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By P. K. Gbor

Over 2 million tonnes of smelter slags containing Co, Ni and Cu are produced and stockpiled in Canada each year. Smelters also produce SO2 an air pollutant. Recycling these materials will maximize the value of natural resources and minimize possible environmental impacts of industrial operations. The objectives of this research were to understand the characteristics of slag, the reaction of slag with SO2(aq) and to develop a novel method for extracting Co, Ni and Cu from slag using SO2. The properties of slags from different smelters were studied, with emphases on the form of Co, Ni, Cu and Fe. Leaching experiments were carried out in a batch reactor. The parameters investigated included concentration of SO2(aq), stirring speed, particle size, temperature and pH. O2 was introduced into the reactor to study its effect on the system. The amount of each of Co, Ni and Cu in all the slags was less than 1%, while Fe was between 30% and 45%. The form of Co and Fe was primarily oxide, however, significant portions of Ni and Cu were present as sulphides. SO2(aq) alone, was effective in leaching Co and Fe. Cu dissolution was negligible due to precipitation. The presence of O2 improved Cu and Ni extraction. SO2(aq) was found to be more effective in leaching slag than H2SO4 at the same pH. The leaching process was modelled using the shrinking core model. A scheme was proposed for the extraction of Co, Ni and Cu from slag using SO2(aq). The process makes efficient use of SO2, separates Co and Cu at an early stage, and minimizes the consumption of base during Fe separation.

Jan 1, 2003

By J. F. Archibald

It is often alleged by mine ventilation engineers that no reliable method exists to forecast the levels of radiation to be encountered in future uranium mines. It results that the design of uranium mine ventilation systems is based on factors other than radiological hazards, such as radon and radon daughter concentrations, for which permissible limits are set. Ventilation has been used to date as the main control mechanism for radon and radon daughters. Although it has become increasingly difficult to provide enough ventilating air to reduce the radon gas and its daughter products to safe levels in some mining arrangements, it is not the object of this paper to discuss alternatives to ventilation. This paper will describe a methodology followed by the authors over the years to estimate the levels of radiation to be encountered in underground and open pit uranium mines. Ventilating air is used to maintain working level concentrations within safe limits. The sources of radon and radon daughters and the quantities of each which will be produced, will be of great value in planning and designing a ventilation system to control them. This information can afterwards be integrated into the overall mine design. The methodology to be outlined can also be used to estimate, given a mine design format, the radiation levels to be encountered. If levels are not acceptable, modifications in the mine design can be made at an early stage. The emphasis is placed on an integrated effort where the ventilation engineers and the mine design engineers work in close collaboration from the very start of the mining project. Estimation of radon and radon daughter levels can be initiated as soon as core samples are obtained from the exploration programmes.

Jan 1, 1980

By Zeynep Aktuna

In this study, the formation of zeolites around Kizkapan and Karlikoy villages (Sothwest Kesan) were investigated. In this region, stratigrafically, Upper Eocene Kesan Formation, i.e. sandstone and rarely shale are observed at the bottom. Early Middle-Oligocene Yenimuhacir Formation is composed of sandstone, marl and tuffs. The zeolitisation is determined in the dasitic tuffs of the Yenimuhacir Formation. In this tuffs' zone, alteration had primarily resulted in zeolites, mainly mordenite, heulandite-clinoptiIolite. Silicification and alteration to clay minerals are also common. The Miocene-Pliocene Ergene Formation and alluvium deposits are the top units in the area. In the studied area, zeolite occurences have economic importance. The results show that successively rapid and short term periods are responsible for the clinoptilolite-heuylandite formations. The homogene chemistry of the solutions may be evaluated for a possible successive zeolitisation period. Multi-periodic vocanic activity and also circulation of thermal water had resulted in a continous dissolution of volcanic glass; moreover, resulted in the formation of suitable conditions of zeolite formation. The mineral crystallization sequences and alteration products as zeolites within the wall-rock, circulated solution reaction depends on a serie of parameters such as chemical composition of both initial materials and volcanic solutions during rock¬solution interaction period. The previous researches and the chemical studies support our results and observations in the studied area. The aim of this study is to investigate the presence of zeolitisation and to explain the formation steps of zeolitisation in Kesan Area by considering the content and distribution of major and minor elements determined in zeolite bearing tuffs. The chemical structures of both zeolite bearing volcanics and zeolite minerals are compared to the results of previous studies. Two dimentional behaviours of major and minor elements were discussed in order to caracterize zeolitisation development and to postulate a probable formation type of zeolitic alteration.

Jan 1, 2005

By Harry Sutcliffe

The paper discusses the nature of mixed face tunneling and suggests courses of action in planning, exploration, design and contract conditions to minimize problems inherent in this type of excavation.

Jan 1, 1981

By J. L. Marchese

Belt conveyors face their applications life with a promise of constant abuse: heavy and rough products cascade onto the belting without let-up; caustic and abrasive materials such as salt and ore eat away at the cover; high temperatures, even open flame at times, sear and soften belting materials; and unyielding tension stretches and strains every belting component. The only defense against the applications onslaught is to follow the basic rules of proper handling, installation, and maintenance. Under the direction of qualified personnel (one responsible person, if possible), you can insure that conveyor belting begins operation in top condition.

Jan 6, 1980

By S. Behl

A major limitation in developing successful selective, flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper, a correlation between selectivity of flocculant adsorption and separation efficiency is outlined, and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1994

By Daniel P. Farjeat, Hector A. Canseco, Juan M. Schmitter

Since the early sixties, tunneling in the soft clay of Mexico City, has been done with the aid of open face shields and recently with compressed air. The use of pressurized shafts up to 1.5 kilograms per square centimeter, (147 kilo pascals) with vertical locks to launch the shields, have been used in two cases. After advancing almost 200 meters of tunnel, the same vertical locks were transformed into horizontal locks, to continue the work. Due to the high decompression times involved, it was necessary to install long locks, using the tunnel itself as part of the system. This article describes those cases.

Jan 1, 1981

By L. Mao, R. Yoon

The thin film balance (TFB) technique was used to measure the equilibrium thicknesses of the water films formed between two oil phases. The measurements were conducted with dodecane at varying concentrations of dodecylammonium chloride, pH, and electrolyte concentration. The data obtained in the present work were used to calculate the surface forces acting between the two oil phases. The calculation was carried using the Extended-DLVO theory with the surface potentials calculated from the Gibbs adsorption isotherm. The results show that oil droplets suspended in water are hydrophobic and the hydrophobicity changes with surfactant and electrolyte concentrations.

Jan 1, 2004

By P. J. Stewart, S. Tracy

This presentation describes the operation and features of the WCC Carbon Reactivation Kiln. Particular emphasis is placed on minimizing carbon losses, corrosion resistance, fuel efficiency and the fate of mercury during reactivation in the multiple-tube vertical retort. Detailed laboratory work indicates that there is complete vaporization of mercury in the kiln, no refluxing in the upper sections and distinct advantages in using this type of kiln when sizing collection equipment.

Jan 1, 1993

By Muammer Kaya, Derya Oz

The main objective of this study was to remove printing ink from waste newspaper and improve the de-inked paper brightness as close as the unprinted paper by bleaching agents. This paper summarizes results of laboratory investigation into the de-inkability of newsprint printed with offset printing. Different chemicals and process parameters were varied to assess the effect on the brightness and cleanliness. The operations involved in de-inking process are briefly described and some of the problems being encountered are discussed.

Jan 1, 1995

By Arol, A. I., I. Iwasaki

The presence of calcium ion in iron ore pulps causes heterocoagulation of rnontmorillonite on hematite leading to indiscriminate dispersion. Two methods were investigated to control the adverse effect of montmorillonite: a chemical method using such complexing agents as EDTA and sodium tripoly- phosphate, and a mechanical method involving ultra- sonic treatment. Their roles in controlling the adverse effect were investigated by zeta potential measurements, starch adsorption tests, and flocculation and selective flocculation tests.

Jan 1, 1988

By Janine L. Beazley, James H. Kyle

The effects of pH, pH modifier (lime or caustic soda) and cyanide on the pulp rheology of a number of ore types ranging from highly siliceous to highly kaolinitic has been investigated. All experiments were performed in fresh water at solids concentrations of 25 and 45% solids and in the pH range 6 to 11. The kaolinitic ores exhibited greater changes in rheology with pH and calcium ion concentration than did the siliceous ores.

Jan 1, 1989

By Walter Shukin, Mark T. Olsen

An enormous quantity of tailings to be ultimately stored, unfavorable topography, severe climatic conditions, and an environmentally offensive red effluent all contributed to the challenge of designing an effective and cost efficient tailings confinement program at the open-pit iron ore mine operated by Quebec Cartier Mining Co. at Mount Wright in northeastern Quebec. The mine has been operating since 1976, but a detailed disposal plan was first initiated with construction of some channels and ditches during 1980. In the coming years, a system of dams, channels, and tailings confinement dikes will be constructed to accommodate tailings produced in the next 25 years. Careful consideration has been given to environmental effects, and the works under construction have been sized and situated to be extended as required to an ultimate mine life of 87 years.

Jan 8, 1981

By P. J. Bethell

This paper reviews current fine coal cleaning circuitry, including water washing cyclones, tabling and froth flotation. It goes on to examine possible future beneficiation based on emerging technologies. Circuits considered include those incorporating spirals, fine heavy medium cycloning, hydrosizers and column flotation.

Jan 1, 1988

By Jindrich Fiala, Jirí Kout

The paper contains knowledge that have been achieved when the problem of airflow temperature and humidity changes prediction in mine airways was investigated. The substance of physical processes has been consistently applied. The methods of dry-bulb and wet-bulb temperatures calculations can be applied in any type of mine airway. The exceptionality of auxiliary ventilated airways is in the original solution of so called losing air flowing when a ventilation pipe is leaky. The combination of aerodynamics and thermodynamics solutions enable to determine climatic conditions on projected workplaces with a sufficient accuracy.

Jan 1, 1991

By Tor L. Brekke, Alberto Marulanda P.

The paper describes hazardous water inflows during construction that have taken place over the last three years in tunnels in Colombia. The projects involved are the Chivor II Hydroelectric Power Project (penstock tunnel), and the Chingaza Water Project (two tunnels). In all cases, loss of face control led to significant loss of ground; in one case some 70,000 m3 of slide material was involved, much of which came out through the portal situated 1.6 km from the face. Emphasis is given to: (a) the geologic setting, (b) the remedial measures taken, and (c) the main efforts that can be made to prevent hazardous conditions from developing.

Jan 1, 1981

By P. F. R. Altounyan, I. W. Farmer

Groundwater freezing was used to stabilise 8m thick beds of saturated and weakly cemented sands at a depth of 170m, during driving of twin 1 in 4,5.2m o.d. circular drifts from the surface to the Coal Measures through 600m of Permo-Triassic strata. Instrumentation was installed during erection of the lining in frozen and unfrozen ground to measure ground and groundwater pressures on the lining and ground temperatures up to lm into the frozen ground. Observations showed that following thawing, effective lining stresses in the frozen zone were low, indicating minimum strata disturbance during freezing and subsequent machine excavation. Groundwater pressures were lower than expected.

Jan 1, 1981

By Ahmed I. A. Salama

The problem of estimating separation characteristics by utilizing mass distributions of feed and products is considered. The separation characteristics include mass yield and partition curve. The cases of mass balance and partition functions balance are identified. The developed techniques can handle the cases of two- and three-product separation. Actual data are utilized to demonstrate the proposed techniques.

Jan 1, 1992

By J. W. Wilson, Y. Ding

In the ultrafine coal-cleaning process, small coal particles (-400 mesh) are produced during the pulverizing operation. After the coal-cleaning process, these ultrafine particles are very difficult to dewater and create problems in coal transportation, storage and handling at utility plants. Research on ultrafine coal dewatering and briquetting resulted in the development of a single-stage operation that is potentially more effective and economical than conventional thermal drying and briquetting processes. The final coal product has a moisture content of less than 15% and possesses high strength and water resistance that satisfies coal transportation, storage and handling requirements.

Jan 1, 1996

By Scott D. Kinsala, Patrick T. Flynn, Andrew T. Rosol

During calcination of diatomaceous earth, cristobalite is formed in varying percentages. Also, during efforts to recycle products containing natural diatomaceous earth, various heat treatments are used which may or may not result in the formation of cristobalite. The ILO (International Labor Organization) Encyclopaedia of Occupational Health and Safety states that conversion begins at 450'C and in the presence of a flux, is complete at 800'C. Due to the potential adverse health effects associated with crystalline silica, a more thorough understanding of the time/ temperature relationship is needed. Tests performed under controlled conditions do not substantiate the claims made in the ILO Encyclopaedia.

Jan 1, 1991