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By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By S. G. Coultis

Turner Valley is in the foothills of the Rocky mountains, at an altitude of 4,000 feet, and is 42 miles south west of Calgary. The present producing area is 8 miles long by 1 1/2 miles wide, while drilling is being carried on over an area of 10 miles by 2 miles . There are 32 wells producing, 26 wells drilling, and 17 wells shut down, making a total of 75 wells, which range in depth from 2,160 feet to 5,900 feet, varying according toa the well location on the anticline centre wells being shallower than those located on the flank. The first indication of possible production in this field was a gas seepage on the banks of Sheep river, in what is now the Royalite plant yard (Figure 1). Geologically, this seepage proved to be located on an anticline running through the valley in a southwesterly direction. The Calgary Petroleum Products Company was formed in 1912, and under the direction of Mr. A. W. Dingman, President, and associates, the first well was drilled. Production was obtained in this well. Gas was found in several horizons from 884 feet to 3,960 feet, and oil at 1,557, 2,718 and 3,839 feet. In May, 1914, oil was struck at a depth of 3,839 feet, this being a light straw-coloured oil of 60 gravity, which was blown spraying from the well accompanied by three to four million feet of gas. The latter contained some 200 grains of hydrogen sulphide per 100 cu. ft., giving it the disagreeable odour so well known in Turner Valley gas. This strike caused considerable excitement and started the famous 1914 boom, when some 400 oil companies were formed. The well referred to produced from two to five barrels of 60 gravity oil per day, and 4,000,000 cu. ft. of gas. The oil was used in the crude form in cars and trucks.

Jan 1, 1929

By P. Zarate, M. Peart, T. Bhambhani, D. R. Nagaraj

More than 50% of all the molybdenum produced in the world is a by-product of copper production. A bulk Cu-Mo concentrate is first produced, which is subsequently separated into Cu and Mo concentrates. The Cu-Mo separation circuits rely on the use of inorganic Cu sulfide depressants such as NaSH, Na2S, and Nokes, which are hazardous, and sometimes require very large dosages for effective depression. Synthetic polymeric depressants are safer and more efficient, and are now being used on the plant-scale. Data presented in this paper demonstrates that these polymeric depressants can replace 50-90% of all the NaSH in Cu-Mo separation at a fraction of the NaSH dosage. In this paper we provide an overview of the mechanistic and practical aspects of the Cu-Mo separation with inorganic depressants and polymeric depressants. Important practical aspects include depression dynamics (related to conditioning time and rate of depression), optimum pH for effective separation, the role of pH modifiers such as lime and NaOH, and the effect of flotation gas on the efficacy of the separation. Using nitrogen as flotation gas, the NaSH consumption can be reduced by up to 95% by using a small amount of polymeric depressant. The experiments with conditioning time demonstrate that there is a significant rate component to the depression mechanism with NaSH, which is absent for the polymeric depressant system. This has important implications in the effective use and application of the depressant. It is also demonstrated that the pH modifier type (NaOH or Ca(OH)2) has no significant effect on separation efficiency and Mo recovery (i.e. Ca2+ ions do not depress MoS2 in the Cu-Mo separation).

Jan 1, 2014

By Paul C. Lingo

Two recent antitrust cases, coming from widely separated areas, different industries and involving wholly different facts were decided by the Supreme Court on June 7, 1965. The decisions in these two cases may well prove to be the most important and far-reaching decisions in the field of labor law that have been handed down in the last 24 years. These cases, although quite dissimilar factually, had one common element. In both, the gravamen of the antitrust violation was bottomed on the terms of labor agreements negotiated by a multiemployer group. These cases are usually referred to as Pennington1 and Jewel Teat. Since a number.-of references will be made to the antitrust laws, it may be well to state briefly the applicable portions. Section I of the Sherman Antitrust Act makes "every contract, combination in the form of trust or otherwise, or conspiracy, in restraint of trade or commerce among the several states, or with foreign nations, is declared to be illegal...". Section 2 imposes criminal sanctions against "Every person who shall monopolize, or attempt to monopolize, or combine or conspire with any other person or persons, to monopolize any part of the trade or commerce among the several states...". Under Section 4 of the Clayton Act a person who sustains damages as a result of a violation of the antitrust laws is entitled to recover treble damages plus costs.

Jan 1, 1965

By D. Pirouzan

It is customary to use more than one stage of flotation to obtain an acceptable level of separation of valuables. Flotation circuit design is usually accomplished by applying empirical rules which usually results in operations not working at their optimum conditions. Given the capabilities of genetic algorithms (GA) in finding an optimum solution in a very disturbed search spaces, they can be used to obtain the desired flotation circuit configuration. In flotation circuit configuration and optimization problem, a combination of metallurgical parameters such as yield and concentrate ash content could be used as the fitness function for the genetic algorithm. The multi-objective nature of the problem justified to use Pareto method to arrive at a set of solutions. The appropriate configuration based on technical or economical considerations could then be chosen. To obtain the fitness function for any given configuration, it is necessary to model every flotation stage. The proposed method was used to find the optimum circuit configuration for a coal washing plant. The objective was to arrive at the highest yield while producing a concentrate with a certain ash content (< 11%). The feed to the flotation circuit was characterized based on the size fractions and their flotation rate constants. Results showed that with a 95% confidence, the absolute difference between the modeled and measured values were 2.9-5.5% for yield and 0.4-1.1% for concentrate ash content. When the proposed GA-based circuit configuration was implemented in the plant, the yield increased from the original value of 57.6% to 65.7% while producing concentrate ash content (10.9%) within acceptable limits. By adding one stage to the current three-stage circuit, it was predicted that the yield could further increase by 3.8% while keeping the quality of the concentrate within the appropriate level. Keywords: modeling, optimizing, flotation circuit configuration, genetic algorithms

Sep 1, 2012

By Ryszard Prajsnar

During copper production in shaft and flash smelting processes at KGHM Polska Miedz S.A., lead bearing material of sulfide, sulfate, and oxide character is generated in forms such as slime from shaft furnace gas handling systems, converter dusts, and dusts from an electric furnace for copper removal from flash smelting slag. These materials are polymetallic concentrates of Pb, Zn, and Cu, with As, Cl, and Cd as impurities. Shaft furnace slime, containing. about 50% PbS and 15% bituminous substances, is the main lead-bearing material. At the Glogów copper mill, a new plant was commissioned in June 2001 to process 80,000 tonnes per year of lead bearing materials to produce 26,000 tonnes per year of crude lead. The plant consists of a feed conditioning system, three (3) rotary rocking furnaces with a capacity of sixteen (16) tonnes of lead feed fired with natural gas and oxygen-enriched air containing up to 45 vol% O2, and a gas handling system. The gas handling system includes a post-combustion chamber, a gas cooling chamber with Cl neutralization, gas mixing chamber, bag filter, and dry limestone scrubbing system for SO2 removal. The lead-bearing feed is smelted with five (5) wt% Na2CO3 and thirteen (13) wt% iron scrap at a temperature of 950 to 1050°C for three (3) hours. The smelting process consists of four (4) stages; feed drying, firing of gaseous hydrocarbons and solid coal from the feed, lead reduction from slag, and separation of molten products. The flow rates of natural gas and oxygen to the burners are controlled to ensure combustion of the bituminous material in the furnace. The process produces crude lead bullion containing (wt%) 0.1 to 0.5% Cu, 0.02 to 0.5% As, 0.05 to 0.07% Bi, 0.1 to 0.5% Sb, and 0.1 to 0.6%Sn. The process also produces a mixture of sodium silicate slag, Fe-Zn-Pb-Cu-S matte, and Fe-As speiss containing (wt%) 5 to 10% Pb, 2 to 6% Cu, 10 to 15% Zn, 1 to 3% As, 10 to 15% S, 0.5 to 3.0% Cl, 2 to 4% K, 4 to 7% Na, 20 to 30% Fe, and 5 to 10% SiO2. The dust is made up of PbO, ZnO, PbSO4, and PbCI2, KCI, and NaCI with a chemical composition (wt%) of 35 to 50% Pb, 5 to 15% Zn, 3 to 6% As, 4 to 8% Cl, 2 to 5% K, and 2 to 5% Na. The construction of the new lead production plant at the Glogów copper mill will process both current lead-bearing materials as well as lead-bearing material that have been stockpiled over the last fifteen (15) years to give a significant improvement in protection of the natural environment.

Jan 1, 2002

Four data sets are required to put constraints on the tectonic evolution of the southern rim of the Pacific Ocean basinI . data bearing on the dispersal of the major Gondwanaland continental fragments and the birth of the Southern Ocean,2. data bearing on the interaction of the Pacific Ocean basin lithosphere with the South American, Antarctic, and Australasian continental masses,3. data bearing on.the evolution of the Scotia Sea floor, and 4. data bearing on the evolution of the various continents, microcontinents. and volcanic arcs.

Jan 1, 1990

By René Winand

A new process was studied at large laboratory scale at Université Libre de Bruxelles, under contract with Metallurgie Hoboken-Overpelt. A two cathodes (1m long ; 0.2 m high) channel cell was used at 2000 A/m2, with an electrolyte flow rate up to 1.8 m/sec. The main results may be summarized as follows : cathodes are electro¬refined grade in analysis ; metallographic structure and surface roughness are kept under control up to 1.3 cm (one side deposits) ; silver in cathode is controlled by CI and Br ions in solution ; organics must be used at very low concentrations (in the range of 0.1 mg/1, with a consumption of about 0.01 mg/lh).

Jan 1, 1987

By George W. Bain

Deposits of metals in only slightly disturbed strata have been attributed to sedimentation processes contemporary with deposition of the strata. Recently this origin has been extended&apos; to a greater variety&apos; of deposits and local enrichment has been attributed to selective remobilization of metallic minerals in the host stratum. Effects attending metallization and deformation, and exact age&apos; of the metallization are compiled to establish the sequence of events in ore deposit histories in order to clarify importance of remobilization within a formation relative to introduction from an outside source into an fav¬orable host. The pertinence respectively of deposit; origin and geometry to the work of the mining geologist is reviewed. Dwarf faunas in the Clinton iron ore, Tully pyrite bed and Rammelsberg deposit, indicate abnormal metal ions in the sedimentary environment. Slight¬ly disturbed strata are host rocks in the Swedish Kolm, Timna, Kupferschieffer, and White Pine deposit; the latter two have ore only in conjunction with tectonic structures.

Jan 1, 1966

By Mark Vardy, Kasia-Leigh Chidlow, Tim Minshull, Jeorg Bialas, Sven Peterson, Bramley Murton, Alba Gil

Since the discovery of the first black smoker on the East Pacific Rise in 1977 (Francheteau, et al., 1979), the hydrothermal vents, now called seafloor massive sulphides (SMS) deposits, have generated great interest in the geological community, especially regarding their formation and composition. SMS deposits are areas of hard substratum, with high base metal and sulphides content, that form through hydrothermal circulation and are commonly found at hydrothermal vent sites. The high base metal (Fe, Cu, Zn, Pb), sulphur-rich mineral content has interested mining companies, due to their potentially high economic value. Currently, the known SMS deposits do not have the same dimensions as the massive sulphides (MS) found on land (covering just 10s to 100s m2) and pose significant mining challenges (being located in water depths between 800 m and 6000 m), meaning that they do not appear to be economically exploitable at present. However, these deep-sea mineral resources could be important targets in the near future, particularly with our ever-increasing demand for base metals. A key aim of the European Union-funded Blue Mining project is to develop techniques to robustly quantify SMS deposits dimensions (both surface expression and subsurface extent) and therefore assessing the suitability of SMS deposits for future economically viable and environmentally clean deep-sea mining operations.

Jan 1, 2017

By R. R. Hart, R. A. Evans

This paper outlines the the methods currently being used in the West Wales Area for preventing the occurrence of any outbreak of spontaneous combustion. Stress is placed on the importance of correlating the position of a Rider Seam which is prone to spontaneous combustion. The recent introduction of the UNOR Recorder has contributed to the ability to monitor the CO content of the general body of the air during any incident. The use of modern sealants and improved methods of applying them have enabled the few instances of spontaneous combustion in South Wales to be treated promptly and efficiently. The authors describe the current spontaneous combustion problems at two collieries.

May 23, 1905

By H. C. Carpenter

This literature study of methods for desulfurizing residual fuel oil was conducted by the Bureau of Mines at the request of the Department of Health, Education, and Welfare. The sulfur compounds in residual fuels are believed to consist chiefly of condensed thiophenes and other polycyclic sulfur compounds. Hydrodesulfurization appears to be the most promising method for desulfurizing these oils and is the only method applicable to all types of sulfur compounds. There are indications in the literature that hydrodesulfurization without hydrocracking of residual oils may require higher pressures than used in present desulfurization processes, but no cost data and little experimental data are available on the higher pressure operation. Literature proposals for hydrogenating residual oils and heavy crude oils are exclusively for hydrocracking the oils to lower boiling products with accompanying partial desulfurization of the residual fuel fraction. Costs of the hydrocracking operations appear the closest available to probable costs of hydrodesulfurizing the oils, and have been reported (in 1955 to 1957) as $500 to $840 investment cost per daily barrel of capacity, with total operating costs of 70 cents to $1.10 per barrel.

Jan 1, 1963

By Chu E. Ho, Paul Napoli

This paper presents the performance of nineteen open-ended steel pipe piles driven through highly variable overburden soils into glacial till and schist bedrock. The piles were 16 inches in diameter and 0.656 inches thick, with yield strength of 50 ksi. The piles were designed for a service capacity of 250 kips and were driven to achieve an ultimate geotechnical capacity of at least 500 kips. Due to the large variation in the ground conditions, installed pile lengths ranged from 25 to 66 feet. Some piles were driven to refusal on the bedrock while others were terminated at final driving resistance of 2 to 7 blows/in. Two piles were suspected to be plugged during driving while others did not. Each pile was instrumented with strain gages and accelerometers near the pile top, and observed using a Pile Driving Analyzer (PDA) to provide preliminary guidance on pile capacity achieved at end of initial drive (EOID). The influence of plugged and unplugged pile toe conditions on the interpretation of pile capacity was investigated using Case Pile Wave Analysis Program (CAPWAP). Characteristics of driving energy, compressive and tensile stresses developed in the steel pipe piles, and the resulting pile deformation behavior are discussed. INTRODUCTION The Hunters Point South redevelopment in Long Island City, Queens is one of New York City’s major efforts to transform former manufacturing zones into mixed developments for the middle-income community. The site is located along the eastern shoreline of the East River and Newtown Creek. The development included low to high-rise residential buildings, a public school and retail structures. Open spaces were created along the East River and Newtown Creek waterfronts in the form of a continuous park providing for recreational and community related activities. Waterfront structures included small park buildings, walkways and viewing platforms with the shoreline protected by revetments as part of the City’s flood mitigation strategy. The project was implemented in two phases, with completion of construction for Phase 1 in 2013 and Phase 2 in 2019. Based on available historical information, extensive reclamation took place between 1855 and 1898. After 1951, changes to the shoreline were made along the East River, including the removal of reclaimed land along the northern portion of the project site to allow for docking facilities. By 1977, these facilities had been demolished and backfilled to form the current shoreline configuration. The present site was temporarily used as a parking lot with stockpiles of fill mixed with construction demolition rubble, rip-rap and boulders of varying heights across the site. The existing ground surface varied significantly up to approximately 25 feet difference in elevation. The stockpiles were removed and the site was re-graded during final development of the project. This paper discusses the foundation design challenges due to the loose overburden soils and potential obstructions within the fill material, in particular, the issues relating to installation of open-ended steel pipe piles through the ground conditions encountered on site.

Jan 1, 2019

By Ramani R. V

There are many important physical phenomena in mine ventilation which involve transient mass and heat transfer processes. These processes have been modeled using differential equations often solved with close form solution. Within the last two decades, many numerical schemes have been devised to solve these mass-transfer problems. Much of this effort has focused on variants of the finite element and finite difference methods. In this paper, the solution of mass transfer models in mine ventilation by finite difference technique is discussed. Specifically, the computational effort and the accuracy of the solution are presented.

Jan 1, 1988

By William C. McBee

Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the mineral aggregates also come into contact with the corrosive media, concretes were developed utilizing both limestone and quartz aggregates. The sulfur binder used with both aggregates was modified by reaction with 5 pct dicyclopentadiene to improve product durability. Sulfur quartz aggregate concrete was found to have moderately high strength characteristics (6,000 psi compressive) and was extremely resistant to chemical attack by both acid and salt solutions. Sulfur limestone aggregate concrete exhibited very high strength characteristics (9,000 psi compressive) and was extremely resistant to chemical attack of salt solutions. Both types of concretes maintained their strength and integrity after long-term testing in acid and salt solutions and exhibited considerable resistance to damage by the action of freezing and thawing. Potential uses include leach tanks, electrolytic cells, thickeners, bridge decking, industrial flooring, pipe, and tile.

Jan 1, 1979

By Q Fan

The steelmaking desulfurisation plays an important role in coal-based steelmaking route of blast furnace and BOF converter within the flow sheet of BF-deS-BOF. With the advent of H2-based ironmaking and steelmaking process, the transition flow sheet of DRI-Smelter-BOF has been assessed and developed by the steelmaking industry. What is the role of deS in H2-based route of DRI-smelter-BOF? This paper will present the influence of sulfur-containing iron ore on steelmaking desulfurisation and the leading role of EAF-smelter played in H2-based steelmaking route. The sulfur contents of iron ore vary considerably around the world and lower-grade iron ores with high sulfur are likely to be used for H2-based route, a considerable amount of sulfur that comes from DRI will report to the melt of EAF-smelter and the operating conditions of EAF-smelter also impact the sulfur content of the hot melt for steelmaking deS. The EAF-smelter of H2-based route is the focus of the steelmaking industry at moment, unfortunately, an industrial-scale EAF-smelter has been the missing link of the flow sheet of DRI-Smelter-deS-BOF, despite similar EAF-smelters being used for various applications of Fe-Ti and Fe-Ni processes. The latest progress is that several pilot-scale and industrial-scale EAF-smelters with reducing capability are planned for construction within next several years and low-grade Australia iron ores are certainly to be employed as basic feedstocks for H2-based route of DRI-Smelter-deS-BOF.

Sep 18, 2023

By John Henderson

If you missed this year?s Texas State Holmes Safety Association meeting, you missed a great one. On January 23 & 24, 2009, we held the meeting that was rescheduled when Hurricane Ike threatened Corpus Christi in September 2008. Sixty-five persons from across the state attended the meeting held at the Holiday Inn Emerald Beach. The weather was 82 degrees, and the sky was clear and perfect for a safety meeting. Evaluations submitted by the attendees gave the presentations, the networking, and even the food top marks. There were eight councils represented; Big Country, Central Texas, Costal Bend, Heart of Texas, Hill Country, North Texas and North Central. Presentations included Workplace Examinations, Emergency Preparedness, Screen Safety, Contractor Responsibilities, Powered Haulage, Supervising for Safety, and Basic Inspections of Slings and Rigging. Mr. Edward Lopez, SC MSHA District Manager, gave the State of the District Address.

Feb 1, 2009

By Orris C. Herfindahl

Every few years we are treated to a battle over trade policy when the Reciprocal Trade Agreements Act comes up for consideration. In 1962 it is especially appropriate to consider the problem of mineral import -policy and the closely related problem of general import policy, for this year&apos;s struggle is different from those of the past in two ways. First, proposals have been made which are a substantial departure from past trade agreements legislation, and second, the formation and growth of the Europe Economic is Community may have an important bearing on the kind of legislation that is adopted. But this anticipates what is to come later. My task is to examine the problem of mineral import policy, although we shall find soon enough that general trade policy must be considered in order to get an indication of what is in store for minerals.

Jan 1, 1962

By J. P. Harrison, M. Grenon

"This paper summarizes the results of numerical studies on drift stability in moderately jointed rock masses. It investigates the relative pertinence of geomechanical factors such as joint orientation, spacing and stress regime. This is undertaken using a distinct element model and a series of parametric studies. IntroductionIn evaluating the stability of drifts in jointed rock, it is often necessary to compromise by employing models that capture the complexity of the rock mass, but which are still simple enough to allow for their routine implementation. The distinct element method can arguably provide an eloquent method to accomplish this. This paper explores the applicability of the method by means of a parametric study aiming to identify the dominant factors that influence the stability of drifts in moderately jointed rock. To this end a commercially available 2D distinct element numerical model was used. A series of techniques are presented in an effort to quantify the results of any instability predicted by the model.This paper also demonstrates a case study where a 3D joint network model was integrated into the distinct analysis software package. The advantages, as well as the current limitations of this approach, are discussed."

Jan 1, 2001

By M Orunesu Preiata

The Odysseus Project is part of the high-grade Cosmos Nickel Complex that lies 30 km north of Leinster. The Odysseus definitive feasibility study (DFS) was approved by the Western Areas’ board in October 2018. Early works commenced in January 2019 with rehabilitation of the existing underground infrastructure. In June 2022 Western Areas was acquired by IGO Ltd. The project is now well advanced to meet its target of first concentrate. The project included the construction of a haulage shaft. The design of the hoisting equipment and the shaft barrel evolved from the initial DFS design stage to the final execution, as the data were made available from the initial investigation to the data gathered during execution (although this did not change from its initial concept). The design philosophy for the haulage shaft incorporated, from the beginning a multidisciplinary approach with inputs from three main areas involved in such projects, namely excavation techniques, geotechnical assessments, and infrastructure construction. This interaction is a fundamental component for the success of such a critical project. In fact, each of these three areas influences each other in a cyclical manner, triggering a continuous review of the project inputs and outputs, while maintaining the original project goals: the design of an infrastructure able to deliver the desired throughput. The throughput dictates the infrastructure that needs to be built, which in turn controls the size of the shaft. The key assumption applied to this is that the rock mass can accommodate the excavation void, and the excavation technique with its tolerances and limits that ultimately need to be verified back with the initial assumptions used for the infrastructure design. The aim of the paper is to present a case study of the experience gained with the Odysseus hoisting shaft and to propose a possible logic path for similar projects elsewhere.

Mar 29, 2023