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By Roy Norcross, Stephen Gos

For over 100 years Degussa has worked together with the min­ing industry not only providing quality products but also develop­ing technologies to support these products through value added goods and services. For cyanide, these technologies include leach enhancement processes such as PAL™ and Solidox™, and cyanide detoxification with peroxygen based processes such as SILOX™ and Caro's acid using our DegOX™ technology. Degussa has also made important advances in how sodium cyanide is packaged and shipped with our liquid NaCN plant joint venture with MSI, CYANCO in Winnemucca, Nevada, and our Advantage SLS™ solid to liquid cyanide delivery system. All of these innovative technologies developed to support NaCN in mining, provide value to our customers and show Degussa's commitment to Responsible Care·11.1 and dedication to product stewardship. With Responsible Care and the customer in mind, Degussa has developed Advantage CCS™ cyanide control system, which will soon be available for the North American market. Currently there are several CCS units in service installed by Degussa AG (Germany), and we are in the process of designing the next gen­eration of the CCS which should be completed by late '98. Based on our experience working with gold and silver mines all over the world, there appeared to be an opportunity to further assist our customers by providing a better more automated way to control their cyanide additions. By providing the mine with an accurate method for maintaining their desired cyanide levels in their leach circuits, we could help them avoid underdosing and the associated gold and silver losses, and overdosing the cyanide which not only wastes cyanide but may increase treatment costs as well. In the early 1990's, when we began to introduce our CCS units, there were several cyanide controllers and on-line analyzers avail­able. However, they appeared to be too complicated and not made to stand the harsh conditions inside a mill. This resulted in exces­sive downtime and poor analytical results. We also found that many units would be installed but not commissioned by the sup­plier. Based on these observations, along with filtration and con­trol problems on some existing units, Degussa decided to design its own cyanide control system based on our extensive knowledge of cyanide chemistry, using the best components available worldwide.

Jan 1, 1998

By S. A. Hoenig

Introduction In an earlier publication, the application of exoelectron technology to the monitoring of dry grinding in a ball mill was reported. Recently, the author has investigated the ball mill problem in more detail with the system shown in Fig.1 . Here, some of the current generated in the ore-ball-water mixture was picked up by the metal chains and served as a measure of the rate of grinding. While the mechanism of current generation has not been completely clarified, a parallel study of electrical effects associated with rock drilling indicated that the major driving force is the zeta potential*, while oxidation of the freshly fractured material provides the remainder of the current. Both of these effects are sensitive to the exposed surface area, and it might be expected that the observed currents would provide a measure of the grinding rate. This "surface area" effect allows the measurement system to be used in any type of rock or ore grinding. Some studies with sulfide copper ore indicate higher currents than those observed with silica sand, but the overall pattern of current versus grinding rate is essentially the same. Experimental Studies The experimental system was set up as shown in Fig. 1. The initial studies were done with silica sand because of its availability and for comparison with the data of reference 1. The sand was sized to an average of 425 µm (40 mesh); a typical charge consisted of 2.5 kg (5.5 lb) of sand, 0.85 L (0.22 gal) of tap water and 2.5 kg (5.5 lb) of iron grinding balls 25.5 mm (1 in.) in diameter. For a typical "run," the mill was loaded with a fresh charge of ore and operated for periods ranging from 10-60 min. During this time, the current was measured with a Keithley 417 picoammeter and a chart recorder. At the end of the grinding period, the charge was removed and sieved to recover the 425, 300, and 212 pm (40, 50, and 70 mesh) fractions which were then drained and weighed. A fresh charge was used for each test and every attempt was made to keep the draining and weighing processes uniform. *The zeta potential is the voltage developed between the surface of a solid particle and the ion solution in which it is immersed. In the case of rock/ore materials in water, the zeta potential is negative.

Jan 1, 1984

By J. M. Mutmansky

Introduction Since the Hardy Cross numerical algorithm was applied to the solution of mine ventilation networks, numerous developments have taken place in ventilation network analysis procedures. The Newton-Raphson method, the linear theory method and the second-order approximation method are three of the additional approaches that have been applied. The efficiency of a ventilation network analysis procedure depends not only on the method of solving the system of equations derived from ventilation networks but also on the method of deriving the equations through selection of the meshes. This paper investigates the impacts of three mesh selection methods on the efficiencies of four ventilation network procedures. The minimum-resistance spanning tree method is the most popular procedure for selecting meshes. The shortest-path method was suggested by Epp and Fowler (1970) for improvement of the Newton-Raphson method. The minimum-resistance-path method is suggested here as the third method of selecting meshes. The effects of these three methods on the Hardy Cross method, the Newton-Raphson method, the linear theory method and the second-order approximation method are analyzed in this paper. These network analysis methods have been summarized in the paper by Kim and Mutmansky (1991). Mesh selection methods A procedure for mine ventilation network solution based on mesh equations typically consists of two steps: • the mesh selection step and • the network solution step. The mesh selection step establishes a set of independent equations to solve the network. The resulting equations are nonlinear. One method of solving nonlinear equations is to linearize the equations and iteratively solve these linear equations. The four analysis methods previously discussed in this paper use this approach. The linear equations required for solution can be written in matrix form as: P•dQ = dF (1) where P is the pseudo-resistance matrix, Q is the quantity matrix, and F is the Jacobian matrix (Kim and Mutmansky, 1991). The efficiency of the solution method depends on the characteristics of the P matrix, which in turn depend on the method of selecting meshes. To understand the impacts of the mesh selection methods on the efficiency of the ventilation network analysis procedures, the characteristics of the P matrix must be understood first. The diagonal elements of the P matrix, m in number, are the sums of the pseudo-resistances of the branches contained in the m meshes necessary for solution. The off-diagonal elements are the sums of the pseudo-resistances of the branches shared by two meshes. For example, P12 (first row, second column element of the P matrix) is the sum of the pseudo-resistances of the branches common to mesh 1 and mesh 2. When solving the system of equations expressed in Eq. (1), three of the iterative procedures (the Newton-Raphson, the linear theory and the second-order approximation methods) use the direct factorization method (Burden and Faires, 1985) on the P matrix. When the direct factorization method is used, the computational efficiency is enhanced by larger diagonal elements and a sparser P matrix. Generally, the sparsity of the P matrix is more important than the size of the diagonal elements. There is no known mathematical method of predicting the efficiency of these procedures, but heuristic methods can be used to study the efficiency. The Hardy Cross algorithm applies the Gauss-Seidel method of splitting the P matrix and applies the Newton-Raphson procedure. The efficiency of the Hardy Cross method depends on the spectral radius of the matrix[[D-L]-1U], where D is the diagonal, L is the lower triangle and U is the upper triangle of the P matrix for the Newton-Raphson method (Ortega, 1972). The smaller the value of the spectral radius, the faster the convergence. As with the other three methods, larger diagonal elements and a sparser matrix aid in faster convergence. With the Hardy Cross method, however, the size of the diagonal elements is more important than the sparsity of the matrix. Remembering that each of the diagonal elements of the P matrix is the sum of the pseudo-resistances of the branches in a mesh and that each off-diagonal element is the sum of the pseudo-resistances of the branches shared by two different meshes, the following strategies can be used: • Avoid having branches with larger resistance values shared by multiple meshes. This increases the size of the diagonal elements and reduces the chance of off-diagonal elements being large.

Jan 1, 1993

By Jr. Stokowski

Topsoil for revegetation projects is in demand in many urban areas. In this case history, a large aggregate producer manufactured a topsoil from three waste materials. The topsoil was produced in a 200,000 m2 (50-acre) abandoned gravel pit that still had additional gravel under 10 m (30 ft) of overburden uneconomic to strip directly. The topsoil was produced by rotary mixing of sludge, overburden, and a lime admixture; solar drying; and stripping and stockpiling of the product. A major problem was an increase of topsoil drying times for stripping from 40 to over 100 hours when it was rewet by storms. The problem was solved by a research project that evaluated over 50 formulations and over 20 waste materials. . The final formula dried in 15 hours and contained 3-parts sandy mine spoil, 1-part sewage sludge, and 2 % spent-bed, a granular quick-lime produced during power-plant flue-gas desulfurization.

Jan 1, 1988

By G. M. Riddle

As an important part of the concept validation phase of the MX Advanced ICBM development program, Air Force System Command's Intercontinental Ballistic Missiles (ICBM) Program Office developed and demonstrated large trenching and cast-in-place equipment for placing many miles of buried concrete tunnel rapidly and economically. A tunnel or "buried trench" containing a mobile ICBM is one of the candidate basing models for MX. Upon remote command, the cannister housing the missile would break out of its concrete tunnel and earth overburden by erecting itself to a suitable angle and then launching the missile. The ICBM Program Office developed two each trenchers, cast-in-place machines, and breakout mechanisms, as well as a mobile concrete truck unloader. The machines were demonstrated in varying soil conditions in the southwest US. The breakout mechanisms were demonstrated nearby as well. This chapter describes the development program, the machines, and the demonstrations. No manuscript received

Jan 1, 1979

By Stanley Bunk

The fluidized bed was invented by Fritz Winkler of Germany in 1921. The first application in the U.S. was in the development of the fluidized bed catalytic cracking of petroleum in 1942. Today, fluid bed cracking reactors are an integral part of every oil refinery. When fluid bed technology was first considered for applications outside the petroleum industry it was recognized to have uniform temperature, close control of the gaseous atmosphere and excellent mixing between solids and gases. Roasting of sulfide ores and concentrates was an obvious match. The first application was a single stage roaster for gold refining in 1947. There have been over four hundred commercial fluid bed roasters built and operated successfully in the four decades since the fluid bed was invented. There are three general categories of roasting applications. The largest number of roasters fall into the dead roasting category which includes gold ore roasters. The other categories are sulfating roasters and partial roasters (Reference 1).

Jan 1, 1990

By S. Stewart

The topic of sustainability in the mining and minerals industries focusing on economic development, ecological integrity and responsible stewardship of the environment together with community well being are vital issues for our industries at a crucial time in our history. Many of the priorities of the Greek Presidency of the European Community ? Sharing the Future in a Community of Values ? encourage our industry to continue to innovate and develop many of the environmental and social initiatives already underway. Sustainable development is here to stay and has been placed strategically at the heart of all European public policy. The future of the minerals industry here in Europe as well as elsewhere depends on how well professional mining people, both as individuals and through their associations and others, have to present their case for a sustainable mining and minerals industry to a critical world. And, Greece with its strong and expanding mining, minerals and metals base has more to win or lose from this endeavor than many others.

Jan 1, 2003

By Victor F. Hollister

The Society for Mining, Metallurgy, and Exploration has compiled a number of exploration discovery case histories. This section in Volume 3 of the series describes the case histories of deposits found in layered rocks. Metallic and nonmetallic ore deposits described in this section include diverse minerals such as copper-nickel sulfides and carbonate-controlled base metals. Other case history compilations include epithermal precious metal deposits and porphyry systems. The importance of ores in layered rocks justifies their inclusion in a case history compilation. Mineral deposits occurring in layered rocks form an economically important class of ores. For example, most sulfide nickel ores are mined from basic layered intrusive rocks. Although the geologic setting is completely different from economic nickel sulfide concentrations, most barite produced also comes from stratiform and strata-bound ores. Zinc and lead ores importantly occur in beds in carbonate host rocks. Gold and other heavy minerals are concentrated in placer deposits. Indeed, the world's largest gold deposit, the Witwatersrand, is a fossil placer.

Jan 1, 1991

By K. Brady

Making progress on sustainable development will require greater attention to the management of materials produced from mine exploration through use to reuse, recovery and recycling. Material stewardship is a concept that embodies the range of activities required for optimal and appropriate use of minerals and metals in society. The following paper provides an overview of some recent initiatives that promote the stewardship of minerals and metals in society. The initiatives described are being conducted by organisations ? the International Zinc Association, the Canadian Copper & Brass Development Association and the International Council on Mining & Metals. These associations illustrate stewardship activities at three different levels: - an international association representing companies that produce a range of minerals and metals; - an international commodity association; and - a regional association. For each initiative, information is presented on its development, scope and outlook. This paper draws heavily from work of the associations but the viewpoints are the responsibility of the authors.

Jan 1, 2007

By Rudy Rogers

Gas hydrates have unique properties of storing selective gases. As much as 180 volumes of gas (standard conditions) per volume of hydrates may be stored. Recognizing the need for natural gas storage near electrical power plants for peak load use, DOE funded our laboratory to investigate gas hydrates as an economically viable storage means. Our developed process forms hydrates and self-packs the hydrates by only maintaining the gas pressure above a surfactant/water solution while hydrates form and self-pack. The laboratory process was scaled-up and demonstrated storage of 5300 scf of natural gas in hydrates. Subsequent to the demonstration, we discovered preparation procedures whereby laboratory gas hydrates could be stored at 1-atm with less than 1% decomposition over multiple days. The paper will discuss how these two advancements offer potential ways to recover vent gases as well as released hydrate gases from the seafloor. Keywords: gas hydrates, methane storage, surfactants, hydrate stability

Jan 1, 2008

By R. Lee Wooten, Marco D. Boscardin, James M. Taylor

An earth pressure balance (EPB) tunnel boring machine (TBM) and pipe jacking were used to construct a 430-meter-long segment of sanitary sewer force main. The force main was constructed by first jacking a 2045-mm-outside-diameter, reinforced concrete cylinder pipe (RCCP) casing through alluvial sands and gravels. Later, a 1220-mm-diameter, ductile iron carrier pipe was installed within the casing pipe. The main concern affecting the construction method selection was the elimination of the need for dewatering, which could cause groundwater flow from deeper, contaminated sands up across a silt aquitard into cleaner, shallower sands. In addition, the method selected reduced the volume of soil to be handled and, consequentially, the potential amount of contaminated soil to be managed. Items discussed in the paper include provisions for handling boulders and controlling ground movements as excavation and jacking occurred approximately 300 mm beneath an active,4800 kPa, 254-mm-diameter natural gas transmission pipeline.

Jan 1, 1997

By Brendan Parker, Joseph Skrypniuk

Boddington Gold Mine1 (BGM) commenced production in 1987 and is currently ranked as the second largest gold producer in Australia. In a strategy to improve plant efficiency, constraints to plant performance were identified and prioritised with a view to maximising benefit for minimal expenditure. After identifying that leach kinetics and circuit residence time were major constraints, the introduction of oxygen was identified as having the greatest potential for the delivery of sig­nificant cost benefits. The application of oxygen, initially by conventional tech­niques, and subsequently by installation of Atomaer's Filblast gas shear reactor, improved gold recovery, reduced the resi­dence time constraint and enabled higher mill throughput to be achieved. Additional benefits included operation at lower pulp densities and a reduction in reagent usage. A significant reduc­tion in unit operating cost resulted from these benefits. This paper quantifies the above benefits in a format accept­able to both metallurgists and accountants by integrating the findings in a techno-economic perspective.

Jan 1, 1996

By C. H. Bucknam, S. A. Wilson, G. E. McClelland

The Meteoric Water Mobility Procedure (MWMP) was developed in the State of Nevada during the 1980’s as part of their mine waste characterization programs. During the 1990’s the Waste Subcommittee of the Nevada Mining Association (NvMA) contacted ASTM Subcommittee E01.02 on Ores, Concentrates and Related Metallurgical Materials to undertake a standardization program for the method. A cooperative program was developed in conjunction with the Acid Drainage Technology Metal Mining Sector (ADTI-MMS)Prediction Committee, which involved eight of the NvMA labs performing duplicate leaching tests on two test materials: a coarse fraction of the USGS Hard Rock Mine Waste standard and a typical spoils sample from a heap leach operation undergoing closure in Nevada. Solutions for metals analysis were preserved and sent to the USGS Laboratories in Denver to determine the reproducibility and repeatability of the leaching. The history of the method and reference material and the results of the interlaboratory testing and statistical analyses will be presented.

Jan 1, 2003

I was very interested in Professor Park's data on subsidence over longwall panels. His paragraph labeled "Conclusion," however, does not seem appropriate for the article. Nothing in the article gives any discussion of how knowledge of subsidence characteristics can be used in mine design to minimize damage. That thought may have been a reason for undertaking this study, but not a conclusion of it. From his article, I would conclude that subsidence movements last considerably longer at great depth. And the National Coal Board's subsidence prediction model represents this area reasonably accurately, though most literature claims their model predicts far greater disturbances than actually occur in most areas of the United States. Also, I would like to know, is the method used to determine angle of draw? The criterion used can make a significant difference in the value obtained. With 30 m (100 ft) spacing and a 122-m (400-ft) depth the angle between stations can be up to 14°.

Jan 1, 1989

By P. M. Godinho

The debut of the sustainable development concept in the political arena, and the publication of Our Common Future in 1987, represents the starting point of present concerns and efforts associated with the sustainability of the ecosphere and its ecological and human subsystems. The sustainable production and consumption of natural resources, in particular mineral resources, represents a central aspect of the problem. In this context, an important goal has been to develop sophisticated management systems, which consider sustainability principles, in organizations within the system of minerals and metals (SMM). The development of indicators is only part of this challenge. The extractive industries (EI) as an important stakeholder of the SMM (should) have similar priorities. If embraced, this challenge offers great opportunities, one of them being the potential for advancing the understanding of how these organizations learn and change. The identification of its main determinants offers, in theory, the possibility for their management and a faster achievement of the sustainability levels to which they (should) aspire.

Jan 1, 2007

By A. G. Sciulli, G. P. Ballock, G. Hearnshaw, K. K. Wu

Waste disposal underground is the most effective method when viewed from an environmental aspect. As costs of other methods of disposal continue to escalate, the cost effectiveness of underground disposal during the mining cycle becomes increasingly attractive. The use of concrete for sealing abandoned mines has proved to be suspect when associated with a relatively incompetent adjacent strata due to its shrinkage characteristics. Complete failure of the plug has been known to occur in some instances. A more effective, cost competitive seal can be obtained using pneumatically stowed material and incorporating a polyurethane grout, which has greater adhesion characteristics than concrete. Injection of the surrounding strata and of the stowed material helps to ensure an impervious barrier and prevent the plug from moving when subject to high pressure heads. When properly placed, impervious seals cause the old workings to flood, raise the mine pool level, and thus eventually eliminate the potential for oxidation, which is the primary cause of acidity in the water

Jan 1, 1987

By R. J. Sweigard, T. Beckman, C. T. Justice, E. D. Thompson, T. C. Hopkins

As a means of permanent disposal, fine coal refuse is often pumped as a slurry into surface impoundments. As the available volume is filled, the embankment heights are frequently increased. The additional embankment material is often placed upon consolidated fine coal refuse. There has been concern about the long-term effect of consolidation of this material at or above the liquid limit on its shear strength. A laboratory investigation was performed using three different types of fine coal slurry taken from central Appalachian coal-preparation plants. The refuse was consolidated in 3-m (10 ft) Plexiglas columns under incremental amounts of surcharge loading. The incremental loads were designed to simulate the effect of increasing the height of a refuse embankment on top of the consolidating coal slurry. After the refuse in the columns had consolidated for several months, the columns were cut apart, and triaxial tests were performed on both the consolidated and unconsolidated material for comparison of their shear-strength parameters.

Jan 1, 1998

By J. H. White

It is hypothesized that the Hotelling valuation principle (HVP) can determine the value of developed gold reserves using simple methods and easily obtainable data. This paper reports the results of an empirical test of this hypothesis. The model for the HVP is given by [V R=Cp-0(1) or V - CP-0' R(2)] where p = current spot price of gold per oz, [c] = average extraction cost of gold per oz, V = current market value of the gold in the ground (dollars) and R = gold reserves (oz). Using publicly available data from North American gold companies, we obtained data for V, R, p and c, and we ran a simple linear regression using Eq. (1) as the definition of the dependent and explanatory variables. By examining the value of the coefficients of the resulting regression equation, we can draw conclusions as to whether or not the HVP can be confidently used as an estimator of the value of developed gold reserves.

Jan 1, 1997

By Nick J. Miles, Gareth J. Brown

The degree of fragmentation of dispersed systems of brittle materials such as pulverised rock has been described by a fractal dimension i.e. the fragmentation fractal. This fractal dimension represents a power law size-frequency distribution, where, in this case, the size is defined as the square root of the projected area. The existence of a fractal dimension for the number-size distribution, of the progeny of failure event, is direct evidence for scale invariance of the fragmentation process. Since a fractal dimension infers that failure mechanisms operate on all scales it has been suggested that the fractal dimension is a measure of the fracture resistance properties of materials during fragmentation. In order to investigate this a range of rocks of varying fracture toughness were broken under similar levels of impact velocity in the dynamic tensile failure of single particles. The fragmentation fractals determined from the resultant particle populations, of the breakage experiments, were monitored and are discussed.

Jan 1, 1995

By Michael J. Martinson, John R. Larsen, J. Warren Andrews

Measurements reported in the paper were recorded in an active Green River, Wyoming, trona mine, partly as a teaching exercise and partly to provide the mine in question with additional input data for its ventilation network program. Measurements were made: - in representative three-entry intake airways in room and pillar sub-mains; - between the lower portion of a vertical down-cast hoisting shaft and the start of an intake airway system established in a room and pillar main; - in a representative downcast section of a divided vertical shaft, and of the collar entrance loss at the top of the same compartment. Pressure differences were measured with manometers and trailing hoses, air flowrates with calibrated anemometers, and barometric pressures and wet-and dry-bulb temperatures were recorded for density determinations. Where possible, results are quoted as Atkinson friction factors, and relevant measurements are recorded in some detail to show the magnitude of fluctuations in observed pressure differences.

Jan 1, 1987