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By R. E. Fryxell, E. C. Duderstadt, P. K. Conn

Permeation rates for nitrogen through are-cast tungsten were measured in the temperature range 1800° to 2600°C at nitrogen pressure differentials of 1.0 and 0.1 atm. Gas chromatography was used to measure the quantities of nitrogen which permeated through 0.26-and 0.53-mm-thick membranes. Permeation rates were proportional to the difference between the square roots of the nitrogen pressure on each side of the membrane and inversely proportional to membrane thickness, indicating that atomic nitrogen was the difjusing species and that diffusion was the rate-limiting step of the process. Permeation coefficients calculated from the rates may be represented by the equation: where P is expressed in the units cu cm (stP)-mm per 1/2 sq cm-min-atm"' and 70.0 * 0.8 is the activation energy in kcal per mole of permeating species. In a previous paper' permeation rates were reported for hydrogen and for oxygen through tungsten. The permeation cells used for the hydrogen measurements were suitable for measuring nitrogen permeation under similar conditions, so the study was extended to include nitrogen. Permeation rates of nitrogen through the polycrys-talline arc-cast tungsten membranes were measured in the temperature range 1800" to 2600°C using two membrane thicknesses and two nitrogen pressure differentials. Permeation coefficients were calculated and the activation energy of the process determined. THEORY For diatomic gases which dissociate prior to diffusion, the quantity of gas which permeates through a membrane or wall at an elevated temperature where bulk diffusion is the rate-limiting step of the process is given by the equation: where: q = total amount of gas permeating a membrane, P = temperature-dependent permeation coefficient, A = area of membrane, t = time, p1 = gas pressure of high-pressure side, p2 = gas pressure of low-pressure side, and d = thickness of membrane. When bulk diffusion is the rate-controlling step, and the solubility of the gas obeys Henry's law, a further relationship is that, for any given temperature and pressure, the permeation is the product of diffusivity and the amount in solution. The permeation coefficient, P, is temperature-dependent according to the equation: where: Po = permeation constant, Q = activation energy, R = gas constant, and T = absolute temperature. EXPERIMENTAL PROCEDURES Cell Design and Experimental Apparatus. Two of the permeation cells used for the previous measurements of hydrogen permeation are shown in Fig. 1. Each consisted of a cylindrical chamber divided into two parts by a permeation membrane fabricated from high-purity (>99.9 pct W) wrought tungsten sheet made from vacuum arc-cast tungsten. The membrane in one cell was 0.26 mm thick and the other was 0.53 mm. The fabrication of these cells was described previously.' The permeation cells were mounted vertically in a high-temperature tungsten resistance furnace and the membranes and the center portions heated to test temperatures. Temperatures were measured by sighting an optical pyrometer on the edge of the membrane through a small hole in a tungsten plate which was fastened to the side of the cell. This arrangement provided an approximate black-body condition and eliminated the need for emittance corrections. Appropriate corrections were made for the quartz window through which the temperatures were measured. Argon gas flowed through the 10-liter volume of the furnace at the rate of 4.7 liters per min. An impurity

Jan 1, 1969

By W. W. Adams

[S,1.1.8'"' of explordves -permissible explosivos,21 other high explosives, and black blasting povrder -in the Uni ted States during the caJ.endar yenr 1937 reached a ~ombined total that slightly exceeded the quantity sold in 1936. A larger output was re orted. for permisAiblA and other hig! explosives but asmal-ler for black po~~er. Production of the three classes of explosives totaled 404, 744,294 pounds, more than 3 pel'CGnt over 1336. The total qrumti ty produced included 49,579,441 pounds of perminsibles, 2~8,924,253 pounds of other high ex-plosives, 36,403,950 pounds of black powder in pellet form, and 29,836,65q pounds of bla~k powder in granular form.]

Jan 1, 1938

By Leo J. Miller

It is both an honor and a pleasure for me to be the keynote speaker for the Paul F. Kerr's Symposium on Applied Mineralogy. Professor Kerr was a man for all seasons to his students, and he treated all students as distinct individuals. Philip Bethke in his memorial to Dr. Kerr summed up our remembrance best by stating that "We have lost our most successful educator-administrator-scholar, who was our steadfast teacher-counselor-mentor-friend." His unique trait was the ability to bring out the best in a variety of individuals In order that their performance was at the peak of quality.

Jan 1, 1985

By W. W. Kephart

The glass container industry is the largest producer of glass in the United States. As of this writing, there are approximately 89 active domestic production locations. In 1984, the industry shipped 11.8 million tons of glass containers. Approximately 70% of this production was clear or flint glass, 20% amber, 7% green, and the remainder miscellaneous colors. Although the production of nearly 12 million tons of glass is impressive, anyone following the industry over the last five years is aware that the industry has changed from a pattern of growth in the 1970's to one of maturity in the 1980's. Some observers, less generous, perhaps, have described the 1980's as a period of decline. In 1981, there were 119 production facilities which produced 13.2 million tons of glass the previous year. This equates to a 10% reduction in glass container production from 1980 to 1984, with a corresponding impact on the segment of the industrial minerals producers serving the container glass industry, as shown in Figures 1 and 2.

Jan 1, 1986

By Alexander Schultz Rizek

O trabalho que será apresentado irá descrever o projeto realizado de atualização tecnológica do sistema de controle com controladores Automax instalado em um laminador de fio máquina de dois veios, a Acerías Paz del Río, da Votorantim Siderurgia na Colômbia. Este projeto consistiu na substituição do antigo sistema de controle com PLC’s Automax do laminador fio máquina de dois veios, mantendo-se parte do sistema antigo Automax convivendo com o novo sistema Contollogix. O novo PLC instalado para o controle do laminador foi o Rockwell ControlLogix, através do qual foi desenvolvido o controle principal do laminador, como: cascata de velocidade utilizando o fator R, que poderia ser ajustado do IHM (antes os ajustes eram feitos diretamente no rpm dos motores), controle de laços, controle das mesas de laço, as primeiras da Russula, produzidas e programadas em companhia com a Russula Itália exclusivamente para esse projeto, controle de tração, ciclos de posicionamentos manuais e automáticos, intertravamentos, etc.

Jul 30, 2018

By James R. Walpole

Less than 100 years ago the first major federal regulatory agency, the Interstate Commerce Commission was established (in 1887), and since that time literally hundreds of other federal agencies have been created. The regulations set by these agencies tremendously affect the individual citizens of this country as well as U.S. institutions. A few examples of the myriad agencies established include the Food and Drug Administration. (1907), the Bureau of Mines (1910), the Federal Reserve System (1913), the Federal Trade Commission (1914), the Tennessee Valley Authority (1933), the Securities and Exchange Commission (1934), the National Labor Relations Board (1935), the Small Business Administration (1953), the Federal Maritime Commission (1961), the Equal Employment Opportunity Commission (1965), the Farm Credit Administration (1971), etc., etc. Eight years ago, on December 2, 1970, still another federal agency was established by the reorganization plan of President Nixon -- the Environmental Protection Agency (EPA). The Administrator of EPA was given authority to regulate certain activities affecting the environ-ment, which were formerly within the jurisdiction of the Department of Interior, the Department of Health, Education and Welfare, the Federal Radiation Council, the Atomic Energy Commission, the Department of Agriculture, etc. Within weeks after the formation of this Agency, Congress began to enact legislation which would be administered by EPA. Over the last eight years a considerable number of such laws have been passed, a few of which include: the Clean Air Act (1970), the Noise Control Act (1972), the Federal Water Pollution Control Act (1972), the Marine Protection, Research, and Sanctuaries Act (1972), the Federal Insecticide, Fungicide and Rodenticide Act (1973), the Safe Drinking Water Act (1974), the Toxic Substances Control Act (1976), the Resource Conservation and Recovery Act (1976), the Clean Air Act Amendments of 1977, etc. It may be helpful to review, in a summary fashion, the major provisions in some of these statutes, and accompanying regulations, as they relate to water quality control in the mining industry. The Safe Drinking Water Act and the Federal Water Pollution Control Act contain provisions to be examined, as well as the Resource Conservation and Recovery Act and the Toxic Substances Control Act. One other law, the Surface Mining Control and Reclamation Act (1977), is not administered by EPA although it does contain many provisions related to environmental control, and it will also be dis-cussed because of its importance to the mining community.

Jan 1, 1978

By P. Kordi, L. Egorova, R. J. Bowell, D. Gurevich, V. Sedov, A. Mikhailov, D. A. Holwell

ABSTRACT Reconnaissance exploration in the Kuene region Namibia has included geological mapping, soil and stream sediment geochemistry, and ground geophysical methods. Copper mineralization occurs within a well-defined belt with north-northwest to south-southeast trend, parallel to the regional strike of the sedimentary rocks. The occurrences vary in size but are generally stratabound. The mineralization is centred on the transition from calcareous shale and interbedded limestone, through carbonate rocks, to quartzite. Geochemical anomalies have been identified correlating to induced polarization (IP) and magnetic anomalies. The anomalies identify one potential metallogenic zone more than 17 km in strike length.

Jan 1, 2012

By K. N. Subramanian

Previously reported work on total oxidative leaching of chalcopyrite concentrates ha s shown that high copper extractions are obtained at 210°C and 0.4 MPa oxygen pressure. A simple integrated flow sheet using pressure leaching, solution treatment involving precipitation with a calcium base, and electrowinning to produce wire-bar-quality copper is described. Reagent and energy requirements developed from this work indicate that the process could be attractive for small operations where a smelting-refining complex cannot be justified.

Jan 1, 1978

By D. R. Pyke, R. S. Middleton

"Three main types of base metal sulphide mineralization are present in the Timmins area:(1) -Massive and stringer-type copper-zinc deposits occurring mainly in pyroclastic rocks, as typified by the mines of Kam-Kotia, Jameland and Canadian Jamieson, or within or close to possible breccia pipes as shown by the Genex and Kidd Creek mines. With the exception of the Kidd Creek mine, all of these orebodies occur northwest of Timmins (Kamiskotia area) and appear to lie within or close to a major center of volcanic activity characterized by a thick accumulation of felsic pyroclastic rocks and subordinate epizonal intrusions. The margins of the rhyolitic pile are interfingered with mafic volcanics; overlying sedi-ments mark the termination of a vol-canic cycle. The copper-zinc deposits in the Kamiskotia area are confined to a particular stratigraphic unit. Ore-bearing solutions were probably derived from the intrusive complex of the volcanic pile.(2) -Porphyry copper deposit of the Mcintyre mine. The deposit occurs in a quarz porphyry intrusion related to the volcanism in the area (Hurst, 1936). Mineralization was probably introduced at the time of intrusion, and subsequently redistributed within the porphyry during deformation. (3) -Massive and disseminated nickel mineralization, associated with serpentinized alpine-type ultramafic intrusions, as shown by the Alexo, McWatters, Hart, Inco and Texmont deposits. The nickel mineralization occurs at or near contacts of the serpentinites with felsic or mafic volcanics, or sulphide-bearing iron formations. The nickel deposits south of Timmins are confined to a particular stratigraphic unit along the margins of domical-shaped structures which appear to outline former volcanic centers. Sulphurization as pro-posed by Naldrett (1966) appears to be a workable hypothesis for the formation of some of the deposits."

Jan 1, 1971

By Gordon Jackson

"There are two accomplishments of air and gas drilling: a new series of economic and mechanical challenges; and, acceptance as a standard drilling and completion tool.The new challenges are related to the concept of using a gaseous circulating medium in drilling for oil or gas. For purposes of discussion, a two part division has been made: the challenge of fluid invasion control and that of equipment and tools. Great strides have been made in the development of materials and techniques to combat formation fluid invasion. Chemicals and the ""mist drilling"" technique, now in use, have the versatility to cope with a wide range of downhole fluid entry conditions.Equipment and tools have been developed to meet the challenges of better, more economic drilling and completion possible with a gaseous circulating fluid. Economic and operational challenges remain.Acceptance of air and gas drilling as a normal operating tool was reached with difficulty. It is now established as a means of reducing costs in exploratory and develop-mental well drilling, exemplified in a recent study of 226 wells covering 419,407 feet of hole in the United States. Air reached the projected depth in 85 per cent of the operations, although formation water was encountered in 48.7 per cent of the holes. Slim hole bit performance and cost all compared for overall bit averages as part of analysis."

Jan 1, 1961

By R. A. Friedel

THE UTILIZATION by the Bureau of Mines of infrared and ultraviolet-visible spectrometry in connection with coal research has led to some basic improvements in methods, including a calibration method, a quantitative assessment of infrared spectral energy sources, and the development and perfection of infrared filters and cells. The adoption of a micropipet method to flush organic samples into absorption cells permits the investigation of vapors from organic liquids and the identification of volatile organic compounds. The spectral method has been used to investigate the infrared spectra of metal chelates, the charge-transfer complexing properties of aniline and nitrobenzene, an infrared method for determining the presence of methane in coal-mine air that has been adopted for use in enforcing the regulations of the National Coal Mine Safety Act, and atmospheric pollution including smog and odor-causing oxidation and decomposition of organic materials. Correlation of spectra and structure of organic compounds, particularly aromatics, was studied.

Jan 1, 1966

By M. Vallée, J. -P. Charette, D. P. Gold

"The Oka Carbonatite and Alkaline Complex is a Lower Cretaceous intrusive body of the Monteregian petrographic province. Carbonate rocks of various types, and associated alkaline rocks of the ijolite and okaite suites, are distributed in a double ring-dyke structure 4 Yi miles long by 1 1/2 miles across. Alnoite and alrioite breccia pipes intrude all rocks of the Complex and indicate, from inclusions, that a cover of Palaeozoic rocks existed at the time of emplacement.The results of radiometric, magnetic and gravity surveys of the Complex are compiled and discussed both with respect to the regional pattern and, locally, the bed-rock geology. The Complex is characterized by high-intensity anomalies.Exploration activities started during 1953, and mining operations began in 1961 on the property of St. Lawrence Columbium and Metals Corporation, at one time the world's largest producer of niobium concentrates. Because of the boudinaged and fractured nature of many of the rocks and the variability in grade of the ore minerals, the role of the mining geologist is both demanding and exacting. Rock types are varied and their mutual relation-ships ambiguous, the minerals are rare and complex, and close geological control of the ore is needed in the mine and in the mill. Closely spaced diamond drill holes are needed for mining control, and the ore-waste contact is defined mainly by assay results.In the exploration for 'carbonatites' in Eastern Canada, aeromagnetic surveys are judged to be the best exploration tool, followed in decreasing order by the search for circular structures on aerial photographs, regional gravity surveys and radiometric surveys."

Jan 1, 1967

"INTRODUCTION Early in 1936 the Interstate Oil Compact Commission and other groups interested in forecasts of demand for petroleum requested the Bureau of Mines to make a physical inventory of crude-oil stocks in the United States, Accordingly, the 74th Congress appropriated funds for conducting such a survey during the fiscal year ended June 30, 1937. In the discussions and hearing 2/ relative to the need for the survey, the opinion was expressed that crude oil held in storage for long periods had lost so much of its gasoline content that the economic significance of total stocks should be discounted materially. Therefore, a primary objective of the survey was to make a physical inventory of the crude oil held in storage above ground and to determine the quantities and characteristics of the light fractions contained in the various stocks."

Sep 1, 1938

By F. X. Tartaron

Behavior of hard-burned quicklime was compared with that of soft-burned quicklime in an oxygen converter utilizing oxygen blowing in a rotating cylindrical vessel, set at a 30° to 60° angle to the horizontal and operated at a predetermined speed of rotation. Four pairs of tests were made) each comparing hard lime with soft lime. Three of the pairs differed from one another in the quantity of lime employed) and the fourth differed in blowing time, All four pairs showed an increase in yield when soft lime was used. Three of the pairs revealed that the ratio of the oxygen consumed with soft lime to the oxygen consumed with hard lime was the same as the ratio of metal yield with soft lime to the metal yield with hard lime. The fourth pair contained an error and could not be included. Finally, a close inverse relation was found between the combined iron in the slag and the combined lime in the slag, which can be expressed by the equation pct Fe = 52.67 -0,906 (pct CaO).

Jan 1, 1967

By T. E. Howard

The western phosphate field, comprising parts of Idaho, Montana, Wyoming, and Utah, contains one of the world's largest known reserves of phosphate rock. Although phosphate-rock deposits of good-grade have been known since before the turn of the century and production has been recorded since 1906, real development of this important field did not begin until immediately after World War II. Since then fertilizer-manufacturing facilities using western phosphate rock have been expanded, and three electric-furnace plants for producing elemental phosphorus have been installed, resulting in a rise in mine production from 323,955 long tons2/ in 1945 to 1,653,916 long tons3/ in 1953. Interest in the field is increasing, and it is reasonable to expect that the western phosphate industry will continue to expand. Before 1945 all western production was from underground mines. In that year the first strip mine in the field was started near Montpelier, Idaho,~ and in sub-sequent years a number of other open-pit mines were opened in southeast Idaho and western Wyoming. At present the major part of the production comes from surface mines. Underground mining has continued, and new underground mines have been opened in the field, but recent exploration by operating companies has been aimed primarily at developing additional deposits suitable for low-cost surface mining. Preliminary reserve estimates by the Federal Geological Survey5/ indicate that only a very small part of the total resource may be recovered by surface methods and that the industry eventually must depend largely on underground mining. Because one function of the Bureau of Mines is promoting the conservation and development of the Nation's mineral resources, it is appropriate that research be conducted to develop low-cost maximum-recovery underground mining methods applicable to western phosphate-rock deposits.

Jan 1, 1956

By Paul Meadows

The Buckrange reservoir, Stephens field, Ark., is approaching the economic limit of production under present operating conditions. Over 100 million barrels of oil remaining in the reservoir will not be recovered by primary producing methods. The Bureau of Mines, in cooperation with the Arkansas Oil and Gas Com-mission, made the petroleum-engineering study presented in this report to aid operators in evaluating secondary-recovery possibilities in the reservoir and in planning secondary-recovery programs if their initiation is decided. The Stephens field, in Columbia, Nevada, and Ouachita Counties, Ark., is about 12 miles northeast of Magnolia, Ark., and 15 miles west of the Smackover field. Surface elevations in the area average about 240 feet above sea level.

Jan 1, 1956

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By E. Isokangas

A mine is essentially a series of operations, including drilling and blasting, crushing, milling, flotation, and leaching, that are interconnected and therefore interrelated, with the performance of one operation affecting the performance of another. Optimizing each stage separately without considering the whole system often causes potential economic benefits and energy savings to be missed. However, the PIO methodology is a thorough approach which considers these individual process activities within the context of the whole process. The basic principle is to optimize the process as a whole, rather than each process step in isolation from the others. Metso?s Process Technology and Innovation (PTI) group offers a global consulting service for the mining and construction industries. A significant amount of this consulting work involves process integration and optimization (PIO) studies. When conducting a PIO study, every aspect of the process is considered. In addition to drilling and blasting, transportation, handling and storage, crushing, screening, grinding, flotation, separation, and recovery, other aspects including equipment utilization and energy consumption and even greenhouse gas emissions are also included if necessary. In a PIO project, it is very important to understand what type of material is being processed at any point in time. That is, which domain or domains is the material part of? This is necessary in order to observe the effect of different ore sources (and the blending of sources) on concentrator performance. Linking the ore from the pit to the concentrator required the development of an ore tracking system. As a result, PTI developed a radio-frequency based material tracking system called SmartTag?. This system allows tracking of ore from its source through blasting, run-of-mine (ROM) pads, crushers, intermediate stockpiles, and finally into the concentrator. Using the SmartTag? system, definitive correlations can be made between the performance of the plant and the plant feed characteristics, including the domain from which the feed ore originated. Since its commercialization in 2007, SmartTag? has been used in the majority of PTI?s consulting projects and several permanent systems have been installed worldwide1. Successful applications of the SmartTag? system have encouraged development to allow the system to be used in a wider variety of plants, in particular plants with finer crushing and screening stages. This paper describes how the SmartTag? system is being utilized by PTI and the benefits being gained by its use in PIO projects, as well as presenting some case studies.

Jan 1, 2012

By Kendall W. T C

This paper provides a brief overview of the history of the Chaffers Dewatering Project which was successfully commissioned in August 1993. Until the end of 1992 the `Superpit' and the deep mines of the Golden Mile had all been dewatered by a staged pumping system from the 28 level in the Lake View Shaft, which was removed at that time when the Lake View Mine was absorbed into the Superpit. Feasibility analysis had indicated that adaptation of oil industry technology offered the greatest potential for a low cost solution to the problem of dewatering the open pit and deep mines. A KCGM engineer and one of the authors visited the Jackson oilfields to look at the deep well pumping technology in use there in early-1991. In the final analysis a new dewatering station was established in the 23 level crushing station of the Chaffers Shaft using conventional plunger pumps, but the rising main was screwed 178 mm OD (7 inch) casing the suspended from the surface to a depth of 686 metres, and was installed using oilfield personnel and methods. Only the second installation of its kind in Australia, the project achieved the dewatering objective at about half of the capital cost of the more conventional approach and at lower operating costs as well.

Jan 1, 1995