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By De-qing Zhu, Feng Zhang, Jian Pan

Sintering performance of a series of sinter blends with high ratio of limonite was investigated. The metallurgical performance and mineralogy of product sinter were also examined. The results show that good sintering performance could be obtained when the ratio of limonite was below 43% in the blends of iron ore fines, while good microstructure and metallurgical properties were achieved under optimum sintering conditions. In contrast, sintering performance will rapidly deteriorate when the ratio of limonite is elevated up to 63% in the blends.

Mar 1, 2017

By Norman Schapiro

Future ore bodies will, most likely, be more costly to find, mine and process than those now in production because most of them will be of lower grade or found deeper. To evaluate an ore deposit for extraction of metal values it is important to select the optimum economic process from among the many available options. The physical and chemical behavior of the minerals present should govern the process selection. Process mineralogy which combines mineralogy and petrography with process development engineering generates the data on mineralogy, composition and texture of gangue and valuable minerals from which the optimum process steps can be selected in the commercial design of the ore processing plant. These insights also help in solving operating problems caused by changes in the ore body

Jan 1, 1981

By Jianhang Hu, Li Yang, Yonggang Wei, Kongzhai Li

"In this paper, the pyrolysis of biomasses including bamboo, sawdust and walnut shell were performed in a tube furnace under temperatures between 400? and 600? to obtain biomass carbon, gas, and tar. Textural parameters analysis revealed the caloric value of biomass carbons between 32 MJ/kg and 34 MJ/kg. It also indicated that the surface of biomass carbon consists of mesopore and macropore structures. By using GC analysis, it was determined the main ingredients of pyrolysis gas are CO, H2, CO2, CH4, C2H4 and C2H6. Calculation states that the density of pyrolysis gas is roughly between 1.0 kg/m3 and 1.7 kg/m3, while the calorific value of pyrolysis gas is between 12000 kJ/m3 and 16500 kJ/m3, illustrating that pyrolysis gas is a median gas. The calorific value of biomass tar was found to be between 32 MJ/kg and 34 MJ/kg, with more than 80 compounds in the biomass tar identified by GC-MS method.IntroductionBiomass as a renewable source is the world's largest and most sustainable energy resource [1].The conversion of biomass has the potential to be a renewable and carbon neutral method of producing fuels and chemicals [2-4]. Pyrolysis is a thermo-chemical process defined as applying heat to degrade biomass in an inert atmosphere. It transforms unstable biomass and other organic materials into biomass carbon, gas, and tar [5]. Biomass carbon can be stored or transported much easier as compared to parent biomass or be converted to value added products such as activated carbons[6]; gas is a relatively low-energy-density fuel; tar can be considered as a source of useful chemicals[7].The characterization of biomass pyrolysis will lead to its increased understanding and utilization as a source of solid, liquid and gaseous products which can be used as fuels and petrochemical feedstock[8,9].In recent years, many researchers studied the effect of temperature on biomass pyrolysis product distribution characteristics in a variety of pyrolysis reactor[10]. Ramin Azargohar's paper [11] presents the results of characterization for biomass and investigates the effects of pyrolysis temperature on the pyrolysis products obtained by fast pyrolysis of four different types of biomass."

Jan 1, 2014

By Zhucheng Huang, Lingyun Yi, Bin Chai, Tao Jiang

"A high iron content manganese ore was reduced at 900~1200°C and followed by a magnetic separation process. SEM and EDS analyzes were employed to examine the transformation of microstructure and phase in reduced sample and the mechanism was revealed. Results showed that elements enriched during reduction. Iron existed in the metal iron phase and most of oxygen formed compound with manganese. Consequently a clear distinguish between iron phase and manganese minerals formed, which was beneficial to the separation of iron and manganese. But the iron phase can not be monomer dissociation in grinding process and manganese compounds turned into magnetic product as package and mechanic inclusion due to the isomorphism of iron and manganese and the small particle size. And MnO could be found partially in iron phase, which hindered the further separation of manganese and iron.IntroductionManganese is widely used in industry. The amount of manganese used in steel industry is very huge and 90% manganese is used in steel industry. Manganese ore resources are rich in China, yet with fewer rich ore but more low-grade ore which accounts for 93.6% and fine refractory ore. The constitution of the ore is very complex and more than 73% of all the manganese ore contains iron[l,2]. With the increasing of consumption of steel, the demand for manganese is becoming larger and larger and the imported ore accounts for more than 50%. Therefore, how to use the manganese ore efficiently has very significant meaning. The main method is manganese residual, which is simple and stable. However, the development of the method is limited by the quality of manganese ore, the huge amount of manganese residual, the technology of blast furnace process and economics[3,4]. Chemical benefication which may pollute environment and is difficult to recover iron is still being researched[5,6]. The paper investigated the process in which anthracite coal was the reducing agent for coal-based direct reduction and magnetic separation of the ore, and SEM with EDS measurements were employed to examine the transformation of phase in reduced sample and the mechanism was revealed[7,8]."

Jan 1, 2013

By Zhang Duomo

A novel homogenous precipitation method, including microwave heating, solution conductivity controlling and freeze drying, was developed for the preparation of US nanoparticles. The effects of the precipitation conditions on the structure and morphology of CdS particles were discussed individually. It was found that under the experimental conditions the particle sizes were controllable in the range of 14nm to 100nm. Blend-type CdS was obtained from nitrate or sulphate solution and the more stable wurtzite-type US was obtained from chloride solution, which was ascribed to the coordination of C1 and Cd2+ altering the supersaturation of the solution as well as the different growth units and their connecting patterns, In the precipitation process the surface of US nanoparticles were surface modified with CH3CHSCOOH. The results demonstrate that the bifunctional thiols of thioglycolic acid modified the surface through Cd-S coordination bonding and the induced counter ion AOT-SO3 as the balance charge further increased the stability and dispersity of US nanoparticles. This surface-modified US nanoparticles had been used to prepare nonlinear optics and self-assemble catalysts.

Jan 1, 2003

By V. Reiter, K. Reinharter, C. Wenzl, D. Gregurek, A. Spanring

The refractory linings in lead furnaces are exposed to several stresses rather complex in their interaction. In the present study the magnesia-chromite brick out of a lead recycling furnace suffered from a high chemical attack by the process slag. The high CaO, BaO and sulfur bearing silicate slag, as well as a high NaO2 supply from soda resulted both in a deep-reaching infiltration of the brick microstructure and a severe corrosion of the brick components. Both the sintered magnesia and chromite were attacked chemically. The FactSage calculations showed the formation of high amounts of liquid phase in the infiltrated microstructure. Further phenomena affecting the refractory performance such as iron oxide attack, redox effects, and boron attack are also discussed in the paper. The obtained information and insights serve as a basis for improving refractory materials (i.e., choice of refractories for individual process and new developments) and consequently furnace operations.

Mar 1, 2017

By Tianzu Yang, Weifeng Liu, Lin Chen, Deyu Wang

"Due to the gradual exhaustion of easily extractive gold ores, it is vital to make efficient use of refractory gold ores which hold 30% gold storage of the world. However, the disadvantage of current processing technologies for refractory gold ores consists of severe pollution, low gold extraction ratio, high investment, etc, thus great research interests were attracted during recent years. This article provides an overview of the distribution and categories of the refractory gold ores in the world. The state of art in processing refractory gold ores by pyrometallurgy, hydrometallurgy and biometallurgy techniques and their industrial applications are highlighted. Potential environmental conservative techniques for efficient gold extraction are also reviewed.IntroductionResources of Refractory Gold OresAs easily extractive gold ores are going to be exhausted with the large scale mining nowadays, refractory gold ores are becoming more and more important. Gold in the refractory gold ore cannot be fully extracted using conventional method (cyanidation) even with fine grinding. The amount of gold in the refractory gold ores is about 1500~2000t in China, which occupies 30~40% of the total gold storage [1]. Therefore, it is vital to make efficient use of refractory gold ores."

Jan 1, 2013

By Shigehito Deki

"A new wet process has been developed for the synthesis of various kinds of oxide thin films on various kinds of substrates, even which have complex surface morphology, from aqueous solution. The process was named as the LPD, Liquid Phase Deposition, method, which has some advantages over the conventional dry processes. This process can be applied to an on-site synthesis of advanced materials in the thin film technology. In this paper, some current topics on the synthesis of the composite thin oxide films by the LPD method, are presented.IntroductionGenerally, metal oxide thin films have been made by different preparative processes such as r.f. sputtering, chemical vapor depositon, CVD, laser ablation and sol-gel method, etc [1-3]. Each method has it own advantages and disadvantage. In some cases, the process is not suitable for the preparation of thin film on substrate with large surface area or complex surface morphology, and makes the deposition apparatus complicated and expenisve. By using Liquid Phase Deposition, LPD, method which overcomes some of those problems, metal oxide or hydroxide thin film can be formed on the substrate with large surface area and complex surface morphology, which are immersed into the aqueous solution only at ambient temperature and under atmosphere without any special equipments and high energy. And also, multicomponent oxide thin films can be formed readily by mixing solutions containing the objective metal ions, because it is performed in the aqueous solution which is typically a homogeneous mixing system. This process utilizes ligand-exchange, hydrolysis, equlibrium reaction of metal-fluoro complex species, MF x (x-2n>-, and F consumptive reaction. In the aqueous solution, MFx<x-2n>-is hydrolyzed with water to release F ions by a ligand exchange equilibrium reaction as following;"

Jan 1, 2000

By M. M. Kim

As-electrogalvanized coatings of pure Zn, Zn-11% Fe, and Zn-18% Fe coatings were characterized in terms of initial crystal structure and surface morphology. Samples were then subjected to heat treatments simulating the paint bake cycle of automobile manufacturers. Surface morphology changes were correlated with the process variables, and crystallo.graphic changes were interpreted by mapping heat treatment routes on the Fe-Zn phase diagram. The morphology of pure zinc electrogalvanized coatings with heat treatment from platelets to smeared platelets. The zn-11% Fe coating changes with heat treatment from tetrahedral nodules to a mixture of round and tetrahedral nodules, with the Zn-:18% Fe coating always having round nodules. Regarding crystal structure, a critical transformation time can be defined at any selected temperature, below which the crystal structure does not change. This temperature is related to iron content.

Jan 1, 1990

By Rina Kim

The addition of lead to a gold leaching reactor can effectively accelerate or retard the gold cyanidation reaction. This study explored the effect of lead on the gold dissolution kinetics using cyclic voltammetry (CV) experiments. It was illustrated that the gold leaching kinetics in the cyanide solution enhanced with the addition of lead salt in the low overpotential region (–0.35 V vs. Ag/AgCl). The similar behavior was observed in the presence of ore containing 0.25% galena. In contrast, the gold oxidation kinetics retarded at –0.35 V (vs. Ag/AgCl) in the presence of silicate and lead-bearing mineral under certain conditions. Likewise, the lead addition was not functional for the high sulfur ore. This was attributed to the oxidation of the sulfides to the elemental sulfur, which subsequently formed a passivating layer on the gold surface. The results were evidently affirmed by the electrochemical tests and X-ray photoelectron spectroscopy (XPS) analysis.

By Mohamed Y. Bakr, Aly M. Abdel-Rehim

The present work is related with mechanical activation of processing of Egyptian wolframite by simultaneous ball-milling and pressure alkaline leaching, to improve the recovery of tungsten from wolframite. The results show a total recovery of tungsten from wolframite (97.8- 98.7%) by simultaneous ball–milling and alkaline leaching at temperature 175-200oC. It is concluded that processing of wolframite by simultaneous ball- milling and leaching is mechanically activated and accelerated as a result of the grinding action of steel balls that caused the immediate rupture by continuous removing the product layer of the reaction ( sodium tungstate and iron and manganese hydroxides ) from reacting particle surfaces. This leads to the exposing of fresh and activated wolframite particle surfaces to alkaline leach solution and consequently the acceleration of the reaction of wolframite leaching .The results of the kinetic study 0f alkaline processing of wolframite and its mechanical activation show that the system is under kinetic control.

Jan 1, 2015

By R. Hamar, G. Lamanthe

"To realize complex shaped pieces, like turbine blades, superalloys are cast with the lost-wax process. The end properties of these parts depend upon their microstructure as well as upon the occurence of casting defects such as micropores and hot tears. Such features are governed by the local solidification conditions which may be describe by the calculation of thermal transfers between alloy and mould. It needs the evaluation of numerous parameters which are fitted from experimental measurements in real castings. In further simulations, any parameter may be changed, in order to determine its influence. Such a single modification is quite impossible to realize in real castings, which shows that numerical modeling is a very good way to study casting processes.This modeling technique of casting is applied here to the real study of a typical low pressure turbine blade of a civil engine.IntroductionAircraft engine manufacturers use superalloys to produce turbine blades. They have to obtain a given microstructure and to avoid solidification defects to give good mechanical properties to theirs castings. For example, microporosity is induced by a large shrinkage that cannot be completely fed with the remaining liquid alloy .The optimization of casting processes needs a good Knowledge of the solidification process, that must be controlled at every place in the casting, and at every time of its freezing. Material and heat transfers that occur during the solidification, can be estimated from rather complex calculations. To model these physical phenomena, the evaluation of many parameters must be made. In this aim, some casting experiments are fitted with numerous thermal captors. The identification of experimental and computed thermograms let us estimate these parameters.A long-range scientific cooperation between SNECMA and INPG has enabled the realization of such studies on this topic. From all of them, this paper describes an experimental and computed investigation which has been led on a typical low pressure turbine blade of a civil engine."

Jan 1, 1986

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Furnace refractories are in most cases chemically incompatible with smelter slag, which leads to a steady erosion in their thickness over time. Once too thin, refractory walls become mechanically unstable and catastrophic failure can result. Historically, external shell cooling was applied to generate a freeze lining of slag and thus prevent refractory erosion. Many modern high intensity smelting furnaces instead maintain their physical integrity by the use of internally cooled wall panels, plates or finger coolers. An initial refractory lining is often installed inside of the coolers, such that the furnace originally operates with a temperature (insulated) rather than a heat flux (freeze lined) boundary condition. This paper examines the change in slag-wall heat transfer coefficient and slag superheat as a function of process intensity. The implications of the changes in heat transfer on residual brick thickness are explored using analytical modelling.

Jan 1, 2016

By F. Tailoka

Microporous membranes have been used to create a very fine dispersion of bubbles which greatly enhances the mass transfer of electroactive species to the electrode. Using this system, it has been shown that it is possible to electrowin copper as a coherent planar deposit, at high current densities, from copper chloride solutions.

Jan 1, 1990

By Kotaro Ogura

"Ethylene has been produced in aqueous solution from CO2 by the electrochemical reduction driven by a natural energy. This process is useful for storing a large amount of the natural energy. In the closed system, the conversion efficiency of CO2 is almost 100%, and the maximum selectivity for the formation of ethylene is more than 70%. On the other hand, the current efficiency for the competitive reduction of water is less than 10%. The electrolysis is practicable under such special conditions as three-phase interface consisting of gas, solution and metal, concentrated solution of potassium halide, low pH and copper or copper halide-confined metal electrode. These requirements are thoroughly examined, and the grounds to reply upon are revealed. A series of chemical apparatuses including an electrolytic cell in a large scale are designed for the ethylene production, which allow us continuously to supply raw CO2 and to extract the product.IntroductionIn connection with the depletion of the petroleum reserve, much attention has been paid to the utilization of natural energies such as sunlight, wind force and waves. However, these energies are always changeable, and some means of storing them are necessary for the common use. In general, natural energies are transformed to the electric energy at the time of utilization, but the electricity is not very storable. This is one of the reasons why the application of natural energy is not so expanded. On the other hand, the storing of natural energy by plants is very skilful. In the photosynthesis, solar energy is transformed to chemical energy by fixing carbon dioxide."

Jan 1, 2009

By N. B. Gray, A. E. Guerra, D. E. Morton

"The formation of splash in pyrometallurgical operations that involve the injection of gases into a liquid has been the subject of a number of studies over the last few decades. Given the complexity of the phenomena, there have been some advances in understanding the microscale formation of splash but the ability to accurately predict the amount and character of the splash formed is still in its infancy. First, the macroscale mechanisms for splash formation is very varied. Second, the timescales for splash formation are very small, usually less than 100 milliseconds, making experiments elucidating the formation of splash difficult and costly. Work at the GKW CRC has shown that the microscale mechanism of splash formation is primarily is due to the Kelvin-Helmholtz instability. Substantial progress has been made in understanding the behaviour of large bubbles in effecting splash formation and a simple model has been developed to estimate the behaviour of splash formed from a top submerged lance. Direct numerical computation of splash formation using the GKMAC codes developed at the Centre has been successful in simulating the impact of liquid drops onto a liquid bath.IntroductionInjection of gases into melts is used in the metallurgical industry to promote mixing to ensure acceptable heat and mass transfer rates, conveying solids for alloying, provide efficient contact for gas-melt reactions, and as a reactant. High gas injection rates bring about the formation of splash and slop. Extensive splash formation leads to loss of valuable product, creation of safety hazards, formation of accretion on refractory lining and exhaust ducts, and increased load on dust removal equipment. Many operators and researchers have claimed that splash formation is the limiting factor in many gas injected processes. The problems listed above lead to loss of production and increased maintenance, adding to the cost of processing base metals. Over the last five years, the GKW CRC has been studying the formation of splash from a number of sources. They include the impingment of drops on liquids[ l·2.31, slopping of bath liquidI4.51, breakup of gas bubbles at the liquid-gas interfacel61, shearing of liquids by gases[7·81, and impact of packets of fluids on solidsl81. Theoretically, the extreme deformation of fluid shape and the influence of surface tension makes the simulation of flow resulting from only a drop impacting on a liquid surface a very challenging computational fluid dynamics problem. Recently, we have been successful in simulating the formation of the Rayleigh jet resulting from a drop impact showing the effect of drop Froude number on the shape of the Rayleigh jet."

Jan 1, 1996

By H. H. Kellogg

The thermochemical properties of molten solutions in the binaries Cu-Bi, Cu-Sb and Bi-Sb, as well as the ternary Cu-Bi-Sb, have been correlated and described in mathematical form by use of the associated species concept combined with the three-suffix Margules equations to account for the non-idea 1 behavior of the solution species. Agreement of the correlations with experimental data is excellent (relative deviation of less than 2.5% in the values of the activity coefficients) in most cases. The correlations are applicable over the entire composition range of each system, and in the temperature range 700°-1250°C.

Jan 1, 1985

The viscosity of high magnesium content FeO-Fe3O4-SiO2-CaO-MgO slags at nickel flash smelting conditions was investigated using a commercial rotational viscometer. The studied parameters were compositions of slag and temperature. The viscosity of these slags was measured as a function of CaO, MgO, SiO2, FeO. Fe3O4 and Fe/SiO2 in temperature range from 1473K to 1723K. These slags contained 5.81 to 10.59 pct MgO, 0 to 10.37 pct CaO, 28.21 to 36.21 pct SiO2, 39.40 to 55.42 pct Fe and 1.1 to 1.5 Fe/SiO2.

Jan 1, 1999

By Guojun Qi

This work relates to wafer bumping technologies for flip chip packaging applications in the electronics industry. Nickel and its alloys are alternative under bump metallization (UBM) materials because of their slower reaction rates with Sn-based solder as compared to Cu-based UBMs. In this study, we compared the morphologies of the intermetallic compounds (IMC) formed between Sn-bearing solders (Sn3.5Ag and eutectic Sn-Pb) and two types of nickel- based UBMs, electroless Ni-P (EN) and sputtered nickel. Both chunky-type and needle-type of intermetallics were observed between the EN UBM and the solders. In the case of sputtered Ni UBM, there is only a layer of scallop-type intermetallics formed. The morphology change and growth kinetics of the IMC in thermal aging process were analysed. Kirkendall voids were noticed from samples of Sn3.5Ag solder vs Ni-P UBM that have undergone prolonged thermal aging at high temperature.

Jan 1, 2003

By Guojun Qi

This work relates to wafer bumping technologies for flip chip packaging applications in the electronics industry. Nickel and its alloys are alternative under bump metallization (UBM) materials because of their slower reaction rates with Sn-based solder as compared to Cu-based UBMs. In this study, we compared the morphologies of the intermetallic compounds (IMC) formed between Sn-bearing solders (Sn3.5Ag and eutectie Sn-Pb) and two types of nickel- based UBMs, electro less Ni-P (EN) and sputtered nickel. Both chunky-type and needle-type of intermetallics were observed between the EN UBM and the solders. In the case &apos;of sputtered Ni UBM, there is only a layer of scallop-type intermetallics formed, The morphology change and growth kinetics of the IMC in thermal aging process were analysed. Kirkendall voids were noticed from samples ofSn3.5Ag solder vs Ni-P UBM that have undergone prolonged thermal aging at high temperature.

Jan 1, 2003