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By R. O. Ifill

Alternating current electrocoagulation (AC/EC) may be an alternative to chemical coagulation in the thickening of tailings in the mineral, coal and petroleum industries. In the current study, ground silica (d50 as received, 20 µm) served as the model tailings solid with characteristically poor settling behavior. Its natural initial settling rate was 1.6 x 10-3 cm/min. This paper discusses the indirect application of AC/EC via aluminum electrodes to the enhancement of the settling behavior of the silica. ?Indirect AC/EC? means that the silica was coagulated upon dispersion in water that had been treated by AC/EC. The effect of AC/EC retention time on settling behavior is examined and the water chemistry is analyzed. Test results show that the initial settling rate of silica was enhanced by a factor of 4,000 at its maximum of 6.4 cm/min, under the conditions employed. Settling enhancement was achieved upon contact between the AC/EC-treated water and the silica, and the enhanced initial settling rate was dictated by the floc size. The aluminum dosage increased with AC/EC retention time, reaching a maximum concentration that was equivalent to 13.1% of that predicted by Faraday?s law. Complex aluminum ions are considered to have adsorbed onto the silica surface and an adsorption mass ratio of 0.3 mg Al/g silica was the most effective in enhancing settling behavior. Owing to pH change or slow kinetics, aluminum hydroxide precipitation did not lower the ion product ([Al3+][OH-]3) below the KSP of 6.3 x 10-32.

Jan 1, 2011

By D. F. Kidd

Introduction In a companion article, Surveys at Great Bear Lake, 1931, R. C. McDonald has described the general character, topography, and climate of the Great Bear Lake-Coppermine River area and the main means of access (l). The present paper will largely be confined to the geological features of the district. In the last two years, the rocks of the region have received considerable attention, and papers including references to .the geological succession have been written by Knight(2), Duncan(3), Norris( 4), Reid(5), Cameron(6),and Kidd(7). The writer confined his field-work during the 1931 season to the district between LaBine point and Hunter bay and northwest to the head of McTavish arm. Brief trips were made down the Sloan river from McLaren lake, 25 miles northeast of Hunter bay, to that place, to Dowdell (Sixty-six) point, the south point of Echo bay, and to the region north of the Dismal lakes and west of the Coppermine river. The inner part of Echo bay, which is the area discussed by Reid and Cameron, has not been seen by the writer and the geology there will not be discussed.

Jan 1, 1932

By Lin Zhu, Zheng Wei, Meng Li, Xueli Cao, Hanying Wen, Guodong Shi, Lei Yu, Wen-xin Tang, Tao Li

Low energy electron microscopy and photoemission electron microscopy (LEEM/PEEM), as powerful in-situ surface-sensitive electron microscopy, find wide applications in surface physics, chemistry and catalysis. The high reflectivity of incident low-energy electrons (0–100 eV), allows it to image the surface structures in the topmost few atomic layers within less than one second, while the sample can be heated up to 1200 °C in real time which is potentially very useful in metallurgy and materials fields. A unique three-prism aberration correction (ac-) LEEM was commissioned successfully in Chongqing University, with a lateral resolution below 2 nm. A multiple gas source in the ac-LEEM system was installed as well, which allowed us to observe chemical reactions of nanoscale mineral powders on metallic substrates. In this paper, the latest results on the applications of this three-prism ac-LEEM on oxidation and reduction processes on copper and iron polycrystalline surfaces are demonstrated.

Mar 1, 2018

By M. J. Jackson

MIGRATOM is a third-generation PC-based computer program developed by the U.S. Bureau of Mines for geophysical tomography. Like its predecessors, BOMTOM and BOMCRATR, MIGRA TOM was developed to enable users to address a variety of mining-related problems by mathematically reconstructing the distribution of physical properties in a rock mass, using measurements of travel time or amplitude of wave energy propagated through the rock mass. Examples of applications include lithologic characterization, fracture detection, fluid monitoring, stress evaluation, and blast assessment. The resolution and accuracy of tomographic reconstructions generally depend very strongly on the geometry of source and receiver locations. In many practical applications, such as cross-borehole tomography, limited coverage results in nonunique reconstructions. MIGRATOM follows the precedent of BOMTOM and BOMCRATR in allowing the user to constrain the inversion, in order to reduce the nonuniqueness problem. A new approach to application of constraints implemented in MIGRATOM is based on fuzzy logic techniques. Refraction of wave energy is modeled in MIGRATOM using an approach based on Huygens' Principle. Propagation of a continuous wavefront is modeled as a constructive interference phenomenon, which obviates the shadow-zone problem that affects conventional ray-tracing calculations. MIGRATOM has been tested with both synthetic and field data sets.

Jan 1, 2010

By Jonkion M. Font, Ramana G. Reddy

A thermodynamic model for a priori predictions of arsenic and antimony impurity capacity in Ni-Cu mattes and slags was developed based on the Reddy-Blander (RB) capacity model. The As and Sb capacities were calculated a-priori considering the RB capacity model in Ni-Cu mattes and FeO-FeO1.5-MgO-CuO0.5-NiO-SiO2 slag at 1573 K and 0.1 to 1 atm partial pressure of SO2. The results showed an excellent agreement between the model calculated and experimental data of arsenic and antimony capacities between the mattes and slag. The impurity capacity model developed here, can be extended for prediction of impurity capacities in multi-component base metal slags and base metal mattes. Such a priori predictions of impurity capacities can lead to develop or improve the efficiency of impurity removal from the base metal smelting, converting and refining processes.

Jan 1, 2014

By Ronie Magno Pinheiro de Souza

A partir do segundo semestre de 2013, iniciou-se um período de maior dispêndio energético para o controle da resistência à compressão da pelota AFXX. A este problema somou-se o desafio de atingir elevados patamares de produção e chegar à produção nominal da usina. Desta forma, foi necessário fazer a partir de um complexo diagnóstico de todas as etapas do processo para encontrar a causa do problema e determinar a melhor forma de contorná-lo. Observou-se uma elevada geração de superfície específica granular somada à dificuldade de obter granulometria (-325#) na moagem, além da elevação da umidade do filter cake. Além disso, observou-se uma considerável elevação do PPC (perda por calcinação) no período, o que explica as constatações anteriores. Os objetivos do trabalho são avaliar os efeitos do aumento do PPC no pellet feed na produção da pelota AFXX e buscar explicação para a queda da resistência à compressão.

Aug 1, 2018

By N. Waters

"Nickel saprolite ores are normally mined as feed to Fe-Ni smelters or Ni matte smelting operations. The smelting processes typically require high Ni cut-off grades of approximately 1.5 to 2.2% Ni, depending on the operation. These very high cut-off grades result in a significant portion of the saprolite profile being regarded as “waste” and hence having little to no value. The Starved Acid Leach Technology (SALT) was developed to recover nickel and cobalt from nickel saprolites and Caron plant residues. Relatively small amounts of acid are applied to ground saprolites or Caron residues in order to selectively leach nickel and cobalt. The leaching is performed atmospherically under low free acid conditions. Nickel and cobalt may be recovered from the leachate as a mixed hydroxide. The mixed hydroxide may be added directly to a saprolite smelting operation or refined separately. InCoR Technologies is advancing the application of SALT at a number of sites. Bench scale testing has provided a relationship between acid addition and nickel extraction in leaching. Conceptual engineering studies have been completed by SNC Lavalin. The simplicity of the SALT technology provides the benefits of low capital and operating cost and an expected rapid ramp up to full production.INTRODUCTION The recent history of hydrometallurgical nickel laterite treatment plants has demonstrated mixed financial and operational performance. Table 1 summarizes the next generation plants built after the financial and/or technical failure of the Bulong, Cawse and Murrin-Murrin plants in Australia. The Coral Bay plants (Line 1 and 2) stand out (and now Taganito) as relatively low capital cost, simple (no acid plant, production of mixed sulfide product), and modest in scale (10, 12 and 36 kt Ni/a). However, the other plants in the list (Ravensthorpe, Ramu, Goro and Ambatovy) are all characterized by financial and technical challenges. All plants have a very high capital cost ($67,000 to $120,000 USD/annual t of Ni production). Ravensthorpe was sold by BHP Billiton after a poor startup. Ramu has had a steady ramp up but only produces mixed hydroxide for refining by others. Goro has had an extended construction period (since 2001), is high cost and has been very slow to ramp up to design production rates. Ambatovy has had a steady ramp up."

Jan 1, 2017

By Ross W. Smith

In recent years there has been a considerable amount of research work done relative to the effect of pretreatment and aging in water on the surface properties of both simple metal oxides and more complex oxides such as the silicate minerals 1-6. Of particular interest is the work of Somasundaran6 who states that after preparing minerals by size reduction and washing with dilute acids "... it is essential to treat it (the mineral) with water in order to remove any effects of leaching itself." Somasundaran also states, "... it is advisable to use a solution close to the point of zero charge for conditioning purposes." Parksl notes that, "Dehydration, dehydroxylation, and increased crystallinity can be expected to decrease the PZC. The presence of anionic impurities or of pH-independent potential determining ions will decrease the PZC. Cationic species will increase the PZC." Healy and Jellett4 believe that in the Zn0-water system "the surface charge of Zn0 in water and each pH is determined by the concentration and adsorption of each hydrolyzed (charged and uncharged) Zn(II) species." Finally, according to Parks 2, "The PZC of an unaltered com¬plex oxide in a system devoid of specific electrolytes is approximately the average of the PZC's of its component oxides... Equilibration with water results in loss of mono and divalent cations by exchange with H+, thus a loss of influence on the PZC by those cations, i.e., a shift in the PZC with time in the direction of that remaining oxide. The present paper investigates the change of point of zero charge (PZC) of a number of simple oxides and several complex oxides as a function of aging time in water. In some cases acid pretreatment of minerals was performed. However, in most cases the minerals were not acid pretreated. In several systems pH change as a function of aging time in water was monitored.

Jan 1, 1972

By Flanelson Maciel Monteiro

Os materiais cerâmicos são essenciais para o desenvolvimento da humanidade. O homem os utiliza para os mais variados fins, desde a confecção de utensílios domésticos até a produção de peças de alto desempenho tecnológico. Neste sentido, são extremamente necessárias à produção de pesquisas científicas para prospectar novos materiais para a indústria cerâmica. As argilas são consideradas o principal componente para fabricação de massas cerâmicas. Para produção de peças de cerâmica branca, revestimentos e outras categorias cerâmicas onde a coloração clara é prioridade, usam-se argilas cauliníticas. Todavia, esse tipo de argila possui pouca ocorrência na esfera terrestre, em comparação com outros tipos, tais como as argilas de coloração vermelha. Por tal motivo, encontrar novas jazidas de argila caulinítica para abastecer à indústria ceramista é extremamente imprescindível. Nesse sentido, objetiva-se com esse trabalho caracterizar uma argila caulinítica proveniente de uma jazida localizada no município de São Gonçalo do Amarante, região metropolitana de Natal-RN. O referido trabalho configura-se como a primeira parte de uma caracterização do material estudado. Sendo reservado para esse artigo os ensaios físicoquímicos e na segunda parte os ensaios tecnológicos. A caracterização fisioquímica foi realizada através das seguintes análises: DRX, FRX, Análise Granulométrica (AG), Dilatometria e ATG/DTG. Os resultados obtidos demostram a viabilidade técnica da utilização do material para fabricação de produtos cerâmicos, tais como: telhas, lajotas, revestimentos e outros materiais cerâmicos.

Oct 30, 2017

By Lucas Travi

Os problemas gerados no processamento do aço inoxidável AISI 316 são um grande problema do setor metal mecânico, por exemplo, no processo de usinagem, onde o material sofre altas taxas de deformação plástica e elevadas temperaturas na região de contato ferramenta-peça. Além disso, a adesão de aço inoxidável em materiais de maior dureza, no caso a ferramenta, também são problemas enfrentados. Neste trabalho foi feito um estudo qualitativo em escala laboratorial do contato entre um material de maior dureza (aço AISI M2 nitretado a plasma) e o aço AISI 316. Foram realizados ensaios de microdureza Vickers e rugosidade afim de caracterizar as amostras de aço AISI M2. Ensaios tribológicos do tipo Ball-on-Plate foram realizados com a finalidade de determinar o coeficiente de atrito ao longo do tempo para os pares tribológicos formados. Análises feitas via MEV/EDS foram feitas tanto nas trilhas geradas nas superfícies das amostras quanto nas esferas, para detectar pontos de adesão, deformação plástica e transferência de material entre as duas superfícies. Ficou comprovado que a nitretação a plasma com gaiola catódica proporcionou um menor coeficiente de atrito ao longo do tempo quando posta em contato com a esfera de aço inoxidável, bem como foi possível observar a formação de uma menor quantidade de pontos de adesão de aço inoxidável para esta superfície.

Aug 17, 2017

By E. C. Strycula

Solid-state equipment offers a number of potential advantages in the coal mining industry. These advantages can only be realized, however, through careful and judicious design of the control and protection circuitry. Problems relating to the interaction of solid-state equipment on the electrical system and the special design considerations which apply to solid-state circuitry are examined. Design guidelines are provided for solid-state applications in the areas of: (a) equipment operated from a DC trolley wire, (b) drive systems for surface mining equipment, (c) AC motor starters, and (d) electromagnetic interference.

Jan 1, 1981

By Frederick McNeill, John Harper, Mahmood Khwaja, Shawn Lavoie, Timothy Cloughert, David Polcari

City of Manchester, NH, is implementing a 20-year plan to control and significantly reduce overflow of its sewer system. The long-term control plan had called for large scale box culvert installation through downtown Manchester. The City and the project team evaluated, and eventually selected, tunneling as an alternative to mitigate construction related impacts for open trench approach. This paper provides an overview of the alternative evaluation process; discusses the development of the preliminary design for the 12,000 feet long, 12-ft internal diameter tunnel, including plan and profile selection, subsurface conditions, drop shafts and the anticipated packaging of the separation areas.

Dec 1, 2022

By D. E. Shanks

The Bureau of Mines surveyed a variety of inorganic ion-exchange materials to determine their suitability for removing valuable accessory elements and troublesome contaminants from metallurgical process and waste streams. Most of the materials, which included molecular sieves, heteropolyacid salts, and hydrous metal oxides, did not give adequate separations, did not have the necessary stability in strong acids or bases, or were not in a physical form suitable for ion-exchange use. Many of the suitable inorganic materials, especially the hydrous oxides, were capable of cation exchange with high capacity only in basic conditions, which caused hydrolysis of most of the cations tested. Multivalent anions, such as arsenate and phosphate, were easily removed from acidic solutions by hydrous oxides. Hydrous zirconia was the best material for this purpose. Multivalent anions were not easily des orbed because of compound formation; therefore, conventional ion-exchange techniques could not be employed. As an alternative approach, hydrous ferric hydroxide was used as a filter material to remove arsenate and phosphate from acid solutions. One gram of arsenic was removed from solution for each 20 g of ferric hydroxide. Ferric hydroxide is preferable to hydrous zirconia for use as a filter material because of low cost.

Jan 1, 1983

By Robert Torbin

The objectives of the Continuous Shaft Lining (CSL) System are to reduce the costs, safety hazards, and time currently required in lining mine shafts with concrete. The CSL will line machine bored shafts downward from the shaft collar on a continuous basis using an inverted, pressurized slipforming technique. The technique for slip-forming downwards has been demonstrated and refined under this program. The approach taken involved laboratory scale testing of key features of the CSL concept. These feature tests included concrete distribution, concrete sealing, concrete slipforming and development of a reliable concrete mix. Based on these results, a full scale above-ground test facility and CSL were designed and fabricated. The objectives of these tests were to demonstrate the viability of the basic concept; to establish operating limits; and to provide input data and information for the design of a second generation shaft lining system. The results of the program have led to a CSL design and operational philosophy which will need to be tested in an underground environment before industry will accept the technology. However, the next generation CSL promises to meet all the original program technical objectives.

Jan 1, 1983

By D. R. Wilburn

This summary of international mineral exploration activities for 2012 draws upon information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration for 2012: 1) budgetary statistics expressed in U.S. nominal dollars provided by SNL Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2012 as compiled by the USGS and 3) regional events including economic, social and political conditions that affected exploration activities, which were derived from published sources and unpublished discussions with USGS and industry specialists.

May 1, 2013

By J. O. G. Sanderson

THE Brazeau river is a relatively short foothills stream in western Alberta and its drainage area is limited to approximately 2,400 square miles. It rises near the head of the North Saskatchewan river, about two-thirds of the way from Banff to Jasper, and is confluent with the North Saskatchewan at a point about 40 miles north of Rocky Mountain House. It is not the purpose of this paper to describe the geology of all of this area. Only the central portion, which lies east of the outer limestone ranges and takes in the outer folds of the foothills belt, will be dealt with. This area is shown on Figure 1. A small portion of the area described lies in the drainage basin of Pembina river, which flows into Athabaska river. The area to be discussed may conveniently be termed the 'Brazeau area', since Brazeau is the name of the river basin referred to above, of an out-lying limestone range, and of the only large settlement or community in the region, the mining town Brazeau. One of the first Factors of the fur trading post of Rocky Mountain House in the early years of the nineteenth century was Louis Brazeau. Coal mining during the past 25 years, and more recently exploratory drilling for oil, have brought the district into some prominence. The Brazeau area was visited by D. B. Dowling for the Geological Survey of Canada in 1906 and 1907 (1). His traverses and reports dealt mainly with the Kootenay coal deposits. It is doubtful if he traversed the outer foothills area with which the present paper deals. His reports on rich coal deposits in the Bighorn Basin area attracted commercial interests, and in 1908 large tracts were leased as coal lands. James McEvoy mapped and studied the coal seams in that year, and G. S. Malloch, of the Geological Survey of Canada, made a complete survey of the whole of the Bighorn basin. His report (2), published by the Survey in 1911, describes the stratigraphical geology and names the formations. Further references to the geology of the district, mainly in relation to coal, are made by D. B. Dowling (3) and by J. S. Stewart ( 4). In the period between 1913 and 1920, the area was traversed by private interests in search of likely oil structures. A well was started in 1914 along the Saskatchewan river about 19 miles west of Rocky Mountain House, and drilling was undertaken by Imperial Oil, Limited, in 1921 at Coalspur.

Jan 1, 1939

By Noan Tonini SImonassi

Fibras de rami (Boehmeria nivea) estão entre as lignocelulósicas naturais com potencial para utilização em compósitos poliméricos. O presente trabalho avalia a resistência ao impacto deste tipo de compósito. Corpos de prova normalizados foram confeccionados com percentuais de até 30% em volume de tecido de rami alinhadas ao longo de todo o comprimento. As fibras foram embutidas sob pressão em matriz de resina poliéster do tipo ortoftálica curada à temperatura ambiente por 24 horas. Os corpos de prova foram ensaiados em pêndulo de impacto Izod e as superfícies de fratura analisadas por microscopia eletrônica de varredura, MEV. A resistência ao impacto aumentou exponencialmente com a quantidade relativa de tecido de rami reforçando o compósito. Este desempenho foi associado à dificuldade de ruptura imposta pelas fibras bem como ao tipo de trincas resultantes da interação tecido de rami/matriz de poliéster que ajuda a absorver a energia do impacto.

Aug 17, 2017

By R. D. Nelson, S. D. Dahlgren

The conditions of temperature, strain rate, and total strain favoring deformation by grain boundary sliding, slip, or deformation with concurrent recrystallization were evaluated for alpha plutonium. Grain boundary sliding and slip were studied by examining structures formed on polished surfaces with 4.5 pct compressive deformation. The conditions required for recrystallization were determined from compressive deformation us time curves. At 110" C and at a strain rate of 10&apos;per min, deformation was almost exclusively by grain boundary sliding whereas slip was the predominant deformation mode at -10°C and lo-&apos; per min. Defarmation at intermediate tenzperatures and strain rates produced structures showing mixtures of grain boundary sliding and slip. Recrystallization occurred concurrently with deformation only after a critical strain was reached. About 14, 6, and 3 pct strain was required at 105", llO°, and lZO°C, respectively, before recrystallization started, irrespective of the strain rate in the range of lo-&apos;1 to 10&apos;4 per nzin. L HE temperature and strain-rate dependency of the modes of plastic deformation were evaluated for high-purity as-cast alpha plutonium. The techniques used to study slip and grain boundary sliding were similar to those employed previously for alpha plutonium by Bronisz and Gorum,&apos; and spriet.&apos; Recrystallization was investigated using the methods reported by Nelson.3 Bronisz and Gorum&apos; found that slip occurred on more than one slip system at room temperature, and suggested that grain boundary sliding also contributed to the deformation. spriet2 found that deformation was predominantly by slip at room temperature, and observed one to three orientations of slip traces in individual grains. In addition, he deformed polished samples at 10O° C, but concluded that the deformation character of alpha plutonium at 100° C and at room temperature were not essentially different. Several investigators reported that twinning was only occasionally observed.1&apos;2&apos;4 Nelson3 recently found in creep tests that high-purity alpha plutonium would recrystallize concurrently with compressive deformation at temperatures between 25" and 115°C. EXPERIMENTAL PROCEDURE Electrorefined plutonium having less than 300 ppm total impurities was received from Los Alamos Scientific Laboratory in the form of +-in. diarn cast rods. Major impurities were americium, <I00 ppm, and tungsten, (60 ppm. Less than 25 ppm each of other impurities were present. The rods were cut into right half-cylinders 0.35 in. long and 0.25 in. in diam, and the flat faces along the cylinder axes were metal-lographically polished. To avoid loss of the metallo-graphic polish by oxidation, the polished samples were deformed in a silicone fluid heat treating medium contained in a chamber evacuated to a pressure of lo-&apos; torr. Deadweight loading was used to compress the samples between 4.5 and 20 pct at strain rates between 10"4 and lo- &apos; min-&apos;. Strain rates were determined by dividing the total deformation by the elapsed time of the test, even though the strain rate was not constant during deformation. Curves of strain vs time for samples deformed with a constant compressive stress3 show that the strain rate changes by less than a factor of four during the testing of a given sample, which is small compared to the three orders of magnitude change in strain rate investigated. Two samples were loaded into an ordinary metallographic mounting mold and impacted by striking the mold piston with one blow of a 2-lb hammer. Deformation temperatures for the two impact samples were 25" and 90°C. The samples, following deformation, were washed in carbon tetrachloride and their polished and deformed surfaces were immediately inspected metallographi-cally. Subsequently, the deformation structures were replicated with acetate replicating tape for later electron microscope examination, and the samples were then repolished and etched to reveal the microstruc-tures of the deformed metal. Second-stage carbon replicas were prepared from decontaminated acetate replicas using the procedure developed by Miller, Bierlein, and astel.&apos; Additional samples, which were 0.35 in. long by 0.25 in. in diam, were used to obtain constant load deformation vs time curves. These samples were deformed 10 to 20 pct with loads of 15 and 20,000 psi at 120°C; 30, 45, and 55,000 psi at 110°C; and 20 and 30,000 psi at 105°C. Samples were polished and etched to determine whether or not recrystallization or twinning had occurred during deformation. RESULTS AND DISCUSSION The experiments showed that alpha plutonium deforms by grain boundary sliding, slip, and deformation with concurrent recrystallization. Deformation by twinning was insignificant. Metallographic examination of polished and deformed surfaces revealed grain boundary sliding and slip. The start of recrystallization was ascertained from constant load deformation vs time curves. Deformed surface structures of samples compressed 4.5 pct under four different conditions of temperature and strain rate, Fig. 1, show how the deformation mode changes from predominantly grain boundary sliding to predominantly slip with increasing strain rate and decreasing temperature. Deformation at 110°C and 10" 4 min-&apos;, Fig. l(a), was predominantly by grain boundary sliding. Only a few slip traces can be seen in Fig. l(a).

Jan 1, 1969

By Bartosiewicz H

A method for the determination of the gas content of coal seams is presented which improves upon existing methods. The method makes use of a gravitational technique for measurement of the gas desorbed. The amount of lost gas is estimated by determining an empirical relationship relating the desorption of gas with time for each sample separately. This is to replace the assumption that desorp- tion follows a square root law with time. Laboratory investigations have been conducted which indicate that the square root desorption law does not hold good for carbon dioxide. Results of investigations on various factors influencing the technique are presented. It is shown that co-efficients of the empirical equation are dependent upon the elapsed time and the period of observation. Data about gas pressure measurements is presented and it is concluded that gas pressure can be approxi- mated to 0.6 times the pressure below a column of water equal to the depth of cover. This estimate is good enough for adsorption tests to evaluate desorption co-efficients. The technique for repressurisation of the sample,

Jan 1, 1982

By Jack L. Henry

The monocarbide region of the ternary system U-C-O has been investigated at 1,700° C as the first phase of a more extensive study of a portion of the four-component system U-C-O-N. An area bounded by the following compositional limits in atomic percent was studied: U, 44 to 55; C, 30 to 60; 0, 0.2 to 20. Compacts composed of mixtures of uranium, graphite, and uranium dioxide powders were sintered at 1,700° C under an equilibrium pressure of carbon monoxide to produce uranium oxycarbide specimens having a variety of compositions. Sintered specimens were evaluated by X-ray, chemical analysis, and ceramographic techniques. Solid-solution boundaries and phase relations have been established, and the effects of composition on the lattice parameter as well as the decomposition pressure have been investigated. Oxygen can be substituted for carbon in stoichiometric uranium monocarbide to the extent of about 17 atomic percent at 1,700° C. The composition range of the oxycarbide solid solution extends from about 48 to 51 atomic percent uranium in the low oxygen region. Above 10 atomic percent oxygen the composition range narrows to less than 1 atomic percent uranium. Carbon monoxide exists as a gaseous phase in equilibrium with all compositions which contain oxygen. Five separate phase fields were found bounding the solid-solution area. Other phases within this portion of the system include uranium, uranium dioxide, uranium dicarbide, and uranium sesquicarbide. Decomposition pressures of oxycarbide compositions at 1,700° C have been found to vary from a few microns for stoichiometric and uranium-rich compositions to 35 torr for carbon-oxygen-rich specimens. Lattice parameters were found to depend upon the U to C + 0 ratio as well upon the extent of substitution of oxygen into the stoichiometric monocarbide lattice.

Jan 1, 1967