continue to do so for many years. In such a commodity industry, the question arises as to what effort should be expended on innovation, given that for an individual company, the drivers of change are cost and quality as the market demand is essentially assured. This is of course a long-term view. The current conditions are less attractive. In this presentation, we review the broad issues that are considered targets for collaborative development by the industry as recently updated in the alumina industry roadmap published by the International Aluminium Institute in 2010. While they cover areas such as ?mine rehabilitation, residue management and use, alumina production from high sulfur bauxite, bauxite beneficiation, energy efficiency and alternative technologies for alkali and alumina recovery from bauxite residues,? it must be remembered that each refinery is different in terms of the feed material and the circumstances of waste disposal. Of particular interest is the more competitive area of breakthrough technologies. In the presentation, we will consider a range of opportunities that could transform the industry, from relatively near term possibilities such as bauxite activation through possibilities to eliminate crystallization as currently practiced to complete alternatives, such as the use of hyperaccumulating plants. Against this optimism, some of the realities that hold back breakthrough innovation will be presented for discussion.

Sep 1, 2012

By F. Karakas

In this investigation, one of the most energy consuming stage of the cement manufacturing process, grinding stage, was studied. The aim of the study is to reduce the energy consumption. Optimum operating parameters were determined. Experimental studies were performed at three differ-ent stages. Grinding of limestone, clay and marl which are the main components of the cement, to approximately below 90 microns, was the first stage of the cement grinding. At this stage, effect of feed size and ball charge were investigated. At the second stage, the Bond work index of clinker and additives (slag, trass, limestone and gypsum) was found separately. After forming composite cement with clinker and additives, the Bond work index of this mixture was also determined, thus the results of separate grinding and grinding of mixture were compared. The Bond work index of mixture was found as 13.59 kWh/t, while the arithmetic mean of the Bond work index values of components was 14.90 kWh/t. Finally, clinker and additives (slag, trass, limestone and gypsum) were ground under the same conditions. At this stage, laboratory type of ball mill was used in order to understand grinding characteristics of the cement components. As a result of the experiments, it was found that energy consumption for the grinding will be lowered if the mills with 38 % ~ 40 % ball charge are used in the cement grinding. Moreover, grinding with mixture of clinker and additives gave better results than separate grinding of these components in terms of energy consumption.

Jan 1, 2014

By Irena Grigorova, Tashka Ignatova, Ivan Nishkov, Andrian Valchev

"Feldspars used by ceramic and glass industries as fluxing agents are mainly obtained from high quality feldspar deposits. The demand for feldspar as raw material for industrial applications especially in ceramic manufactures is continuously increasing. However, due to the depletion of those deposits, the research activities related to the recovery of feldspar from the lower grade feldspar deposits and feldspar bearing rocks such as pegmatite, granite, arkosic sandstone and syenite have been intensified in the last two decade. In Bulgaria, the main deposit of arkosic sandstone is located in the area of Shumen town, NE Bulgaria. In Srednya deposit arkosic sandstones are found in Upper Cretaceous sediments (Santonian). In this formation, there are two major industrial minerals - feldspar and quartz. They may be of economic value and possibly suitable for commercial uses. The main purpose of the present study was to investigate the beneficiation and upgrading processes of Srednya deposit arkosic sandstones. In a laboratory scale it was studied the possibility to obtain the feldspar concentrate and quartz sand from arkosic sandstones. Particle size distribution, chemical and mineralogical compositions of quartz-feldspar sands were determined. The bench-scale tests using the KOALIN AD laboratory experimental facilities were conducted. Many processing techniques were tested: disintegration, washing, sizing, carbonate flotation and feldspar flotation. The experimental results show that there are possibilities to obtain the silica sand with low content of Fe2O3 - below 0.02 % and potassium feldspar with content of K2O > 14 %. A new technology for recovery of feldspar and silica sand from arkosic sandstone was developed."

Jan 1, 2014

By S. L. Zheng

The compound material of Nano-TiO2 Supported on the diatomite was prepared by the hydrolytic method with purified diatomite and TiCl4. The compound material was characterized by SEM, XRD, TEM, EDX, XPS, and the application test of the compound material was studied. The characterization test results showed that the Nano-TiO2 was coated on the surface of diatomite, the crystal of TiO2 is anatase, and the average crystal size is 12 nm. The pore diameter was reduced, but pore volume and surface area of the compound material are increased after Nano-TiO2 Supported on the diatomite. The application test results for treating coking waste water and formaldehyde gas show that the compound material of Nano-TiO2 / diatomite has adsorption and photo-catalytic function and strong degradation performance for phenol and formaldehyde.

Jan 1, 2014

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014