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By Pier-Lorenzo Solari, Philippe Moisy, Michel Schlegel, Stephane Pellet-Rostaing, Eric Mendes, David Bengio, Richard Husar, Thomas Dumas

Ionic liquids (ILs) are molten salts composed of an organic cation that are liquid below 100 °C. They demonstrate unique physico-chemical properties such as good conductivity, negligible vapor pressure and non-flammability. As a consequence, they are often regarded as green solvents and could become an alternative to the use of both high-temperature molten salts and volatile organic solvents in rare-earth elements processing and recycling. The diversity of interactions existing in an ionic liquid allows the solubilization of both polar and apolar compounds. Moreover, coordinating functions on their composing ions can lead to stabilization of some species. For instance, in non-aqueous media, europium exists in the (II) oxidation state which is not stable in aqueous solutions. Understanding the mechanism of Eu(III) electrochemical reduction to Eu(II) and the stabilization of Eu(II) species in IL media could be of major interest for the development of innovative recycling processes. Using transient electrochemistry and UV-Vis spectroscopy we could get valuable information on the redox behavior of the Eu(III)/(II) couple in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([EMIm][NTf2]). Reduction of Eu(III) to Eu(II) and stability of Eu(II) was also studied thanks to a XAS-spectroelectrochemistry set up used to follow in situ the evolution of the XANES spectrum around the L3 edge of Eu during electrolysis.

Mar 1, 2018

By Alfred H. Brooks

LESS than a decade ago the consumption of coal in Alaska was practically limited to the salmon canneries and the few lode-mines and settlements along the Pacific coast of the Ter¬ritory. The sparse population of the interior depended on the forests, that of the shores of Bering Sea and the Arctic Ocean on driftwood for fuel. All this has changed. The thousands who have sought and mined gold on the Seward peninsula since 1898 have much impoverished the long-accumulated supply of driftwood, and at the same time the constantly increasing demand for fuel, on the part of the placer-camps and steamers, has resulted in heavy inroads being made on the accessible timber of the Yukon and its tributaries. While on the one hand the immediately available store of wood has decreased, on the other the consumption of fuel because of the rapid expansion of the mining and fishery industries and the attendant growth of population has much increased. Alaska, therefore, offers a constantly growing market for coal and other fuels. As the local coal-production has been insignificant, the demand has been met by importations from Washington, British Columbia, and even from Pennsylvania and Australia. Fuel-Consumption Mr. D. H. Jarvis, Collector for Alaska, has kept systematic records of the trade of the Territory since 1903. The statistics of the coal-importations of the past two years are shown in Table I. If data were available for a longer period of years, the increase of coal-importations would be much more striking.

Jul 1, 1905

By Martin Knights

The UK Industry is preparing a new guide on Tunnel Asset Management that reflects current industry advances, in developed technological innovation and evolving tunnel asset owner requirements. This will enable asset owners to have a trusted practical guide that can support technical and commercial decisionmaking regarding tunnel assets and aging infrastructure. It will also provide updated guidance for a spectrum of stakeholders including: • Consultants. • Contractors. • Planners, insurers. • Academia. • Government. Industry views will be crucial in the preparation of the Guide that will assist proactive & predictive planning and maintenance regimes and the availability of the asset. The Guide will enable changes in current working practices, share updated recommendations and provide a route map to implement future requirements for tunnel asset management. The generic content of the Guide would be applicable to North American practice.

Dec 1, 2022

RÉSUMÉ Cet article traite d’une analyse technique et économique du concept du triage optique en vue d’améliorer la rentabilité des opérations minières. Le principe du tri optique et les principaux systèmes et modules servant au fonctionnement de l’appareil de triage sont décrits. un modèle a été développé pour analyser l’intérêt économique d’une opération de triage optique. L’étude est basée sur des données provenant d’une halde de minerai à faible teneur en or, déposé à la surface, et de minerai extrait des opérations souterraines courantes de la mine Beaufor au Québec. Les résultats de cette analyse indiquent que l’opération de triage optique permet d’améliorer grandement la performance économique; l’opération devient alors rentable pour des teneurs en or relativement petites.

Jan 1, 2010

By M. Hertzberg

The Bureau of Mines measured the energy requirements for the spark ig-nition in air of Pittsburgh seam bituminous coal dust, lycopodium spores, and polyethylene powder with a 1.2-L furnace and 8-L and 20-L chambers. Thermal autoignition temperatures of the same dusts were mea-sured in the 1.2-L furnace. Electrical ignition requirements are given in terms of both effective spark gap energies, [ ] and stored circuit energies, 1/2 CE2. The measured order of electrical ignitability for the three dusts is consistent with the data of other researchers; however, the absolute values are systematically higher, probably because of higher flow and turbulence levels in the chambers used and lower electrical efficiency in the circuit used here. The temperature dependence of the lean limit of flammability for lyco-podium was measured wi th the 1.2-L sys tem, and those measurements con--firm the applicability of the modified Burgess-Wheeler law to a dust. Due to experimental complexities, the minimum ignition energies for dusts may not reflect intrinsic flammability behavior. However, some valuable information may be obtained from the relative ignition energies of various dusts at ambient and elevated temperatures. In addition, the concept of minimum electrical ignition energies for homogeneous gas mixtures is reevaluated theoretically.

Jan 1, 1985

By A Lyon

The minerals industry, as many other industries, has a wealth of indicators and a thriving æindustryÆ in their development, measurement and reporting. It is natural for this to occur for a new endeavour. However, perhaps it is time for the community concerned with minerals industry indicators to ask whether we have achieved a certain maturation whereby proliferation of indicators may be replaced by a more disciplined and constrained approach. In many natural and engineered systems, thermodynamics provides well-understood and tested constraints. Indicators that are uninterpretable in this framework are not considered acceptable. This paper provides initial evidence that such a formalism may be possible for mine sustainability. The formalism developed does not claim to have the rigour of thermodynamics. However, it does provide a first step towards formalising selection of indicators on the basis of their true comprehensibility. A set of simple equations is developed that represent the conventional five capitals (actually we use six because we separate renewable and non-renewable natural capital) and how they are linked. This is coded into a simulation model. The base equations are then used to develop a system level indicator of sustainability performance, which is asserted to be a reflection of the mineÆs reputation. We define a least sustainable state, termed æmaximum revenue mining (MRM)Æ in the system and define the degree of system sustainability as how far the system is from the MRM. We then introduce a simple mechanism whereby different actors can express differing views on the emphasis for the distance from MRM. Sustainability thereby becomes a non-unique thing that is defined by a distance from MRM and a set of preferences across the capitals.

Jan 1, 2009

By M. T. Ityokumbul

The liquid phase mixing in Western Research Centre (WRC) pilot plant flotation column with diameter of 0.76 m has been characterized using a salt tracer. The process variables studied were gas and liquid flow rates. The response of the column to a tracer pulse input was monitored at three axial and two radial locations. For all the experimental conditions investigated in the present study, radial and axial concentration gradients were not observed. It is thus concluded that the 2 tph flotation column is behaving as a well mixed tank. This finding is consistent with the observed poor recoveries of coarse fractions in the column flotation circuit. Based on the findings of this report, it is recommended that several schemes of reducing the backmixing be implemented and evaluated for their effectiveness in improving the column recoveries.

Jan 1, 1994

By Víctor R. Cabrera

Para un mayor avance en su producción, las minas de cielo abierto u "open it" de Marcona, utilizan unidades de mayor tamaño en el transporte, puesto que reduce el costo unitario del trabajo. En este aspecto, el objetivo del trabajo describe el uso de máquinas comprendidas para su uso, rendimiento de costo, pala, control de tiempo, tiempo de operaciones y el trabajo con traillas dentro de esta modalidad. etc. Como primer punto, las máquinas cargadoras, las palas mecánicas, etc, incrementan su tamaño constantemente y como tal, las operaciones de transporte cambiaron de uso de ferrocarril a de los camiones con 10,15, 20. 30 y 50 tonelajes por viaje. Posteriormente con el advenimiento de motores diesel, diseño, construcción, perforación y transporte de las máquinas cargadoras, se creó una minería de cielo abierto más económica, flexible y eficiente. En este punto, las operaciones estacionarias, sea con palas o las perforadoras de voladura, utilizaron preferiblemente la energía eléctrica que simplifica la operación y facilita el mantenimiento y las reparaciones. Mientras que las operaciones de perforación, voladura, carguío y acarreo se analiza las características de toneladas rotas por perforación, los cálculos de sobreperforación, los materiales explosivos usados, respectivamente. En cuanto la extracción de palas y volquetes, se evalúa la calidad del disparo, número de voloquetes, capacidad horaria. Finalmente en el trabajo con traillas, se evalúa la influencia del costo de las demoras relativas en las palas y los volquetes, pérdidas de la capacidad potencial de la pala cuando hay insuficiencia de volquetes, asi como las variaciones de la capacidad según la distancia de acarreo.

Jul 20, 1956

By David K. Sitler

Continuing advances in manufactured diamond materials used in rock cutting tools have created a new generation of high production tools for mining. This paper will review the three major manufactured diamond products available for the mining industry as supplied by General Electric Company, Specialty Materials Department, and examine the ways in which these materials are employed. As an integral part of this examination, the economic impact of manufactured diamond tools will be evaluated. Time and again, one will find that the premium price of these tools is economically justified when compared to traditional tools.

Jan 1, 1985

By Atta Ur Rehman, Kwame Awuah-Offei

This work evaluated the effect of bucket orientation and operating parameters on resistive forces and penetration for rubber tire loaders. The work used a 1:16 scale LHD model to test a rubber tire loader (RTL) bucket operating at different levels of tractive effort, speed, digging height, and rake angles in a full factorial design experiment. The work repeated the test on two different muck piles with different particle sizes and used generalized regression modeling to test the association of rake angle, tractive effort, speed, and digging height on penetration and resistive forces for RTL buckets. The results show that speed and tractive effort are more important in explaining RTL penetration and resistive forces than height above the floor and rake angle. Speed, tractive effort, and height above the floor are positively correlated to bucket penetration, whereas the rake angle is negatively correlated to penetration. Similarly, speed, tractive effort, rake angle, and height above the floor are all positively correlated to resistive forces incurred during initial penetration. The observation that the combined effect of speed and tractive effort is negatively correlated to penetration and resistive forces is a novel contribution that enhances our understanding of RTL loading. The results also show that the effect of speed, tractive effort, and height above the floor all change with changes in particle sizes. This work adds to the literature on the effect of rake angle, height above the floor, tractive effort, and speed on penetration and resistive forces for rubber tire loaders.

Aug 24, 2020

By Luis Velásquez

El shotcrete reforzado con fibras de acero es un conjunto discreto discontinuo de fibras de acero contenidas en el concreto, los cuales son proyectados neumáticamente a altas velocidades sobre una superficie. En este sentido, el presente texto describe la importancia de dicha materia prima -en tanto otorga resistencia a la rotura y es un esfuerzo estructural del shotcrete en las operaciones mineras. Al tiempo que reduce el empleo y tiempo de la mano de obra, así como contribuye la seguridad del personal minero.

Sep 14, 2009

By Richard H. Johnson

White Pine Copper Company, a subsidiary of Copper Range Company located in Michigan's Upper Peninsula, mines a Precambrian sedimentary deposit containing finely disseminated chalcocite, native cop- per and native silver. Silver occurs predominately in certain strata and presently provides a mill head averaging 0.25 ounces per ton. This technical publication traces the development of silver recovery at White Fine beginning in early 1961. White Pine refined copper contains an excess of silver over and above that required to impart Lake Copper properties. The copper does not require electrolytic refining to meet industry purity requirements, nor is there sufficient silver to justify electrolysis.

Jan 1, 1970

By J. Starwood

Post-super-cycle mining executives must exploit every aspect of the value chain to deliver continued value to stakeholders. Integrating enterprise-wide information technology with value-chain-wide operational technology, known as IT-OT integration, is essential to extracting optimal results from the value chain. Mining companies trail other industries with respect to IT-OT integration across the value chain. Manual data consolidation and value chain optimization using spreadsheets and human intelligence are widespread practices within the industry. Increasing automation with smart devices and controllers means the volume and velocity of data will soon increase beyond human abilities. Enterprise Architecture provides a method for aligning information technology with the business operating model to successfully implement IT-OT integration. A Value Realization Framework (VRF) provides a means for predictable traceable value realization from IT investments and assets. With these principles, frameworks, models, methods, and techniques, mining organizations can accomplish IT-OT integration that provides their executives with a strategic value-chain-aligned platform for sustained value realization over the long term.

Feb 23, 2014

By R. Perlman

This paper describes the various new computer-aided techniques being used by economists in the construction of economic models. It discusses the relevance of these techniques to mining industries. In particular, it describes their role in making it possible to obtain better estimates of future price and demand developments on the markets on which metals are sold, and how these estimates can be used to improve forward planning by mining companies.

Jan 1, 2014

By R. B. Anderson

As a part of a Bureau of Mines program on the conversion of coal to liquid and gaseous fuels, the kinetics of the Fischer-Tropsch synthesis on iron catalysts was investigated. Nitrided catalysts were studied at 21.4 atmospheres using feed gases ranging from 2H2+1CO to 0.25H2+1CO, and at 7.8 to 21.4 atmospheres using 1H2+1CO gas. The overall apparent activation energy increased with increasing carbon monoxide content of the feed gas from 19.5 kcal/mole for 2H2+1CO to 23.7 for 0.7H2+1CO. The rate of synthesis with 1H2+1CO feed increased linearly with operating pressure from 7.8 to 21.4 atmospheres. A semifundamental rate equation of the form [r=a'PH2 0.6pco 0.4- ?r0.5PH200.5] was shown to fit the data satisfactorily. The relative usage of hydrogen to carbon monoxide decreased with increasing conversion, passed a minimum, and then increased. Apparently water is the principal primary product and carbon dioxide is produced by subsequent water-gas shift reaction. In another group of experiments water, carbon dioxide, argon, and methane were added to 1H2+1CO feed to a nitrided iron catalyst. Argon and methane were only diluents. Carbon dioxide was a slight inhibitor and water vapor was a strong inhibitor to the rate of synthesis. Water accelerated the water-gas shift and usually increased methane production. Important factors of catalyst geometry in determining rate were found to be particle size and extent of reduction. Apparently the active portion of the catalyst is confined to a layer of 0.01 to 0.02 cm from the external surface of particles. A special solution was made of differential equations relating re¬action at the catalyst surface to diffusion in pores of the catalyst for spherical particles with an active layer surrounding an inert core. The equation derived expressed the experimental data reasonably well. Diffusivities determined by this equation varied from 3 to 24X10-6 cm2/sec; these values are of the same magnitude as observed for the diffusion of gases in liquid. The appendix presents a group of synthesis experiments at pressures of 21.4 to 103 atmospheres. In this range the rate of synthesis on nitrided iron catalysts increased with pressure to the 0.74 to 0.84 power.

Jan 1, 1964

By Alla D. Mah

THERMODYNAMIC data for manganese and its inorganic compounds have not been critically surveyed since the work of Maier (31) 3 in 1934. At that time data were lacking or inadequate for many of the important metallurgical compounds. Experimental work, conducted during the intervening years, has supplied so many new thermodynamic values that it is again desirable to examine the available data and compile them into a single publication for handy reference. This paper consists of three main sections. The first summarizes the basic metallurgical thermodynamic data for manganese and its compounds, including heat capacities, entropies, heat contents, temperatures and heats of phase changes, vapor pressures, and heats and free energies of formation. All data available to May 1959 have been considered. The second section contains heats, free energies, equilibrium pressures, and equilibrium constants of reactions of manganese compounds, with special emphasis on metallurgical reactions. The third section supplies basic thermodynamic data for other elements and compounds encountered in metallurgical reactions of manganese, thus making it possible for the reader to conduct thermodynamic calculations without recourse to other literature.

Jan 1, 1960

By P J. Willems, B J. Junor

Blackwater Mine is in the central-southern Bowen Basin, immediately south of the township of Blackwater on the Capricorn Highway. The current open cut operation extracts coal from three main seams, designated Top, Middle and Lower, in the Late Permian Rangal Coal Measures cropping out on the eastern flank of the Comet Ridge. Complex geological structures, dominated by E-W normal faults and N-S reverse faults, have significant detrimental effects on coal mining operations. Historical exploration before 2010 involved several types of drilling only to understand structure, coal quality and washability. Hence, although drilling data was combined with limited pit mapping and observation, unknown structures were still often encountered during excavations and led to mining surprises. In 2010 BHP completed 200-line km of closely spaced 2D seismic survey to capture gross and detailed structures followed by fit for purpose structural drilling to confirm major structures in the northern part of the mine. In 2018 a high density 9.2 km2 3D seismic survey was completed in the southern part of the mine. Subsequently, a 17.2 km2 survey was completed in 2020 to cover the northern active mining area. It allowed geoscientists to successfully map previously unknown major faults and seam splits, which could potentially impact the mineability of the area. It is important to note, that faults interpreted using modern high-density 3D data can be interpreted with dramatically higher confidence in the fault dip and azimuth orientation in comparison to the legacy 2D data. Along with targeted drilling, pit mapping and structural interpretation, the outcome adds value to mine planning and operations. This paper outlines recent successful seismic 3D data acquisition and interpretation. In detail, the paper presents case studies on how the data can be incorporated into a structural model to improve geological knowledge, enable geotechnical assessment, and support safe and efficient coal mining in a large and structurally complex mine.

Mar 22, 2022

By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

By . José Arango O

El presente trabajo describe las nuevas técnicas de lixiviación aplicadas en Cerro Verde ante un posible desabastecimiento del mineral en un futuro y por ende, ocurra un alza de costos en el tota de la producción. En este sentido, se implementa nuevas técnicas en el el sistema como la lixiviación con curado, la lixiviación en capas delgadas y el retratamiento de los pads, las cuales prolongan la operatividad de sus plantas y mejoran el nivel de ingresos de divisas.

Nov 8, 1984

By Ben E. Lindsly

The study of "bottom-hole' samples follow,-is in natural sequence the study of samples3 obtained under high pressures at the well heads of flowing wells. The principal object of this phase of gas-solubility research, started actively in January, 1530, was to gain a more accurate knowledge of the physical and chemical characteristics of the oil-gas mixtures that exist in natural reservoirs. In possession of actual data regarding the condition of the oil; the quantity of gas liberated from solution upon dimunition of pressure; and the relative volumetric proportions of gas to oil at various pressures throughout the flow string in a well, it should be possible to predict, with a fair degree of accuracy, what physical changes these mixtures would undergo throughout the life of a pool. Such information not only is important in designing flow strings in flowing wells but is important also in solving problems relating to pumping efficiency and the power required for pumping. Although certain fundamental rata Mere obtained in the stud of samples taken at the well head, "bottom-hole" samples are more representative of subsurface mixtures of oil and gas because they are obtained at reservoir temperatures, and before the oil has had the opportunity of intermingling with extraneous gas; that is, gas which either was not in solution originally, or which was liberated from solution at some higher pressure, and later became mired with the original undissolved gas.

Jan 1, 1933